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1. 发明授权

US4152163A Silver halide photographic emulsion containing cyanine and hemicyanine sensitizing dyes 失效
标题翻译：含有花青和半花青素敏化染料的卤化银照相乳剂
公开(公告)号：US4152163A
公开(公告)日：1979-05-01
申请号：US777229
申请日：1977-03-14
申请人： Akira Sato , Tadashi Ikeda , Takeo Sakai , Haruo Takei , Jun Hayashi
发明人： Akira Sato , Tadashi Ikeda , Takeo Sakai , Haruo Takei , Jun Hayashi
IPC分类号： G03C1/28 , G03C1/14 , G03C1/19
CPC分类号： G03C1/28
摘要： A spectrally sensitized silver halide photographic emulsion comprising a silver halide emulsion containing a combination of at least one sensitizing dye represented by the following general formula (I): ##STR1## at least one sensitizing dye represented by the following general formula (II): ##STR2## and at least one organic heterocyclic compound represented by the following general formula (III) or (IV): ##STR3## wherein Z.sup.1 and Z.sup.2, which may be the same or different, each represents a group of atoms necessary for forming a thiazole nucleus or a selenazole nucleus; Z.sup.3 has the same meaning as Z.sup.1 and Z.sup.2 ; Z.sup.4 represents a group of atoms necessary for forming an imidazole nucleus or an oxazole nucleus; Z.sup.5 represents a group of atoms necessary for forming an imidazole nucleus; R.sup.1, R.sup.2, R.sup.4, R.sup.5 and R.sup.7, which may be the same or different, each represents an alkyl group, with at least one of R.sup.1, R.sup.2, R.sup.4 and R.sup.5 being an alkyl group substituted with a carboxy group, a hydroxy group or a sulfo group; R.sup.3 and R.sup.6, which may be the same or different, each represents a lower alkyl group, an aryl group or a hydrogen atom; R.sup.8 represents a hydrogen atom or an alkylene group necessary for forming a ring through a combination with R.sup.7 ; R.sup.9 represents an aryl group (including a monocyclic aryl group and a bicyclic aryl group); X.sub.1.sup.-, X.sub.2.sup.- and X.sub.3.sup.- each represents an acid anion; m, n and p each represents 1 or 2, but when m, n or p is 1, the dye forms an intramolecular salt.The photographic emulsion exhibits a high sensitivity with a reduced fog and stain, and a good stability with the lapse of time during and after production, and further an improved latent image stability with the lapse of time of from image-wise exposure to development.
摘要翻译：包含含有由以下通式（I）表示的至少一种敏化染料的组合的卤化银乳剂的光谱增感卤化银照相乳剂：（I）至少一种由以下通式（II）表示的增感染料）（II）和由以下通式（III）或（IV）表示的至少一种有机杂环化合物：其中Z 1和Z 2可以是相同或不同，每个表示形成噻唑核或硒唑核所需的一组原子; Z3与Z1和Z2具有相同的含义; Z4表示形成咪唑核或恶唑核所需的一组原子; Z5表示形成咪唑核所需的一组原子; R 1，R 2，R 4，R 5和R 7可以相同或不同，各自表示烷基，R 1，R 2，R 4和R 5中的至少一个为被羧基，羟基或磺基; R 3和R 6可以相同或不同，各自表示低级烷基，芳基或氢原子; R8表示通过与R 7的组合形成环所需的氢原子或亚烷基; R9表示芳基（包括单环芳基和双环芳基）; X 1，X 2和X 3各自表示酸性阴离子; m，n和p各自表示1或2，但当m，n或p为1时，染料形成分子内盐。

2. 发明授权

US4147553A Supersensitized photographic emulsion 失效
标题翻译：超感光照相乳剂
公开(公告)号：US4147553A
公开(公告)日：1979-04-03
申请号：US875728
申请日：1978-02-07
申请人： Akira Sato , Tadashi Ikeda , Takeo Sakai , Haruo Takei , Jun Hayashi
发明人： Akira Sato , Tadashi Ikeda , Takeo Sakai , Haruo Takei , Jun Hayashi
IPC分类号： C09B23/00 , G03C1/28 , G03C1/08
CPC分类号： G03C1/28
摘要： A silver halide photographic emulsion containing, in supersensitizing amounts, the combination of at least one compound represented by the following general formula (I): ##STR1## wherein Z.sub.1 represents the atoms necessary for forming a benzene ring or a naphthalene ring; W.sub.1 represents a sulfur atom or a selenium atom; Y represents an oxygen atom or a sulfur atom; R.sub.1 represents an alkyl group or an aryl group; and R.sub.2 represents a lower alkyl group having 1 to 6 carbon atoms in the alkyl moiety or an aryl group;At least one carbocyanine dye represented by the following general formula (II): ##STR2## wherein Z.sub.2 represents the atoms necessary for forming a thiazole ring, a selenazole ring, an oxazole ring, an imidazole ring or a pyrroline ring; Z.sub.3 represents the atoms necessary for forming an oxazole ring or an imidazole ring; R.sub.4 and R.sub.5, which may be the same or different, each represents an alkyl group; R.sub.6 represents a hydrogen atom or a lower alkyl group having 1 to 6 carbon atoms in the alkyl moiety; X.sub.a.sup..crclbar. represents an acid anion; and p represents 0 or 1 and, when an inner salt is formed, p represents 0; andAt least one dye represented by the following general formula (III): ##STR3## wherein Z.sub.4 and Z.sub.5, which may be the same or different, each represents the atoms necessary for forming a thiazole ring or a selenazole ring; R.sub.7 and R.sub.8, which may be the same or different, each represents an alkyl group; R.sub.9 represents a hydrogen atom, a lower alkyl group having 1 to 6 carbon atoms in the alkyl moiety or an aryl group; X.sub.b.sup..crclbar. represents an acid anion; and q represents 0 or 1 and, when an inner salt is formed, q represents 0.
摘要翻译：（I）表示的至少一种化合物的组合：（I）其中Z1表示形成苯环或萘环所需的原子的卤化银感光乳剂，其以超敏化剂量含有至少一种化合物的组合。 W1表示硫原子或硒原子; Y表示氧原子或硫原子; R1表示烷基或芳基; 并且R 2表示在烷基部分或芳基中具有1至6个碳原子的低级烷基; （II）表示的至少一种碳青霉烷衍生物：其中Z2表示形成噻唑环所需的原子，硒唑环，恶唑环，咪唑环或吡咯啉环; Z 3表示形成恶唑环或咪唑环所必需的原子; R 4和R 5可以相同或不同，各自表示烷基; R6表示烷基部分中的氢原子或碳原子数1〜6的低级烷基; Xa（ - ）表示酸性阴离子; p表示0或1，当形成内盐时，p表示0; （III）表示的至少一种染色剂：其中Z4和Z5可以相同或不同，分别表示形成噻唑环或硒唑环所需的原子; R 7和R 8可以相同或不同，各自表示烷基; R9表示氢原子，烷基部分或芳基中具有1〜6个碳原子的低级烷基; Xb（ - ）表示酸性阴离子; q表示0或1，当形成内盐时，q表示0。

3. 发明授权

US4307185A Photographic silver halide emulsions 失效
标题翻译：摄影卤化银乳剂
公开(公告)号：US4307185A
公开(公告)日：1981-12-22
申请号：US720291
申请日：1976-09-03
申请人： Masanao Hinata , Haruo Takei , Akira Sato , Atsuo Iwamoto , Jun Hayashi
发明人： Masanao Hinata , Haruo Takei , Akira Sato , Atsuo Iwamoto , Jun Hayashi
IPC分类号： G03C1/28 , G03C1/29 , G03C1/14
CPC分类号： G03C1/29
摘要： A silver halide photographic emulsion spectrally sensitized with a sensitizing combination of at least one sensitizing dye represented by General formula (I), at least one sensitizing dye represented by General formula (II) and at least one sensitizing dye represented by General formula (III): ##STR1## wherein Z.sup.1 and Z.sup.2 each is the atoms necessary to form a benzothiazole nucleus or a benzoselenazole nucleus, R.sup.1 and R.sup.2 each is an alkyl group or a substituted alkyl group, wherein at least one of R.sup.1 and R.sup.2 is a substituted alkyl group having a sulfo group, R.sup.3 is an alkyl group, X.sub.1 is an acid anion and m is 1 or 2 and when the dye forms an intermolecular salt (betaine like structure), m is 1; ##STR2## wherein Z.sup.3 is a sulfur atom or a selenium atom, Z.sup.4 is the atoms necessary to form a benzothiazole nucleus, a benzoselenazole nucleus, a naphtho[1,2-d]thiazole nucleus or a naphtho[1,2-d]selenazole nucleus, R.sup.4 and R.sup.5 each is an alkyl group or a substituted alkyl group, wherein at least one of R.sup.4 and R.sup.5 is a substituted alkyl group having a sulfo group, R.sup.6 is an alkyl group, an aryl group, a furyl group or a thienyl group, X.sub.2 is an acid anion and n is 1 or 2, and n is 1 when the dye forms an intermolecular salt (betaine like structure); wherein Z.sup.5 is the atomic group necessary to complete a naphthothiazole nucleus, Z.sup.6 is the atomic group necessary to complete a benzimidazole nucleus, R.sup.7 and R.sup.8 each is an alkyl group or a substituted alkyl group, where at least one of R.sup.7 and R.sup.8 is a carboxyalkyl group or a substituted alkyl group having a sulfo group, X.sub.3 is an acid anion, and p is 1 or 2, and p is 1 when the dye forms an intermolecular salt.
摘要翻译：用由通式（I）表示的至少一种敏化染料，至少一种由通式（II）表示的增感染料和至少一种由通式（III）表示的增感染料）的敏化组合进行光敏增感的卤化银照相乳剂，（I）其中Z1和Z2各自是形成苯并噻唑核所需的原子或苯并硒唑核，R1和R2各自是烷基或取代的烷基，其中R1和R2中的至少一个是具有磺基的取代烷基，R3是烷基，X1是酸阴离子，m是1或2，当染料形成分子间盐（甜菜碱结构）时，m是1; （II）其中Z3为硫原子或硒原子，Z4为形成苯并噻唑核所需的原子，苯并硒唑核，萘并[1,2-d]噻唑核或萘并[1,2 -d]硒唑核，R4和R5各自为烷基或取代的烷基，其中R4和R5中的至少一个是具有磺基的取代烷基，R6是烷基，芳基，呋喃基基团或噻吩基，X 2为酸性阴离子，n为1或2，当染料形成分子间盐（甜菜碱样结构）时，n为1; （III）其中Z5是完成萘并噻唑核所需的原子团，Z6是完成苯并咪唑核所必需的原子团，R7和R8各自为烷基或取代的烷基，其中至少一个为 R7和R8是羧基烷基或具有磺基的取代烷基，X3是酸阴离子，p是1或2，当染料形成分子间盐时，p是1。

4. 发明授权

US4135933A Silver halide photographic emulsion 失效
公开(公告)号：US4135933A
公开(公告)日：1979-01-23
申请号：US856449
申请日：1977-12-01
申请人： Masanao Hinata , Haruo Takei , Akira Sato , Atsuo Iwamoto , Jun Hayashi
发明人： Masanao Hinata , Haruo Takei , Akira Sato , Atsuo Iwamoto , Jun Hayashi
IPC分类号： G03C1/29 , G03C1/40 , G03C1/14
CPC分类号： G03C1/29
摘要： A supersensitized silver halide photographic emulsion containing a cyan coupler and, in combination, at least one of the sensitizing dyes represented by the following general formula (I) and at least one of the sensitizing dyes represented by the general formula (II): ##STR1## WHEREIN W.sup.1 and W.sup.2 each represents a hydrogen atom, an alkyl group, an alkoxyl group, a halogen atom, an alkoxycarbonyl group, an acyl group or an aryl group; R.sup.1 and R.sup.2 each represents a sulfoalkyl group; R.sup.3 represents an alkyl group or an allyl group; X.sub.1 represents an acid anion; and m is 1 or 2, m being 1 in the case that the dye forms an inner salt of a betaine-like structure; ##STR2## wherein Z.sup.1 and Z.sup.2 each represents an atomic group required for forming a benzothiazole nucleus, a benzoselenazole nucleus, a .beta.-naphthothiazole nucleus or a .beta.-naphthoselenazole nucleus; R.sup.4 and R.sup.5 each represents an aliphatic group and at least one of R.sup.4 and R.sup.5 represents a carboxyalkyl group or a sulfoalkyl group; R.sup.6 represents an alkyl group, an aryl group, a thienyl group or a furyl group; X.sub.2 represents an acid anion; and n is 1 or 2, n being 1 in the case that the dye forms an inner salt of a betaine-like structure.

5. 发明授权

US4308345A Silver halide photographic emulsion 失效
标题翻译：卤化银照相乳剂
公开(公告)号：US4308345A
公开(公告)日：1981-12-29
申请号：US730900
申请日：1976-10-08
申请人： Masanao Hinata , Haruo Takei , Akira Sato , Atsuo Iwamoto , Jun Hayashi
发明人： Masanao Hinata , Haruo Takei , Akira Sato , Atsuo Iwamoto , Jun Hayashi
IPC分类号： G03C1/28 , G03C1/29 , G03C1/14
CPC分类号： G03C1/29
摘要： A silver halide photographic emulsion selectively spectrally sensitized, particularly to red light, with a combination of at least one sensitizing dye represented by general formula (I): ##STR1## wherein Z.sup.1 and Z.sup.2 each represents the atoms necessary to form a benzothiazole nucleus or a benzoselenazole nucleus, R.sup.1 and R.sup.2 l each represents an alkyl group or a substituted alkyl group, wherein at least one of R.sup.1 or R.sup.2 should represent a sulfo group-containing substituted alkyl group, a carboxyalkyl group or a hydroxyalkyl group, R.sup.3 represents an alkyl group, X.sub.1 represents an acid anion, and m represents 1 or 2, wherein m equals 1 when the dye forms an intramolecular salt (betaine-like structure); at least one sensitizing dye represented by general formula (II): ##STR2## wherein Z.sup.3 represents a sulfur atom or a selenium atom, Z.sup.4 represents the atoms necessary to form a benzothiazole nucleus, a benzoselenazole nucleus, a naphtho[1,2-d]thiazole nucleus or a naphtho[1,2-d]selenazole nucleus, R.sup.4 and R.sup.5 each represents an alkyl group or a substituted alkyl group, wherein at least one of R.sup.4 or R.sup.5 should be a sulfo group-containing substituted alkyl group, a carboxyalkyl group or a hydroxyalkyl group, R.sup.6 represents an alkyl group, an aryl group, a furyl group or a thienyl group, X.sub.2 represents an acid anion, and n represents 1 or 2, wherein n equals 1 when the dye forms an intramolecular salt (betaine-like structure), and at least one benzimidazolothiacarbocyanine dye, which exhibits increased color reproducibility, high sensitivity and reduced residual coloration.
摘要翻译：通过至少一种由通式（I）表示的敏化染料的组合，选择性地光致敏化，特别是红光的卤化银照相乳剂：其中Z1和Z2各自表示形成苯并噻唑所必需的原子核或苯并硒唑核，R 1和R 2各自表示烷基或取代的烷基，其中R 1或R 2中的至少一个应表示含磺基的取代的烷基，羧基烷基或羟烷基，R 3表示烷基，X1表示酸阴离子，m表示1或2，当染料形成分子内盐（甜菜碱样结构）时，m等于1; 至少一种由通式（II）表示的敏化染料：其中Z 3表示硫原子或硒原子，Z 4表示形成苯并噻唑核所需的原子，苯并硒唑核，萘并[1， 2-d]噻唑核或萘并[1,2-d]硒唑核，R 4和R 5各自表示烷基或取代的烷基，其中R 4或R 5中的至少一个应为含磺基取代的烷基基团，羧基烷基或羟烷基，R6表示烷基，芳基，呋喃基或噻吩基，X2表示酸阴离子，n表示1或2，其中当染料形成时，n等于1 分子内盐（甜菜碱样结构）和至少一种苯并咪唑硫羰花青染料，其表现出增加的颜色再现性，高灵敏度和降低的残留着色。

6. 发明授权

US4039335A Photographic silver halide emulsions 失效
标题翻译：摄影卤化银乳剂
公开(公告)号：US4039335A
公开(公告)日：1977-08-02
申请号：US737130
申请日：1976-10-29
申请人： Masanao Hinata , Haruo Takei , Akira Sato , Atsuo Iwamoto , Jun Hayashi
发明人： Masanao Hinata , Haruo Takei , Akira Sato , Atsuo Iwamoto , Jun Hayashi
IPC分类号： G03C1/28 , G03C1/29 , G03C1/14
CPC分类号： G03C1/29
摘要： A silver halide photographic emulsion spectrally sensitized with a combination of sensitizing dyes consisting essentially of at least one sensitizing dye represented by the following general formula [I] and at least one sensitizing dye represented by the following general formula [II] in supersensitizing amounts: ##STR1## wherein R.sup.1 and R.sup.2 each is an alkyl group, R.sup.3 is an alkyl group, X.sub.1 is an acidic anion, m is 1 or 2, and m is 1 when the dye forms an intramolecular salt (betaine-like structure). ##STR2## WHEREIN Z.sup.1 is a sulfur atom or a selenium atom, Z.sup.2 is an atomic group necessary to form a benzothiazole ring, a benzoselenazole ring, a naphtho[1,2-d]thiazole ring or a naphtho[1,2-d]selenazole ring, R.sup.4 and R.sup.5 is an alkyl group, R.sup.6 is an alkyl group, a phenyl group, an aralkyl group, a furyl group or a thienyl group, X.sub.2 is an acidic anion, n is 1 or 2, and n is 1 when the dye forms an intramolecular salt (betaine-like structure).
摘要翻译：用基本上由以下通式[I]表示的至少一种敏化染料和至少一种由以下通式[II]表示的敏化染料在超敏化剂中组合的敏化染料的光致增感的卤化银照相乳剂：一般其中R1和R2各自为烷基，R3为烷基，X1为酸性阴离子，m为1或2，当染料形成分子内时，m为1 盐（甜菜碱样结构）。通式[II]其中Z 1为硫原子或硒原子，Z 2为形成苯并噻唑环所需的原子团，苯并硒唑环，萘并[1,2-d]噻唑环或萘并[ 1,2-d]硒唑环，R4和R5是烷基，R6是烷基，苯基，芳烷基，呋喃基或噻吩基，X2是酸性阴离子，n是1或2 ，当染料形成分子内盐（甜菜碱样结构）时，n为1。

7. 发明授权

US4028115A Silver halide photographic emulsion sensitized to red with four carbocyanine dyes 失效
标题翻译：卤化银照相乳剂用四种碳菁染料敏化为红色
公开(公告)号：US4028115A
公开(公告)日：1977-06-07
申请号：US717837
申请日：1976-08-26
申请人： Masanao Hinata , Haruo Takei , Akira Sato , Atsuo Iwamoto , Jun Hayashi
发明人： Masanao Hinata , Haruo Takei , Akira Sato , Atsuo Iwamoto , Jun Hayashi
IPC分类号： G03C1/28 , G03C1/29 , G03C1/14
CPC分类号： G03C1/29
摘要： A spectrally sensitized silver halide photographic emulsion containing, in combination, four carbocyanine sensitizing dyes.
摘要翻译：含有四种碳菁感光染料的光谱增感卤化银照相乳剂。

8. 发明授权

US4001020A Developing a silver ha1ide emulsion in contact with a heterocyclic thione and a polyalkylene oxide 失效
标题翻译：开发一种与异戊二烯和一种聚氧乙烯氧化物接触的银HAIIDE乳液
公开(公告)号：US4001020A
公开(公告)日：1977-01-04
申请号：US548843
申请日：1975-02-10
申请人： Jun Hayashi , Akira Sato , Tadao Shishido
发明人： Jun Hayashi , Akira Sato , Tadao Shishido
IPC分类号： G03C1/043 , G03C1/34 , G03C5/20
CPC分类号： G03C1/043 , G03C1/346
摘要： A method for forming photographic images of particularly improved sharpness in which a photographic element is developed in the presence of an alkylene oxide polymer and a compound of the general formula ##STR1## wherein Q represents the atoms required to form an optionally substituted, defined heterocyclic ring and R is as defined in the specification, or a compound of the general formula ##STR2## wherein W is a sulfur, selenium or oxygen atom or a group >N--R.sub.3, R.sub.1, R.sub.2, and R.sub.3 each is an optionally substituted, defined alkyl group and Z represents the atoms required to form an optionally substituted, defined heterocyclic ring.

9. 发明授权

US09134313B2 Method of detecting colorectal cancer of stages 0 to I 有权
标题翻译：检测0〜I期结直肠癌的方法
公开(公告)号：US09134313B2
公开(公告)日：2015-09-15
申请号：US12480983
申请日：2009-06-09
申请人： Masao Kawakita , Kyoko Hiramatsu , Keiichi Takahashi , Naotaka Hamasaki , Koji Yamaguchi , Tsunehisa Kaku , Koichiro Muta , Munechika Enjoji , Seiji Naito , Jun Hayashi , Shoshu Mitsuyama , Hiroyuki Yamashita , Toru Inoue , Masato Kato
发明人： Masao Kawakita , Kyoko Hiramatsu , Keiichi Takahashi , Naotaka Hamasaki , Koji Yamaguchi , Tsunehisa Kaku , Koichiro Muta , Munechika Enjoji , Seiji Naito , Jun Hayashi , Shoshu Mitsuyama , Hiroyuki Yamashita , Toru Inoue , Masato Kato
IPC分类号： G01N33/574 , C07K16/30
CPC分类号： G01N33/574 , C07K16/30
摘要： A tumor marker comprising diacetylspermine, and a method of evaluating the state of a tumor, comprising reacting an antibody to diacetylspermine with a biological sample to thereby detect diacetylspermine and evaluating the state of the tumor using the obtained detection results as an indicator.
摘要翻译：包含二乙酰精胺的肿瘤标志物和评价肿瘤状态的方法，包括使抗体与二乙酰精胺与生物样品反应，从而检测二乙酰精胺，并使用所获得的检测结果作为指标来评价肿瘤的状态。

10. 发明授权

US07650144B2 Monitoring control apparatus, monitoring system, monitoring method, wireless communication apparatus and wireless communication system 有权
标题翻译：监控控制装置，监控系统，监控方式，无线通讯装置及无线通讯系统
公开(公告)号：US07650144B2
公开(公告)日：2010-01-19
申请号：US11362800
申请日：2006-02-28
申请人： Akihiko Nakamura , Takaaki Ombe , Jun Hayashi , Noriaki Hayakawa
发明人： Akihiko Nakamura , Takaaki Ombe , Jun Hayashi , Noriaki Hayakawa
IPC分类号： H04M3/00
CPC分类号： G08B25/10 , H04L12/2803 , H04L12/2827 , H04W48/18 , H04W84/18 , Y02D70/10
摘要： A main controller used in a security system having a sensor or a camera performs wireless communication with the sensor or the camera so as to control the sensor or the camera. The main controller has a plurality of communication sections that perform wireless communication by using communication systems having different communication speeds. The camera transmits and receives information by performing wireless communication with the main controller. The camera is provided with a first camera communication section and a second camera communication section that perform wireless communication by using communication systems having different communication speeds, and a camera communication control section for selecting the first camera communication section and the second camera communication section according to the information to be transmitted and received, as a communication section to perform communication.
摘要翻译：在具有传感器或相机的安全系统中使用的主控制器执行与传感器或相机的无线通信，以便控制传感器或相机。主控制器具有通过使用具有不同通信速度的通信系统来执行无线通信的多个通信部分。相机通过与主控制器进行无线通信来发送和接收信息。相机具有第一相机通信部分和第二相机通信部分，其通过使用具有不同通信速度的通信系统执行无线通信，以及相机通信控制部分，用于根据第一相机通信部分和第二相机通信部分根据要发送和接收的信息，作为通信部分进行通信。

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