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    • 5. 发明授权
    • Granular material of polyimide precursor, mixture comprising the
material and process for producing the material
    • 聚酰亚胺前体的颗粒材料,包含该材料的混合物和用于生产该材料的方法
    • US5463016A
    • 1995-10-31
    • US193887
    • 1994-02-09
    • Isao TomiokaTakeshi NakanoMikio FurukawaYoshiaki Echigo
    • Isao TomiokaTakeshi NakanoMikio FurukawaYoshiaki Echigo
    • B29C55/02B29K79/00C08G73/10C08J3/12C08J3/14C08L79/08C09D179/08H01B3/30C08G77/10C08G69/26
    • C08G73/1032C08J3/12C08J3/14C08J2379/08
    • This invention provides (1) a granular material of a polyimide precursor, which has excellent solubility in solvents and excellent moldability and from which a polyimide molding having excellent mechanical properties can be produced, (2) a mixture of a granular material of a polyimide precursor with a solvent, in which the polyimide precursor shows excellent storage stability and (3) a process for the production of a granular material of a polyimide precursor, in which a solvent can be easily removed. Particularly provided are a polyimide precursor granular material having an intrinsic viscosity of 0.7 or higher and a polyimide precursor mixture which consists of a polyimide precursor granular polyimide having an intrinsic viscosity of 0.7 or higher and a solvent that does not exhibit a strong-mutual interaction with the polyimide precursor, as well as a process for the production of the polyimide precursor granular material. The granular material of a polyimide precursor can be obtained by allowing a tetracarboxylic dianhydride to undergo polymerization reaction with a diamine in a solvent that does not exhibit a strong mutual interaction with the polyimide precursor.
    • 本发明提供(1)聚酰亚胺前体的粒状材料,其在溶剂中的溶解性优异,成型性优异,可以制造出具有优异的机械性能的聚酰亚胺成型体,(2)聚酰亚胺前体的粒状材料 与聚酰亚胺前体显示优异的储存稳定性的溶剂和(3)可以容易地除去溶剂的聚酰亚胺前体的粒状材料的制造方法。 特别提供特性粘度为0.7以上的聚酰亚胺前体粒状材料和由特性粘度为0.7以上的聚酰亚胺前体粒状聚酰亚胺构成的聚酰亚胺前体混合物和不显示与 聚酰亚胺前体,以及聚酰亚胺前体粒状材料的制造方法。 聚酰亚胺前体的粒状材料可以通过使四羧酸二酐与不与聚酰亚胺前体表现出强相互作用的溶剂中的二胺进行聚合反应来获得。