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1. 发明授权

US4664936A Aromatic polyamide fiber-based composite prepreg 失效
标题翻译：芳香族聚酰胺纤维复合预浸料
公开(公告)号：US4664936A
公开(公告)日：1987-05-12
申请号：US816309
申请日：1986-01-06
申请人： Susumu Ueno , Shigehiro Hoshida , Hirokazu Nomura
发明人： Susumu Ueno , Shigehiro Hoshida , Hirokazu Nomura
IPC分类号： B29B15/08 , B29C59/14 , C08J5/06 , D06M10/02 , B05D3/06
CPC分类号： B29B15/08 , B29C59/14 , C08J5/06 , D06M10/025 , B29K2105/08 , B29K2277/00 , D06M2101/36 , D06M2200/50
摘要： The resin-impregnated composite prepreg based on a fabric material of an aromatic polyamide fiber is prepared by exposing the fabric material to low temperature plasma generated in an atmosphere of an inorganic gas, which is preferably oxygen or an oxygen-containing gaseous mixture, under a pressure of 0.5 to 5 Torr to such an extent that ruggedness of 0.01 to 0.5 .mu.m is formed on the surface and then impregnating the fabric material with an organic resinous binder. The adhesive bonding strength between the binder and the fiber surface can further be increased when the plasma-treated fabric material is brought into contact with an unsaturated compound polymerizable by free radical polymerization without contacting with air so as to form a graft-polymerized layer on the fiber surface.
摘要翻译：基于芳族聚酰胺纤维的织物材料的树脂浸渍的复合预浸料通过将织物材料暴露于无机气体（其优选为氧或含氧气体混合物）的气氛中产生的低温等离子体来制备，压力为0.5〜5托，至表面形成0.01〜0.5微米的凹凸，然后用有机树脂粘合剂浸渍织物。当等离子体处理的织物材料与通过自由基聚合可聚合的不饱和化合物接触而不与空气接触以在粘合剂和纤维表面之间形成接枝聚合层时，可以进一步增加粘合剂和纤维表面之间的粘合强度纤维表面。

2. 发明授权

US4607088A Shaped body for gas separation 失效
标题翻译：成型体用于气体分离
公开(公告)号：US4607088A
公开(公告)日：1986-08-19
申请号：US732377
申请日：1985-05-03
申请人： Hirokazu Nomura , Susumu Ueno , Hajime Kitamura
发明人： Hirokazu Nomura , Susumu Ueno , Hajime Kitamura
IPC分类号： B01D53/22 , B01D67/00 , B01D71/06 , B01D71/44 , B01D71/70 , C08F38/00 , C08J5/18 , C08J7/00
CPC分类号： B01D67/009 , B01D71/44 , C08F38/00
摘要： The inventive shaped body for gas separation is prepared on the base of a film shaped of a poly(silyl acetylene) such as poly(1-methyl-2-trimethylsilyl acetylene) by subjecting the base film to a treatment of exposure to an atmosphere of low temperature plasma of an inorganic gas, e.g. nitrogen, hydrogen, argon, etc. Contrary to expectation, the base film is stable against the plasma treatment without decrease in the mechanical strengths and imparted with high performance for gas separation, especially, for the enrichment of oxygen in air with a separation factor between oxygen and nitrogen of 2.5 to 3.5.
摘要翻译：本发明的用于气体分离的成形体通过对基底膜进行处理以暴露于大气中的方式制备在聚（甲基硅烷基乙炔）如聚（1-甲基-2-三甲基甲硅烷基乙炔）上的聚（甲硅烷基乙炔）无机气体的低温等离子体，例如氮气，氢气，氩气等。与预期相反，基膜对于等离子体处理是稳定的，而不降低机械强度，并赋予气体分离高性能，特别是用于富集空气中的氧气，分离因子介于氧和氮为2.5〜3.5。

3. 发明授权

US4560458A Method for improving surface properties of a shaped article of a synthetic resin 失效
标题翻译：改善合成树脂成型制品表面性能的方法
公开(公告)号：US4560458A
公开(公告)日：1985-12-24
申请号：US690380
申请日：1985-01-10
申请人： Susumu Ueno , Hirokazu Nomura
发明人： Susumu Ueno , Hirokazu Nomura
IPC分类号： C08J7/00 , B29C59/14 , C08J7/12 , C08L59/00 , C08L81/06
CPC分类号： C08J7/123 , B29C59/14
摘要： Surface properties or, in particular, antistatic performance of a shaped article of a synthetic resin can be remarkably and lastingly improved by the exposure of the surface to low temperature plasma in two steps, in one of which the plasma is generated in an atmosphere containing a nitrogen-containing organic compound, e.g. amine, amide and the like compounds, and in the other of which the plasma is generated in an atmosphere containing a fluorine-containing organic compound, e.g. fluorinated hydrocarbon compounds. Alternatively, the plasma treatment is undertaken in one step with low temperature plasma generated in an atmosphere containing both of the nitrogen- and fluorine-containing organic compounds.
摘要翻译：通过在两个步骤中将表面暴露于低温等离子体，合成树脂的成形制品的表面性质，特别是抗静电性能可以显着地和持久地改善，其中等离子体在含有含氮有机化合物，例如胺，酰胺等化合物，另一种是在含有有机化合物的气氛中产生等离子体。氟化烃化合物。或者，等离子体处理是在含有含氮和含氟有机化合物的气氛中产生的低温等离子体一步进行的。

4. 发明授权

US4429024A Method of making antistatic magnetic recording tapes and recording tapes 失效
标题翻译：制造抗静电磁记录带和记录带的方法
公开(公告)号：US4429024A
公开(公告)日：1984-01-31
申请号：US406058
申请日：1982-08-06
申请人： Susumu Ueno , Hirokazu Nomura , Kiyoshi Imada
发明人： Susumu Ueno , Hirokazu Nomura , Kiyoshi Imada
IPC分类号： G11B5/708 , G11B5/72 , G11B5/735 , G11B5/738 , G11B5/84 , B05D3/06
CPC分类号： G11B5/738 , G11B5/735 , Y10S428/90
摘要： The invention provides a novel means for solving and overcoming the problems in the magnetic recording tapes caused by the accumulation of static electricity during travelling of the tape affecting the quality of the reproduced sounds and picture images by playing the tape. The inventive method comprises providing at least one surface of the plastic-made film base with a layer of a plasma-polymerized gaseous compound of a specific type by exposing the surface of the film base to the atmosphere of low temperature plasma generated in the low pressure atmosphere of the gas or vapor of a compound such as an amine, organosilane, aliphatically unsaturated compound and aromatic compound, preferably, before coating the film base with a magnetic coating composition. The plasma-polymerized layer is effective to decrease the surface resistivity of the film base and to reduce the accumulation of static electricity induced by rubbing.
摘要翻译：本发明提供了一种用于解决和克服磁带记录带中由于通过播放磁带而影响再现声音质量和图像图像的磁带行进期间的静电积累引起的问题的新颖手段。本发明的方法包括通过将薄膜基材的表面暴露于低压产生的低压等离子体气氛中，使塑料制成的薄膜基材的至少一个表面具有特定类型的等离子体聚合的气态化合物的层优选在用磁性涂料组合物涂覆薄膜基材之前，优选胺，有机硅烷，脂肪族不饱和化合物和芳族化合物等化合物的气体或蒸气的气氛。等离子体聚合层有效地降低膜基材的表面电阻率并减少由摩擦引起的静电积累。

5. 发明授权

US4603057A Method for the preparation of a polyvinyl chloride resin shaped article with metallized surface 失效
标题翻译：用于制备具有金属化表面的聚氯乙烯树脂成形制品的方法
公开(公告)号：US4603057A
公开(公告)日：1986-07-29
申请号：US690379
申请日：1985-01-10
申请人： Susumu Ueno , Hirokazu Nomura
发明人： Susumu Ueno , Hirokazu Nomura
IPC分类号： B05D3/06 , C08J7/00 , C08J7/04 , C08L27/06 , C23C14/02 , C23C14/20 , C23C18/20
CPC分类号： C08J7/123 , C23C14/022 , C08J2327/06
摘要： The invention provides a method for the preparation of a shaped article of a flexible or semi-rigid polyvinyl chloride resin having a metallized surface, of which the adhesive bonding of the metallizing layer to the substrate surface is greatly improved. In the inventive method, the surface of the shaped article is first exposed to low temperature plasma generated in an atmosphere containing a vapor of a specified organosilicon compound before the metallizing treatment in a dry process such as vacuum vapor deposition, ion plating and the like.
摘要翻译：本发明提供一种用于制备具有金属化表面的柔性或半刚性聚氯乙烯树脂的成型制品的方法，其中金属化层与基材表面的粘合性大大提高。在本发明的方法中，成形制品的表面首先在诸如真空气相沉积，离子电镀等干法进行金属化处理之前，首先暴露于在含有特定有机硅化合物的气体的气氛中产生的低温等离子体。

6. 发明授权

US4548867A Fluorine-containing synthetic resin shaped articles having improved surface properties and a method for the preparation thereof 失效
标题翻译：具有改进的表面性质的含氟合成树脂成形制品及其制备方法
公开(公告)号：US4548867A
公开(公告)日：1985-10-22
申请号：US521833
申请日：1983-08-10
申请人： Susumu Ueno , Hirokazu Nomura , Kiyoshi Imada
发明人： Susumu Ueno , Hirokazu Nomura , Kiyoshi Imada
IPC分类号： B41M1/30 , B29C71/04 , B32B27/00 , B32B27/30 , C07G13/00 , C08J7/00 , C08J7/12 , C08L27/12 , C09J5/00 , C09J5/02
CPC分类号： C08J7/123 , C08J2327/12 , Y10T428/31 , Y10T428/3154 , Y10T428/31544
摘要： The invention provides a shaped article of a fluorine-containing synthetic resin having improved surface properties such as increased wettability with water, printability, susceptibility to adhesive bonding and less accumulation of static electricity. The improved shaped article is obtained by subjecting the surface of the article to exposure to low temperature plasma generated in a low pressure atmosphere of a nitrogen-containing gaseous organic compound such as amines, imides and amides.
摘要翻译：本发明提供一种含水合成树脂的成形制品，其具有改善的表面性能，例如增加水的润湿性，可印刷性，对粘合剂粘合的敏感性和较少的静电积累。改进的成型制品通过使制品的表面暴露于低压气氛中的含氮气态有机化合物如胺，酰亚胺和酰胺中产生的低温等离子体而获得。

7. 发明授权

US4410784A Method for modifying surface properties of a disc-like shaped article of a vinyl chloride-based resin 失效
标题翻译：用于改进氯乙烯类树脂的盘状成形制品的表面性质的方法
公开(公告)号：US4410784A
公开(公告)日：1983-10-18
申请号：US230070
申请日：1981-01-29
申请人： Kiyoshi Imada , Susumu Ueno , Yasuhide Nishina , Hirokazu Nomura
发明人： Kiyoshi Imada , Susumu Ueno , Yasuhide Nishina , Hirokazu Nomura
IPC分类号： B23K9/00 , B29C59/14 , B29D17/00 , C08L27/06 , G11B3/58 , H05F1/02
CPC分类号： C08J7/123 , B29C59/14 , G11B3/58 , B29K2027/06 , B29L2017/00 , C08J2327/06 , Y10S425/81
摘要： The invention provides a novel method for modifying the surface properties, e.g. antistatic performance and anti-wearing resistance, of a disc-like shaped article made of a vinyl chloride-based resin such as a gramophone record by treating with low temperature plasma so as that the surface of the record is rendered antistatic and the noise generation in playing of the record is remarkably decreased. Different from conventional methods, a great uniformity of the effect by the plasma treatment is ensured by the inventive method all over the surface of the record since the record is transferred through the space between two parallel arrays of electrodes, preferably, with rotation around its axis during the plasma treatment. The manner of connecting the electrodes to the terminals of the high frequency generator may be in two different ways. For example, all of the electrodes in one array are connected to the grounded terminal while all of the electrodes in the other array are connected to the power-input terminal. Alternatively, each of the electrodes is connected to a terminal different from that to which both of the neighboring electrodes in the same array and the electrode in the other array oppositely facing it are connected. The record after the plasma treatment is preferably coated with a surface active agent and dried to enhance the effectiveness.
摘要翻译：本发明提供了一种用于改变表面性质的新方法，例如，通过用低温等离子体处理，由诸如留声机记录的氯乙烯类树脂制成的盘状成型制品的抗静电性能和抗磨损性能使得记录表面变得抗静电，并且产生噪音创历史新高。与传统方法不同，通过本发明的方法在记录的整个表面上确保了通过等离子体处理的效果的大的均匀性，因为记录通过两个平行的电极阵列之间的空间传送，优选地绕其轴线旋转在等离子体处理期间。将电极连接到高频发生器的端子的方式可以有两种不同的方式。例如，一个阵列中的所有电极连接到接地端子，而另一个阵列中的所有电极都连接到电源输入端子。或者，每个电极连接到与相同阵列中的两个相邻电极和与其相对面对的另一阵列中的电极不同的端子。等离子体处理后的记录优选用表面活性剂涂布并干燥以提高有效性。

8. 发明授权

US4344981A Method for modifying surface properties of a shaped article of a silicone 失效
标题翻译：改善硅酮成型制品表面性能的方法
公开(公告)号：US4344981A
公开(公告)日：1982-08-17
申请号：US158407
申请日：1980-06-11
申请人： Kiyoshi Imada , Susumu Ueno , Yasuhide Nishina , Hirokazu Nomura
发明人： Kiyoshi Imada , Susumu Ueno , Yasuhide Nishina , Hirokazu Nomura
IPC分类号： C08J7/00 , B01J19/08 , B05D3/06 , B29C71/04 , B29K83/00 , C08J7/02 , C08L83/04
CPC分类号： C08J7/123 , C08J2383/04
摘要： A novel method is proposed for improving the surface properties or, in particular, for increasing the affinity to water of the surface of a shaped article made of a silicone, e.g. a silicone rubber. The inventive method comprises first exposing the surface of the shaped article of the silicone to low temperature plasma of an inorganic gas and then bringing the plasma-treated surface into contact with a liquid inert to the silicone which is an aqueous solution containing a surface active agent. The treated surface retains sufficient affinity to water even 6 months after the treatment.
摘要翻译：提出了一种改进表面性质的新方法，特别是用于提高由硅酮制成的成型制品的表面对水的亲和性。硅橡胶。本发明的方法包括首先将硅氧烷成型制品的表面暴露于无机气体的低温等离子体中，然后使等离子体处理的表面与含有表面活性剂的水溶液的硅氧烷惰性的液体接触。处理后的表面在治疗6个月后仍保持足够的亲和力。

9. 发明授权

US4310564A Method for modifying surface properties in polyvinyl chloride shaped articles 失效
标题翻译：改进聚氯乙烯制品表面性能的方法
公开(公告)号：US4310564A
公开(公告)日：1982-01-12
申请号：US204195
申请日：1980-11-05
申请人： Kiyoshi Imada , Susumu Ueno , Yasuhide Nishina , Hirokazu Nomura
发明人： Kiyoshi Imada , Susumu Ueno , Yasuhide Nishina , Hirokazu Nomura
IPC分类号： C08J7/00 , B05D3/04 , B05D3/06 , B29C59/14 , C08F14/06 , C08J7/12 , C08J7/14 , C08L27/06
CPC分类号： C08J7/123 , C08J2327/06
摘要： The undesirable phenomenon of bleeding of, for example, a plasticizer contained in a shaped article of a plasticized polyvinyl chloride resin on the surface of the article in a long-run use is effectively prevented by the inventive method and the effectiveness of the method is durable over a long period of time even when the article is used in an outdoor environment or under irradiation with ultraviolet light. The method of the invention comprises the first step of exposing the surface of the article to an atmosphere of low temperature plasma of an inorganic gas and then the second step of contacting the thus plasma-treated surface with a halogen or hydrogen halide, preferably, in gaseous state.
摘要翻译：通过本发明的方法有效地防止了在长期使用的物品表面上塑化的聚氯乙烯树脂的成型制品中所含的增塑剂出现的不期望的现象，该方法的有效性是耐用的即使当在室外环境中使用物品或在紫外线照射下使用时，也可以长时间使用。本发明的方法包括将制品的表面暴露于无机气体的低温等离子体的气氛中的第一步骤，然后第二步骤将等离子体处理的表面与卤素或卤化氢接触，优选在气态。

10. 发明授权

US4276138A Method for reducing electrostatic charging on shaped articles of polyvinyl chloride resins 失效
标题翻译：降低聚氯乙烯树脂成型制品静电荷的方法
公开(公告)号：US4276138A
公开(公告)日：1981-06-30
申请号：US051148
申请日：1979-06-22
申请人： Michihiko Asai , Yoshio Suda , Kiyoshi Imada , Susumu Ueno , Hirokazu Nomura
发明人： Michihiko Asai , Yoshio Suda , Kiyoshi Imada , Susumu Ueno , Hirokazu Nomura
IPC分类号： C08J3/28 , C08J5/00 , C08J5/18 , C08J7/12 , C08J7/18 , C08K5/04 , C08K5/06 , C08K5/09 , C08K5/17 , C08K5/42 , C08L27/06 , G02B1/10
CPC分类号： C08J7/123 , C08J2327/06 , Y10S260/19 , Y10S260/20
摘要： A method for reducing static electricity on the surface of a shaped article made of polyvinyl chloride resins, which method comprises the steps of (a) blending a surface active agent with the polyvinyl chloride resin prior to fabrication of the resin into a shaped article, (b) fabricating the resin admixed with the surface active agent into a shaped article, and (c) subjecting the shaped article to a treatment with low temperature plasma of a gas.
摘要翻译：一种用于减少由聚氯乙烯树脂制成的成型制品表面的静电的方法，该方法包括以下步骤：（a）在将树脂制成之前将表面活性剂与聚氯乙烯树脂混合成成型制品（ b）将与表面活性剂混合的树脂制成成型制品，和（c）使成形制品用气体的低温等离子体处理。

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