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1. 发明授权

US06316661B1 Process for the production of 2,3,5-trimethylhydroquinone diesters 失效
标题翻译：制备2,3,5-三甲基氢醌二酯的方法
公开(公告)号：US06316661B1
公开(公告)日：2001-11-13
申请号：US09493065
申请日：2000-01-28
申请人： Steffen Krill , Horst Weigel , Klaus Huthmacher , Nongyuan Shi , Georg Markowz , Volker Hafner
发明人： Steffen Krill , Horst Weigel , Klaus Huthmacher , Nongyuan Shi , Georg Markowz , Volker Hafner
IPC分类号： C07C6900
CPC分类号： C07C67/00 , Y02P20/582 , C07C69/017 , C07C69/16 , C07C69/28
摘要： A process for the production of 2,3,5-trimethylhydroquinone diesters by aromatization of 2,6,6-trimethyl-2-cyclohexene-1,4-dione (4-oxoisophorone, ketoisophorone, KIP) with an acylating agent and an acidic soluble or insoluble catalyst, which process may be operated alternatively continuously or discontinuously. The process includes the following steps: a) a carboxylic anhydride having a C1 to C4 alkyl residue is used as the acylating agent, b) after the reaction, a proportion of the resultant carboxylic acid is optionally removed by distillation, c) the reaction solution is cooled, d) the product which has crystallized out is separated and washed, and e) the filtrate is returned to step a).
摘要翻译：通过2,6,6-三甲基-2-环己烯-1,4-二酮（4-氧异佛尔酮，酮异佛尔酮，KIP）与酰化剂和酸性化合物的芳构化生产2,3,5-三甲基氢醌二酯的方法可溶或不溶的催化剂，该方法可以交替连续或不连续地操作。该方法包括以下步骤：a）具有C1至C4烷基残基的羧酸酐用作酰化剂，b）反应后，任选地通过蒸馏除去所得羧酸的一部分，c）反应溶液被冷却，d）结晶出来的产物被分离和洗涤，e）将滤液返回到步骤a）。

2. 发明授权

US06566559B2 Process for the production of isopropenyl methyl ether 失效
标题翻译：异丙烯基甲基醚的制备方法
公开(公告)号：US06566559B2
公开(公告)日：2003-05-20
申请号：US09871000
申请日：2001-06-01
申请人： Steffen Krill , Stephan Kretz , Volker Häfner , Georg Markowz
发明人： Steffen Krill , Stephan Kretz , Volker Häfner , Georg Markowz
IPC分类号： C07C4128
CPC分类号： C07C41/38 , C07C41/28 , C07C43/15
摘要： Process for the production of unsaturated ethers, in particular isopropenyl methyl ether (IPM), by pyrolysis of a ketal-containing or acetal-containing mixture, in particular dimethoxypropane (DMP), in the liquid phase in the presence of an organic carboxylic acid, according to the following reaction scheme: wherein R1=H or alkyl with 1-8 C atoms; R2=H, CH3—, C2H5—, or Cl—; R3=alkyl with 1-8 C atoms; R4=H, CH3—, C2H5—, or C3H7—, and R1 and R4 may be joined to form a 5-, 6-, or 7-membered ring. DMP is produced by the process from acetone and methanol by reaction in an acidic heterogeneous ion exchanger, the product being isolated by extraction with aqueous alkaline solution. In particular the process involves combining the IPM reaction product with the DMP reaction product, which permits the execution of a stable recycling process in which the methanol-containing streams of the IPM and DMP stages can be simultaneously extracted. The product may be isolated by the process by simple distillation of IPM from a mixture containing IPM, DMP and acetone.
摘要翻译：通过在有机羧酸的存在下在液相中热解含缩酮或含缩醛的混合物，特别是二甲氧基丙烷（DMP），生产不饱和醚，特别是异丙烯基甲基醚（IPM）的方法，根据以下反应方案：其中R1 = H或具有1-8个C原子的烷基; R2 = H，CH3-，C2H5-或Cl-; R3 =具有1-8个C原子的烷基; R 4 = H，CH 3 - ，C 2 H 5 - 或C 3 H 7 - ，并且R 1和R 4可以连接形成5-，6-或7-元环。通过在酸性异质离子交换剂中反应，通过丙酮和甲醇的方法制备DMP，产物通过碱性水溶液萃取分离。特别地，该方法包括将IPM反应产物与DMP反应产物组合，这允许执行稳定的再循环过程，其中可以同时萃取IPM和DMP阶段的含甲醇流。通过从含有IPM，DMP和丙酮的混合物中简单蒸馏IPM可以通过该方法分离产物。

3. 发明申请

US20150315936A1 INTEGRATED SYSTEM AND METHOD FOR THE FLEXIBLE USE OF ELECTRICITY 审中-公开
标题翻译：电力灵活使用的集成系统和方法
公开(公告)号：US20150315936A1
公开(公告)日：2015-11-05
申请号：US14648036
申请日：2013-11-08
申请人： Georg MARKOWZ , Jurgen Erwin LANG , Rudiger SCHUTTE , EVONIK DEGUSSA GMBH
发明人： Georg Markowz , Jürgen Erwin Lang , Rüdiger Schütte
IPC分类号： F01K23/18 , C07C2/80 , F01K23/06 , B01J19/08 , F02C3/20 , F01K15/00
CPC分类号： F01K23/18 , B01J19/0006 , B01J19/088 , B01J2219/0805 , B01J2219/0894 , C07C2/80 , F01K15/00 , F01K23/06 , F02C3/20 , H01M8/0612 , H01M2250/10 , H01M2250/402 , Y02B90/12 , Y02B90/14 , Y02E20/16 , Y02P70/56 , C07C11/24
摘要： The present invention relates to an integrated plant which comprises a plant for the electrothermic production of ethyne and a plant for electricity generation, the plant for the electrothermic production of ethyne being connected to the plant for electricity generation via a conduit and electricity being generated in the plant for electricity generation from a product gas obtained in the plant for the electrothermic production of ethyne. This integrated plant affords flexible use of electricity by a method in which, at times of a high electricity supply, the plant for the electrothermic production of ethyne is operated and at least some of the hydrogen and/or gaseous hydrocarbons obtained in addition to ethyne is stored and, at times of a low electricity supply, stored hydrogen and/or gaseous hydrocarbons are fed to the plant for electricity generation.
摘要翻译：本发明涉及一种综合植物，其包括用于电热生产乙炔的植物和用于发电的植物，用于电热生产乙炔的工厂通过管道连接到工厂用于发电并在从工厂获得的用于电热生产乙炔的产品气发电厂。该综合工厂通过一种方法灵活地使用电力，其中在高电力供应的时候，用于电热生产乙炔的设备运行，并且除了乙炔之外获得的至少一些氢气和/或气态烃是储存并且在低电力供应的时候储存的氢气和/或气态碳氢化合物被供给到工厂用于发电。

4. 发明申请

US20140327404A1 METHOD FOR PROVIDING CONTROL POWER BY AN ENERGY STORE BY USING TOLERANCES IN THE DETERMINATION OF THE FREQUENCY DEVIATION 有权
标题翻译：通过使用公差在确定频率偏差的情况下通过能量存储来提供控制功率的方法
公开(公告)号：US20140327404A1
公开(公告)日：2014-11-06
申请号：US14357313
申请日：2012-10-29
申请人： Georg Markowz , Wolfgang Schweissthal , Carsten Kolligs , Holger Brezski , Wolfgang Deis , Michael Igel , Anna Flemming , Dennis Gamrad , Sebastien Cochet , Stefan Winternheimer
发明人： Georg Markowz , Wolfgang Schweissthal , Carsten Kolligs , Holger Brezski , Wolfgang Deis , Michael Igel , Anna Flemming , Dennis Gamrad , Sebastien Cochet , Stefan Winternheimer
IPC分类号： H02J7/00
CPC分类号： H02J7/00 , H02J3/24 , H02J3/32 , H02J7/0013 , H02J7/007 , H02K5/10 , H05K5/068
摘要： A method for providing control power for an electricity network in which at least one energy store connected to the electricity network supplies energy to the electricity network as required and/or takes up energy from the electricity network as required, the control power being delivered in dependence on a frequency deviation from a setpoint value of a network frequency, a tolerance with respect to the frequency deviation being used to set a charging state of the energy store at a same time as providing the control power by the energy store. A device for carrying out such a method includes a control system and an energy store, the device being connected or connectable to an electricity network, the control system being connected to the energy store and controlling the control power that is given off and/or taken up by the energy store.
摘要翻译：一种用于为电网提供控制电力的方法，其中连接到电网的至少一个能量存储器根据需要向电网提供能量和/或根据需要从电力网络占用能量，所述控制功率依赖地被传递在与网络频率的设定值的频率偏差上，相对于频率偏差的公差用于在与由能量存储提供控制功率的同时设置能量存储器的充电状态。用于执行这种方法的装置包括控制系统和能量存储器，该设备被连接或连接到电力网络，该控制系统连接到能量存储器并且控制被释放和/或采取的控制功率由能源商店。

5. 发明申请

US20100160649A1 SYSTEM AND PROCESS FOR CONTINUOUS INDUSTRIAL PREPARATION OF 3-GLYCIDYLOXYPROPYLALKOXYSILANES 审中-公开
标题翻译： 3-GLYCIDYLOXYPROPYLALKOXYSILESES连续工业制备的系统与工艺
公开(公告)号：US20100160649A1
公开(公告)日：2010-06-24
申请号：US12376786
申请日：2007-07-09
申请人： Juergen Erwin Lang , Georg Markowz , Dietmar Wewers , Harald Metz , Norbert Schladerbeck , Peter Jenkner
发明人： Juergen Erwin Lang , Georg Markowz , Dietmar Wewers , Harald Metz , Norbert Schladerbeck , Peter Jenkner
IPC分类号： C07F7/08 , B01J19/00 , B01J8/00
CPC分类号： B01J19/0093 , B01J2219/00783 , B01J2219/00788 , B01J2219/00822 , B01J2219/00831 , B01J2219/00835 , B01J2219/00837 , B01J2219/0086 , B01J2219/00867 , B01J2219/00869 , B01J2219/00873 , B01J2219/00889 , C07F7/1876
摘要： The present invention relates to a system, to a reactor and to a process for continuous industrial performance of a reaction wherein allyl glycidyl ether A is reacted with an HSi compound B in the presence of a catalyst C and optionally of further assistants, and the system is based at least on the combination of reactants (3) for components A (1) and B (2), at least one multielement reactor (5) which in turn comprises at least two reactor units in the form of exchangeable pre-reactors (5.1) and at least one further reactor unit (5.3) connected downstream of the prereactors, and on a product workup (8).
摘要翻译：本发明涉及反应器的系统，以及连续工业化反应的方法，其中烯丙基缩水甘油醚A与催化剂C和任选的其它助剂的存在下与HSi化合物B反应，并且系统至少基于组分A（1）和B（2）的反应物（3）的组合，至少一个多元素反应器（5），其又包含至少两个可交换的预反应器形式的反应器单元（ 5.1）和连接在预反应器下游的至少一个另外的反应器单元（5.3）和产品后处理（8）。

6. 发明申请

US20090259063A1 SYSTEM AND PROCESS FOR CONTINUOUS INDUSTRIAL PREPARATION OF FLUOROALKYLCHLOROSILANE 审中-公开
标题翻译：连续工业制备氟烷基氯硅烷的系统和方法
公开(公告)号：US20090259063A1
公开(公告)日：2009-10-15
申请号：US12375033
申请日：2007-07-09
申请人： Jürgen Erwin Lang , Georg Markowz , Dietmar Wewers , Harald Metz , Norbert Schladerbeck
发明人： Jürgen Erwin Lang , Georg Markowz , Dietmar Wewers , Harald Metz , Norbert Schladerbeck
IPC分类号： C07F7/16 , B01J8/04
CPC分类号： B01J19/0093 , B01J2219/00783 , B01J2219/00788 , B01J2219/00822 , B01J2219/00831 , B01J2219/00835 , B01J2219/00837 , B01J2219/0086 , B01J2219/00867 , B01J2219/00869 , B01J2219/00871 , B01J2219/00873 , B01J2219/00889 , C07F7/14
摘要： The present invention relates to a system, to a reactor and to a process for continuous industrial performance of a reaction wherein an α,β-unsaturated fluorine-substituted olefin A is reacted with an HSi compound B in the presence of a catalyst C and optionally of further assistants, and the system is based at least on the combination of reactants (3) for components A (1) and B (2), at least one multielement reactor (5) which, in turn, comprises at least two reactor units in the form of exchangeable prereactors (5.1) and at least one further reactor unit (5.3) connected downstream of the prereactors, and on a product workup (8).
摘要翻译：本发明涉及反应器的系统，以及连续工业化反应的方法，其中α，β-不饱和氟取代的烯烃A在催化剂C存在下与HSi化合物B反应，任选地该系统至少基于组分A（1）和B（2）的反应物（3）的组合，至少一个多元件反应器（5），其又包含至少两个反应器单元以可交换的预反应器（5.1）的形式和连接在预反应器下游的至少一个另外的反应器单元（5.3）以及产品加工（8）。

7. 发明申请

US20080306288A1 Method for Producing Olefin Oxides and Peroxides, Reactor and the Use Thereof 审中-公开
标题翻译：生产烯烃氧化物和过氧化物，反应器及其用途的方法
公开(公告)号：US20080306288A1
公开(公告)日：2008-12-11
申请号：US11665357
申请日：2005-09-16
申请人： Steffen Schirrmeister , Bernd Langanke , Karsten Bueker , Frank Becker , Johannes Albrecht , Georg Markowz , Ruediger Schutte
发明人： Steffen Schirrmeister , Bernd Langanke , Karsten Bueker , Frank Becker , Johannes Albrecht , Georg Markowz , Ruediger Schutte
IPC分类号： C07D301/02 , C07C409/00
CPC分类号： B01J37/0215 , B01J19/0093 , B01J19/249 , B01J37/0246 , B01J2219/00783 , B01J2219/00835 , B01J2219/00873 , B01J2219/00891 , B01J2219/2453 , B01J2219/2462 , B01J2219/247 , B01J2219/2479 , C07D301/12
摘要： A process for reactions with or to form peroxidic compounds in a wall reactor whose reaction space has a specific material coating is described.Both higher space-time yields and increased selectivities can be achieved by means of the process.
摘要翻译：描述了在其反应空间具有特定材料涂层的壁式反应器中与或与其形成过氧化合物的方法。通过该过程可以实现较高的时空收益率和增加的选择性。

8. 发明申请

US20080286176A1 Catalyst-Coated Support, Method For Producing The Same, Reactor Comprising The Same And Use Thereof 有权
标题翻译：催化剂涂层支撑，其生产方法，反应器包括它和使用它
公开(公告)号：US20080286176A1
公开(公告)日：2008-11-20
申请号：US11912031
申请日：2006-04-18
申请人： Steffen Schirmeister , Karsten Bueker , Martin Schmitz-Niederau , Bernd Langanke , Andreas Geisselmann , Georg Markowz , Klaus Thomas Schwarz , Elias Johannes Klemm , Frank Becker , Reinhard Machnik
发明人： Steffen Schirmeister , Karsten Bueker , Martin Schmitz-Niederau , Bernd Langanke , Andreas Geisselmann , Georg Markowz , Klaus Thomas Schwarz , Elias Johannes Klemm , Frank Becker , Reinhard Machnik
IPC分类号： B01J19/00 , B01J27/198 , B01J23/54 , B01J23/28 , B01J23/30 , B01J23/745 , B01J23/75 , B01J23/72 , B01J23/50 , B01J21/00
CPC分类号： B01J15/005 , B01J19/0093 , B01J19/249 , B01J23/002 , B01J23/52 , B01J29/89 , B01J35/1066 , B01J35/108 , B01J37/0215 , B01J37/0217 , B01J37/0226 , B01J2219/00783 , B01J2219/00835 , B01J2219/00873 , B01J2219/2453 , B01J2219/2458 , B01J2219/2462 , B01J2219/2479 , B01J2219/2497 , B01J2523/00 , C07C51/265 , C07C51/313 , Y10T428/249953 , C07C63/16 , B01J2523/19 , B01J2523/41 , B01J2523/824
摘要： Supports having a catalytic coating comprising at least one porous and cavity-containing catalyst layer are described, cavities being irregular spaces having dimensions greater than 5 μm in at least two dimensions or having cross-sectional areas of at least 10 μm2.The catalytic coatings are distinguished by a high adhesive strength and can preferably be used in microreactors.
摘要翻译：描述了具有包含至少一个多孔和含空腔的催化剂层的催化涂层的载体，空腔是在至少两个维度上具有大于5um的尺寸的不规则空间或具有至少10mum 2的横截面积< / SUP>。催化涂层的特征在于高粘合强度，并且可优选用于微反应器。

9. 发明授权

US07332139B2 Process and device for carrying out reactions in reactor with slot-shaped reaction spaces 失效
标题翻译：在具有槽形反应空间的反应器中进行反应的方法和装置
公开(公告)号：US07332139B2
公开(公告)日：2008-02-19
申请号：US09934085
申请日：2001-08-22
申请人： Rüdiger Schütte , Torsten Balduf , Catrin Becker , Ina Hemme , Birgit Bertsch-Frank , Werner Wildner , Jürgen Rollmann , Georg Markowz
发明人： Rüdiger Schütte , Torsten Balduf , Catrin Becker , Ina Hemme , Birgit Bertsch-Frank , Werner Wildner , Jürgen Rollmann , Georg Markowz
IPC分类号： B01J19/24 , B01J8/02
CPC分类号： F28F3/12 , B01F5/0403 , B01F13/0059 , B01F15/00935 , B01F2215/0036 , B01J19/0093 , B01J19/249 , B01J2208/022 , B01J2219/00265 , B01J2219/00835 , B01J2219/0086 , B01J2219/00889 , B01J2219/2453 , B01J2219/2458 , B01J2219/2462 , B01J2219/2465 , B01J2219/2467 , B01J2219/2479 , B01J2219/2481 , B01J2219/2485 , B01J2219/2487 , B01J2219/2493 , B01J2219/2495 , B01J2219/2497 , B01J2219/2498 , C01B15/029 , C07C45/35 , C07C51/252 , C07D301/12 , F28D9/0081 , C07C47/22 , C07C57/04
摘要： Reactions between at least two fluid reactants are performed in a reactor comprising wall elements (1), slot-shaped reaction spaces (3) and cavities (5) for conducting a fluid heat-carrier through. Depending on the process and throughput, a modular structural design is chosen wherein an arbitrary number of wall elements (1) are assembled to a right-parallelepipedal block (24), the reaction spaces (3) are formed between lateral surfaces (2) of right-parallelepipedal wall elements (1), the reactants are introduced into the reaction spaces (3) from edge regions of one side of the block (24) and are conducted through the reaction spaces (3) in parallel flows and the fluid heat-carrier is conducted through the tubular cavities (5) extending in the interior of the wall elements (1).
摘要翻译：在包括壁元件（1），槽形反应空间（3）和空腔（5）的反应器中进行至少两种流体反应物之间的反应，用于使流体热载体通过。根据工艺和生产量，选择模块化结构设计，其中任意数量的壁元件（1）组装到右平行六面体块（24），反作用空间（3）形成在右平行六面体壁元件（1），将反应物从块体（24）的一侧的边缘区域引入反应空间（3）中，并通过平行流动的反应空间（3）载体通过在壁元件（1）的内部延伸的管状空腔（5）进行。

10. 发明授权

US6106803A Granulates which contain titanium silicalite-1 失效
标题翻译：含钛硅沸石-1的颗粒
公开(公告)号：US6106803A
公开(公告)日：2000-08-22
申请号：US121309
申请日：1998-07-23
申请人： Steffen Hasenzahl , Georg Markowz , Mathias Viandt , Eckehart E. Roland , Georg Thiele , Gustaaf Goor , Alexander Moller
发明人： Steffen Hasenzahl , Georg Markowz , Mathias Viandt , Eckehart E. Roland , Georg Thiele , Gustaaf Goor , Alexander Moller
IPC分类号： B01J29/89 , B01J37/00 , C01B37/00 , C01B34/08 , B01J29/40 , C01B39/36 , C07D301/12 , B01J29/30
CPC分类号： B01J37/0045 , B01J29/89 , C01B37/005 , Y10S423/22
摘要： Granulates which contain titanium silicalite-1 are composed of silicon dioxide, titanium dioxide and titanium silicalite-1 crystals. The granulates can be prepared by spray-drying or spray granulating the crystallization suspension. The granulates may be used as suspension catalysts, such as for the epoxidation of olefins using hydrogen peroxide.
摘要翻译：含钛硅沸石-1的颗粒由二氧化硅，二氧化钛和钛硅沸石-1晶体组成。颗粒可以通过喷雾干燥或喷雾造粒结晶悬浮液来制备。颗粒可以用作悬浮催化剂，例如用于使用过氧化氢的烯烃的环氧化。

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