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1. 发明申请

US20080045690A1 Azetidine Derivatives, Method for Producing Said Derivatives and Use Thereof 失效
标题翻译：氮杂环丁烷衍生物，生产所述衍生物的方法及其用途
公开(公告)号：US20080045690A1
公开(公告)日：2008-02-21
申请号：US10581624
申请日：2004-12-02
申请人： Stefan Ingrisch , Alois Maier , Thomas Pfeuffer , Norbert Steidl , Andrea Gantner , Herbert Winkelmann
发明人： Stefan Ingrisch , Alois Maier , Thomas Pfeuffer , Norbert Steidl , Andrea Gantner , Herbert Winkelmann
IPC分类号： C07D205/04 , C08F8/32 , C08J3/24 , C08K5/3412
CPC分类号： C08F8/30 , C07D205/06
摘要： A description is given of azetidine derivatives and methods for producing them, and of their use as a latent curing component for resins having functional groups which are reactive toward amino groups. The particular advantages of the curing component proposed in accordance with the invention, such as effective producibility, high environmental friendliness, and excellent storage stability of the resin/curing agent mixtures, make these azetidine derivatives outstandingly suitable for one-component, moisture-hardening polymer compositions, which are of special interest in particular for the production of (floor) coatings, sealants, and adhesives.
摘要翻译：给出了氮杂环丁烷衍生物及其生产方法及其作为具有对氨基具有反应性的官能团的树脂的潜在固化组分的用途的描述。根据本发明提出的固化组分的特别优点，例如有效的可生产性，高环境友好性和优异的树脂/固化剂混合物的储存稳定性，使得这些氮杂环丁烷衍生物显着地适用于单组分，湿固化聚合物特别是用于生产（地板）涂料，密封剂和粘合剂的组合物。

2. 发明授权

US07745565B2 Azetidine derivatives, method for producing said derivatives and use thereof 失效
标题翻译：氮杂环丁烷衍生物，所述衍生物的制备方法及其用途
公开(公告)号：US07745565B2
公开(公告)日：2010-06-29
申请号：US10581624
申请日：2004-12-02
申请人： Stefan Ingrisch , Alois Maier , Thomas Pfeuffer , Norbert Steidl , Herbert Winkelmann , Andrea Gantner, legal representative
发明人： Stefan Ingrisch , Alois Maier , Thomas Pfeuffer , Norbert Steidl , Herbert Winkelmann
IPC分类号： C07D205/04
CPC分类号： C08F8/30 , C07D205/06
摘要： A description is given of azetidine derivatives and methods for producing them, and of their use as a latent curing component for resins having functional groups which are reactive toward amino groups. The particular advantages of the curing component proposed in accordance with the invention, such as effective producibility, high environmental friendliness, and excellent storage stability of the resin/curing agent mixtures, make these azetidine derivatives outstandingly suitable for one-component, moisture-hardening polymer compositions, which are of special interest in particular for the production of (floor) coatings, sealants, and adhesives.
摘要翻译：给出了氮杂环丁烷衍生物及其生产方法及其作为具有对氨基具有反应性的官能团的树脂的潜在固化组分的用途的描述。根据本发明提出的固化组分的特别优点，例如有效的可生产性，高环境友好性和优异的树脂/固化剂混合物的储存稳定性，使得这些氮杂环丁烷衍生物显着地适用于单组分，湿固化聚合物特别是用于生产（地板）涂料，密封剂和粘合剂的组合物。

3. 发明申请

US20060194931A1 Use of diazepine derivatives as latent hardening components 审中-公开
标题翻译：二氮杂衍生物作为潜在硬化组分的使用
公开(公告)号：US20060194931A1
公开(公告)日：2006-08-31
申请号：US10555775
申请日：2004-05-05
申请人： Stefan Ingrisch , Alois Maier , Thomas Pfeuffer , Norbert Steidl , Herbert Winkelmann , Fleix Gantner , Andrea Gantner
发明人： Stefan Ingrisch , Alois Maier , Thomas Pfeuffer , Norbert Steidl , Herbert Winkelmann , Fleix Gantner , Andrea Gantner
IPC分类号： C08L63/00 , C08L75/04 , B32B27/00
CPC分类号： C08G18/10 , C08G18/3848 , C08G59/5073 , C08K5/3442 , C08L75/04
摘要： The invention relates to the use of diazepine derivates of general formula (I) and/or (II), wherein R1, R2, R3 and R5 independently represent H, C1-C20-alkyl, C3-C8-cycloakyl, C6-C10-aryl or alkylaryl comprising C1-C4-alkyl and C6-C10-aryl groups, R4═H, C1-C6-alkyl(iden), as latent hardening components for resinous substances comprising functional groups which can react with amines. Based on the particular advantages of the inventive hardening components, such as good producibility, environmentally friendly and having an excellent shelf life of the resin/hardening mixture, said diazepine derivatives are outstanding for single-componented, moisture-hardening polymer masses, which are particularly useful in the production of sealing materials, adhesives and coating materials.
摘要翻译：本发明涉及通式（I）和/或（II）的二氮杂衍生物的用途，其中R 1，R 2，R 3， SUP＆gt;和R 5独立地表示H，C 1 -C 20 - 烷基，C 3 -C 包括C 1 -C 4 - 环烷基，C 6 -C 10 - 芳基或包括C 1 -C 4 - C 1 -C 6烷基和C 6 -C 10 - 芳基，R 4 -H，C 1〜 -C 6 - 烷基（iden），作为包含可与胺反应的官能团的树脂状物质的潜在硬化成分。基于本发明的硬化组分的特别优点，例如良好的可生产性，环境友好并且具有优异的树脂/硬化混合物的保存期限，所述二氮杂衍生物对于单组分，湿润固化的聚合物质量是显着的，特别是可用于生产密封材料，粘合剂和涂料。

4. 发明授权

US07265178B2 Polyurethane-polymer hybrid-dispersion with enhanced surface properties, method for the production and utilization thereof 失效
标题翻译：具有增强表面性能的聚氨酯 - 聚合物杂化分散体，其生产和利用方法
公开(公告)号：US07265178B2
公开(公告)日：2007-09-04
申请号：US10563903
申请日：2004-07-09
申请人： Alois Maier , Stefan Ingrisch , Norbert Steidl , Frank Weinelt
发明人： Alois Maier , Stefan Ingrisch , Norbert Steidl , Frank Weinelt
IPC分类号： C08J3/00 , C08K3/20 , C08L75/00 , C08L83/00 , C08F8/30
CPC分类号： C09D151/08 , C08F283/00 , C08F283/006 , C08F289/00 , C08G18/0819 , C08G18/2885 , C08L51/08 , C08L2666/02 , C09D175/04 , C09J151/08 , Y10T428/31551
摘要： A description is given of an optionally fluorinated polyurethane-polymer hybrid dispersion with enhanced surface properties (low critical surface tensions γc and very high contact angles θ) which is obtainable by a) preparing a dispersion component (binder) based on an aqueous solution or dispersion of an optionally hydroxy- and/or amino-functional polyurethane-polymer hybrid having optionally fluorinated side chains and, if desired, b) subsequently reacting the dispersion component from stage a) with a crosslinker component (D). The polyurethane-polymer hybrid dispersion of the invention can be prepared in solvent-free or low-solvent fashion and with high solids content and requires only a very low level of stabilizing groups.
摘要翻译：给出了具有增强的表面性质（低临界表面张力γ和非常高的接触角θ）的任选氟化的聚氨酯 - 聚合物混合分散体的描述，其可通过以下步骤获得：a）制备分散体组分）基于具有任选氟化侧链的任选羟基和/或氨基官能的聚氨酯 - 聚合物杂化物的水溶液或分散体，如果需要，b）随后使来自a）步的分散体组分与交联剂组分（D ）。本发明的聚氨酯 - 聚合物混合分散体可以以无溶剂或低溶剂方式制备并具有高固体含量，并且仅需要非常低水平的稳定基团。

5. 发明申请

US20060167206A1 Fluorine-modified polyurethane resins containing one or two constituents, method for the production thereof, and use of the same 审中-公开
标题翻译：含有一种或两种成分的氟改性聚氨酯树脂，其制备方法及其用途
公开(公告)号：US20060167206A1
公开(公告)日：2006-07-27
申请号：US10563539
申请日：2004-07-06
申请人： Alois Maier , Norbert Steidl , Stefan Ingrisch , Frank Weinelt
发明人： Alois Maier , Norbert Steidl , Stefan Ingrisch , Frank Weinelt
IPC分类号： C08G18/00
CPC分类号： C08G18/6225 , C08G18/2885 , C08G18/3275 , C08G18/3812 , C08G18/718 , C09D175/04
摘要： A description is given of a fluorine-modified one- or two-component polyurethane resin having improved surface properties, which is obtainable by a) preparing a fluorine-modified polyurethane prepolymer having free isocyanate groups or free amino and/or hydroxyl groups, or a fluorine-modified polyol mixture having free hydroxyl groups (binder), and by b) preparing a fluorine-modified polyurethane resin having a polymer-bonded fluorine content of 1% to 4% by weight in the system as a whole by reacting the fluorine-modified polyurethane prepolymer from stage a3) in the case of a one-component application with atmospheric moisture, or reacting the fluorine-modified polyurethane prepolymer or polyol mixture (binder) in the case of a two-component application with a crosslinker component (D) (curing agent), with a formulating component (F)(ii) in the presence if desired of a solvent component (L)(iii) and also of a catalyst. Through the use of suitable fluorinated macromonomers in the one- or two-component polyurethane resins of the invention it is possible to produce hard coating systems and/or surfaces having very low surface tensions and very high contact angles. Furthermore, the dirt pickup tendency of these polyurethane resins is also significantly reduced as compared with the known prior art.
摘要翻译：对具有改善的表面性质的氟改性单组分或双组分聚氨酯树脂进行描述，其可通过以下步骤获得：a）制备具有游离异氰酸酯基或游离氨基和/或羟基的氟改性聚氨酯预聚物，或具有游离羟基的氟改性多元醇混合物（粘合剂），以及b）通过使该氟改性多元醇混合物中的氟 - 在具有大气湿度的单组分施用的情况下，或者在双组分的情况下使氟改性的聚氨酯预聚物或多元醇混合物（粘合剂）反应，从阶段a 3阶段的改性聚氨酯预聚物）在需要溶剂组分（L）（iii）和催化剂的情况下，用交联剂组分（D）（固化剂）与配制组分（F）（ii）的应用。通过在本发明的单组分或双组分聚氨酯树脂中使用合适的氟化大分子单体，可以生产具有非常低的表面张力和非常高的接触角的硬涂层体系和/或表面。此外，与已知的现有技术相比，这些聚氨酯树脂的污垢吸收趋势也显着降低。

6. 发明申请

US20060189750A1 Polyurethane-polymer hybrid-dispersion with enhanced surface properties, method for the production and utilization thereof 失效
标题翻译：具有增强表面性能的聚氨酯 - 聚合物杂化分散体，其生产和利用方法
公开(公告)号：US20060189750A1
公开(公告)日：2006-08-24
申请号：US10563903
申请日：2004-07-09
申请人： Alois Maier , Stefan Ingrisch , Norbert Steidl , Frank Weinelt
发明人： Alois Maier , Stefan Ingrisch , Norbert Steidl , Frank Weinelt
IPC分类号： C08G18/08
CPC分类号： C09D151/08 , C08F283/00 , C08F283/006 , C08F289/00 , C08G18/0819 , C08G18/2885 , C08L51/08 , C08L2666/02 , C09D175/04 , C09J151/08 , Y10T428/31551
摘要： A description is given of an optionally fluorinated polyurethane-polymer hybrid dispersion with enhanced surface properties (low critical surface tensions γc and very high contact angles θ) which is obtainable by a) preparing a dispersion component (binder) based on an aqueous solution or dispersion of an optionally hydroxy- and/or amino-functional polyurethane-polymer hybrid having optionally fluorinated side chains and, if desired, b) subsequently reacting the dispersion component from stage a) with a crosslinker component (D). The polyurethane-polymer hybrid dispersion of the invention can be prepared in solvent-free or low-solvent fashion and with high solids content and requires only a very low level of stabilizing groups.
摘要翻译：给出了具有增强的表面性质（低临界表面张力γ和非常高的接触角θ）的任选氟化的聚氨酯 - 聚合物混合分散体的描述，其可通过以下步骤获得：a）制备分散体组分）基于具有任选氟化侧链的任选羟基和/或氨基官能的聚氨酯 - 聚合物杂化物的水溶液或分散体，如果需要，b）随后使来自a）步的分散体组分与交联剂组分（D ）。本发明的聚氨酯 - 聚合物混合分散体可以以无溶剂或低溶剂方式制备并具有高固体含量，并且仅需要非常低水平的稳定基团。

7. 发明申请

US20050234191A1 Method for the production of homo-, co- and block copolymers 失效
标题翻译：制备均聚物，共聚物和嵌段共聚物的方法
公开(公告)号：US20050234191A1
公开(公告)日：2005-10-20
申请号：US10515937
申请日：2003-08-01
申请人： Stefan Ingrisch , Maier Alois , Thomas Pfeuffer , Norbert Steidl
发明人： Stefan Ingrisch , Maier Alois , Thomas Pfeuffer , Norbert Steidl
IPC分类号： C08F2/10 , C08F2/38 , C08G63/48 , C08F4/04 , C08G63/91
CPC分类号： C08F2/38 , C08F2/10
摘要： A process is described for producing homo-, co- and block copolymers by controlled radical polymerization in aqueous solution, wherein a monomer component (A) consisting of at least one radically polymerizable monomer, an initiator component (B) consisting of at least one radical initiator, a polysaccharide component (C) consisting of at least one cyclic polysaccharide (derivative) and a regulator component (D) consisting of at least one compound of the general formula (Ia) or/and (Ib) are reacted in the presence of water, in which R1 to R6 can each independently denote hydrogen, an optionally substituted C1-C20 alkyl residue, C3-C8 cycloalkyl residue, C7-C34 aralkyl residue or optionally an aromatic C6-C14 hydrocarbon residue and R2 and R5 can additionally denote polymer residues having an average molecular mass (number average) of 100 to 50,000 Daltons, and at least two but at most four of the residues R1 to R6 represent an aromatic hydrocarbon residue. In this manner it is possible to produce polymers with a very narrow molecular weight distribution. Moreover, due to the much lower amounts of initiator and regulator compared to the prior art, the polymers contain only very small amounts of regulator and initiator decomposition products.
摘要翻译：描述了通过在水溶液中控制自由基聚合制备均聚物，共聚物和嵌段共聚物的方法，其中由至少一种可自由基聚合的单体，由至少一个基团组成的引发剂组分（B）组成的单体组分（A）引发剂，由至少一种环状多糖（衍生物）组成的多糖组分（C）和由至少一种通式（Ia）或/和（Ib）的化合物组成的调节剂组分（D）在存在下反应水，其中R 1至R 6可各自独立地表示氢，任选取代的C 1 -C 20 烷基残基，C 3 -C 8环烷基残基，C 7 -C 34芳烷基残基或任选地芳族C 6 -C 14烃残基和R 2和R 5可另外表示具有平均值的聚合物残基分子量（数均）为100〜50,000道尔顿，并且至少两个但最多四个残基R 1至R 6代表芳烃残基。以这种方式，可以生产具有非常窄的分子量分布的聚合物。此外，由于与现有技术相比，引发剂和调节剂的量低得多，所以聚合物仅含有非常少量的调节剂和引发剂分解产物。

8. 发明申请

US20090054588A1 Fluoride-modified additive for cementitious products, process for its preparation and use thereof 审中-公开
标题翻译：用于水泥质产品的氟化物改性添加剂，其制备方法和用途
公开(公告)号：US20090054588A1
公开(公告)日：2009-02-26
申请号：US12279605
申请日：2007-03-09
申请人： Alois Maier , Norbert Steidl , Johann Huber , Christian Huber , Marita Staudhammer
发明人： Alois Maier , Norbert Steidl , Johann Huber , Christian Huber , Marita Staudhammer
IPC分类号： C04B28/02
CPC分类号： C08G18/2885 , C04B24/282 , C04B24/288 , C04B24/32 , C04B28/04 , C04B2111/203 , C04B2111/2038 , C04B2111/25 , C04B2111/26 , C04B2111/27 , C08G18/10 , C08G18/283 , C08G18/36 , C08G18/792 , C08G18/8051 , Y02W30/92 , C04B14/06 , C04B18/08 , C04B20/0076 , C04B24/267 , C08G18/302
摘要： A fluoromodified admixture containing isocyanate and urethane and/or urea groups is described. Surprisingly, it has been found that the fluoromodified admixture according to the invention is outstandingly suitable even at a very low dosage for the permanent hydrophobic and/or oleophobic and/or dirt-repellent in-bulk finishing of products based on inorganic or hydraulic or mineral binders, without the fundamental property profile (e.g. compressive and flexural tensile strengths) of these products being substantially influenced. Moreover, it was not to be foreseen that in the case of the products treated with the fluoromodified admixtures according to the invention (e.g. hardened building material compositions) a markedly lower water absorption (avoidance of frost damage and corrosion) and a suppression of bleeding on the surfaces (avoidance of visual impairment) are to be observed. Furthermore, it could not be expected that in spite of the high fluorine modification an adequate self-dispersibility is afforded.
摘要翻译：描述了含有异氰酸酯和氨基甲酸酯和/或脲基团的氟改性混合物。令人惊奇的是，已经发现，基于无机或水力或矿物质的产品，即使在非常低的剂量下，基于无机或水力或矿物的产品的永久性疏水和/或疏油和/或污垢排斥的整体加工，本发明的氟改性混合物是显着的没有基本影响的这些产品的基本性质（例如压缩和弯曲拉伸强度）的粘合剂。此外，不要指出，在使用根据本发明的含氟改性混合物处理的产品（例如硬化的建筑材料组合物）的情况下，显着降低吸水率（避免霜冻损伤和腐蚀）和抑制出血要观察表面（避免视力损伤）。此外，不能指望尽管氟改性高，但仍具有足够的自分散性。

9. 发明申请

US20100285311A1 Dual component (aqueous) hybrid reactive resin system, method for production and use thereof 审中-公开
标题翻译：双组分（水性）混合反应性树脂体系，其生产和使用方法
公开(公告)号：US20100285311A1
公开(公告)日：2010-11-11
申请号：US12279081
申请日：2007-04-03
申请人： Norbert Steidl , Alois Maier , Michael Schroers , Roswitha Waldherr
发明人： Norbert Steidl , Alois Maier , Michael Schroers , Roswitha Waldherr
IPC分类号： B32B27/38 , C08L75/04 , C04B28/00 , C08K3/22 , C08K3/30 , C08K5/12 , C08K5/11 , C08K5/101 , C08K5/357 , B32B27/06 , B32B13/12
CPC分类号： C08G18/2845 , C08G18/4244 , C09D163/00 , Y10T428/269 , Y10T428/273 , Y10T428/31511 , Y10T428/31525 , Y10T428/31529 , C08L2666/14
摘要： A dual component (aqueous) hybrid reactive system obtained by a) the production of an epoxy-functional (aqueous) binding agent component (I) with an epoxide equivalent of 100 to 12,500 g/eq, and average molecular mass of 200 to 25,000 Daltons and a viscosity of 1,000 to 15,000 mPas 920° C., Brookfield) and b) the production of a (latent) amino-functional hardener component (II).
摘要翻译：通过以下方法获得的双组分（水性）混合反应体系：a）制备环氧官能（水性）结合剂组分（I），其环氧当量为100至12,500g / eq，平均分子量为200至25,000道尔顿粘度为1000至15,000mPas 920℃，Brookfield）和b）（潜伏）氨基官能的硬化剂组分（II）的生产。

10. 发明授权

US07501472B2 Aqueous fluoromodified polyurethane system for anti-graffiti and anti-soiling coatings 失效
标题翻译：水性氟改性聚氨酯体系，用于防涂鸦和防污涂料
公开(公告)号：US07501472B2
公开(公告)日：2009-03-10
申请号：US10485617
申请日：2003-02-26
申请人： Norbert Steidl , Alois Maier , Franz Wolfertstetter , Wolfgang Hiller , Rupert Stadler
发明人： Norbert Steidl , Alois Maier , Franz Wolfertstetter , Wolfgang Hiller , Rupert Stadler
IPC分类号： C08J3/03 , C08G18/10 , C08G18/12 , C08G18/32 , C09D175/04
CPC分类号： C09D175/04 , C08F283/006 , C08G18/0823 , C08G18/12 , C08G18/2885 , C08G18/3275 , C08G18/3812 , C08G18/44 , C08G18/6659 , C08G18/3271
摘要： An aqueous fluoromodified polyurethane system for one- or two-component anti-graffiti and anti-soiling coatings is prepared by (a) preparing a binder component based on an aqueous solution or dispersion of optionally hydroxy- and/or amino-functional oligourethanes and/or polyurethanes having fluorinated side chains, and, optionally, (b) subsequently reacting the binder component with a crosslinker.
摘要翻译：通过（a）基于任选的羟基和/或氨基官能的低聚氨酯和/或氨基官能的低聚氨酯的水溶液或分散体制备粘合剂组分来制备用于单组分或双组分防涂层和防污涂料的含水氟改性聚氨酯体系和/ 或具有氟化侧链的聚氨酯，和任选地（b）随后使粘合剂组分与交联剂反应。

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