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1. 发明申请

US20090054588A1 Fluoride-modified additive for cementitious products, process for its preparation and use thereof 审中-公开
标题翻译：用于水泥质产品的氟化物改性添加剂，其制备方法和用途
公开(公告)号：US20090054588A1
公开(公告)日：2009-02-26
申请号：US12279605
申请日：2007-03-09
申请人： Alois Maier , Norbert Steidl , Johann Huber , Christian Huber , Marita Staudhammer
发明人： Alois Maier , Norbert Steidl , Johann Huber , Christian Huber , Marita Staudhammer
IPC分类号： C04B28/02
CPC分类号： C08G18/2885 , C04B24/282 , C04B24/288 , C04B24/32 , C04B28/04 , C04B2111/203 , C04B2111/2038 , C04B2111/25 , C04B2111/26 , C04B2111/27 , C08G18/10 , C08G18/283 , C08G18/36 , C08G18/792 , C08G18/8051 , Y02W30/92 , C04B14/06 , C04B18/08 , C04B20/0076 , C04B24/267 , C08G18/302
摘要： A fluoromodified admixture containing isocyanate and urethane and/or urea groups is described. Surprisingly, it has been found that the fluoromodified admixture according to the invention is outstandingly suitable even at a very low dosage for the permanent hydrophobic and/or oleophobic and/or dirt-repellent in-bulk finishing of products based on inorganic or hydraulic or mineral binders, without the fundamental property profile (e.g. compressive and flexural tensile strengths) of these products being substantially influenced. Moreover, it was not to be foreseen that in the case of the products treated with the fluoromodified admixtures according to the invention (e.g. hardened building material compositions) a markedly lower water absorption (avoidance of frost damage and corrosion) and a suppression of bleeding on the surfaces (avoidance of visual impairment) are to be observed. Furthermore, it could not be expected that in spite of the high fluorine modification an adequate self-dispersibility is afforded.
摘要翻译：描述了含有异氰酸酯和氨基甲酸酯和/或脲基团的氟改性混合物。令人惊奇的是，已经发现，基于无机或水力或矿物质的产品，即使在非常低的剂量下，基于无机或水力或矿物的产品的永久性疏水和/或疏油和/或污垢排斥的整体加工，本发明的氟改性混合物是显着的没有基本影响的这些产品的基本性质（例如压缩和弯曲拉伸强度）的粘合剂。此外，不要指出，在使用根据本发明的含氟改性混合物处理的产品（例如硬化的建筑材料组合物）的情况下，显着降低吸水率（避免霜冻损伤和腐蚀）和抑制出血要观察表面（避免视力损伤）。此外，不能指望尽管氟改性高，但仍具有足够的自分散性。

2. 发明申请

US20090240004A1 FUNCTIONALIZED POLYURETHANE RESIN, METHOD FOR THE PRODUCTION THEREOF, AND USE THEREOF 审中-公开
标题翻译：功能性聚氨酯树脂，其生产方法及其用途
公开(公告)号：US20090240004A1
公开(公告)日：2009-09-24
申请号：US12441589
申请日：2007-09-04
申请人： Alois Maier , Norbert Steidl , Christian Huber , Helmut Mack , Johann Huber , Thomas Schuhbeck , Franz Wolfertetter
发明人： Alois Maier , Norbert Steidl , Christian Huber , Helmut Mack , Johann Huber , Thomas Schuhbeck , Franz Wolfertetter
IPC分类号： C08G71/04
CPC分类号： C08G18/3812 , C08G18/0823 , C08G18/10 , C08G18/2885 , C08G18/792 , C09D175/04 , D21H27/26 , C08G18/3275 , C08G18/2865
摘要： Disclosed is a functionalized polyurethane resin containing a binder component, a hardener component and, optionally, a formulation component. The binder component consists essentially of urethane dispersions with defined structural components which, in turn, consist of special reaction products. Such polyurethane resins are used for the production of fluorine-modified polyurethane coatings and generally in construction or industrial applications for the permanent oil-, water- and dirt-resistant coating of mineral and non-mineral surfaces on the basis of, for example, hydraulically setting components.
摘要翻译：公开了含有粘合剂组分，硬化剂组分和任选的制剂组分的官能化聚氨酯树脂。粘合剂组分基本上由具有限定结构组分的氨基甲酸酯分散体组成，其又由特殊的反应产物组成。这种聚氨酯树脂用于生产氟改性聚氨酯涂料，一般用于建筑或工业应用中，用于矿物和非矿物表面的永久性耐油，防水和防污涂层，例如基于液压设置组件。

3. 发明授权

US07414092B2 Electrosterically stabilized aqueous polyurethane resins, method for the production thereof, and use thereof 失效
标题翻译：电化学稳定的水性聚氨酯树脂，其制备方法及其用途
公开(公告)号：US07414092B2
公开(公告)日：2008-08-19
申请号：US10551526
申请日：2004-04-01
申请人： Norbert Steidl , Alois Maier , Franz Wolfertstetter , Christian Huber , Sascha Raspl
发明人： Norbert Steidl , Alois Maier , Franz Wolfertstetter , Christian Huber , Sascha Raspl
IPC分类号： C08J3/00 , C08K3/20 , C08L75/00
CPC分类号： C08G18/12 , C08G18/0823 , C08G18/283 , C08G18/3275 , C08G18/4854 , C08G18/6692 , C09D175/04 , C08G18/50
摘要： Stabilized polyurethane resins and methods for their preparation are disclosed.
摘要翻译：公开了稳定的聚氨酯树脂及其制备方法。

4. 发明申请

US20060205869A1 Electrosterically stabilized aqueous polyurethane resins, method for the production thereof, and use thereof 失效
公开(公告)号：US20060205869A1
公开(公告)日：2006-09-14
申请号：US10551526
申请日：2004-04-01
申请人： Norbert Steidl , Alois Maier , Franz Wolferstetter , Christian Huber , Sascha Raspl
发明人： Norbert Steidl , Alois Maier , Franz Wolferstetter , Christian Huber , Sascha Raspl
IPC分类号： C08G18/08
CPC分类号： C08G18/12 , C08G18/0823 , C08G18/283 , C08G18/3275 , C08G18/4854 , C08G18/6692 , C09D175/04 , C08G18/50
摘要： A description is given of electrosterically stabilized polyurethane resins having an improved profile of properties, obtainable by a) preparing a hydrophilic and solvent-free macromonomer (A)(ii) with monomodal molecular mass distribution, by a1)reacting 50 to 100 parts by weight of a hydrophilic alkyl- or arylpolyalkylene glycol (A)(i) with 1 to 100 parts by weight of a polyisocyanate component (B)(i) optionally in the presence of a catalyst in the absence of solvents, and subsequently a2) reacting the uniform preadduct from stage a1) completely with 0.5 to 200 parts by weight of a compound (C) in the absence of solvents, and b) by preparing the polyurethane dispersion, by b1)reacting 2 to 50 parts by weight of the hydrophilic and solvent-free macromonomer (A)(ii) with 25 to 250 parts by weight of the polyisocyanate component (B)(i), optionally in the presence of 0 to 50 parts by weight of a solvent component (D) and also of a catalyst, b2) reacting the polyurethane preadduct from stage b1) with 50 to 100 parts by weight of a polymeric polyol (A)(iii) and optionally with 0.5 to 10 parts by weight of a low molecular mass polyol component (A)(iv), optionally in the presence of a catalyst, b3)reacting the homogeneous polyurethane preadduct from stage b2) with 2 to 20 parts by weight of a polyol component (A)(v), optionally in the presence of a catalyst, b4) admixing the homogeneous polyurethane prepolymer from stage b3), before or during dispersion in 50 to 1500 parts by weight of water, with 2 to 20 parts by weight of a neutralizing component (E), b5)dispersing the optionally (partially) neutralized polyurethane prepolymer from stage b4) in 50 to 1500 parts by weight of water, which optionally further contains 0 to 100 parts by weight of a formulating component (F), and finally b6)reacting the (partially) neutralized polyurethane prepolymer dispersion from stage b5) with 3 to 60 parts by weight of a chain extender component (G) and also, subsequently or simultaneously, with 0 to 30 parts by weight of a chain stopper component (H). The performance properties of the polyurethane dispersions of the invention in terms of absence of solvent, and also material properties, are excellent. Also deserving of emphasis are the simplicity and reproducibility of the process and the storage stability of the products.

5. 发明申请

US20080045690A1 Azetidine Derivatives, Method for Producing Said Derivatives and Use Thereof 失效
标题翻译：氮杂环丁烷衍生物，生产所述衍生物的方法及其用途
公开(公告)号：US20080045690A1
公开(公告)日：2008-02-21
申请号：US10581624
申请日：2004-12-02
申请人： Stefan Ingrisch , Alois Maier , Thomas Pfeuffer , Norbert Steidl , Andrea Gantner , Herbert Winkelmann
发明人： Stefan Ingrisch , Alois Maier , Thomas Pfeuffer , Norbert Steidl , Andrea Gantner , Herbert Winkelmann
IPC分类号： C07D205/04 , C08F8/32 , C08J3/24 , C08K5/3412
CPC分类号： C08F8/30 , C07D205/06
摘要： A description is given of azetidine derivatives and methods for producing them, and of their use as a latent curing component for resins having functional groups which are reactive toward amino groups. The particular advantages of the curing component proposed in accordance with the invention, such as effective producibility, high environmental friendliness, and excellent storage stability of the resin/curing agent mixtures, make these azetidine derivatives outstandingly suitable for one-component, moisture-hardening polymer compositions, which are of special interest in particular for the production of (floor) coatings, sealants, and adhesives.
摘要翻译：给出了氮杂环丁烷衍生物及其生产方法及其作为具有对氨基具有反应性的官能团的树脂的潜在固化组分的用途的描述。根据本发明提出的固化组分的特别优点，例如有效的可生产性，高环境友好性和优异的树脂/固化剂混合物的储存稳定性，使得这些氮杂环丁烷衍生物显着地适用于单组分，湿固化聚合物特别是用于生产（地板）涂料，密封剂和粘合剂的组合物。

6. 发明授权

US07265178B2 Polyurethane-polymer hybrid-dispersion with enhanced surface properties, method for the production and utilization thereof 失效
标题翻译：具有增强表面性能的聚氨酯 - 聚合物杂化分散体，其生产和利用方法
公开(公告)号：US07265178B2
公开(公告)日：2007-09-04
申请号：US10563903
申请日：2004-07-09
申请人： Alois Maier , Stefan Ingrisch , Norbert Steidl , Frank Weinelt
发明人： Alois Maier , Stefan Ingrisch , Norbert Steidl , Frank Weinelt
IPC分类号： C08J3/00 , C08K3/20 , C08L75/00 , C08L83/00 , C08F8/30
CPC分类号： C09D151/08 , C08F283/00 , C08F283/006 , C08F289/00 , C08G18/0819 , C08G18/2885 , C08L51/08 , C08L2666/02 , C09D175/04 , C09J151/08 , Y10T428/31551
摘要： A description is given of an optionally fluorinated polyurethane-polymer hybrid dispersion with enhanced surface properties (low critical surface tensions γc and very high contact angles θ) which is obtainable by a) preparing a dispersion component (binder) based on an aqueous solution or dispersion of an optionally hydroxy- and/or amino-functional polyurethane-polymer hybrid having optionally fluorinated side chains and, if desired, b) subsequently reacting the dispersion component from stage a) with a crosslinker component (D). The polyurethane-polymer hybrid dispersion of the invention can be prepared in solvent-free or low-solvent fashion and with high solids content and requires only a very low level of stabilizing groups.
摘要翻译：给出了具有增强的表面性质（低临界表面张力γ和非常高的接触角θ）的任选氟化的聚氨酯 - 聚合物混合分散体的描述，其可通过以下步骤获得：a）制备分散体组分）基于具有任选氟化侧链的任选羟基和/或氨基官能的聚氨酯 - 聚合物杂化物的水溶液或分散体，如果需要，b）随后使来自a）步的分散体组分与交联剂组分（D ）。本发明的聚氨酯 - 聚合物混合分散体可以以无溶剂或低溶剂方式制备并具有高固体含量，并且仅需要非常低水平的稳定基团。

7. 发明申请

US20060167206A1 Fluorine-modified polyurethane resins containing one or two constituents, method for the production thereof, and use of the same 审中-公开
标题翻译：含有一种或两种成分的氟改性聚氨酯树脂，其制备方法及其用途
公开(公告)号：US20060167206A1
公开(公告)日：2006-07-27
申请号：US10563539
申请日：2004-07-06
申请人： Alois Maier , Norbert Steidl , Stefan Ingrisch , Frank Weinelt
发明人： Alois Maier , Norbert Steidl , Stefan Ingrisch , Frank Weinelt
IPC分类号： C08G18/00
CPC分类号： C08G18/6225 , C08G18/2885 , C08G18/3275 , C08G18/3812 , C08G18/718 , C09D175/04
摘要： A description is given of a fluorine-modified one- or two-component polyurethane resin having improved surface properties, which is obtainable by a) preparing a fluorine-modified polyurethane prepolymer having free isocyanate groups or free amino and/or hydroxyl groups, or a fluorine-modified polyol mixture having free hydroxyl groups (binder), and by b) preparing a fluorine-modified polyurethane resin having a polymer-bonded fluorine content of 1% to 4% by weight in the system as a whole by reacting the fluorine-modified polyurethane prepolymer from stage a3) in the case of a one-component application with atmospheric moisture, or reacting the fluorine-modified polyurethane prepolymer or polyol mixture (binder) in the case of a two-component application with a crosslinker component (D) (curing agent), with a formulating component (F)(ii) in the presence if desired of a solvent component (L)(iii) and also of a catalyst. Through the use of suitable fluorinated macromonomers in the one- or two-component polyurethane resins of the invention it is possible to produce hard coating systems and/or surfaces having very low surface tensions and very high contact angles. Furthermore, the dirt pickup tendency of these polyurethane resins is also significantly reduced as compared with the known prior art.
摘要翻译：对具有改善的表面性质的氟改性单组分或双组分聚氨酯树脂进行描述，其可通过以下步骤获得：a）制备具有游离异氰酸酯基或游离氨基和/或羟基的氟改性聚氨酯预聚物，或具有游离羟基的氟改性多元醇混合物（粘合剂），以及b）通过使该氟改性多元醇混合物中的氟 - 在具有大气湿度的单组分施用的情况下，或者在双组分的情况下使氟改性的聚氨酯预聚物或多元醇混合物（粘合剂）反应，从阶段a 3阶段的改性聚氨酯预聚物）在需要溶剂组分（L）（iii）和催化剂的情况下，用交联剂组分（D）（固化剂）与配制组分（F）（ii）的应用。通过在本发明的单组分或双组分聚氨酯树脂中使用合适的氟化大分子单体，可以生产具有非常低的表面张力和非常高的接触角的硬涂层体系和/或表面。此外，与已知的现有技术相比，这些聚氨酯树脂的污垢吸收趋势也显着降低。

8. 发明申请

US20100285311A1 Dual component (aqueous) hybrid reactive resin system, method for production and use thereof 审中-公开
标题翻译：双组分（水性）混合反应性树脂体系，其生产和使用方法
公开(公告)号：US20100285311A1
公开(公告)日：2010-11-11
申请号：US12279081
申请日：2007-04-03
申请人： Norbert Steidl , Alois Maier , Michael Schroers , Roswitha Waldherr
发明人： Norbert Steidl , Alois Maier , Michael Schroers , Roswitha Waldherr
IPC分类号： B32B27/38 , C08L75/04 , C04B28/00 , C08K3/22 , C08K3/30 , C08K5/12 , C08K5/11 , C08K5/101 , C08K5/357 , B32B27/06 , B32B13/12
CPC分类号： C08G18/2845 , C08G18/4244 , C09D163/00 , Y10T428/269 , Y10T428/273 , Y10T428/31511 , Y10T428/31525 , Y10T428/31529 , C08L2666/14
摘要： A dual component (aqueous) hybrid reactive system obtained by a) the production of an epoxy-functional (aqueous) binding agent component (I) with an epoxide equivalent of 100 to 12,500 g/eq, and average molecular mass of 200 to 25,000 Daltons and a viscosity of 1,000 to 15,000 mPas 920° C., Brookfield) and b) the production of a (latent) amino-functional hardener component (II).
摘要翻译：通过以下方法获得的双组分（水性）混合反应体系：a）制备环氧官能（水性）结合剂组分（I），其环氧当量为100至12,500g / eq，平均分子量为200至25,000道尔顿粘度为1000至15,000mPas 920℃，Brookfield）和b）（潜伏）氨基官能的硬化剂组分（II）的生产。

9. 发明授权

US07501472B2 Aqueous fluoromodified polyurethane system for anti-graffiti and anti-soiling coatings 失效
标题翻译：水性氟改性聚氨酯体系，用于防涂鸦和防污涂料
公开(公告)号：US07501472B2
公开(公告)日：2009-03-10
申请号：US10485617
申请日：2003-02-26
申请人： Norbert Steidl , Alois Maier , Franz Wolfertstetter , Wolfgang Hiller , Rupert Stadler
发明人： Norbert Steidl , Alois Maier , Franz Wolfertstetter , Wolfgang Hiller , Rupert Stadler
IPC分类号： C08J3/03 , C08G18/10 , C08G18/12 , C08G18/32 , C09D175/04
CPC分类号： C09D175/04 , C08F283/006 , C08G18/0823 , C08G18/12 , C08G18/2885 , C08G18/3275 , C08G18/3812 , C08G18/44 , C08G18/6659 , C08G18/3271
摘要： An aqueous fluoromodified polyurethane system for one- or two-component anti-graffiti and anti-soiling coatings is prepared by (a) preparing a binder component based on an aqueous solution or dispersion of optionally hydroxy- and/or amino-functional oligourethanes and/or polyurethanes having fluorinated side chains, and, optionally, (b) subsequently reacting the binder component with a crosslinker.
摘要翻译：通过（a）基于任选的羟基和/或氨基官能的低聚氨酯和/或氨基官能的低聚氨酯的水溶液或分散体制备粘合剂组分来制备用于单组分或双组分防涂层和防污涂料的含水氟改性聚氨酯体系和/ 或具有氟化侧链的聚氨酯，和任选地（b）随后使粘合剂组分与交联剂反应。

10. 发明申请

US20050027092A1 Aqueous, highly cross-linked two-component polyurethane coating system, method for the production and use thereof 有权
标题翻译：水性高交联双组分聚氨酯涂料体系，其制备和使用方法
公开(公告)号：US20050027092A1
公开(公告)日：2005-02-03
申请号：US10830743
申请日：2004-04-23
申请人： Norbert Steidl , Alois Maier , Franz Wolfertstetter
发明人： Norbert Steidl , Alois Maier , Franz Wolfertstetter
IPC分类号： C08G18/08 , C08G18/12 , C08G18/42 , C08G18/44 , C08G18/66 , C09D175/04 , C08G18/00
CPC分类号： C09D175/04 , C08G18/0823 , C08G18/12 , C08G18/4277 , C08G18/44 , C08G18/6659 , C08G18/792 , C08G18/3206 , C08G18/3275 , C08G18/348
摘要： An aqueous highly cross-linked two-component polyurethane coating system is described with reduced hydrophilicity and improved resistance to chemicals which can be obtained by a) producing a binder component based on an aqueous solution or dispersion of low-molecular hydroxyfunctional and/or aminofunctional oligourethanes or polyurethanes and b) by subsequently reacting the binder component a) with a cross-linking component (H) in a ratio of 3:1 to 5:1, wherein water-dispersible polyisocyanates are used as the cross-linking component (H).
摘要翻译：描述了一种水性高度交联的双组分聚氨酯涂料体系，其具有降低的亲水性和改善的抗化学药品性能，其可以通过以下方式获得：a）基于低分子量羟基官能团和/或氨基官能低聚氨酯的水溶液或分散体生产粘合剂组分或聚氨酯，和b）通过随后使粘合剂组分a）与3:1至5:1的比例的交联组分（H）反应，其中使用水分散性多异氰酸酯作为交联组分（H）。

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