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1. 发明申请

US20060025644A1 Conversion of oxygenates to olefins 有权
标题翻译：含氧化合物转化为烯烃
公开(公告)号：US20060025644A1
公开(公告)日：2006-02-02
申请号：US10903717
申请日：2004-07-30
申请人： Shun Fung , Doron Levin , Jose Santiesteban , Nicolas Coute
发明人： Shun Fung , Doron Levin , Jose Santiesteban , Nicolas Coute
IPC分类号： C07C1/00
CPC分类号： C10G3/62 , C10G3/42 , C10G3/48 , C10G3/49 , C10G3/55 , C10G2300/708 , C10G2400/20 , Y02P30/20 , Y02P30/40 , Y02P30/42
摘要： A process is described for converting an oxygenate-containing feedstock into one or more olefins in a moving bed reactor system operating in countercurrent flow using a catalyst composition comprising a molecular sieve and at least one metal oxide having an uptake of carbon dioxide at 100° C. of at least 0.03 mg/m2 of the metal oxide.
摘要翻译：描述了一种用于使用包含分子筛和至少一种在100℃摄入二氧化碳的金属氧化物的催化剂组合物将逆境流反应器中的含氧化合物原料转化为一种或多种烯烃的方法至少为0.03mg / m 2的金属氧化物。

2. 发明申请

US20060025646A1 Conversion of oxygenates to olefins 有权
标题翻译：含氧化合物转化为烯烃
公开(公告)号：US20060025646A1
公开(公告)日：2006-02-02
申请号：US10909014
申请日：2004-07-30
申请人： Shun Fung , Doron Levin , Jose Santiesteban , Nicolas Coute
发明人： Shun Fung , Doron Levin , Jose Santiesteban , Nicolas Coute
IPC分类号： C07C1/00
CPC分类号： C07C1/20 , B01J23/10 , B01J29/85 , B01J29/90 , B01J38/30 , C10G3/42 , C10G3/48 , C10G3/49 , C10G3/57 , C10G3/62 , C10G2300/708 , C10G2400/20 , Y02P20/584 , Y02P30/20 , Y02P30/40 , C07C11/02
摘要： A process is described for converting an oxygenate-containing feedstock into one or more olefins in which the feedstock is contacted in a reaction zone with a fluidized bed of a particulate catalyst composition comprising a molecular sieve and at least one metal oxide having an uptake of carbon dioxide at 100° C. of at least 0.03 mg/m2 of the metal oxide whereby at least part of the feedstock is converted into a product stream comprising one or more olefins and a carbonaceous material is deposited on the catalyst composition to produce a coked catalyst composition. The coked catalyst composition is separated from the product stream and divided into at least first and second portions. The first portion of the coked catalyst composition is contacted with a regeneration medium in a regeneration zone under conditions to remove at least part of the carbonaceous material from the coked catalyst composition and produce a regenerated catalyst composition, which is subsequently recycled to the reaction zone. The second portion of the coked catalyst composition is also recycled to the reaction zone but without being initially contacted with a regeneration medium.
摘要翻译：描述了一种用于将含氧化合物的原料转化成一种或多种烯烃，其中原料在反应区中与包含分子筛和至少一种具有碳吸收性的金属氧化物的颗粒催化剂组合物的流化床接触的烯烃二氧化碳在100℃下为至少0.03mg / m 2的金属氧化物，由此至少部分原料转化为包含一种或多种烯烃的产物流，并将碳质材料沉积在用于生产焦化催化剂组合物的催化剂组合物。将焦炭催化剂组合物与产物流分离并分成至少第一和第二部分。焦化催化剂组合物的第一部分与再生区中的再生介质接触，在从焦炭催化剂组合物中除去至少一部分含碳材料的条件下，并产生再生的催化剂组合物，随后再循环到反应区。焦炭催化剂组合物的第二部分也被循环到反应区，但不最初与再生介质接触。

3. 发明申请

US20060025645A1 Conversion of oxygenates to olefins 有权
标题翻译：含氧化合物转化为烯烃
公开(公告)号：US20060025645A1
公开(公告)日：2006-02-02
申请号：US10909012
申请日：2004-07-30
申请人： Shun Fung , Doron Levin , Jose Santiesteban , Nicolas Coute
发明人： Shun Fung , Doron Levin , Jose Santiesteban , Nicolas Coute
IPC分类号： C07C1/00
CPC分类号： C07C1/20 , C07C2521/04 , C07C2521/06 , C07C2521/10 , C07C2521/16 , C07C2523/02 , C07C2523/10 , C07C2529/70 , C07C2529/85 , Y02P20/584 , C07C11/02
摘要： A process is described for converting an oxygenate-containing feedstock into one or more olefins in a reactor system including a plurality of fixed bed reactors each containing a catalyst composition comprising a molecular sieve and at least one metal oxide having an uptake of carbon dioxide at 100° C. of at least 0.03 mg/m2 of the metal oxide. Each reactor is sequentially rotated between at least one operating mode, wherein the catalyst composition in the reactor is contacted with the oxygenate-containing feedstock, and a regeneration mode, wherein the catalyst composition in the reactor is contacted with a regeneration medium.
摘要翻译：描述了一种在含有含氧化合物的原料转化为一种或多种烯烃的方法，该反应器系统包括多个固定床反应器，每个反应器均含有包含分子筛和至少一种二氧化碳吸收量的至少一种金属氧化物，至少为0.03mg / m 2的金属氧化物。每个反应器在至少一个操作模式之间依次旋转，其中反应器中的催化剂组合物与含氧化合物的原料接触，再生模式，其中反应器中的催化剂组合物与再生介质接触。

4. 发明申请

US20060270881A1 Multi-component molecular sieve catalyst compositions and their use in aromatics reactions 有权
公开(公告)号：US20060270881A1
公开(公告)日：2006-11-30
申请号：US11392804
申请日：2006-03-29
申请人： Jihad Dakka , James Vartuli , John Buchanan , Jose Santiesteban , Doron Levin , Lorenzo DeCaul
发明人： Jihad Dakka , James Vartuli , John Buchanan , Jose Santiesteban , Doron Levin , Lorenzo DeCaul
IPC分类号： C07C2/68
CPC分类号： B01J37/0009 , B01J21/06 , B01J21/066 , B01J23/10 , B01J29/06 , B01J29/40 , B01J29/82 , B01J35/0006 , B01J35/002 , B01J37/03 , B01J2229/20 , B01J2229/32 , B01J2229/36 , B01J2229/42 , C07C2/864 , C07C2521/06 , C07C2523/10 , Y02P20/52 , C07C15/08
摘要： The invention relates to a process for producing alkylated aromatic hydrocarbons, preferably with an oxygen or sulfur containing alkylating agent, in the presence of a multi-component molecular sieve catalyst composition that includes a molecular sieve and an active metal oxide. The invention is also directed to methods of making and formulating the multi-component molecular sieve catalyst composition useful in producing alkylated aromatics.

5. 发明申请

US20080086018A1 Process For Producing Phenol And Methyl Ethyl Ketone 失效
标题翻译：生产苯酚和甲基乙基酮的方法
公开(公告)号：US20080086018A1
公开(公告)日：2008-04-10
申请号：US11660065
申请日：2005-08-05
申请人： Jane Cheng , John Buchanan , Doron Levin , Michael Steckel , Jihad Dakka , James Stokes , John Robbins , Jon Stanat , Charles Smith , Jose Santiesteban
发明人： Jane Cheng , John Buchanan , Doron Levin , Michael Steckel , Jihad Dakka , James Stokes , John Robbins , Jon Stanat , Charles Smith , Jose Santiesteban
IPC分类号： C07C45/00
CPC分类号： C07C37/08 , C07C45/53 , C07C409/08 , C07C2529/70 , Y02P20/127 , Y02P20/52 , C07C49/10 , C07C39/04
摘要： A process for producing phenol and methyl ethyl ketone comprises contacting benzene with a C4 alkylating agent under alkylation conditions with catalyst comprising zeolite beta or a molecular sieve having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstrom to produce an alkylation effluent comprising sec-butylbenzene. The sec-butylbenzene is then oxidized to produce a hydroperoxide and the hydroperoxide is decomposed to produce phenol and methyl ethyl ketone.
摘要翻译：一种生产苯酚和甲基乙基酮的方法包括在烷基化条件下使苯与C 4烷基化试剂在含沸石β的催化剂或具有包括d间距最大值的X射线衍射图谱的分子筛上接触 12.4±0.25,6.9±0.15,3.57±0.07和3.42±0.07埃，以产生包含仲丁基苯的烷基化流出物。然后将仲丁基苯氧化生成氢过氧化物，氢过氧化物分解生成苯酚和甲基乙基酮。

6. 发明授权

US07199278B2 Conversion of oxygenates to olefins 有权
标题翻译：含氧化合物转化为烯烃
公开(公告)号：US07199278B2
公开(公告)日：2007-04-03
申请号：US10903717
申请日：2004-07-30
申请人： Shun Chong Fung , Doron Levin , Jose Santiesteban , Nicolas P. Coute
发明人： Shun Chong Fung , Doron Levin , Jose Santiesteban , Nicolas P. Coute
IPC分类号： C07C1/00
CPC分类号： C10G3/62 , C10G3/42 , C10G3/48 , C10G3/49 , C10G3/55 , C10G2300/708 , C10G2400/20 , Y02P30/20 , Y02P30/40 , Y02P30/42
摘要： A process is described for converting an oxygenate-containing feedstock into one or more olefins in a moving bed reactor system operating in countercurrent flow using a catalyst composition comprising a molecular sieve and at least one metal oxide having an uptake of carbon dioxide at 100° C. of at least 0.03 mg/m2 of the metal oxide.
摘要翻译：描述了一种用于使用包含分子筛和至少一种在100℃摄入二氧化碳的金属氧化物的催化剂组合物将逆境流反应器中的含氧化合物原料转化为一种或多种烯烃的方法至少为0.03mg / m 2的金属氧化物。

7. 发明授权

US07186875B2 Conversion of oxygenates to olefins 有权
标题翻译：含氧化合物转化为烯烃
公开(公告)号：US07186875B2
公开(公告)日：2007-03-06
申请号：US10909012
申请日：2004-07-30
申请人： Shun Chong Fung , Doron Levin , Jose Santiesteban , Nicolas P. Coute
发明人： Shun Chong Fung , Doron Levin , Jose Santiesteban , Nicolas P. Coute
IPC分类号： C07C1/00
CPC分类号： C07C1/20 , C07C2521/04 , C07C2521/06 , C07C2521/10 , C07C2521/16 , C07C2523/02 , C07C2523/10 , C07C2529/70 , C07C2529/85 , Y02P20/584 , C07C11/02
摘要： A process is described for converting an oxygenate-containing feedstock into one or more olefins in a reactor system including a plurality of fixed bed reactors each containing a catalyst composition comprising a molecular sieve and at least one metal oxide having an uptake of carbon dioxide at 100° C. of at least 0.03 mg/m2 of the metal oxide. Each reactor is sequentially rotated between at least one operating mode, wherein the catalyst composition in the reactor is contacted with the oxygenate-containing feedstock, and a regeneration mode, wherein the catalyst composition in the reactor is contacted with a regeneration medium.
摘要翻译：描述了一种在含有含氧化合物的原料转化为一种或多种烯烃的方法，该反应器系统包括多个固定床反应器，每个反应器均含有包含分子筛和至少一种二氧化碳吸收量的至少一种金属氧化物，至少为0.03mg / m 2的金属氧化物。每个反应器在至少一个操作模式之间依次旋转，其中反应器中的催化剂组合物与含氧化合物的原料接触，再生模式，其中反应器中的催化剂组合物与再生介质接触。

8. 发明授权

US07166757B2 Conversion of oxygenates to olefins 有权
标题翻译：含氧化合物转化为烯烃
公开(公告)号：US07166757B2
公开(公告)日：2007-01-23
申请号：US10909014
申请日：2004-07-30
申请人： Shun Chong Fung , Doron Levin , Jose Santiesteban , Nicolas P. Coute
发明人： Shun Chong Fung , Doron Levin , Jose Santiesteban , Nicolas P. Coute
IPC分类号： C07C1/00
CPC分类号： C07C1/20 , B01J23/10 , B01J29/85 , B01J29/90 , B01J38/30 , C10G3/42 , C10G3/48 , C10G3/49 , C10G3/57 , C10G3/62 , C10G2300/708 , C10G2400/20 , Y02P20/584 , Y02P30/20 , Y02P30/40 , C07C11/02
摘要： A process is described for converting an oxygenate-containing feedstock into one or more olefins in which the feedstock is contacted in a reaction zone with a fluidized bed of a particulate catalyst composition comprising a molecular sieve and at least one metal oxide having an uptake of carbon dioxide at 100° C. of at least 0.03 mg/m2 of the metal oxide whereby at least part of the feedstock is converted into a product stream comprising one or more olefins and a carbonaceous material is deposited on the catalyst composition to produce a coked catalyst composition. The coked catalyst composition is separated from the product stream and divided into at least first and second portions. The first portion of the coked catalyst composition is contacted with a regeneration medium in a regeneration zone under conditions to remove at least part of the carbonaceous material from the coked catalyst composition and produce a regenerated catalyst composition, which is subsequently recycled to the reaction zone. The second portion of the coked catalyst composition is also recycled to the reaction zone but without being initially contacted with a regeneration medium.
摘要翻译：描述了一种用于将含氧化合物的原料转化成一种或多种烯烃，其中原料在反应区中与包含分子筛和至少一种具有碳吸收性的金属氧化物的颗粒催化剂组合物的流化床接触的烯烃二氧化碳在100℃下为至少0.03mg / m 2的金属氧化物，由此至少部分原料转化为包含一种或多种烯烃的产物流，并将碳质材料沉积在用于生产焦化催化剂组合物的催化剂组合物。将焦炭催化剂组合物与产物流分离并分成至少第一和第二部分。焦化催化剂组合物的第一部分与再生区中的再生介质接触，在从焦炭催化剂组合物中除去至少一部分碳质材料的条件下，并产生再生催化剂组合物，随后再循环到反应区。焦炭催化剂组合物的第二部分也被循环到反应区，但不最初与再生介质接触。

9. 发明申请

US20070004944A1 Process and catalyst for oxidation of hydrocarbons 有权
标题翻译：碳氢化合物的氧化工艺和催化剂
公开(公告)号：US20070004944A1
公开(公告)日：2007-01-04
申请号：US11173594
申请日：2005-07-01
申请人： Bi-Zeng Zhan , Bjorn Moden , Jihad Dakka , Jose Santiesteban , Sebastian Reyes , Enrique Iglesia
发明人： Bi-Zeng Zhan , Bjorn Moden , Jihad Dakka , Jose Santiesteban , Sebastian Reyes , Enrique Iglesia
IPC分类号： C07C27/00
CPC分类号： C07C29/50 , B01J29/064 , B01J29/076 , B01J29/48 , B01J29/7253 , B01J29/7292 , B01J29/7853 , B01J29/7892 , B01J2229/186 , C07C45/33 , C07C45/36 , C07C51/215 , C07C51/265 , Y02P20/582 , C07C49/04 , C07C53/00 , C07C63/06 , C07C31/125
摘要： A process for the oxidation of hydrocarbons comprises contacting the hydrocarbon with an oxygen-containing gas in the presence of a catalyst comprising a microporous solid support, preferably a zeolite, having from 8- to 12-ring open windows and comprising non-framework metal cations selected from manganese, iron, cobalt, vanadium, chromium, copper, nickel, and ruthenium, and mixtures thereof, providing that the oxygen-containing gas does not contain significant amounts of added hydrogen. The catalyst is novel and forms part of the invention. The process may be used for oxidation of alkanes, cycloalkanes, benzene and alkylbenzenes, and is suitable for use in regioselective terminal oxidation of straight chain alkanes and for selective oxidation/separation of p-dialkylbenzenes from an alkylbenzene mixture, for example, p-xylene from an isomeric mixture of xylenes.
摘要翻译：烃的氧化方法包括使烃与含氧气体在催化剂存在下接触，所述催化剂包含微孔固体载体，优选沸石，具有8-至12-环开放的窗口并且包含非骨架金属阳离子选自锰，铁，钴，钒，铬，铜，镍和钌，以及它们的混合物，条件是含氧气体不含显着量的加氢。该催化剂是新颖的并且构成本发明的一部分。该方法可用于烷烃，环烷烃，苯和烷基苯的氧化，并且适用于直链烷烃的区域选择性末端氧化和用于从烷基苯混合物中选择性氧化/分离对二烷基苯，例如对二甲苯来自异构体的二甲苯混合物。

10. 发明申请

US20060247461A1 Hydrogenation of benzene polycarboxylic acids or derivatives thereof 有权
公开(公告)号：US20060247461A1
公开(公告)日：2006-11-02
申请号：US10535531
申请日：2003-11-18
申请人： Richard Schlosberg , Jose Santiesteban , Stuart Soled , Andrzej Malek , Joseph Baumgartner , Shifang Luo , Sabato Miseo , James Vartuli
发明人： Richard Schlosberg , Jose Santiesteban , Stuart Soled , Andrzej Malek , Joseph Baumgartner , Shifang Luo , Sabato Miseo , James Vartuli
IPC分类号： C07C67/02
CPC分类号： B01J29/0325 , B01J23/462 , B01J29/0308 , B01J29/041 , B01J29/043 , B01J37/0203 , B01J2229/186 , C07C51/36 , C07C67/303 , C07C2601/14 , C07C61/22 , C07C61/24 , C07C61/08 , C07C61/09 , C07C69/75
摘要： A process for hydrogenating benzenepolycarboxylic acids or derivatives thereof, such as esters and/or anhydrides, by bringing one or more benzenepolycarboxylic acids or one or more derivatives thereof into contact with a hydrogen-containing gas in the presence of one or more catalytically active metal, such as platinum, palladium, ruthenium or mixtures thereof, deposited on a catalyst support comprising one or more ordered mesoporous materials.

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