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1. 发明申请

US20180290954A1 METHOD FOR RECOVERING PHENOL AND ACETONE FROM CRACKING REACTION PRODUCT OF BISPHENOL-A RESIDUE (As Amended) 审中-公开
公开(公告)号：US20180290954A1
公开(公告)日：2018-10-11
申请号：US15751360
申请日：2016-12-07
申请人： LG CHEM, LTD.
发明人： Sang-Beom LEE , Joon-Ho SHIN , In-Yong JEONG , Jong-Hui Park , Myeong-Yeon KEUM , Jeong-Ho KIM , Tae-Ho KIM
IPC分类号： C07C37/08 , C07C37/74 , C07C37/68 , C07C45/53 , C07C45/78 , C07C45/82 , C07C37/52 , C07C45/51
CPC分类号： C07C37/08 , C07C37/52 , C07C37/68 , C07C37/72 , C07C37/74 , C07C37/86 , C07C45/512 , C07C45/517 , C07C45/53 , C07C45/78 , C07C45/80 , C07C45/82 , C07C39/04 , C07C49/08
摘要： Disclosed is a method for recovering phenol and acetone from the cracking reaction product of bisphenol-A residue, by which economic feasibility and efficiency may be improved by utilizing a phenol/acetone purification process used for preparing bisphenol-A.

2. 发明申请

US20170210708A1 ALKYLBENZENE HYDROPEROXIDE PRODUCTION USING DISPERSED BUBBLES OF OXYGEN CONTAINING GAS 有权
公开(公告)号：US20170210708A1
公开(公告)日：2017-07-27
申请号：US15501187
申请日：2015-08-07
申请人： SABIC GLOBAL TECHNOLOGIES B.V.
发明人： Mark Erik Nelson , Andrey Vladimirovich Zinenkov , Arkady Samuilovich Dykman
IPC分类号： C07C407/00 , B01J19/24 , B01J10/00 , B01J19/00 , C07C37/08 , C07C45/53
CPC分类号： C07C407/00 , B01J4/004 , B01J10/002 , B01J19/0006 , B01J19/2425 , B01J19/248 , B01J2219/00094 , B01J2219/00166 , B01J2219/00177 , C07C37/08 , C07C45/53 , C07C39/04 , C07C49/08 , C07C409/10
摘要： An apparatus for oxidation of a C8-C12 alkylbenzene reactant to a C8-C12 alkylbenzene hydroperoxide product, the re-actor can comprise: a flow reactor comprising a reactant inlet, an oxidate product outlet, wherein the reactor is configured to provide a liquid flow from the reactant inlet to the product outlet, a gas inlet configured to introduce an oxygen-containing gas into the reactor and an inlet sparger configured to flow gas bubbles comprising the oxygen-containing gas within the liquid flow, and wherein: the inlet sparger is configured to flow the gas bubbles having a diameter of 1.0 mm to 5.0 mm over a gas bubble residence time from 1 to 200 seconds, and/or the inlet sparger configured to flow the gas bubbles such that greater than or equal to 80% of the gas bubbles do not coalesce into larger bubbles over a gas bubble residence time of 1 to 200 seconds.

3. 发明授权

US09663430B2 Process for making phenol and/or cyclohexanone 有权
公开(公告)号：US09663430B2
公开(公告)日：2017-05-30
申请号：US14912569
申请日：2014-08-27
申请人： ExxonMobil Chemical Patents Inc.
发明人： Francisco M. Benitez , Christopher L. Becker , Keith H. Kuechler , Jason D. Davis
IPC分类号： C07C45/53 , C07C37/08 , C07C2/74 , C07C407/00 , C07C45/00
CPC分类号： C07C37/08 , C07C45/00 , C07C45/53 , C07C407/00 , C07C407/003 , C07C2601/14 , C07C39/04 , C07C49/403 , C07C409/14
摘要： A process for making phenol and/or cyclohexanone, the process comprising: (A) oxidizing a cyclohexylbenzene feed to obtain an oxidation product comprising cyclohexylbenzene, cyclohexylbenzene hydroperoxide and water; (B) removing at least a portion of the water from at least a portion of the oxidation product to obtain a cleavage feed; and (C) contacting at least a portion of the cyclohexylbenzene hydroperoxide in the cleavage feed with an acid catalyst in a cleavage reactor under cleavage conditions to obtain a cleavage product comprising phenol and cyclohexanone. The removing step may also comprises a step of removing a portion of the cyclohexylbenzene contained in the oxidation product. Water removal may be advantageously conducted in a water flashing drum before a cyclohexylbenzene hydroperoxide concentrator.

4. 发明申请

US20170036979A1 NEUTRALIZATION OF ACIDIC CATALYSTS IN THE PRODUCTION OF PHENOL 有权
标题翻译：酸性催化剂在生产苯酚中的中和
公开(公告)号：US20170036979A1
公开(公告)日：2017-02-09
申请号：US15304698
申请日：2014-04-23
申请人： Dow Global Technologies LLC
发明人： Xin JIANG , Jianhai MU
IPC分类号： C07C37/08 , C07C407/00 , B01J27/053
CPC分类号： C07C37/08 , B01J27/053 , C07C37/86 , C07C45/53 , C07C407/00 , C07C2601/14 , Y02P20/52 , C07C39/04 , C07C49/403 , C07C409/14
摘要： An improved method for the production of phenol. The method comprises (a) synthesizing phenol through a process that utilizes an acidic catalyst; (b) neutralizing the acidic catalyst after substantial completion of step (a) by addition thereto of a neutralization composition, wherein the neutralization composition contains an ethyleneamine derivative.
摘要翻译：一种改进的苯酚生产方法。该方法包括（a）通过利用酸性催化剂的方法合成苯酚; （b）通过加入中和组合物中和步骤（a）基本完成后的酸性催化剂，其中中和组合物含有亚乙基胺衍生物。

5. 发明申请

US20160376210A1 Process for Making Phenol and/or Cyclohexanone 有权
标题翻译：制备苯酚和/或环己酮的方法
公开(公告)号：US20160376210A1
公开(公告)日：2016-12-29
申请号：US15038975
申请日：2014-11-14
申请人： EXXONMOBIL CHEMICAL PATENTS INC.
发明人： Jason D. DAVIS , Ashiey J. POUCHER , Jörg F.W. WEBER , Jonathan J. WATTS , Christopher L. BECKER
IPC分类号： C07C37/08 , C07C407/00 , C07C37/80 , C07C45/53
CPC分类号： C07C37/08 , C07C2/74 , C07C37/80 , C07C45/53 , C07C407/00 , C07C2601/14 , C07C2601/16 , C07C13/28 , C07C39/04 , C07C49/403 , C07C409/14
摘要： Disclosed is (i) a process of making phenol and/or cyclohexanone from cyclohexylbenzene including a step of removing methylcyclopentylbenzene from (a) the cyclohexylbenzene feed supplied to the oxidation step and/or (b) the crude phenol product (ii) a phenol composition and (iii) a cyclohexylbenzene composition that can be made using the process.
摘要翻译：公开了（i）从环己基苯制备苯酚和/或环己酮的方法，包括从（a）供应到氧化步骤的环己基苯进料和/或（b）粗苯酚产物（ii）中除去甲基环戊基苯的步骤，苯酚组合物和（iii）可以使用该方法制备的环己基苯组合物。

6. 发明授权

US09388102B2 Process for producing phenol 有权
标题翻译：苯酚生产工艺
公开(公告)号：US09388102B2
公开(公告)日：2016-07-12
申请号：US14110859
申请日：2011-12-15
申请人： Kun Wang , Roberto Garcia , Jihad M. Dakka , Edmund J. Mozeleski
发明人： Kun Wang , Roberto Garcia , Jihad M. Dakka , Edmund J. Mozeleski
IPC分类号： C07C37/08 , C07C407/00 , C07C409/16 , C07C45/53 , C07C2/74 , C07C39/04 , C07C49/403 , B01J29/06 , B01J29/08 , C07C37/86
CPC分类号： C07C37/08 , B01J29/06 , B01J29/08 , B01J29/082 , B01J29/084 , B01J37/30 , C07C2/74 , C07C37/86 , C07C39/04 , C07C45/53 , C07C49/403 , C07C407/00 , C07C409/16 , C07C2101/14 , C07C2601/14 , Y02P20/52 , C07C409/14 , C07C13/28
摘要： In a process for producing phenol, cyclohexylbenzene is contacted with an oxygen-containing compound in the presence of an oxidation catalyst comprising a cyclic imide under oxidation conditions effective to produce a product comprising cyclohexylbenzene hydroperoxide and unreacted cyclic imide catalyst. Without removing all the unreacted cyclic imide catalyst, at least a portion of the product is contacted with an acidic molecular sieve under conditions effective to adsorb at least a portion of the unreacted cyclic imide and to convert at least part of the cyclohexylbenzene hydroperoxide in the product portion into phenol and cyclohexanone.
摘要翻译：在生产苯酚的方法中，在有效产生包含环己基苯氢过氧化物和未反应的环状酰亚胺催化剂的产物的氧化条件下，环己基苯在含有环状酰亚胺的氧化催化剂存在下与含氧化合物接触。在不除去所有未反应的环状酰亚胺催化剂的情况下，至少一部分产物在有效吸附至少一部分未反应的环状酰亚胺的条件下与酸性分子筛接触，并将至少部分环己基苯氢过氧化物转化成产物部分成苯酚和环己酮。

7. 发明授权

US09376359B2 Process for preparing a para-linear alkyl-substituted hydroxyaromatic compound 有权
标题翻译：制备对 - 直链烷基取代的羟基芳族化合物的方法
公开(公告)号：US09376359B2
公开(公告)日：2016-06-28
申请号：US14069271
申请日：2013-10-31
申请人： Cedrick Mahieux , Curtis B. Campbell , Alexander E. Kuperman
发明人： Cedrick Mahieux , Curtis B. Campbell , Alexander E. Kuperman
IPC分类号： C07C37/08 , C10M129/10
CPC分类号： C07C37/08 , C07C2/66 , C07C407/00 , C07C2529/18 , C10M129/10 , C10M177/00 , C10M2207/023 , C10N2270/00 , C07C39/06 , C07C15/107 , C07C409/08
摘要： Disclosed herein is a process for preparing an isomeric mixture comprising a major amount of a para-linear mono-alkyl-substituted hydroxyaromatic compound. The process involves the steps of: (a) providing an isomeric mixture comprising a major amount of a para-di(alkyl-substituted)aromatic compound; wherein a first alkyl substituent is a C3 to C8 alkyl moiety and a second alkyl substituent is a C4+n to C8+n linear alkyl moiety, wherein n is 0 to 42 and further wherein the second alkyl substituent is at least one carbon atom greater than the first alkyl substituent; (b) subjecting the isomeric mixture comprising a major amount of a para-di(alkyl-substituted)aromatic compound to oxidation conditions in the presence of an oxygen-containing source, thereby converting the first alkyl substituent which is a C3 to C8 alkyl moiety to a hydroperoxide-containing substituted moiety to produce an isomeric mixture comprising a major amount of a para-linear alkyl-substituted, hydroperoxide-containing substituted aromatic compound; and (c) converting the hydroperoxide-containing substituted moiety to a hydroxyl moiety thereby providing an isomeric mixture comprising a major amount of a para-linear mono-alkyl-substituted hydroxyaromatic compound.
摘要翻译：本文公开了一种制备包含主要量的对位线性单烷基取代的羟基芳族化合物的异构体混合物的方法。该方法包括以下步骤：（a）提供包含主要量的对二（烷基取代的）芳族化合物的异构体混合物; 其中第一烷基取代基是C3至C8烷基部分，第二烷基取代基是C 4 + n至C 8 + n直链烷基部分，其中n为0至42，并且其中第二烷基取代基为至少一个碳原子较大比第一烷基取代基; （b）在含氧源的存在下使含有主要量的对二（烷基取代）芳族化合物的异构体混合物经受氧化条件，由此转化为C3至C8烷基部分的第一烷基取代基涉及含氢过氧化物的取代部分以产生包含主要量的对位线性烷基取代的含氢过氧化物的取代的芳族化合物的异构体混合物; 和（c）将含氢过氧化物的取代的部分转化为羟基部分，从而提供包含主要量的对位线性单烷基取代的羟基芳族化合物的异构体混合物。

8. 发明授权

US09335285B2 Method for measuring acid strength in reaction medium using trimethylphosphine oxide and 31P NMR 有权
标题翻译：使用三甲基氧化膦和31 P NMR测定反应介质中酸强度的方法
公开(公告)号：US09335285B2
公开(公告)日：2016-05-10
申请号：US14498332
申请日：2014-09-26
申请人： ExxonMobil Chemical Patents Inc.
发明人： Kun Wang , Roberto Garcia
IPC分类号： G01N31/22 , G01N24/08 , C07C37/08 , G01R33/46 , C07C45/53
CPC分类号： G01N24/088 , C07C37/08 , C07C45/53 , C07C2601/14 , G01N24/085 , G01N31/221 , G01R33/46 , Y10T436/163333 , C07C39/04 , C07C49/403
摘要： A method to determine the strength of an acid in a medium is disclosed. The method includes (I) providing multiple samples comprising trimethylphosphine oxide (TMPO), the acid, and the medium, wherein the multiple samples have different [H+]/[TMPO] ratios, [H+] is the concentration of hydrons in the sample in mole·liter−1, and [TMPO] is the concentration of TMPO in the sample in mole·liter−1. (II) The 31P chemical shifts of the multiple samples are measured by 31P NMR and compared to standardized samples to determine the acid strength of the medium.
摘要翻译：公开了确定介质中酸的强度的方法。该方法包括（I）提供包含三甲基氧化膦（TMPO），酸和介质的多个样品，其中多个样品具有不同的[H +] / [TMPO]比，[H +]是样品中氢化物的浓度摩尔·升-1，[TMPO]是样品中TMPO的浓度，摩尔·升-1。（II）通过31P NMR测量多个样品的31P化学位移，并与标准样品进行比较，以确定培养基的酸强度。

9. 发明申请

US20160107970A1 Process for Producing Phenol and/or Cyclohexanone 有权
标题翻译：生产苯酚和/或环己酮的方法
公开(公告)号：US20160107970A1
公开(公告)日：2016-04-21
申请号：US14891177
申请日：2014-06-04
申请人： EXXONMOBIL CHEMICAL PATENTS INC.
发明人： Hari Nair , Christopher L. Becker , Jason D. Davis , Charles Morris Smith
IPC分类号： C07C45/53 , C07C2/74 , C07C37/08
CPC分类号： C07C45/53 , C07C2/74 , C07C37/08 , C07C407/00 , C07C2529/08 , C07C2601/14 , C07C39/04 , C07C409/14 , C07C49/403 , C07C13/28
摘要： In a process for producing phenol and/or cyclohexanone, cyclohexylbenzene is contacted with an oxygen-containing gas in the presence of an oxidation catalyst under oxidation conditions effective to produce an oxidation effluent comprising cyclohexylbenzene hydroperoxide. At least a portion of the oxidation effluent is then subjected to a concentrating step to produce a cleavage feed having a higher concentration of cyclohexylbenzene hydroperoxide than the oxidation effluent. A cleavage reaction mixture comprising the cleavage feed is then contacted with a solid acid catalyst in a cleavage reaction zone under conditions effective to produce a cleavage product comprising phenol and cyclohexanone.
摘要翻译：在生产苯酚和/或环己酮的方法中，在有效产生包含环己基苯氢过氧化物的氧化流出物的氧化条件下，在氧化催化剂存在下，使环己基苯与含氧气体接触。然后将氧化流出物的至少一部分进行浓缩步骤以产生具有比氧化流出物更高浓度的环己基苯氢过氧化物的裂解进料。然后在有效产生包含苯酚和环己酮的裂解产物的条件下，将裂解进料的裂解反应混合物与裂解反应区中的固体酸催化剂接触。

10. 发明申请

US20160075623A1 Process for Producing Phenol 有权
标题翻译：生产苯酚的方法
公开(公告)号：US20160075623A1
公开(公告)日：2016-03-17
申请号：US14787862
申请日：2014-04-09
申请人： EXXONMOBIL CHEMICAL PATENTS INC.
发明人： Bryan A. Patel , John S. Coleman
IPC分类号： C07C37/50 , C07C407/00 , C07C2/74 , C07C45/53
CPC分类号： C07C37/50 , C07C2/74 , C07C37/08 , C07C45/53 , C07C407/00 , C07C409/14 , C07C2529/70 , C07C2601/14 , C07C39/04 , C07C49/403 , C07C13/28
摘要： In a process for producing phenol and cyclohexanone, reaction components comprising cyclohexylbenzene hydroperoxide and an acid catalyst are supplied to a cleavage reaction zone, mixed under mixing conditions effective to combine the reaction components into a reaction mixture and at least part of the cyclohexylbenzene hydroperoxide in the reaction mixture is converted under cleavage conditions to into phenol and cyclohexanone; and a cleavage effluent is recovered from the cleavage reaction zone. The cleavage and mixing conditions are controlled such that the ratio tR/tM is at least 10, where tR is the half-life of cyclohexylbenzene hydroperoxide under the cleavage conditions and tM is the time required after injection of a tracer material into the reaction mixture under the mixing conditions for at least 95% by volume of the entire reaction mixture to attain at least 95% of the volume-averaged tracer material concentration.
摘要翻译：在生产酚和环己酮的方法中，将包含环己基苯氢过氧化物和酸催化剂的反应组分供应至裂解反应区，在有效将反应组分混合成反应混合物和至少部分环己基苯氢过氧化物的混合条件下混合，在裂解条件下将反应混合物转化成苯酚和环己酮; 并从裂解反应区回收裂解流出物。控制裂解和混合条件使得tR / tM的比例至少为10，其中t R是在切割条件下环己基苯氢过氧化物的半衰期，tM是将示踪材料注入反应混合物中所需的时间整个反应混合物的至少95体积％的混合条件达到体积平均示踪剂材料浓度的至少95％。

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