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1. 发明授权

US07825287B2 Process for production of triptane and triptene 有权
标题翻译：生产曲坦和三肽的方法
公开(公告)号：US07825287B2
公开(公告)日：2010-11-02
申请号：US12058300
申请日：2008-03-28
申请人： John Ahn , Burcin Temel , Enrique Iglesia
发明人： John Ahn , Burcin Temel , Enrique Iglesia
IPC分类号： C07C1/00
CPC分类号： C07C1/20 , C07C9/16 , C07C11/107
摘要： High octane C7 hydrocarbons, particularly 2,2,3-trimethylbutane (“triptane”) and 2,2,3-trimethyl-but-1-ene (“triptene”) (collectively “triptyls”) are produced by homologation of a feed comprising dimethyl ether and/or methanol and optionally including one or more aliphatic hydrocarbons in the presence of certain acidic zeolite catalysts. The process can be carried out at temperatures lower than those previously used for conversion of dimethyl ether and/or methanol to higher alkanes, including C7 alkanes, and results in selective production of triptane and/or triptene with relatively little isomerization to or production of other C7 alkanes.
摘要翻译：高辛烷值的C7烃，特别是2,2,3-三甲基丁烷（“triptane”）和2,2,3-三甲基 - 丁-1-烯（“triptene”）（统称为“triptyl”）是通过进料包括二甲醚和/或甲醇，并且在某些酸性沸石催化剂的存在下任选地包括一种或多种脂族烃。该方法可以在比以前用于将二甲醚和/或甲醇转化为高级烷烃（包括C 7烷烃）的温度低的温度下进行，并且导致选择性生产具有相对较少的异构化或生产其它的三烷基和/或三丁烯 C7烷烃。

2. 发明申请

US20090247803A1 Process for Production of Triptane and Triptene 有权
标题翻译：三甲苯和三氯甲烷生产工艺
公开(公告)号：US20090247803A1
公开(公告)日：2009-10-01
申请号：US12058300
申请日：2008-03-28
申请人： John Ahn , Burcin Temel , Enrique Iglesia
发明人： John Ahn , Burcin Temel , Enrique Iglesia
IPC分类号： C07C1/00
CPC分类号： C07C1/20 , C07C9/16 , C07C11/107
摘要： High octane C7 hydrocarbons, particularly 2,2,3-trimethylbutane (“triptane”) and 2,2,3-trimethyl-but-1-ene (“triptene”) (collectively “triptyls”) are produced by homologation of a feed comprising dimethyl ether and/or methanol and optionally including one or more aliphatic hydrocarbons in the presence of certain acidic zeolite catalysts. The process can be carried out at temperatures lower than those previously used for conversion of dimethyl ether and/or methanol to higher alkanes, including C7 alkanes, and results in selective production of triptane and/or triptene with relatively little isomerization to or production of other C7 alkanes.
摘要翻译：高辛烷值的C7烃，特别是2,2,3-三甲基丁烷（“triptane”）和2,2,3-三甲基 - 丁-1-烯（“triptene”）（统称为“triptyl”）是通过进料包括二甲醚和/或甲醇，并且在某些酸性沸石催化剂的存在下任选地包括一种或多种脂族烃。该方法可以在比以前用于将二甲醚和/或甲醇转化为高级烷烃（包括C 7烷烃）的温度低的温度下进行，并且导致选择性生产具有相对较少的异构化或生产其它的三烷基和/或三丁烯 C7烷烃。

3. 发明申请

US20060287551A1 Process for carbonylation of alkyl ethers 有权
标题翻译：烷基醚羰基化方法
公开(公告)号：US20060287551A1
公开(公告)日：2006-12-21
申请号：US11417415
申请日：2006-05-03
申请人： Patricia Cheung , Enrique Iglesia , John Sunley , Aditya Bhan , David Law
发明人： Patricia Cheung , Enrique Iglesia , John Sunley , Aditya Bhan , David Law
IPC分类号： C07C67/36
CPC分类号： C07C51/09 , C07C67/37 , C07C53/08 , C07C69/14
摘要： A product comprising a lower alkyl ester of a lower aliphatic carboxylic acid is produced by a process comprising reacting a lower alkyl ether with carbon monoxide in the presence of a catalyst comprising mordenite and/or ferrierite, optionally including an additional framework metal such as gallium, boron and/or iron, under substantially anhydrous conditions. More specifically, methyl acetate is selectively produced by reaction of dimethyl ether with carbon monoxide in the presence of a catalyst comprising mordenite or ferrierite, under substantially anhydrous conditions.
摘要翻译：包含低级脂族羧酸的低级烷基酯的产物是通过包括在包含丝光沸石和/或镁碱沸石的催化剂存在下使低级烷基醚与一氧化碳反应的方法制备的，任选地包括另外的骨架金属如镓，硼和/或铁。更具体地说，在基本上无水条件下，在包含丝光沸石或镁碱沸石的催化剂的存在下，通过二甲醚与一氧化碳反应选择性地生产乙酸甲酯。

4. 发明授权

US5157199A Isomerization of paraffins with strong solid acid catalyst and adamantane 失效
标题翻译：具有强固体酸催化剂和ADAMANTANE的PARAFFINS的异构化
公开(公告)号：US5157199A
公开(公告)日：1992-10-20
申请号：US677905
申请日：1991-04-01
申请人： Stuart L. Soled , Enrique Iglesia , George M. Kramer , William E. Gates , Richard H. Ernst
发明人： Stuart L. Soled , Enrique Iglesia , George M. Kramer , William E. Gates , Richard H. Ernst
IPC分类号： B01J27/053 , C07B61/00 , C07C5/27 , C07C9/16
CPC分类号： C07C5/2794
摘要： A process for isomerizing a paraffin feed comprising contacting the feed with a strong, solid acid catalyst comprising a sulfated Group IVB metal oxide and at least one Group VIII metal in the presence of hydrogen and an adamantane compound.

5. 发明授权

US5157054A Catalyst fluidization improvements (C-2546) 失效
标题翻译：催化剂流化改进（C-2546）
公开(公告)号：US5157054A
公开(公告)日：1992-10-20
申请号：US660198
申请日：1991-02-25
申请人： Eric Herbolzheimer , Frederick J. Kaiser, Jr. , Enrique Iglesia
发明人： Eric Herbolzheimer , Frederick J. Kaiser, Jr. , Enrique Iglesia
IPC分类号： B01J8/22 , B01J8/32 , B01J8/34 , C07C1/04 , C10G2/00
CPC分类号： C10G2/342 , B01J8/22 , B01J8/32 , B01J8/34 , C07C1/0415 , C07C2521/06 , C07C2523/02 , C07C2523/12 , C07C2523/36 , C07C2523/46 , C07C2523/75
摘要： Three phase reactions are carried out in a slurry bubble column, e.g., hydrocarbon synthesis, wherein rising gas bubbles fluidize a catalytically active solid dispersed in a liquid phase and in the presence of at least one other solid different chemically or physically from the catalytically active solid.
摘要翻译：在淤浆气泡塔中进行三相反应，例如烃合成，其中上升的气泡使分散在液相中的催化活性固体和在化学或物理上不同于催化活性固体的至少一种其它固体的存在下流化。

6. 发明授权

US5118715A Selective fixed-bed fischer-tropsch synthesis with high surface area Cu and K promoted, iron/manganese spinels 失效
标题翻译：选择性固定床费托合成高表面积Cu和K促进，铁/锰尖晶石
公开(公告)号：US5118715A
公开(公告)日：1992-06-02
申请号：US576251
申请日：1990-08-31
申请人： Enrique Iglesia , Stuart L. Soled , Rocco A. Fiato , Joseph E. Baumgartner
发明人： Enrique Iglesia , Stuart L. Soled , Rocco A. Fiato , Joseph E. Baumgartner
IPC分类号： B01J23/00 , B01J23/889 , C07C1/04
CPC分类号： B01J23/005 , B01J23/8892 , C07C1/044 , C07C2521/02 , C07C2521/06 , C07C2521/08 , C07C2521/16 , C07C2523/34 , C07C2523/745 , C07C2523/889 , C07C2527/232 , C07C2529/04
摘要： Pelletized, high surface area, Cu and Group IA or IIA dual metal promoted Mn-Fe spinels which are reduced and operated in a fixed-bed reactor provide exceptionally high catalytic activity and selectivity in the conversion of CO/H.sub.2 to high molecular weight hydrocarbons. These copper and Group IA or IIA metal promoted iron-manganese catalysts maintain good activity and selectivity to C.sub.5 + hydrocarbons, and give low selectivity to CO2.
摘要翻译：造粒，高表面积，Cu和IA或IIA双金属促进的Mn-Fe尖晶石在固定床反应器中还原和操作，在CO / H2转化为高分子量烃时具有特别高的催化活性和选择性。这些铜和IAA或IIA族金属促进的铁锰催化剂对C5 +烃保持良好的活性和选择性，并且对CO 2的选择性低。

7. 发明授权

US5100856A Iron-zinc based catalysts for the conversion of synthesis gas to alpha-olefins 失效
标题翻译：用于将合成气转化成α-烯烃的基于铁 - 锌的催化剂
公开(公告)号：US5100856A
公开(公告)日：1992-03-31
申请号：US591304
申请日：1990-10-01
申请人： Stuart L. Soled , Sabato Miseo , Enrique Iglesia , Rocco A. Fiato
发明人： Stuart L. Soled , Sabato Miseo , Enrique Iglesia , Rocco A. Fiato
IPC分类号： B01J23/80 , C07C1/04
CPC分类号： C07C1/044 , B01J23/80 , C07C2523/04 , C07C2523/06 , C07C2523/72 , C07C2523/745 , C07C2523/80
摘要： New copper-potassium promoted iron-zinc catalysts wherein the iron:zinc atomic ratio is 5:1 or greater, exhibit improved activity, selectivity and stability in the synthesis of alpha-olefins from hydrogen and carbon monoxide.
摘要翻译：新的铜 - 钾促进的铁 - 锌催化剂，其中铁：锌原子比为5:1或更大，在氢和一氧化碳合成α-烯烃中表现出改进的活性，选择性和稳定性。

8. 发明授权

US4754092A Reducing methane production and increasing liquid yields in Fischer-Tropsch reactions 失效
标题翻译：在费托反应中减少甲烷生产和提高液体产率
公开(公告)号：US4754092A
公开(公告)日：1988-06-28
申请号：US944656
申请日：1986-12-22
申请人： Enrique Iglesia , Rostam Madon
发明人： Enrique Iglesia , Rostam Madon
IPC分类号： B01J21/06 , B01J23/46 , B01J23/75 , B01J23/889 , C07C1/06 , C07C1/04
CPC分类号： C07C1/06 , B01J21/063 , B01J23/462 , B01J23/75 , B01J23/8896 , C07C2521/06 , C07C2523/46 , C07C2523/745 , C07C2523/75
摘要： A process for reducing methane formation and increasing liquid (C.sub.5.sup.+) yields in Fischer-Tropsch hydrocarbon synthesis processes of CO and H.sub.2 comprising adding one or more olefins to the reactor bed at a point below 10% of the distance from the top to the bottom of the reactor bed and above a point 10% above the bottom of the reactor bed to the top of the reactor bed in an amount sufficient to reduce said methane formation.
摘要翻译：在CO和H 2的费 - 托烃合成方法中减少甲烷形成和增加液体（C5 +）产率的方法，包括在低于反应器床的顶部至底部的距离的10％以下的点加入一种或多种烯烃反应器床并且高于反应器底部的10％的点至足以减少所述甲烷形成的量的反应器床的顶部。

9. 发明授权

US4738948A Cobalt-ruthenium catalysts for Fischer-Tropsch synthesis and process for their preparation 失效
标题翻译：用于费 - 托合成的钴 - 钌催化剂及其制备方法
公开(公告)号：US4738948A
公开(公告)日：1988-04-19
申请号：US881347
申请日：1986-07-02
申请人： Enrique Iglesia , Stuart L. Soled , Rocco A. Fiato
发明人： Enrique Iglesia , Stuart L. Soled , Rocco A. Fiato
IPC分类号： B01J21/06 , B01J23/89 , B01J37/14 , B01J37/18 , B01J38/10 , C07C1/04
CPC分类号： C07C1/0445 , B01J23/8913 , B01J37/14 , B01J37/18 , B01J21/063 , B01J38/10 , C07C2521/06 , C07C2523/46 , C07C2523/75 , C07C2523/89 , Y02P20/584
摘要： A hydrogen regenerable hydrocarbon synthesis catalyst useful for preparing higher hydrocarbons from synthesis gas is prepared by depositing cobalt and ruthenium on a refractory carrier and oxidizing and reducing the catalytic metals to form a catalyst in which the cobalt and ruthenium are in intimate contact.
摘要翻译：通过将钴和钌沉积在耐火载体上并氧化和还原催化金属以形成其中钴和钌紧密接触的催化剂来制备可用于从合成气制备高级烃的氢可再生烃合成催化剂。

10. 发明授权

US09938157B2 Interzeolite transformation and metal encapsulation in the absence of an SDA 有权
公开(公告)号：US09938157B2
公开(公告)日：2018-04-10
申请号：US14708833
申请日：2015-05-11
申请人： Sarika Goel , Stacey Ian Zones , Enrique Iglesia
发明人： Sarika Goel , Stacey Ian Zones , Enrique Iglesia
IPC分类号： B01J29/06 , C01B39/46 , B01J29/40 , C01B39/44 , B01J29/44 , B01J29/67 , B01J29/74 , C01B39/38 , C01B39/42 , C01B39/02 , C01B39/40 , B01J29/12 , B01J29/80 , B01J35/00
CPC分类号： C01B39/46 , B01J29/061 , B01J29/126 , B01J29/40 , B01J29/44 , B01J29/67 , B01J29/74 , B01J29/743 , B01J29/80 , B01J35/002 , B01J2229/18 , B01J2229/186 , B01J2229/40 , C01B39/026 , C01B39/38 , C01B39/40 , C01B39/42 , C01B39/44
摘要： Provided is a method of encapsulating a metal in a zeolite. The method comprises inserting a metal precursor into a parent zeolite, and then converting the parent zeolite to a zeolite having a higher framework density than the parent zeolite. The conversion is achieved without the need of an organic structure directing agent.

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