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1. 发明申请

US20160031787A1 SYNTHESIS OF BIOBASED AND SUBSTITUTED TEREPHTHALIC ACIDS AND ISOPHTHALIC ACIDS 有权
标题翻译：生物化学和取代的邻苯二甲酸和异辛酸的合成
公开(公告)号：US20160031787A1
公开(公告)日：2016-02-04
申请号：US14775149
申请日：2014-03-14
申请人： BOARD OF TRUSTEES OF MICHIGAN STATE UNIVERSITY
发明人： John W. FROST
IPC分类号： C07C51/265 , C07C51/353 , C08G63/183 , C07C51/377
CPC分类号： C07C51/265 , C07C51/353 , C07C51/377 , C07C2601/16 , C07C2602/44 , C08G63/183 , C08G63/78 , C07C61/22 , C07C63/04 , C07C63/26 , C07C63/24 , C07C61/29 , C07C62/38
摘要： Methods for producing bio-terephthalic acid and bio-isophthalic acid. Methods comprise a cycloaddition reaction to produce bio-4-methyl-3-cyclohexene-1-carboxylic acid, and bio-3-methyl-3-cyclohexene-1-carboxylic from bio-isoprene and bio-acrylic acid. An aromatization reaction produces bio-para-toluic acid and bio-meta-toluic acid from the bio-4-methyl-3-cyclohexene-1-carboxylic acid, and bio-3-methyl-3-cyclohexene-1-carboxylic. An oxidation reaction produces the bio-terephthalic acid and isophthalic acid from the bio-para-toluic acid and bio-meta-toluic acid.
摘要翻译：生物对苯二甲酸和生物间苯二甲酸生产方法。方法包括产生生物-4-甲基-3-环己烯-1-羧酸的环加成反应和生物异戊二烯和生物丙烯酸的生物-3-甲基-3-环己烯-1-羧酸。芳构化反应从生物-4-甲基-3-环己烯-1-羧酸和生物-3-甲基-3-环己烯-1-羧酸生成生物对甲苯甲酸和生物间甲苯甲酸。氧化反应从生物对甲苯甲酸和生物间甲苯甲酸产生生物对苯二甲酸和间苯二甲酸。

2. 发明授权

US08367858B2 Terephthalic and trimellitic based acids and carboxylate derivatives thereof 失效
标题翻译：对苯二酸和偏苯三酸类的酸及其羧酸衍生物
公开(公告)号：US08367858B2
公开(公告)日：2013-02-05
申请号：US12816763
申请日：2010-06-16
申请人： John W. Frost , Adeline Miermont , Dirk Schweitzer , Vu Bui , Douglas A. Wicks
发明人： John W. Frost , Adeline Miermont , Dirk Schweitzer , Vu Bui , Douglas A. Wicks
IPC分类号： C07C67/04 , C07C63/26
CPC分类号： C07D307/89 , C07B2200/09 , C07C51/353 , C07C67/08 , C07C67/303 , C07C67/317 , C07C67/333 , C07C67/347 , C07C69/75 , C07C2601/14 , C07C2601/16 , C08G63/183 , C07C57/16 , C07C69/602 , C07C69/76 , C07C69/82 , C07C61/22
摘要： The present invention relates to novel substituted and unsubstituted terephthalic acid and carboxylate derivatives and products prepared therefrom having a significant renewable content. The invention also relates to processes for preparing substituted and unsubstituted terephthalic and carboxylate derivatives thereof wherein a portion of the starting materials utilized is derived from renewable resources. The invention also relates to novel cyclohexene based intermediates prepared in these processes and to conversion of these intermediates to substituted and unsubstituted cyclohexane-1,4-dicarboxylates and carboxylate derivatives thereof and novel forms of the resulting products having renewable content. The invention also relates to products prepared from substituted and unsubstituted terephthalic acid and carboxylate derivatives thereof derived from starting materials derived from renewable resources.
摘要翻译：本发明涉及新的取代和未取代的对苯二甲酸和羧酸酯衍生物以及由其制备的具有显着可再生含量的产物。本发明还涉及制备取代和未取代的对苯二甲酸和羧酸酯衍生物的方法，其中所用起始物质的一部分来自可再生资源。本发明还涉及在这些方法中制备的新型环己烯基中间体以及将这些中间体转化为取代和未取代的环己烷-1,4-二羧酸酯及其羧酸酯衍生物以及具有可再生含量的所得产物的新型形式。本发明还涉及由衍生自可再生资源的起始原料的取代和未取代的对苯二甲酸及其羧酸衍生物制备的产品。

3. 发明授权

US07557148B2 Cyclic carboxylic acid compound and use thereof 有权
标题翻译：环状羧酸化合物及其用途
公开(公告)号：US07557148B2
公开(公告)日：2009-07-07
申请号：US10581039
申请日：2004-11-26
申请人： Takahiro Nishiguchi , Naoya Nakamura , Makoto Tsuboi
发明人： Takahiro Nishiguchi , Naoya Nakamura , Makoto Tsuboi
IPC分类号： C07C62/30 , C09D5/16
CPC分类号： C07C403/02 , C07C61/22 , C07C61/29 , C07C61/35 , C07C69/75 , C07C2601/16 , C07C2602/44 , C09D5/1662
摘要： A novel cyclic carboxylic acid formed by the addition reaction of an unsaturated carboxylic acid with a conjugated diene compound and a metal salt thereof are disclosed. A compounding agent (A) for an antifouling paint comprising one or more substances selected from the novel cyclic carboxylic acid, a derivative of the cyclic carboxylic acid (except a metal salt), a metal salt of the cyclic carboxylic acid and a metal salt of a derivative of the cyclic carboxylic acid, and an antifouling paint composition comprising the compounding agent (A) and a copolymer (B) for a self-polishing type antifouling paint are also disclosed. The antifouling paint composition can form an antifouling coating film which is a small burden to the environment, is uniformly eroded at a given rate, is capable of maintaining excellent antifouling performance for a long period of time and is applicable to ships or the like used in the highly fouling sea area.
摘要翻译：公开了通过不饱和羧酸与共轭二烯化合物及其金属盐的加成反应形成的新型环状羧酸。一种用于防污涂料的配混剂（A），其包含一种或多种选自新型环状羧酸，环状羧酸衍生物（金属盐除外），环状羧酸的金属盐和金属盐环状羧酸的衍生物，以及包含配合剂（A）和用于自抛光型防污涂料的共聚物（B））的防污涂料组合物。防污涂料组合物可以形成对环境负担小的防污涂膜，以给定的速率均匀地侵蚀，能够长时间保持优异的防污性能，适用于船舶等高度污染的海域。

4. 发明申请

US20060247461A1 Hydrogenation of benzene polycarboxylic acids or derivatives thereof 有权
公开(公告)号：US20060247461A1
公开(公告)日：2006-11-02
申请号：US10535531
申请日：2003-11-18
申请人： Richard Schlosberg , Jose Santiesteban , Stuart Soled , Andrzej Malek , Joseph Baumgartner , Shifang Luo , Sabato Miseo , James Vartuli
发明人： Richard Schlosberg , Jose Santiesteban , Stuart Soled , Andrzej Malek , Joseph Baumgartner , Shifang Luo , Sabato Miseo , James Vartuli
IPC分类号： C07C67/02
CPC分类号： B01J29/0325 , B01J23/462 , B01J29/0308 , B01J29/041 , B01J29/043 , B01J37/0203 , B01J2229/186 , C07C51/36 , C07C67/303 , C07C2601/14 , C07C61/22 , C07C61/24 , C07C61/08 , C07C61/09 , C07C69/75
摘要： A process for hydrogenating benzenepolycarboxylic acids or derivatives thereof, such as esters and/or anhydrides, by bringing one or more benzenepolycarboxylic acids or one or more derivatives thereof into contact with a hydrogen-containing gas in the presence of one or more catalytically active metal, such as platinum, palladium, ruthenium or mixtures thereof, deposited on a catalyst support comprising one or more ordered mesoporous materials.

5. 发明授权

US5001260A Tetracarboxylic acids 失效
标题翻译：四羧酸
公开(公告)号：US5001260A
公开(公告)日：1991-03-19
申请号：US818221
申请日：1986-01-13
申请人： Kathryn S. Hayes
发明人： Kathryn S. Hayes
IPC分类号： C07C61/12 , B01J21/00 , B01J27/00 , C07B61/00 , C07C51/00 , C07C51/353 , C07C55/00 , C07C57/02 , C07C57/13 , C07C61/22 , C07C61/28 , C07C67/00
CPC分类号： C07C61/22 , C07C51/353 , C07C57/13
摘要： A process for polymerizing unsaturated dicarboxylic acids comprises heating the acids in the presence of a catalytic proportion of an unactivated clay and water. The product dimer is distilled to separate unreacted monomer acids. The product dimers of 36, 40 and 44 content are useful as corrosion inhibitors, epoxy resin curing agents, lubricants and intermediates for synthetic polymeric resins and polymeric resin plasticizers.
摘要翻译：聚合不饱和二羧酸的方法包括在催化剂比例的未活化的粘土和水的存在下加热酸。将产物二聚物蒸馏以分离未反应的单体酸。 36,40和44含量的产物二聚体可用作腐蚀抑制剂，环氧树脂固化剂，润滑剂和合成聚合物树脂和聚合物树脂增塑剂的中间体。

6. 发明授权

US4606925A Flavoring with alkyl-substituted cyclohexyl and cyclohexenyl carboxylic acids 失效
标题翻译：用烷基取代的环己基和环己烯羧酸调味
公开(公告)号：US4606925A
公开(公告)日：1986-08-19
申请号：US446933
申请日：1982-12-06
申请人： Martin Rohr , N. Peter Vallone , Cormack Flynn
发明人： Martin Rohr , N. Peter Vallone , Cormack Flynn
IPC分类号： A23L27/20 , A24B3/12 , A24B15/34 , A61K8/36 , A61Q13/00 , C07C61/08 , C07C61/22 , C11B9/00 , A23L1/226
CPC分类号： A24B15/34 , C07C61/08 , C07C61/22 , C11B9/0034
摘要： The present invention discloses fragrance and flavor compositions comprising 4-alkyl substituted cyclohexyl and cyclohex-3-enyl carboxylic acids wherein the 4-alkyl substituent is an ethyl, propyl or butyl group, and methods for preparing same.
摘要翻译：本发明公开了包含4-烷基取代的环己基和环己-3-烯基羧酸的香料和风味组合物，其中4-烷基取代基是乙基，丙基或丁基，及其制备方法。

7. 发明授权

US4226779A Process for isomerizing methyl-delta-4-tetrahydrophthalic anhydride 失效
标题翻译：异构化甲基-Δ4-四氢邻苯二甲酸酐的方法
公开(公告)号：US4226779A
公开(公告)日：1980-10-07
申请号：US34502
申请日：1979-04-30
申请人： Motoyuki Yamato , Tadao Natsuume
发明人： Motoyuki Yamato , Tadao Natsuume
IPC分类号： C07C61/22 , C07D307/89
CPC分类号： C07C61/22
摘要： A process for isomerizing methyl-delta-4-tetrahydrophthalic anhydride, which comprises heat-treating it at 60.degree. to 300.degree. C. for 0.1 to 30 hours in the presence of at least one nitrogen-containing compound selected from the group consisting of (a) a quaternary ammonium compound and (b) a compound having a nitrogen atom bonded to the carbon atom of the carbonyl group (e.g., an amide, imide, carbamate, urea or semicarbazide compound). The product is liquid at room temperature, and especially suitable for use as a curing agent for epoxy resins.
摘要翻译：一种使甲基-Δ4-四氢邻苯二甲酸酐异构化的方法，其包括在至少一种选自以下的含氮化合物存在下，在60℃至300℃下热处理0.1-30小时（ a）季铵化合物和（b）具有与羰基的碳原子键合的氮原子的化合物（例如酰胺，酰亚胺，氨基甲酸酯，脲或氨基脲化合物）。该产品在室温下为液体，特别适合用作环氧树脂的固化剂。

8. 发明授权

US3121738A Hexachlorocyclopentadiene derivatives 失效
标题翻译：六氯环戊二烯衍生物
公开(公告)号：US3121738A
公开(公告)日：1964-02-18
申请号：US19649662
申请日：1962-05-21
申请人： STANDARD OIL CO
发明人： FIELDS ELLIS K
IPC分类号： A23D9/007 , C07C61/22 , C07C61/40 , C10L1/20
CPC分类号： A23D9/007 , C07C61/22 , C07C61/40 , C10L1/205 , C10M1/08 , C10M2205/00 , C10M2207/282 , C10M2207/34 , C10M2209/103 , C10M2211/044 , C10N2240/201 , C10N2240/202 , C10N2250/10 , C10N2270/02

9. 发明授权

US07893295B2 Hydrogenation of benzene polycarboxylic acids or derivatives thereof 有权
标题翻译：苯多元羧酸或其衍生物的氢化
公开(公告)号：US07893295B2
公开(公告)日：2011-02-22
申请号：US12426704
申请日：2009-04-20
申请人： Richard Henry Schlosberg , Jose Guadalupe Santiesteban , Stuart L. Soled , Andrzej Mariusz Malek , Joseph E. Baumgartner , Shifang L. Luo , Sabato Miseo , James Clarke Vartuli
发明人： Richard Henry Schlosberg , Jose Guadalupe Santiesteban , Stuart L. Soled , Andrzej Mariusz Malek , Joseph E. Baumgartner , Shifang L. Luo , Sabato Miseo , James Clarke Vartuli
IPC分类号： C07C69/74 , C07C61/00
CPC分类号： B01J29/0325 , B01J23/462 , B01J29/0308 , B01J29/041 , B01J29/043 , B01J37/0203 , B01J2229/186 , C07C51/36 , C07C67/303 , C07C2601/14 , C07C61/22 , C07C61/24 , C07C61/08 , C07C61/09 , C07C69/75
摘要： A process for hydrogenating benzenepolycarboxylic acids or derivatives thereof, such as esters and/or anhydrides, by bringing one or more benzenepolycarboxylic acids or one or more derivatives thereof into contact with a hydrogen-containing gas in the presence of one or more catalytically active metal, such as platinum, palladium ruthenium or mixtures thereof, deposited on a catalyst support comprising one or more ordered mesoporous materials.
摘要翻译：通过使一种或多种苯多羧酸或其一种或多种衍生物在含有一种或多种催化活性金属的存在下与含氢气体接触来使苯多元羧酸或其衍生物如酯和/或酸酐氢化的方法，例如沉积在包含一种或多种有序介孔材料的催化剂载体上的铂，钯钌或其混合物。

10. 发明申请

US20070105976A1 Cyclic carboxylic acid compound and use thereof 有权
标题翻译：环状羧酸化合物及其用途
公开(公告)号：US20070105976A1
公开(公告)日：2007-05-10
申请号：US10581039
申请日：2004-11-26
申请人： Takahiro Nishiguchi , Naoya Nakamura , Makoto Tsuboi
发明人： Takahiro Nishiguchi , Naoya Nakamura , Makoto Tsuboi
IPC分类号： C09D5/16 , C07C62/30
CPC分类号： C07C403/02 , C07C61/22 , C07C61/29 , C07C61/35 , C07C69/75 , C07C2601/16 , C07C2602/44 , C09D5/1662
摘要： [Means to solve problem] A novel cyclic carboxylic acid formed by the addition reaction of an unsaturated carboxylic acid with a conjugated diene compound and a metal salt thereof are disclosed. A compounding agent (A) for an antifouling paint comprising one or more substances selected from the novel cyclic carboxylic acid, a derivative of the cyclic carboxylic acid (except a metal salt), a metal salt of the cyclic carboxylic acid and a metal salt of a derivative of the cyclic carboxylic acid, and an antifouling paint composition comprising the compounding agent (A) and a copolymer (B) for a self-polishing type antifouling paint are also disclosed. [Effect] The antifouling paint composition can form an antifouling coating film which is a small burden to the environment, is uniformly eroded at a given rate, is capable of maintaining excellent antifouling performance for a long period of time and is applicable to ships or the like used in the highly fouling sea area.
摘要翻译： [解决问题的方法]公开了通过不饱和羧酸与共轭二烯化合物及其金属盐的加成反应形成的新型环状羧酸。一种用于防污涂料的配混剂（A），其包含一种或多种选自新型环状羧酸，环状羧酸衍生物（金属盐除外），环状羧酸的金属盐和金属盐环状羧酸的衍生物，以及包含配合剂（A）和用于自抛光型防污漆的共聚物（B））的防污涂料组合物。 [效果]防污涂料组合物可以形成对环境负担小的防污涂膜，以规定的速度均匀地侵蚀，能够长时间保持优异的防污性能，适用于船舶或像在高度污染的海域使用。

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