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1. 发明授权

US4507221A Anthraquinone dye and liquid crystal composition containing the same 失效
标题翻译：蒽醌染料和含有其的液晶组合物
公开(公告)号：US4507221A
公开(公告)日：1985-03-26
申请号：US510111
申请日：1983-07-01
申请人： Shuji Imazeki , Akio Mukoo , Mikio Sato , Masaharu Kaneko , Tetsuo Ozawa , Tomio Yoneyama
发明人： Shuji Imazeki , Akio Mukoo , Mikio Sato , Masaharu Kaneko , Tetsuo Ozawa , Tomio Yoneyama
IPC分类号： C09B1/26 , C09K19/60 , C09K3/34 , G02F1/13
CPC分类号： C09K19/603 , C09B1/26
摘要： An anthraquinone dye and a liquid crystal composition containing the same are disclosed. The anthraquinone dye shows a cyan color and has excellent order parameter, solubility and stability. The liquid crystal composition is particularly used in an electro-optic cell, which is interposed between two facing electrode plates and permits the realization of good color displays utilizing the guest-host effect of a liquid crystal.
摘要翻译：公开了一种蒽醌染料和含有它们的液晶组合物。蒽醌染料显示青色，具有优异的顺序参数，溶解性和稳定性。液晶组合物特别用于插入在两个面对的电极板之间的电光电池中，并且允许利用液晶的客体主体效应实现良好的彩色显示。

2. 发明授权

US5026505A Guest-host type liquid crystal composition 失效
标题翻译：宾主型液晶组成
公开(公告)号：US5026505A
公开(公告)日：1991-06-25
申请号：US426962
申请日：1982-09-29
申请人： Masaharu Kaneko , Tetsuo Ozawa , Tomio Yoneyama , Shuji Imazeki , Akio Mukoh , Mikio Sato
发明人： Masaharu Kaneko , Tetsuo Ozawa , Tomio Yoneyama , Shuji Imazeki , Akio Mukoh , Mikio Sato
IPC分类号： C09B1/08 , C09B1/20 , C09B1/503 , C09B1/51 , C09B1/54 , C09B1/60 , C09B5/24 , C09B23/10 , C09B25/00 , C09B29/01 , C09B29/08 , C09B29/36 , C09B31/02 , C09K19/60 , G02F1/137 , G09F9/00 , G09F9/35
CPC分类号： C09B5/24 , C09B1/08 , C09B1/20 , C09B1/503 , C09B1/51 , C09B1/542 , C09B1/60 , C09B23/102 , C09B25/00 , C09B29/0003 , C09B29/083 , C09B29/3604 , C09B31/02 , C09K19/60
摘要： A guest-host type liquid crystal composition comprising one or more host liquid crystals and dissolved therein one or more pleochroic dyes having a trans-4-substituted cyclohexyl group, preferably in an amount of 70% by mole or more of said trans-4-substituted cyclohexyl group among 4-substituted cyclohexyl groups, can afford a liquid crystal display device improved in display contrast and good stability due to no photochemical reaction of the liquid crystal composition.
摘要翻译：一种客体型液晶组合物，其包含一种或多种主体液晶，并溶解有一种或多种具有反式-4-取代的环己基的多色染料，优选为所述反式-4-取代的环己基的70摩尔％在4-取代的环己基中的取代的环己基可以提供显示对比度提高的液晶显示装置，并且由于液晶组合物没有光化学反应而具有良好的稳定性。

3. 发明授权

US4610804A Anthraquinone dyes and liquid crystal compositions including the same 失效
标题翻译：蒽醌染料和包含它们的液晶组合物
公开(公告)号：US4610804A
公开(公告)日：1986-09-09
申请号：US592255
申请日：1984-03-22
申请人： Shuji Imazeki , Akio Mukoh , Mikio Sato , Masaharu Kaneko , Tetsuo Ozawa , Tomio Yoneyama
发明人： Shuji Imazeki , Akio Mukoh , Mikio Sato , Masaharu Kaneko , Tetsuo Ozawa , Tomio Yoneyama
IPC分类号： C09B1/20 , C09B1/50 , C09B1/54 , C09B1/58 , C09K19/60 , C07C103/75 , C09B1/36 , G02F1/13
CPC分类号： C09B1/20 , C09B1/50 , C09B1/542 , C09B1/58 , C09K19/603
摘要： A liquid crystal composition comprising a host liquid crystal material and at least one guest novel anthraquine dye dissolved in said host liquid crystal material has a high order parameter, sufficient solubility in the host liquid crystal and high stability.
摘要翻译：包含主体液晶材料和溶解在所述主体液晶材料中的至少一种客体新型蒽醌染料的液晶组合物具有高阶参数，在主液晶中具有足够的溶解性和高稳定性。

4. 发明授权

US4528113A Anthraquinone dye and liquid crystal composition containing the dye 失效
标题翻译：蒽醌染料和含有染料的液晶组合物
公开(公告)号：US4528113A
公开(公告)日：1985-07-09
申请号：US593788
申请日：1984-03-27
申请人： Shuji Imazeki , Akio Mukoh , Mikio Sato , Masaharu Kaneko , Tetsuo Ozawa , Tomio Yoneyama
发明人： Shuji Imazeki , Akio Mukoh , Mikio Sato , Masaharu Kaneko , Tetsuo Ozawa , Tomio Yoneyama
IPC分类号： C09B1/58 , C09B1/60 , C09B1/62 , C09K19/60 , G02F1/13 , G02F1/137 , C09K3/34 , C09B1/22
CPC分类号： C09K19/603 , C09B1/58 , C09B1/62
摘要： An anthraquinone dye and a liquid crystal composition containing the dye are disclosed.The liquid crystal composition is preferably used in an electro-optic cell which enables a good color display utilizing the guest-host effect of the liquid crystal.
摘要翻译：公开了一种蒽醌染料和含有该染料的液晶组合物。液晶组合物优选用于能够利用液晶的客体主体效果的良好的彩色显示的电光单元中。

5. 发明授权

US4493532A Pleochroic azo dyes, a liquid crystal composition containing the azo dyes and a display device using the liquid crystal composition 失效
标题翻译：多色偶氮染料，含有偶氮染料的液晶组合物和使用该液晶组合物的显示装置
公开(公告)号：US4493532A
公开(公告)日：1985-01-15
申请号：US442057
申请日：1982-11-16
申请人： Masaharu Kaneko , Tetsuo Ozawa , Tomio Yoneyama , Shuji Imazeki , Akio Mukoh , Mikio Sato
发明人： Masaharu Kaneko , Tetsuo Ozawa , Tomio Yoneyama , Shuji Imazeki , Akio Mukoh , Mikio Sato
IPC分类号： C09B29/00 , C09B31/00 , C09B43/18 , C09B43/30 , C09K19/60 , G02F1/13 , C09F9/00 , C09K3/34
CPC分类号： C09B43/18 , C09B29/00 , C09B31/00 , C09B43/30 , C09K19/601
摘要： Pleochroic azo dyes represented by the formula (I): ##STR1## wherein X represents group --OCOR.sup.1 or --COOR.sup.1 (wherein R.sup.1 represents an alkyl group, an alkoxyalkyl group, an alkoxyphenyl group, an alkylcyclohexyl group, an alkoxyalkylcyclohexyl group, a cycloalkylcyclohexyl group, an alkoxycyclohexyl group, or a phenyl group substituted by a substituent selected from among an alkyl group containing 3 to 18 carbon atoms, an alkoxyalkyl group, a cycloalkyl group, an aryl group, a cyano group, a halogen atom, an acyloxy group, a carboxylic acid ester group, and an arylazo group); Y represents a hydrogen atom, an alkyl group, an alkoxyalkyl group, a cycloalkyl group, an alkoxy group, a nitro group, a cyano group, a carboxylic acid ester group, an acyloxy group, an alkylsulfonyl group, an aryl group, a halogen atom, or group ##STR2## wherein R.sup.2 and R.sup.3 each represents a hydrogen atom, an alkyl group, an alkoxyalkyl group, or R.sup.2 and R.sup.3 may be connected to each other to form a nitrogen-containing ring together with the adjacent nitrogen atom; Z.sup.1 to Z.sup.9 each represents a hydrogen atom, a halogen atom, a methyl group, a hydroxy group, a methoxy group or a cyano group, or Z.sup.1, Z.sup.2 and Z.sup.3 may be connected to R.sup.2 or R.sup.3 to form a nitrogen-containing ring, or Z.sup.1 and Z.sup.2, and Z.sup.4 and Z.sup.5, or Z.sup.7 and Z.sup.8 may be connected to each other to form an aromatic ring; at least one of ##STR3## and n represents 0, 1 or 2, a liquid crystal composition containing the pleochroic azo dyes and a display device using the liquid crystal composition.
摘要翻译：由式（I）表示的多色偶氮染料：其中X表示-OCOR1或-COOR1基团（其中R1表示烷基，烷氧基烷基，烷氧基苯基，烷基环己基，烷氧基烷基环己基，环烷基环己基，烷氧基环己基或被选自含有3至18个碳原子的烷基，烷氧基烷基，环烷基，芳基，氰基，卤素原子，酰氧基，羧酸酯基和芳基偶氮基）。 Y表示氢原子，烷基，烷氧基烷基，环烷基，烷氧基，硝基，氰基，羧酸酯基，酰氧基，烷基磺酰基，芳基，卤素原子或基团，其中R 2和R 3各自表示氢原子，烷基，烷氧基烷基或R 2和R 3可以彼此连接形成与相邻氮原子一起形成含氮环; Z1〜Z9各自表示氢原子，卤素原子，甲基，羟基，甲氧基或氰基，Z 1，Z 2和Z 3可以与R 2或R 3连接形成含氮环，或Z 1和Z 2以及Z 4和Z 5或Z 7和Z 8可以彼此连接形成芳香环; + TR 中的至少一个，n表示0,1或2，含有双色偶氮染料的液晶组合物和使用该液晶组合物的显示装置。

6. 发明授权

US4454057A Liquid crystal composition 失效
标题翻译：液晶组成
公开(公告)号：US4454057A
公开(公告)日：1984-06-12
申请号：US392909
申请日：1982-06-28
申请人： Masaharu Kaneko , Tetsuo Ozawa , Tomio Yoneyama , Shuji Imazeki , Akio Mukoh , Mikio Sato
发明人： Masaharu Kaneko , Tetsuo Ozawa , Tomio Yoneyama , Shuji Imazeki , Akio Mukoh , Mikio Sato
IPC分类号： C09B3/14 , C09K19/60 , G02F1/137 , G09F9/00 , G09F9/35 , C09K3/34 , G02F1/13
CPC分类号： C09K19/60 , C09B3/14
摘要： A liquid crystal composition comprising a host liquid crystal and at least one perylene dye dissolved therein represented by the formula: ##STR1## wherein X represents an oxygen atom or a sulfur atom, R.sup.1 and R.sup.2 each represents an aryl group when X represents an oxygen atom; or an aryl group or an alkyl group containing 1 to 18 carbon atoms when X represents a sulfur atom.
摘要翻译：一种液晶组合物，其包含主要液晶和至少一种苝染料，其溶解于下式：其中X表示氧原子或硫原子，当X表示氧原子时，R 1和R 2各自表示芳基 ; 或当X代表硫原子时，芳基或含有1至18个碳原子的烷基。

7. 发明授权

US4588517A Liquid crystal composition 失效
标题翻译：液晶组成
公开(公告)号：US4588517A
公开(公告)日：1986-05-13
申请号：US509051
申请日：1983-06-29
申请人： Masaharu Kaneko , Tomio Yoneyama , Junko Iwanami , Shuji Imazeki , Akio Mukoh , Mikio Sato
发明人： Masaharu Kaneko , Tomio Yoneyama , Junko Iwanami , Shuji Imazeki , Akio Mukoh , Mikio Sato
IPC分类号： C09B1/20 , C09B1/51 , C09B1/54 , C09B1/56 , C09B3/14 , C09B19/02 , C09B25/00 , C09B29/01 , C09B29/036 , C09B29/08 , C09B29/26 , C09B31/043 , C09B31/08 , C09B31/157 , C09B35/02 , C09B35/34 , C09B57/08 , C09B57/12 , C09B57/14 , C09B69/00 , C09K19/60 , G02F1/13
CPC分类号： C09B69/00 , C09B1/20 , C09B1/51 , C09B1/542 , C09B1/56 , C09B19/02 , C09B25/00 , C09B29/0003 , C09B29/0011 , C09B29/0029 , C09B29/081 , C09B29/0813 , C09B29/26 , C09B3/14 , C09B31/043 , C09B31/08 , C09B31/157 , C09B35/02 , C09B35/34 , C09B57/08 , C09B57/12 , C09B57/14 , C09K19/60
摘要： The description is concerned with a liquid crystal composition of the guest-host type which contains a pleochroic dye dissolved therein. The dye molecule has an end group or end groups in the molecule represented by the general formula: ##STR1## where Ro designates a straight chain of alkyl group, in which methylene group not adjacent to the nitrogen atom may be substituted by oxygen atom or sulfer atom; R1 designates an alkyl group having a chain length different from that of the alkyl group of Ro or a group ##STR2## in R1 a methylene group not adjacent to the nitrogen atom may be substituted by oxygen atom or sulfur atom, and R2 designates hydrogen atom, alkyl group, alkoxy group, cycloalkyl group or dialkylamino group.
摘要翻译：该描述涉及含有溶解在其中的多色染料的客体类型的液晶组合物。染料分子在由以下通式表示的分子中具有端基或端基：其中，R a表示烷基的直链，其中不与氮原子相邻的亚甲基可以被氧原子或硫原子取代原子; R1表示与R 1的烷基或R 1基团的链长不同的烷基，与氮原子不相邻的亚甲基可以被氧原子或硫原子取代，R 2表示氢原子，烷基，烷氧基，环烷基或二烷基氨基。

8. 发明授权

US4737310A Liquid crystal composition containing azo dyes 失效
标题翻译：含有偶氮染料的液晶组合物
公开(公告)号：US4737310A
公开(公告)日：1988-04-12
申请号：US864392
申请日：1986-05-19
申请人： Shuji Imazeki , Akio Mukoh , Mikio Sato , Masaharu Kaneko , Tomio Yoneyama , Junko Iwanami
发明人： Shuji Imazeki , Akio Mukoh , Mikio Sato , Masaharu Kaneko , Tomio Yoneyama , Junko Iwanami
IPC分类号： C09B29/00 , C09B31/00 , C09B35/00 , C09B43/10 , C09B43/28 , C09K19/60 , G02F1/137 , G09F9/00 , C09K19/00 , G02F1/13
CPC分类号： C09B29/00 , C09B31/00 , C09B35/00 , C09B43/10 , C09B43/28 , C09K19/601
摘要： A liquid crystal composition containing azo dyes represented by the formula (I.sub.0) ##STR1## wherein X represents ##STR2## A.sup.1 represents --O-- or --NH--; R.sup.1 represents a hydrogen atom, an alkyl group, an alkoxyalkyl group, an aryloxyalkyl group, a dialkylaminoalkyl group, an arylaminoalkyl group, a cycloalkyl group, an alkoxy group, an alkoxyalkoxy group, an arylalkoxy group, an aryl group, a halogen atom or a group of ##STR3## D.sup.1 and D.sup.2 each represents an aromatic group which does not contain an ionic group;U.sup.1 and U.sup.2 each represents a hydrogen atom, a halogen atom, a methyl group, a methoxy group or an ethoxy group;Y.sup.1 represents --O-- or ##STR4## R represents a hydrogen atom, an alkyl group or may be connected to Z.sup.10 to Z.sup.12 to form a ring;Z.sup.4 to Z.sup.12 each represents a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, a hydroxy group, an acylamino group or a cyano group, or Z.sup.4 and Z.sup.5, Z.sup.7 and Z.sup.8, and Z.sup.10 and Z.sup.11 may be connected to each other to form an aromatic ring; andn represents 0, 1 or 2.

9. 发明授权

US4600527A Liquid crystal composition 失效
标题翻译：液晶组成
公开(公告)号：US4600527A
公开(公告)日：1986-07-15
申请号：US465391
申请日：1983-02-10
申请人： Shuji Imazeki , Akio Mukoh , Mikio Sato , Masaharu Kaneko , Tomio Yoneyama , Junko Iwanami
发明人： Shuji Imazeki , Akio Mukoh , Mikio Sato , Masaharu Kaneko , Tomio Yoneyama , Junko Iwanami
IPC分类号： C09B29/00 , C09B31/00 , C09B35/00 , C09B43/10 , C09B43/28 , C09K19/60 , G02F1/137 , G09F9/00 , G02F1/13
CPC分类号： C09B29/00 , C09B31/00 , C09B35/00 , C09B43/10 , C09B43/28 , C09K19/601
摘要： A liquid crystal composition containing azo dyes represented by the formula (I.sub.0) ##STR1## wherein X represents ##STR2## A.sup.1 represents --O-- or --NH--, R.sup.1 represents a hydrogen atom, an alkyl group, an alkoxyalkyl group, an aryloxyalkyl group, a dialkylaminoalkyl group, an arylaminoalkyl group, a cycloalkyl group, an alkoxy group, an alkoxyalkoxy group, an arylalkoxy group, an aryl group, a halogen atom or a group of ##STR3## D.sup.1 and D.sup.2 each represents an aromatic group which does not contain an ionic group; U.sup.1 and U.sup.2 each represents a hydrogen atom, a halogen atom, a methyl group, a methoxy group or an ethoxy group;Y.sup.1 represents --O-- or ##STR4## R represents a hydrogen atom, an alkyl group or may be connected to Z.sup.10 to Z.sup.12 to form a ring;Z.sup.4 to Z.sup.12 each represents a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, a hydroxy group, an acylamino group or a cyano group, or Z.sup.4 and Z.sup.5, Z.sup.7 and Z.sup.8, and Z.sup.10 and Z.sup.11 may be connected to each other to form an aromatic ring; andn represents 0, 1 or 2.
摘要翻译：含有由式（I0）表示的偶氮染料的液晶组合物，其中X表示A1表示-O-或-NH-，R1表示氢原子，烷基，烷氧基烷基，芳氧基烷基，二烷基氨基烷基，芳基氨基烷基，环烷基，烷氧基，烷氧基烷氧基，芳基烷氧基，芳基，卤素原子或者每个表示芳基其不含离子基团; U1和U2各自表示氢原子，卤素原子，甲基，甲氧基或乙氧基; Y1表示-O-或R表示氢原子，烷基或可与Z10至Z12连接形成环; Z4〜Z12各自表示氢原子，卤素原子，烷基，烷氧基，羟基，酰氨基或氰基，或Z4和Z5，Z7和Z8，Z10和Z11可以连接到彼此形成芳环; n表示0,1或2。

10. 发明授权

US4483593A Guest-host type liquid crystal composition and liquid crystal display device 失效
标题翻译：宾主型液晶组合物和液晶显示装置
公开(公告)号：US4483593A
公开(公告)日：1984-11-20
申请号：US359513
申请日：1982-03-18
申请人： Shuji Imazeki , Akio Mukoh , Mikio Sato , Seiichi Imahori , Masaharu Kaneko , Tetsuo Ozawa
发明人： Shuji Imazeki , Akio Mukoh , Mikio Sato , Seiichi Imahori , Masaharu Kaneko , Tetsuo Ozawa
IPC分类号： C09B1/22 , C09B31/043 , C09B31/062 , C09K19/60 , G02F1/13 , G09F9/00 , G09F9/35 , C09K3/34
CPC分类号： C09B1/22 , C09B31/043 , C09B31/062 , C09K19/603
摘要： The present liquid crystal composition is characterized by containing a dye of anthraquinone series represented by the following general formula (1) dissolved as a guest in a host liquid crystal: ##STR1## wherein R represents an alkyl group or a cycloalkyl group. The alkyl group or the cycloalkyl group of the dye of anthraquinone series includes those substituted by alkyl, hydroxyl, alkoxy, cycloalkyl, aryl, aryloxy, dialkylamino, or heterocyclic residue. Furthermore, the liquid crystal composition can contain two or more other kinds of the dye of anthraquinone series, or can be used in combination with other dyes. In the dye of anthraquinone series, the group --COOR at the 2-position and the group --CN at the 3-position are particularly important for realization of cyan color and a high S value.The dye of anthraquinone series is particularly effective for preparation of a black dye.The present liquid crystal display device is characterized by comprising a liquid crystal cell comprising two transparent juxtaposed substrate plates, transparent electrodes formed each on the opposite inner surfaces of the substrate plates, alignment films formed each on the opposite inner surfaces of the substrate plates to cover the transparent electrodes and align liquid crystal molecules, sealing members for keeping the two substrate plates at a predetermined distance, a liquid crystal composition containing the dye represented by the said general formula (1) being filled in the liquid crystal cell, and a light source being provided outside the liquid crystal cell.
摘要翻译：本液晶组合物的特征在于，在主液晶中含有作为客体溶解的下述通式（1）表示的蒽醌系染料：其中，R表示烷基或环烷基。蒽醌系染料的烷基或环烷基包括被烷基，羟基，烷氧基，环烷基，芳基，芳氧基，二烷基氨基或杂环残基取代的烷基或环烷基。此外，液晶组合物可以含有两种以上其它种类的蒽醌系染料，也可以与其它染料组合使用。在蒽醌系染料中，2-位上的-COOR基和3-位的基团-CN对于实现青色和高S值是特别重要的。蒽醌系列的染料对于制备黑色染料是特别有效的。本液晶显示装置的特征在于包括一个液晶单元，该液晶单元包括两个透明的并置的基板，每个在基板的相对的内表面上形成的透明电极，每个在基板的相对的内表面上形成的取向膜覆盖透明电极和对准液晶分子，用于将两个基板保持在预定距离的密封构件，将含有由所述通式（1）表示的染料的液晶组合物填充在液晶单元中，以及光源设置在液晶单元的外部。

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