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    • 1. 发明授权
    • Quadrupole electrode and process for producing the same
    • 四极电极及其制造方法
    • US5373157A
    • 1994-12-13
    • US965258
    • 1993-01-05
    • Seiji HirokiTetsuya AbeYoshio MurakamiYoshishige TakanoAkira YamakawaMasaya Miyake
    • Seiji HirokiTetsuya AbeYoshio MurakamiYoshishige TakanoAkira YamakawaMasaya Miyake
    • H01J49/42H01J1/88
    • H01J49/4215H01J49/068
    • The present invention relates to improvement of a quadrupole electrode for use in a mass spectrometer or the like, in which two pairs of electrode rods 1, 2, 3 and 4 formed in such a manner that the section of the opposed face of each rod is hyperbolic or circular, and each electrode rod is made of a ceramic and the surface of the electrode is coated with a coating layer 5 of a conductive metal. Further, the present invention relates to a production process, characterized by incorporating such four electrodes at predetermined intervals. Since the electrodes are mainly made of a ceramic which is easily formable with a high dimensional accuracy, the adjustment of the positional relationship between the electrodes during assembling can be made without much effort, which enables a quadrupole electrode having a high performance to be provided with a good reproducibility at a low cost.
    • PCT No.PCT / JP92 / 01141 Sec。 371日期:1993年1月5日 102(e)日期1993年1月5日PCT提交1992年9月7日PCT公布。 出版物WO93 / 05532 日本1993年3月18日。本发明涉及用于质谱仪等的四极电极的改进,其中两对电极棒1,2,3和4以这样的方式形成: 每个杆的相对面是双曲线或圆形,并且每个电极棒由陶瓷制成,并且电极的表面涂覆有导电金属的涂层5。 此外,本发明涉及一种制造方法,其特征在于以预定间隔并入这四个电极。 由于电极主要由能够以高尺寸精度容易地形成的陶瓷制成,因此可以在组装期间电极之间的位置关系的调整不需要太多的努力,这使得能够提供具有高性能的四极电极 以低成本实现良好的再现性。
    • 2. 发明授权
    • Method of manufacturing a ceramics-type vacuum vessel
    • 制造陶瓷型真空容器的方法
    • US5603788A
    • 1997-02-18
    • US457013
    • 1995-06-01
    • Tetsuya AbeYoshio MurakamiHisao TakeuchiAkira YamakawaMasaya Miyake
    • Tetsuya AbeYoshio MurakamiHisao TakeuchiAkira YamakawaMasaya Miyake
    • C04B37/00F16J12/00H05H7/14B32B31/12B32B31/26
    • H05H7/14
    • A vacuum vessel is provided in which the majority of a vessel wall including an annular wall portion (1) and a plate-wall portion (2) is formed of ceramic material such as silicon nitride, for example. To bond the plural wall members together, bonding faces having a surface flatness of not more than 1 .mu.m are prepared thereon, and then a ceramic powder bonding substance with an average particle diameter of not more than 1 .mu.m is interposed between adjacent bonding faces and subjected to heating. Because the generation of gas, such as hydrogen, from the wall of the ceramic vessel is reduced, extremely high vacuum can be generated and maintained in the interior of the vacuum vessel. Also, because the wall of the vacuum vessel has a high permeability with respect to a magnetic field and an electric field, the vacuum vessel can be used as a vessel in a particle accelerator that allows the high precision control of charged particles therein by means of an electromagnetic field.
    • 提供一种真空容器,其中包括环形壁部分(1)和板壁部分(2)的容器壁的大部分由诸如氮化硅的陶瓷材料形成。 为了将多个壁构件结合在一起,在其上制备具有不大于1μm的表面平坦度的接合面,然后将平均粒径不大于1μm的陶瓷粉末粘合物置于相邻的接合面 并进行加热。 因为从陶瓷容器的壁产生气体,例如氢气,所以可以在真空容器的内部产生极高的真空度并维持真空。 此外,由于真空容器的壁相对于磁场和电场具有高磁导率,所以真空容器可以用作粒子加速器中的容器,其允许通过以下方式对带电粒子进行高精度控制: 电磁场。
    • 3. 发明授权
    • Armature stator
    • 电枢定子
    • US5280206A
    • 1994-01-18
    • US911453
    • 1992-07-10
    • Shigenori AndoSeiji HirokiTetsuya AbeYoshio Murakami
    • Shigenori AndoSeiji HirokiTetsuya AbeYoshio Murakami
    • H01F5/06H01F7/06H01F27/32H02K3/52H02K15/12H02K15/10
    • H02K15/12H01F27/327H02K3/524
    • An armature stator comprises an iron core and a coil directly mounted on the iron core. The coil is composed of wound electric wire which has a coating comprising an inorganic material, such as ceramic. A bonding material of the inorganic material is formed over the coil and iron core for filling any gaps and adhering the coil and iron core together into a unitary structure. To improve the reliability of the coil, after the electric wire is wound to form the coil, a filling material comprised of the inorganic material is formed over the coil by vacuum impregnation, and then sintered so as to repair defects in the coating disposed on the electric wire. After the bonding material is formed over the coil, which is directly mounted on the iron core, it is cured under high temperature. The armature stator thus constructed can be used with high reliability in high temperature and high vacuum applications.
    • 电枢定子包括铁芯和直接安装在铁芯上的线圈。 线圈由缠绕电线组成,其具有包括诸如陶瓷的无机材料的涂层。 在线圈和铁芯上形成无机材料的接合材料,用于填充任何间隙并将线圈和铁芯粘结在一起成为一体结构。 为了提高线圈的可靠性,在电线缠绕形成线圈之后,通过真空浸渍在线圈上形成由无机材料构成的填充材料,然后烧结以修复设置在线圈上的涂层中的缺陷 电线。 在直接安装在铁芯上的线圈上形成接合材料之后,它在高温下固化。 这样构造的电枢定子可以在高温和高真空应用中具有高可靠性。
    • 5. 发明授权
    • Quadrupole mass spectrometer having plural stable regions
    • 具有多个稳定区域的四极杆质谱仪
    • US5177359A
    • 1993-01-05
    • US781507
    • 1991-10-22
    • Seiji HirokiTetsuya AbeKoji YanagishitaNobuhiko TsuchiyaYoshio Murakami
    • Seiji HirokiTetsuya AbeKoji YanagishitaNobuhiko TsuchiyaYoshio Murakami
    • G01N27/62H01J49/42
    • H01J49/42
    • In a quadrupole mass spectrometer which includes four parallel rod electrodes between opposite pairs of which overlapping voltages.+-.(U+V cos .omega. t) are applied (where U: a continuous voltage and V cos .omega. t: a radio-frequency voltage) and which effects mass-analysis by an electric field formed within the four parallel rod electrodes, at least one parameter of U, V and .omega. has two different values, and the values are changed over to select the first stable region or the second stable region, the first stable region being nearest to the original point and the second stable region being next near to the original point on the a - q plane (where a:ordinate, q:abscissa) showing "stability diagram", and the ions being able to pass through the four parallel electrodes under the conditions of the first and second stable regions, where the variable a=8eU/mr.sub.O.sup.2 .omega..sup.2, q=4eV/mr.sub.O.sup.2 .omega..sup.2, U: level of DC voltage, V: peak of the radio-frequency voltage, e: charge of ion, m:mass of ion, r.sub.O : radius of an inscribed circle of the four parallel rod electrodes and.omega.: angular frequency of the radio frequency voltage.
    • 在四极质谱仪中,包括四个平行的棒状电极,在相对的两对之间施加重叠电压+/-(U + Vcosω),其中U:连续电压和Vcosωt:射频电压)和 其通过形成在四个平行杆电极内的电场进行质量分析,U,V和ω的至少一个参数具有两个不同的值,并且将值改变以选择第一稳定区域或第二稳定区域, 第一稳定区域最接近于原始点,而第二稳定区域靠近a-q平面上原始点(其中a:纵坐标,q:横坐标)显示“稳定性图”,并且离子能够 在第一和第二稳定区域的条件下通过四个平行电极,其中变量a = 8eU /mrO2ω2,q = 4eV /mrO2ω2,U:直流电压电平,V: 频率电压,e:离子电荷,m:离子质量,r0:r 四个平行杆电极的内切圆的像素和ω:射频电压的角频率。
    • 6. 发明授权
    • Method and apparatus for separating isotopes
    • 分离同位素的方法和装置
    • US5653854A
    • 1997-08-05
    • US607467
    • 1996-02-27
    • Goro MiyamotoYoshio MurakamiSeiji HirokiKenji Katsuki
    • Goro MiyamotoYoshio MurakamiSeiji HirokiKenji Katsuki
    • B01D59/34B01D59/48H01J49/26C25B5/00
    • B01D59/34B01D59/48
    • The improved isotope separator comprises a vacuum vessel, a plasma generator located substantially in the center of the vacuum vessel, an electrode bounded by a hyperboloid of one sheet and a pair of electrodes bounded by a hyperboloid of two sheets, said electrodes being located within the vacuum vessel in such a way as to surround the plasma generator, a power source for supplying said electrodes with a fixed voltage and a pulsating voltage, and magnetic field generating means located outside the vacuum vessel. The apparatus is implemented by a method for isotope separation that achieves high separation factor per stage (process), that enables the process throughput to be increased with ease and which yet is applicable to the isotopic separation of many elements.
    • 改进的同位素分离器包括真空容器,基本上位于真空容器中心的等离子体发生器,由一片双曲面界定的电极和由两片双曲面界定的一对电极,所述电极位于 真空容器,以围绕等离子体发生器的方式,用于向固定电压和脉动电压供应所述电极的电源,以及位于真空容器外部的磁场产生装置。 该装置通过一种同步分离方法来实现,该方法在每个阶段达到高的分离因子(工艺),这使得能够容易地提高工艺流程并且还适用于许多元素的同位素分离。
    • 7. 发明授权
    • Method and apparatus for separating isotopes
    • 分离同位素的方法和装置
    • US5805972A
    • 1998-09-08
    • US808642
    • 1997-02-28
    • Goro MiyamotoYoshio MurakamiSeiji HirokiKenji Katsuki
    • Goro MiyamotoYoshio MurakamiSeiji HirokiKenji Katsuki
    • B01D59/34B01D59/48H01J49/26B01J19/12
    • B01D59/34B01D59/48
    • The improved isotope separator comprises a vacuum vessel, a plasma generator located substantially in the center of the vacuum vessel, an electrode bounded by a hyperboloid of one sheet and a pair of electrodes bounded by a hyperboloid of two sheets, said electrodes being located within the vacuum vessel in such a way as to surround the plasma generator, a power source for supplying said electrodes with a fixed voltage and a pulsating voltage, and magnetic field generating means located outside the vacuum vessel. The apparatus is implemented by a method for isotope separation that achieves high separation factor per stage (process), that enables the process throughput to be increased with ease and which yet is applicable to the isotopic separation of many elements.
    • 改进的同位素分离器包括真空容器,基本上位于真空容器中心的等离子体发生器,由一片双曲面界定的电极和由两片双曲面界定的一对电极,所述电极位于 真空容器,以围绕等离子体发生器的方式,用于向固定电压和脉动电压供应所述电极的电源,以及位于真空容器外部的磁场产生装置。 该装置通过一种同步分离方法来实现,该方法在每个阶段达到高的分离因子(工艺),这使得能够容易地提高工艺流程并且还适用于许多元素的同位素分离。
    • 9. 发明授权
    • Device and method for leak location
    • 泄漏位置的设备和方法
    • US4583394A
    • 1986-04-22
    • US638421
    • 1984-08-07
    • Yoshio MurakamiKenjiroh ObaraTetsuya AbeYasuo ShimomuraTakemasa Shibata
    • Yoshio MurakamiKenjiroh ObaraTetsuya AbeYasuo ShimomuraTakemasa Shibata
    • G01M3/20G01M3/22
    • G01M3/202
    • A method and apparatus are disclosed for detecting the presence of very fine leaks through the walls of an enclosure which include a sniffer nozzle (1) open to the atmosphere, a vessel (5) having molecular sieves (4) therein for adsorbing substantially all gaseous products which have entered the sniffer nozzle (1) with the exception of the probe gas which has been pressurized within the enclosure being tested, a pump system (8, 9) for creating vacuum conditions within the system, a mass spectrometer (12) for detecting the presence of the probe gas, and a capillary tube (2) interconnecting the nozzle sniffer (1) and the molecular sieve assembly whereby the probe gas draw rate, and sensitivity of the apparatus of the present invention, are significantly increased.
    • 公开了一种用于检测通过外壳的壁的非常细小的泄漏的存在的方法和装置,其包括向大气开放的嗅探喷嘴(1),在其中具有分子筛(4)的容器(5),用于吸收基本上所有的气体 已经进入嗅探喷嘴(1)的产品除了被测试的外壳内被加压的探针气体外,用于在系统内产生真空条件的泵系统(8,9),质谱仪(12),用于 检测探针气体的存在,以及将喷嘴嗅探器(1)和分子筛组件相互连接的毛细管(2),从而显着提高本发明装置的探针气体抽出速率和灵敏度。