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1. 发明授权

US06610802B2 Process for synthesis of polymer compositions, polymer compositionS obtainable by the process, and use of the same 有权
标题翻译：合成聚合物组合物的方法，通过该方法获得的聚合物组合物及其用途
公开(公告)号：US06610802B2
公开(公告)日：2003-08-26
申请号：US09865526
申请日：2001-05-29
申请人： Sebastian Roos , Boris Eisenberg , Carolin Harpe
发明人： Sebastian Roos , Boris Eisenberg , Carolin Harpe
IPC分类号： C08F406
CPC分类号： C08F6/02
摘要： The present invention relates to a process for synthesis of polymer compositions with reduced catalyst content, wherein ethylenically unsaturated monomers containing less than 0.5 wt % of ethylenically unsaturated monomers with at least one carboxylic group, sulfonic acid group and/or at least one phosphonic acid group relative to the total weight of the ethylenically unsaturated monomers are polymerized by means of initiators containing a transferable group of atoms and of one or more catalysts comprising at least one transition metal in the presence of ligands which can form a coordination compound with the metal catalyst or catalysts and, after the polymerization, the catalyst contained in the polymer is at least partly separated. For this purpose, the polymer composition is filtered, after the polymerization, in the presence of at least one filter aid which contains at least 0.5 wt %, relative to the total weight of the filter aid, of repeating units that contain at least one carboxylic acid group, sulfonic acid group and/or at least one phosphonic acid group.
摘要翻译：本发明涉及一种合成具有降低的催化剂含量的聚合物组合物的方法，其中含有少于0.5重量％的具有至少一个羧基，磺酸基和/或至少一个膦酸基的烯属不饱和单体的烯属不饱和单体相对于烯键式不饱和单体的总重量，通过含有可转移原子基团的引发剂和包含至少一种过渡金属的一种或多种催化剂在可与金属催化剂形成配位化合物的配体存在下聚合，或催化剂，并且在聚合之后，包含在聚合物中的催化剂至少部分地分离。为此目的，在聚合后，在至少一种助滤剂的存在下过滤聚合物组合物，所述助滤剂相对于助滤剂的总重量含有至少0.5wt％的含有至少一个羧酸的重复单元酸基，磺酸基和/或至少一个膦酸基。

2. 发明授权

US06348554B1 Method for preparation of a liquid polymer composition and use of this composition 有权
标题翻译：液体聚合物组合物的制备方法和该组合物的用途
公开(公告)号：US06348554B1
公开(公告)日：2002-02-19
申请号：US09450741
申请日：1999-11-30
申请人： Sebastian Roos , Boris Eisenberg , Michael Mueller
发明人： Sebastian Roos , Boris Eisenberg , Michael Mueller
IPC分类号： C08J410
CPC分类号： C10M145/14 , C08F4/10 , C08F6/02 , C08F6/12 , C08F20/18 , C08F22/12 , C08F2220/1891 , C10M149/06 , C10M2209/084 , C10M2217/024 , C10M2217/06 , C08F220/14
摘要： The invention concerns a method for preparation of a liquid polymer composition, where ethylenically unsaturated monomers are polymerized by means of initiators that have a transferable atomic group, and one or more catalysts that contain at least one transition metal, in the presence of ligands that can form a coordination compound with the metallic catalysts, the catalyst is oxidized after the polymerization and then the catalyst is separated by filtration, where the composition contains a solvent with a dielectric constant less than or equal to 4.
摘要翻译：本发明涉及一种制备液体聚合物组合物的方法，其中烯键式不饱和单体通过具有可转移原子团的引发剂聚合，以及一种或多种含有至少一种过渡金属的催化剂，与金属催化剂形成配位化合物，催化剂在聚合后氧化，然后通过过滤分离催化剂，其中组合物含有介电常数小于或等于4的溶剂。

3. 发明授权

US06403746B1 Method for preparation of a composition that contains polymer ester compounds with long-chain alkyl residues and use of this composition 有权
标题翻译：制备包含具有长链烷基残基的聚合物酯化合物并使用该组合物的组合物的方法
公开(公告)号：US06403746B1
公开(公告)日：2002-06-11
申请号：US09450746
申请日：1999-11-30
申请人： Sebastian Roos , Joseph Martin Bollinger , Markus Scherer , Boris Eisenberg
发明人： Sebastian Roos , Joseph Martin Bollinger , Markus Scherer , Boris Eisenberg
IPC分类号： C08F11802
CPC分类号： C10M145/14 , C08F4/10 , C08F20/12 , C08F20/18 , C08F2220/1891 , C10M145/16 , C10M149/06 , C10M2209/084 , C10M2209/086 , C08F220/14
摘要： This invention concerns a method for preparation of poly(meth)acrylate composition, in which ethylenically unsaturated monomers are polymerized by means of initiators that have a transferable atomic group, and one or more catalysts that include at least one transition metal, in the presence of ligands that can form a coordination compound with the metallic catalyst(s) to form polymers, where ethylenically unsaturated monomers that contain 50-100 wt %, with respect to the total weight of the ethylenically unsaturated monomers, (meth)acrylates of formula (I) where R means hydrogen or methyl, R1 means a linear or branched alkyl residue with 6-40 carbon atoms, R2 and R3 independently mean hydrogen or a group of the formula—COOR′, where R′ is hydrogen or a linear or branched alkyl residue with 6-40 carbon atoms, is polymerized in the presence of 5-95 wt % mineral oil, with respect to the total weight of the composition.
摘要翻译：本发明涉及一种制备聚（甲基）丙烯酸酯组合物的方法，其中烯属不饱和单体通过具有可转移原子团的引发剂聚合，以及一种或多种包含至少一种过渡金属的催化剂，在存在可以与金属催化剂形成配位化合物以形成聚合物的配体，其中相对于烯属不饱和单体的总重量为50-100重量％的烯属不饱和单体，式（I）的（甲基）丙烯酸酯）其中R表示氢或甲基，R1表示具有6-40个碳原子的直链或支链烷基，R2和R3独立地表示氢或式-COOR'的基团，其中R'是氢或直链或支链烷基相对于组合物的总重量，在5-95重量％的矿物油的存在下聚合具有6-40个碳原子的残基。

4. 发明授权

US06989409B2 Method for synthesis of spray-dried poly(METH)acrylate polymers, use of same as polymer components for plastisols, and plastisols produced therewith 失效
标题翻译：用于合成喷雾干燥聚（METH）丙烯酸酯聚合物的方法，使用与聚合物组分相同的增塑溶胶，以及由其生产的增塑溶胶
公开(公告)号：US06989409B2
公开(公告)日：2006-01-24
申请号：US10600832
申请日：2003-06-23
申请人： Gerd Loehden , Sebastian Roos , Winfried Belzner , Hans-Juergen Geyer , Herbert Jung , Ursula Rausch
发明人： Gerd Loehden , Sebastian Roos , Winfried Belzner , Hans-Juergen Geyer , Herbert Jung , Ursula Rausch
IPC分类号： C08L83/00 , C08L3/00 , C08K5/10 , C08J3/02 , C08J3/00
CPC分类号： C09D151/003 , C08F265/06 , C08F2/02
摘要： A plastisol formulation which can be used for coatings of metal sheets, the coatings having high abrasion resistance, contains a) a plasticizer or mixture of plasticizers; and b) a mixture of polymer particles containing at least two components A and B; c) at least one member selected from the group consisting of fillers, coupling agents, stabilizers, desiccants, rheological additives, hollow bodies and mixtures thereof; wherein the polymer particles containing at least two components A and B have one of the following structures ba) a 2-stage structure, a 3-stage structure or multi-stage structure, or bb) a gradient polymer structure.
摘要翻译：可用于金属板涂层的增塑溶胶制剂，具有高耐磨性的涂层包含a）增塑剂或增塑剂混合物; 和b）含有至少两种组分A和B的聚合物颗粒的混合物; c）选自填料，偶联剂，稳定剂，干燥剂，流变添加剂，中空体及其混合物中的至少一种; 其中含有至少两种组分A和B的聚合物颗粒具有以下结构之一：ba）2级结构，3级结构或多级结构，或bb）梯度聚合物结构。

5. 发明申请

US20100324211A1 METHOD FOR THE HIGH-PRESSURE DISPERSION OF REACTIVE MONOMERS 失效
标题翻译：反应性单体的高压分散方法
公开(公告)号：US20100324211A1
公开(公告)日：2010-12-23
申请号：US12528134
申请日：2008-03-20
申请人： Andreas Huether , Sebastian Roos , Oliver Ruscitti , Heike Schuchmann , Karsten Koehler , Caroline Sauter , Freddy Aguilar
发明人： Andreas Huether , Sebastian Roos , Oliver Ruscitti , Heike Schuchmann , Karsten Koehler , Caroline Sauter , Freddy Aguilar
IPC分类号： C08K3/22 , C08K3/04 , C08K3/30 , C08F2/32 , C08L33/08
CPC分类号： B01F3/0811 , B01F3/1214 , B01F5/0077 , B01F2003/125 , C08F2/22 , C08F2/32 , C08F2/44
摘要： The object of the invention is a method for the dispersion of reactive monomers, wherein a monomer emulsion (8) is fed at a first pressure through a dispersion jet (7) and a second dispersion (9) is fed laterally behind the dispersion jet at a second pressure that is less than the first pressure, both the emulsion and the dispersion being dispersed with one another in a mixing chamber. Using the method, nanoparticle-laden monomer emulsions may be produced that, after polymerization, produce polymer-coated nanoparticles.
摘要翻译：本发明的目的是一种分散反应性单体的方法，其中单体乳液（8）以第一压力通过分散射流（7）进料，第二分散体（9）在分散射流的后面横向进料第二压力小于第一压力，乳液和分散体彼此分散在混合室中。使用该方法，可以制备纳米颗粒负载的单体乳液，其在聚合后产生聚合物包被的纳米颗粒。

6. 发明授权

US08025756B2 Method of bonding materials of construction using nanoscale, superparamagnetic poly(meth)acrylate polymers 失效
标题翻译：使用纳米级，超顺磁性聚（甲基）丙烯酸酯聚合物结合材料的方法
公开(公告)号：US08025756B2
公开(公告)日：2011-09-27
申请号：US12279197
申请日：2006-11-21
申请人： Sebastian Roos , Gerd Loehden , Jan Hendrik Schattka , Manfred Braum , Markus Pridoehl , Guido Zimmermann , Andreas Huether
发明人： Sebastian Roos , Gerd Loehden , Jan Hendrik Schattka , Manfred Braum , Markus Pridoehl , Guido Zimmermann , Andreas Huether
IPC分类号： B32B37/00
CPC分类号： C09J5/06 , C08K3/22 , C08K7/00 , C08K9/08 , C09J11/04 , C09J133/08 , C09J133/10 , C09J163/00
摘要： The invention relates to a method of bonding different materials of construction using hybrid materials comprising nanoscale, superparamagnetic, ferromagnetic, ferrimagnetic or paramagnetic powders enveloped or in part not enveloped by poly(meth)acrylates, and to their use.
摘要翻译：本发明涉及使用包含或部分不被聚（甲基）丙烯酸酯包封的纳米尺度，超顺磁性，铁磁性，亚铁磁性或顺磁性粉末的混合材料的不同材料结合的方法，以及它们的用途。

7. 发明授权

US06689844B2 Process for synthesis of polymer compositions with reduced halogen content, polymer composition with reduced halogen content as well as use of this composition 失效
标题翻译：合成具有降低的卤素含量的聚合物组合物的方法，具有降低的卤素含量的聚合物组合物以及该组合物的用途
公开(公告)号：US06689844B2
公开(公告)日：2004-02-10
申请号：US09865519
申请日：2001-05-29
申请人： Sebastian Roos , Joseph Martin Bollinger , Markus Scherer
发明人： Sebastian Roos , Joseph Martin Bollinger , Markus Scherer
IPC分类号： C08F602
CPC分类号： C08F6/02 , C08F8/26 , C08F20/00
摘要： Polymer compositions with reduced living halogen content are used as additive to lubricating oils and are prepared by polymerizing at least one ethylenically unsaturated monomer using a) at least one initiator containing a transferable halogen and b) one or more metal catalysts containing at least one transition metal, in the presence of ligands which can form a coordination compound with the one or more metal catalysts, to obtain a polymer composition having a living halogen content, and after the polymerizing, reacting the polymer composition having a living halogen content with at least one organic nitrogen compound in the presence of a nonpolar solvent, thereby reducing the living halogen content to obtain the polymer composition having a reduced halogen content.
摘要翻译：使用具有降低的活性卤素含量的聚合物组合物用作润滑油的添加剂，并且通过使用以下方法制备：使用以下物质聚合至少一种烯键式不饱和单体：a）至少一种含有可转移卤素的引发剂，和b）一种或多种含有至少一种过渡金属在可以与一种或多种金属催化剂形成配位化合物的配体的存在下，得到具有活性卤素含量的聚合物组合物，并且在聚合之后，使具有活性卤素含量的聚合物组合物与至少一种有机氮化合物在非极性溶剂的存在下，从而减少活性卤素含量，以获得具有降低的卤素含量的聚合物组合物。

8. 发明申请

US20110034599A1 CROSSLINKING ADHESIVES IN SOFTENERS 审中-公开
标题翻译：粘合剂中的交联粘合剂
公开(公告)号：US20110034599A1
公开(公告)日：2011-02-10
申请号：US12937911
申请日：2009-03-09
申请人： Sebastian Roos , Manfred Braum , Andreas Huether
发明人： Sebastian Roos , Manfred Braum , Andreas Huether
IPC分类号： C08L33/12 , C08L63/00 , C08K5/09 , C08K5/07 , C08K5/12 , C08K5/42
CPC分类号： C09J133/14 , C08L33/14 , C08L33/26 , C08L63/00 , C08L2666/02 , C08L2666/04 , C09J133/26
摘要： The invention relates to a polymer mixture comprising a mixture ofpolymer A, comprising polymers with a functional group —NRH and (meth)acrylates andpolymer B, comprising polymers having a functional group —NR—CH2OH and (meth)acrylatesin dispersion in plasticizers or epoxy resins.
摘要翻译：本发明涉及一种包含聚合物A的混合物的聚合物混合物，其包含具有官能团-NRH的聚合物和（甲基）丙烯酸酯和聚合物B，其包含在增塑剂分散体中具有官能团-NR-CH 2 OH和（甲基）丙烯酸酯的聚合物或环氧树脂。

9. 发明申请

US20090159834A1 NANOSCALE SUPERPARAMAGNETIC POLY(METH)ACRYLATE POLYMERS 审中-公开
标题翻译：纳米级超级聚氨酯（甲基）丙烯酸酯聚合物
公开(公告)号：US20090159834A1
公开(公告)日：2009-06-25
申请号：US12279276
申请日：2006-11-21
申请人： Sebastian Roos , Gerd Löhden , Jan Hendrik Schattka , Manfred Braum , Markus Pridöhl , Guido Zimmermann , Andreas Hüther
发明人： Sebastian Roos , Gerd Löhden , Jan Hendrik Schattka , Manfred Braum , Markus Pridöhl , Guido Zimmermann , Andreas Hüther
IPC分类号： H01F1/26 , B05D5/10
CPC分类号： C08K9/08
摘要： The invention relates to hybrid materials comprising polymers which envelop nanoscale, superparamagnetic, ferromagnetic, ferrimagnetic or paramagnetic powders, to a process for producing these materials and to their use.
摘要翻译：本发明涉及包含纳米尺度，超顺磁性，铁磁性，亚铁磁性或顺磁性粉末的聚合物的复合材料，涉及用于生产这些材料的方法及其应用。

10. 发明授权

US08013038B2 Method for the high-pressure dispersion of reactive monomers 失效
标题翻译：反应性单体的高压分散方法
公开(公告)号：US08013038B2
公开(公告)日：2011-09-06
申请号：US12528134
申请日：2008-03-20
申请人： Andreas Huether , Sebastian Roos , Oliver Ruscitti , Heike Schuchmann , Karsten Koehler , Caroline Sauter , Freddy Aguilar
发明人： Andreas Huether , Sebastian Roos , Oliver Ruscitti , Heike Schuchmann , Karsten Koehler , Caroline Sauter , Freddy Aguilar
IPC分类号： C09B67/00
CPC分类号： B01F3/0811 , B01F3/1214 , B01F5/0077 , B01F2003/125 , C08F2/22 , C08F2/32 , C08F2/44
摘要： The object of the invention is a method for the dispersion of reactive monomers, wherein a monomer emulsion (8) is fed at a first pressure through a dispersion jet (7) and a second dispersion (9) is fed laterally behind the dispersion jet at a second pressure that is less than the first pressure, both the emulsion and the dispersion being dispersed with one another in a mixing chamber. Using the method, nanoparticle-laden monomer emulsions may be produced that, after polymerization, produce polymer-coated nanoparticles.
摘要翻译：本发明的目的是一种分散反应性单体的方法，其中单体乳液（8）以第一压力通过分散射流（7）进料，第二分散体（9）在分散射流的后面横向进料第二压力小于第一压力，乳液和分散体彼此分散在混合室中。使用该方法，可以制备纳米颗粒负载的单体乳液，其在聚合后产生聚合物包被的纳米颗粒。

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