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1. 发明授权

US06403746B1 Method for preparation of a composition that contains polymer ester compounds with long-chain alkyl residues and use of this composition 有权
标题翻译：制备包含具有长链烷基残基的聚合物酯化合物并使用该组合物的组合物的方法
公开(公告)号：US06403746B1
公开(公告)日：2002-06-11
申请号：US09450746
申请日：1999-11-30
申请人： Sebastian Roos , Joseph Martin Bollinger , Markus Scherer , Boris Eisenberg
发明人： Sebastian Roos , Joseph Martin Bollinger , Markus Scherer , Boris Eisenberg
IPC分类号： C08F11802
CPC分类号： C10M145/14 , C08F4/10 , C08F20/12 , C08F20/18 , C08F2220/1891 , C10M145/16 , C10M149/06 , C10M2209/084 , C10M2209/086 , C08F220/14
摘要： This invention concerns a method for preparation of poly(meth)acrylate composition, in which ethylenically unsaturated monomers are polymerized by means of initiators that have a transferable atomic group, and one or more catalysts that include at least one transition metal, in the presence of ligands that can form a coordination compound with the metallic catalyst(s) to form polymers, where ethylenically unsaturated monomers that contain 50-100 wt %, with respect to the total weight of the ethylenically unsaturated monomers, (meth)acrylates of formula (I) where R means hydrogen or methyl, R1 means a linear or branched alkyl residue with 6-40 carbon atoms, R2 and R3 independently mean hydrogen or a group of the formula—COOR′, where R′ is hydrogen or a linear or branched alkyl residue with 6-40 carbon atoms, is polymerized in the presence of 5-95 wt % mineral oil, with respect to the total weight of the composition.
摘要翻译：本发明涉及一种制备聚（甲基）丙烯酸酯组合物的方法，其中烯属不饱和单体通过具有可转移原子团的引发剂聚合，以及一种或多种包含至少一种过渡金属的催化剂，在存在可以与金属催化剂形成配位化合物以形成聚合物的配体，其中相对于烯属不饱和单体的总重量为50-100重量％的烯属不饱和单体，式（I）的（甲基）丙烯酸酯）其中R表示氢或甲基，R1表示具有6-40个碳原子的直链或支链烷基，R2和R3独立地表示氢或式-COOR'的基团，其中R'是氢或直链或支链烷基相对于组合物的总重量，在5-95重量％的矿物油的存在下聚合具有6-40个碳原子的残基。

2. 发明授权

US06348554B1 Method for preparation of a liquid polymer composition and use of this composition 有权
标题翻译：液体聚合物组合物的制备方法和该组合物的用途
公开(公告)号：US06348554B1
公开(公告)日：2002-02-19
申请号：US09450741
申请日：1999-11-30
申请人： Sebastian Roos , Boris Eisenberg , Michael Mueller
发明人： Sebastian Roos , Boris Eisenberg , Michael Mueller
IPC分类号： C08J410
CPC分类号： C10M145/14 , C08F4/10 , C08F6/02 , C08F6/12 , C08F20/18 , C08F22/12 , C08F2220/1891 , C10M149/06 , C10M2209/084 , C10M2217/024 , C10M2217/06 , C08F220/14
摘要： The invention concerns a method for preparation of a liquid polymer composition, where ethylenically unsaturated monomers are polymerized by means of initiators that have a transferable atomic group, and one or more catalysts that contain at least one transition metal, in the presence of ligands that can form a coordination compound with the metallic catalysts, the catalyst is oxidized after the polymerization and then the catalyst is separated by filtration, where the composition contains a solvent with a dielectric constant less than or equal to 4.
摘要翻译：本发明涉及一种制备液体聚合物组合物的方法，其中烯键式不饱和单体通过具有可转移原子团的引发剂聚合，以及一种或多种含有至少一种过渡金属的催化剂，与金属催化剂形成配位化合物，催化剂在聚合后氧化，然后通过过滤分离催化剂，其中组合物含有介电常数小于或等于4的溶剂。

3. 发明授权

US06610802B2 Process for synthesis of polymer compositions, polymer compositionS obtainable by the process, and use of the same 有权
标题翻译：合成聚合物组合物的方法，通过该方法获得的聚合物组合物及其用途
公开(公告)号：US06610802B2
公开(公告)日：2003-08-26
申请号：US09865526
申请日：2001-05-29
申请人： Sebastian Roos , Boris Eisenberg , Carolin Harpe
发明人： Sebastian Roos , Boris Eisenberg , Carolin Harpe
IPC分类号： C08F406
CPC分类号： C08F6/02
摘要： The present invention relates to a process for synthesis of polymer compositions with reduced catalyst content, wherein ethylenically unsaturated monomers containing less than 0.5 wt % of ethylenically unsaturated monomers with at least one carboxylic group, sulfonic acid group and/or at least one phosphonic acid group relative to the total weight of the ethylenically unsaturated monomers are polymerized by means of initiators containing a transferable group of atoms and of one or more catalysts comprising at least one transition metal in the presence of ligands which can form a coordination compound with the metal catalyst or catalysts and, after the polymerization, the catalyst contained in the polymer is at least partly separated. For this purpose, the polymer composition is filtered, after the polymerization, in the presence of at least one filter aid which contains at least 0.5 wt %, relative to the total weight of the filter aid, of repeating units that contain at least one carboxylic acid group, sulfonic acid group and/or at least one phosphonic acid group.
摘要翻译：本发明涉及一种合成具有降低的催化剂含量的聚合物组合物的方法，其中含有少于0.5重量％的具有至少一个羧基，磺酸基和/或至少一个膦酸基的烯属不饱和单体的烯属不饱和单体相对于烯键式不饱和单体的总重量，通过含有可转移原子基团的引发剂和包含至少一种过渡金属的一种或多种催化剂在可与金属催化剂形成配位化合物的配体存在下聚合，或催化剂，并且在聚合之后，包含在聚合物中的催化剂至少部分地分离。为此目的，在聚合后，在至少一种助滤剂的存在下过滤聚合物组合物，所述助滤剂相对于助滤剂的总重量含有至少0.5wt％的含有至少一个羧酸的重复单元酸基，磺酸基和/或至少一个膦酸基。

4. 发明申请

US20070213237A1 USE OF GRAFT POLYMERS 有权
标题翻译：聚合物的使用
公开(公告)号：US20070213237A1
公开(公告)日：2007-09-13
申请号：US11572181
申请日：2005-06-23
申请人： Markus Scherer , Klaus Hedrich , Alexander Dardin , Michael Muller , Thorsten Stoehr , Boris Eisenberg
发明人： Markus Scherer , Klaus Hedrich , Alexander Dardin , Michael Muller , Thorsten Stoehr , Boris Eisenberg
IPC分类号： C10M145/14
CPC分类号： C10M149/10 , C08L51/06 , C10M149/02 , C10M161/00 , C10M2209/084 , C10M2217/02 , C10M2217/028 , C10N2220/021 , C10N2220/022 , C10N2230/02 , C10N2230/04 , C10N2230/06 , C10N2230/43 , C10N2240/04 , C10N2240/08 , C10N2240/10
摘要： The invention relates to the use of graft polymers obtained by polymerization in two stages. In a first stage, at least one graft basis is produced by radically polymerizing a monomer composition A) containing 0 to 40 percent by weight of one or several ethylenically unsaturated ester compounds of formula (I), wherein R represents hydrogen or methyl, R1 represents a linear or branched alkyl radical comprising 1 to 5 carbon atoms, R2 and R3 independently represent hydrogen or a group of formula —COOR′, wherein R′ represents hydrogen or an alkyl group comprising 1 to 5 carbon atoms, 60 to 100 percent by weight of one or several ethylenically unsaturated ester compounds of formula (II), wherein R represents hydrogen or methyl, R4 represents a linear or branched alkyl radical comprising 6 to 40 carbon atoms, R5 and R6 independently represent hydrogen or a group of formula —COOR′, wherein R′ represents hydrogen or an alkyl group comprising 6 to 40 carbon atoms, and 0 to 40 percent by weight of comonomers, the percentages being relative to the weight of monomer composition A). In a second stage, a monomer composition B) containing 20 to 100 percent by weight of at least one monomer that comprises at least one nitrogen-containing group is grafted onto the graft basis in order to reduce wear in lubricant oil compositions. Said graft polymer comprises a maximum of 200 ppm of sulfur while the weight ratio between monomer composition A) and monomer composition B) ranges between 99.7:0.3 and 80:20.
摘要翻译：本发明涉及通过两步聚合获得的接枝聚合物的用途。在第一阶段中，通过自由基聚合含有0至40重量％的一种或几种式（I）的烯键式不饱和酯化合物，其中R表示氢或甲基， SUP> 1表示包含1至5个碳原子的直链或支链烷基，R 2和R 3独立地表示氢或式-COOR基团 '，其中R'表示氢或包含1至5个碳原子的烷基，60至100重量％的一种或几种式（II）的烯属不饱和酯化合物，其中R表示氢或甲基，R 4 代表含有6至40个碳原子的直链或支链烷基，R 5和R 6独立代表氢或式-COOR'基团，其中 R'表示氢或含有6〜40个碳原子的烷基，0〜40重量％的共聚单体，百分比年龄相对于单体组合物A）的重量。在第二阶段中，将包含20至100重量％的至少一种包含至少一个含氮基团的单体的单体组合物B）接枝到接枝基上以减少润滑油组合物中的磨损。所述接枝聚合物包含最多200ppm的硫，而单体组合物A）和单体组合物B）之间的重量比在99.7:0.3和80:20之间。

5. 发明授权

US09080124B2 Use of graft polymers 有权
标题翻译：接枝聚合物的使用
公开(公告)号：US09080124B2
公开(公告)日：2015-07-14
申请号：US11572181
申请日：2005-06-23
申请人： Markus Scherer , Klaus Hedrich , Alexander Dardin , Michael Mueller , Torsten Stoehr , Boris Eisenberg
发明人： Markus Scherer , Klaus Hedrich , Alexander Dardin , Michael Mueller , Torsten Stoehr , Boris Eisenberg
IPC分类号： C10M149/10 , C10M149/02 , C08L51/06 , C10M161/00
CPC分类号： C10M149/10 , C08L51/06 , C10M149/02 , C10M161/00 , C10M2209/084 , C10M2217/02 , C10M2217/028 , C10N2220/021 , C10N2220/022 , C10N2230/02 , C10N2230/04 , C10N2230/06 , C10N2230/43 , C10N2240/04 , C10N2240/08 , C10N2240/10
摘要： The invention relates to the use of graft polymers obtained by polymerization in two stages. In a first stage, at least one graft basis is produced by radically polymerizing a monomer composition A) containing 0 to 40 percent by weight of one or several ethylenically unsaturated ester compounds of formula (I), wherein R represents hydrogen or methyl, R1 represents a linear or branched alkyl radical comprising 1 to 5 carbon atoms, R2 and R3 independently represent hydrogen or a group of formula —COOR′, wherein R′ represents hydrogen or an alkyl group comprising 1 to 5 carbon atoms, 60 to 100 percent by weight of one or several ethylenically unsaturated ester compounds of formula (II), wherein R represents hydrogen or methyl, R4 represents a linear or branched alkyl radical comprising 6 to 40 carbon atoms, R5 and R6 independently represent hydrogen or a group of formula —COOR′, wherein R′ represents hydrogen or an alkyl group comprising 6 to 40 carbon atoms, and 0 to 40 percent by weight of comonomers, the percentages being relative to the weight of monomer composition A). In a second stage, a monomer composition B) containing 20 to 100 percent by weight of at least one monomer that comprises at least one nitrogen-containing group is grafted onto the graft basis in order to reduce wear in lubricant oil compositions. Said graft polymer comprises a maximum of 200 ppm of sulfur while the weight ratio between monomer composition A) and monomer composition B) ranges between 99.7:0.3 and 80:20.
摘要翻译：本发明涉及通过两步聚合获得的接枝聚合物的用途。在第一阶段中，通过自由基聚合含有0至40重量％的一种或多种式（I）的烯属不饱和酯化合物，其中R表示氢或甲基，R1表示包含1至5个碳原子的直链或支链烷基，R2和R3独立地表示氢或式-COOR'的基团，其中R'表示氢或包含1至5个碳原子的烷基，60至100重量％的一种或几种式（II）的烯键式不饱和酯化合物，其中R表示氢或甲基，R4表示包含6至40个碳原子的直链或支链烷基，R5和R6独立地表示氢或式-COOR' ，其中R'表示氢或含有6至40个碳原子的烷基和0至40重量％的共聚单体，其百分数相对于单体组合物的重量在A上）。在第二阶段中，将包含20至100重量％的至少一种包含至少一个含氮基团的单体的单体组合物B）接枝到接枝基上以减少润滑油组合物中的磨损。所述接枝聚合物包含最多200ppm的硫，而单体组合物A）和单体组合物B）之间的重量比在99.7:0.3和80:20之间。

6. 发明授权

US09914896B2 Lubricant composition with phosphorus-functionalized polymers 有权
公开(公告)号：US09914896B2
公开(公告)日：2018-03-13
申请号：US14119550
申请日：2012-04-19
申请人： Boris Eisenberg , Ellen Suchert
发明人： Boris Eisenberg , Ellen Suchert
IPC分类号： C10M137/10 , C08F24/00 , C08F124/00 , C08F224/00 , C10M153/02
CPC分类号： C10M153/02 , C10M2203/1006 , C10M2203/1025 , C10M2205/0285 , C10M2209/084 , C10M2223/04 , C10M2223/045 , C10M2223/047 , C10M2223/049 , C10M2223/06 , C10M2225/02 , C10N2220/021 , C10N2230/06 , C10N2230/08 , C10N2240/04 , C10N2240/10 , C10N2220/022
摘要： The present invention relates to a lubricant composition comprising at least one polyalkyl(meth)acrylate including repeating units derived from (meth)acrylates having 6 to 22 carbon atoms in the alcohol radical, wherein the polyalkyl(meth)acrylate includes repeating units derived from ethylenically unsaturated monomers having at least one covalently bonded phosphorus atom. The present invention further relates to a polyalkyl(meth)acrylate suitable for such a lubricant composition and to the use of a polyalkyl(meth)acrylate having repeating units derived from ethylenically unsaturated monomers having at least one covalently bonded phosphorus atom for reducing friction.

7. 发明申请

US20110319305A1 USE OF COMB COPOLYMERS FOR IMPROVING SCUFFING LOAD CAPACITY 审中-公开
标题翻译：使用COMB共聚物改善加载负载能力
公开(公告)号：US20110319305A1
公开(公告)日：2011-12-29
申请号：US13255218
申请日：2010-02-09
申请人： Boris Eisenberg , Roland Schweder , Michael Alibert , Torsten Stoehr
发明人： Boris Eisenberg , Roland Schweder , Michael Alibert , Torsten Stoehr
IPC分类号： C10M169/04 , C08F236/22
CPC分类号： C10M145/14 , C10M145/16 , C10M2203/1006 , C10M2203/1065 , C10M2209/084 , C10M2209/086 , C10N2220/021 , C10N2220/022 , C10N2230/06 , C10N2240/08 , C10N2270/00
摘要： The present invention relates to the use of comb polymers comprising, in the main chain, repeat units derived from polyolefin-based macromonomers with a molecular weight of at least 500 g/mol, and repeat units derived from low molecular weight monomers with a molecular weight less than 500 g/mol, for improving the load-bearing capacity of hydraulic fluids. Furthermore, the present invention describes new hydraulic fluids.
摘要翻译：本发明涉及梳状聚合物的用途，其在主链中包含衍生自分子量至少为500g / mol的聚烯烃基大分子单体的重复单元，以及衍生自具有分子量的低分子量单体的重复单元小于500g / mol，用于提高液压油的承载能力。此外，本发明描述了新的液压流体。

8. 发明授权

US08067349B2 Oil soluble comb polymers 有权
标题翻译：油溶性梳状聚合物
公开(公告)号：US08067349B2
公开(公告)日：2011-11-29
申请号：US11909171
申请日：2006-04-07
申请人： Torsten Stoehr , Boris Eisenberg , Michael Mueller
发明人： Torsten Stoehr , Boris Eisenberg , Michael Mueller
IPC分类号： C10M145/14 , C10M149/04 , C10L1/18
CPC分类号： C08F290/04 , C08F299/00 , C10M159/005 , C10M2203/1006 , C10M2203/1025 , C10M2205/028 , C10M2205/0285 , C10M2209/04 , C10M2209/062 , C10M2209/084 , C10M2209/086 , C10N2220/021 , C10N2220/028 , C10N2230/02 , C10N2230/04 , C10N2230/06 , C10N2230/68 , C10N2220/022
摘要： The invention relates to comb polymers which comprise, in the main chain, repeating units which are derived from polyolefin-based macromonomers, and repeating units which are derived from low molecular monomers which are selected from the group consisting of styrene monomers having 8-17 carbon atoms, alkyl(meth)acrylates having 1-10 carbon atoms in the alcohol group, vinyl esters having 1-11 carbon atoms in the acyl group, vinyl ethers having 1-10 carbon atoms in the alcohol group, (Di)alkylfumarates having 1-10 carbon atoms in the alcohol group, (Di)alkylmaleates having 1-10 carbon atoms in the alcohol group and mixtures of said monomers. The molar branching degree lies in the region between 0.1-10 mol. % and the comb polymer represents the sum of at least 80 wt. %, in relation to the weight of the repeating units, on repeating units which are derived from polyolefin-based macromonomers, and repeating units which are selected from low molecular monomers which are selected from the group consisting of styrene monomers having 8-17 carbon atoms, alkyl(meth)acrylates having 1-10 carbon atoms in the alcohol group, vinyl esters having 1-11 carbon atoms in the acyl group, vinyl ethers having 1-10 carbon atoms in the alcohol group, (Di)alkylfumarates having 1-10 carbon atoms in the alcohol group, (Di)alkylmaleates having 1-10 carbon atoms in the alcohol group, and mixtures of said monomers.
摘要翻译：本发明涉及在主链中包含衍生自聚烯烃基大分子单体的重复单元和衍生自低分子单体的重复单元的梳状聚合物，所述低分子单体选自具有8-17个碳原子的苯乙烯单体原子，醇基中具有1-10个碳原子的（甲基）丙烯酸烷基酯，酰基中具有1-11个碳原子的乙烯基酯，醇基中具有1-10个碳原子的乙烯基醚，具有1个碳原子的（Di）烷基富马酸盐 -10个碳原子，醇基中具有1-10个碳原子的（Di）烷基马来酸酯和所述单体的混合物。摩尔分支度位于0.1-10mol之间的区域。％，梳状聚合物代表至少80wt。相对于重复单元的重量，衍生自聚烯烃基大分子单体的重复单元的重复单元和选自具有8-17个碳原子的苯乙烯单体的低分子单体的重复单元，醇基中具有1-10个碳原子的（甲基）丙烯酸烷基酯，酰基中具有1-11个碳原子的乙烯基酯，醇基中具有1-10个碳原子的乙烯基醚，具有1- 醇基中的10个碳原子，醇基中具有1-10个碳原子的（Di）烷基马来酸化物，以及所述单体的混合物。

9. 发明授权

US09783630B2 Use of comb polymers for reducing fuel consumption 有权
公开(公告)号：US09783630B2
公开(公告)日：2017-10-10
申请号：US12668209
申请日：2008-04-10
申请人： Torsten Stoehr , Dieter Janssen , Juergen Schnabel , Boris Eisenberg , Hans Goerlitzer , Michael Mueller
发明人： Torsten Stoehr , Dieter Janssen , Juergen Schnabel , Boris Eisenberg , Hans Goerlitzer , Michael Mueller
IPC分类号： C10M145/14 , C08F290/04 , C10M143/12 , C10M143/00 , C10M143/10
CPC分类号： C08F290/04 , C10M143/00 , C10M143/10 , C10M143/12 , C10M145/14 , C10M2205/00 , C10M2205/04 , C10M2205/06 , C10M2209/00 , C10M2209/08 , C10N2220/022 , C10N2230/02 , C10N2230/54 , C10M2209/084
摘要： The present invention relates to the use of comb polymers comprising, in the main chain, repeat units which are derived from polyolefin-based macromonomers, and repeat units which are derived from low molecular weight monomers selected from the group consisting of styrene monomers having 8 to 17 carbon atoms, alkyl (meth)acrylates having 1 to 10 carbon atoms in the alcohol group, vinyl esters having 1 to 11 carbon atoms in the acyl group, vinyl ethers having 1 to 10 carbon atoms in the alcohol group, (di)alkyl fumarates having 1 to 10 carbon atoms in the alcohol group, (di)alkyl maleates having 1 to 10 carbon atoms in the alcohol group and mixtures of these monomers, where the molar degree of branching is in the range of 0.1 to 10 mol % and the comb polymer comprises a total of at least 80% by weight, based on the weight of the repeat units, of repeat units which are derived from polyolefin-based macromonomers and repeat units which are derived from low molecular weight monomers selected from the group consisting of styrene monomers having 8 to 17 carbon atoms, alkyl (meth)acrylates having 1 to 10 carbon atoms in the alcohol group, vinyl esters having 1 to 11 carbon atoms in the acyl group, vinyl ethers having 1 to 10 carbon atoms in the alcohol group, (di)alkyl fumarates having 1 to 10 carbon atoms in the alcohol group, (di)alkyl maleates having 1 to 10 carbon atoms in the alcohol group and mixtures of these monomers, for reducing the fuel consumption of vehicles.

10. 发明申请

US20140274835A1 METHOD OF PROVIDING HIGH COEFFICIENTS OF FRICTION ACROSS OIL-LUBRICATING FRICTION CLUTCHES 审中-公开
标题翻译：提供油润滑摩擦离合器摩擦系数高的方法
公开(公告)号：US20140274835A1
公开(公告)日：2014-09-18
申请号：US13798404
申请日：2013-03-13
申请人： Raymond F. Watts , Joe R. Noles, JR. , Michael Müller , Torsten Stöhr , Boris Eisenberg
发明人： Raymond F. Watts , Joe R. Noles, JR. , Michael Müller , Torsten Stöhr , Boris Eisenberg
IPC分类号： C10M133/44 , C10M129/72 , C10M129/70
CPC分类号： C10M149/10 , C10M145/14 , C10M145/16 , C10M159/005 , C10M2209/084 , C10M2209/086 , C10M2215/28 , C10M2217/02 , C10M2217/028 , C10M2221/02 , C10N2220/021 , C10N2230/06 , C10N2240/042 , C10N2240/044 , C10N2240/045
摘要： The invention concerns a method of increasing the dynamic coefficient of friction in an oil-lubricated friction clutch by using a lubricating oil containing at least one specific copolymer, the presence of which develops higher dynamic friction levels in the clutch.
摘要翻译：本发明涉及通过使用含有至少一种特定共聚物的润滑油来增加油润滑摩擦离合器中的动态摩擦系数的方法，其存在在离合器中产生更高的动态摩擦水平。

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