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1. 发明授权

US06506935B1 Combination pretreatment/adsorption for treating a liquid stream contaminated with an iodine-containing compound 失效
标题翻译：用于处理受含碘化合物污染的液态物流的组合预处理/吸附
公开(公告)号：US06506935B1
公开(公告)日：2003-01-14
申请号：US09905454
申请日：2001-07-13
申请人： Santi Kulprathipanja , Bipin V. Vora , William A. Leet
发明人： Santi Kulprathipanja , Bipin V. Vora , William A. Leet
IPC分类号： C07C5142
CPC分类号： C07B63/00 , C07C51/47
摘要： For the removal of trace quantities of iodine-containing contaminants from corrosive liquid feed streams (e.g. commercial acetic acid), an adsorbent with distinct advantages over prior-art materials is provided. The overall treatment method involves the use of a suitable zeolite having a silica to alumina molar ratio from about 5 to less than 15 that has been cation-exchanged with an iodine-reactive metal. This inorganic adsorbent may be used in unbound form, or it can be bound with a substantially insoluble porous inorganic refractory metal oxide binder. Reactivation and regeneration techniques, which are generally incompatible with prior-art adsorbent materials, are also disclosed. In general, it is advantageous to pretreat the feed streams to remove the most easily separable contaminants (e.g. iodine, hydrogen iodide, and metal cations) and thereby reduce the iodine compound loading and detrimental effects of metals on the adsorbent. Thus, the expensive iodine reactive metal (e.g. silver) used in the adsorbent preparation is judiciously used for the removal of trace quantities of iodine-containing species (e.g. alkyl iodides) that are not readily separable by other means.
摘要翻译：为了从腐蚀性液体进料流（例如商业乙酸）中除去痕量的含碘污染物，提供了与现有技术材料相比具有明显优点的吸附剂。总体处理方法包括使用与碘反应性金属进行阳离子交换的具有约5至小于15的二氧化硅与氧化铝摩尔比的合适的沸石。该无机吸附剂可以以未结合的形式使用，也可以与基本上不溶的多孔无机难熔金属氧化物粘合剂结合。还公开了通常与现有技术吸附材料不相容的再活化和再生技术。通常，有利的是预处理进料流以除去最容易分离的污染物（例如碘，碘化氢和金属阳离子），从而降低碘化合物的负载量和金属对吸附剂的不利影响。因此，在吸附剂制备中使用的昂贵的碘反应性金属（例如银）被明智地用于除去不易通过其它方法分离的痕量的含碘物质（例如烷基碘化物）。

2. 发明授权

US6007724A Method for treating a liquid stream contaminated with an iodine-containing compound using a solid absorbent comprising a metal phthalocyanine 失效
标题翻译：使用含有金属酞菁的固体吸收剂处理被含碘化合物污染的液态物流的方法
公开(公告)号：US6007724A
公开(公告)日：1999-12-28
申请号：US216767
申请日：1998-12-21
申请人： Santi Kulprathipanja , Bipin V. Vora , Yan Li
发明人： Santi Kulprathipanja , Bipin V. Vora , Yan Li
IPC分类号： B01D15/00 , B01J20/32 , B01J20/34
CPC分类号： B01D15/00 , B01J20/20 , B01J20/223 , B01J20/3204 , B01J20/3265 , B01J20/3416 , B01J20/3425 , B01J20/3458 , B01J20/3475 , B01J2220/66
摘要： For the removal of trace quantities of iodine-containing contaminants from corrosive liquid feed streams, an adsorbent with distinct advantages over prior-art materials is provided. The treatment method involves the use of a metal phthalocyanine compound where the metal selected from the group consisting of silver, mercury, copper, lead, thallium, palladium, or mixtures thereof. Such metals are known to be reactive with the iodine-containing contaminants in the feed stream. Furthermore, the metal phthalocyanine is deposited on a carrier material selected from the group consisting of an activated carbon, a phenolic polymer, and an inorganic refractory metal oxide. Such adsorbent materials have proven substantially insoluble even in corrosive liquid feed streams associated with the invention. Reactivation and regeneration techniques, which are generally incompatible with prior-art adsorbent materials, are also disclosed.
摘要翻译：为了从腐蚀性液体进料流中除去痕量的含碘污染物，提供了与现有技术材料相比具有明显优点的吸附剂。处理方法涉及使用金属酞菁化合物，其中选自银，汞，铜，铅，铊，钯或其混合物的金属。已知这些金属与进料流中的含碘污染物反应。此外，金属酞菁沉积在选自活性炭，酚醛聚合物和无机难熔金属氧化物的载体材料上。已经证明这种吸附材料即使在与本发明相关的腐蚀性液体进料流中也基本不溶。还公开了通常与现有技术吸附材料不相容的再活化和再生技术。

3. 发明授权

US07102044B1 Process for removal of oxygenates from a paraffin stream 有权
标题翻译：从石蜡流中除去含氧化合物的方法
公开(公告)号：US07102044B1
公开(公告)日：2006-09-05
申请号：US10882887
申请日：2004-06-30
申请人： Santi Kulprathipanja , James W. Priegnitz , Stephen W. Sohn , Bryan K. Glover , Bipin V. Vora
发明人： Santi Kulprathipanja , James W. Priegnitz , Stephen W. Sohn , Bryan K. Glover , Bipin V. Vora
IPC分类号： C07C2/64
CPC分类号： C07C5/333 , C07C2/66 , C07C7/12 , C07C7/13 , C07C15/107 , C07C9/14 , C07C11/02
摘要： The present invention comprises a process for removal of oxygenates from a paraffin-rich or olefin-rich paraffin stream which comprises passing a feed stream, comprising one or more C10 to C15 feed paraffins or C10 to C15 olefin-rich paraffin stream and one or more oxygenates through an adsorbent bed comprising one or more adsorbents selected from silica gel, activated alumina and sodium x zeolites to remove essentially all of said oxygenates; and recovering said paraffins. A second adsorbent bed may be employed to more thoroughly remove these oxygenates.
摘要翻译：本发明包括从富含链烷烃或富烯烃的石蜡流中除去含氧化合物的方法，该方法包括将含有一个或多个C 10的进料流通入C 15 通过吸附床将含有一种或多种选自硅胶，活性氧化铝和吸附剂的吸附剂的烷烃或C 10向富含C 15的富烯烃链烷烃流和一种或多种含氧化合物进料，钠x沸石以除去基本上所有的含氧化合物; 并回收所述石蜡。可以使用第二吸附剂床来更彻底地除去这些含氧化合物。

4. 发明授权

US07368618B2 Process for removal of oxygenates from a paraffin stream 有权
标题翻译：从石蜡流中除去含氧化合物的方法
公开(公告)号：US07368618B2
公开(公告)日：2008-05-06
申请号：US11457889
申请日：2006-07-17
申请人： Santi Kulprathipanja , James W. Priegnitz , Stephen W. Sohn , Bryan K. Glover , Bipin V. Vora
发明人： Santi Kulprathipanja , James W. Priegnitz , Stephen W. Sohn , Bryan K. Glover , Bipin V. Vora
IPC分类号： C07C5/327
CPC分类号： C07C5/333 , C07C2/66 , C07C7/12 , C07C7/13 , C07C15/107 , C07C9/14 , C07C11/02
摘要： The present invention comprises a process for removal of oxygenates from a paraffin-rich or olefin-rich paraffin stream which comprises passing a feed stream, comprising one or more C10 to C15 feed paraffins or C10 to C15 olefin-rich paraffin stream and one or more oxygenates through an adsorbent bed comprising one or more adsorbents selected from silica gel, activated alumina and sodium x zeolites to remove essentially all of said oxygenates; and recovering said paraffins. A second adsorbent bed may be employed to more thoroughly remove these oxygenates.
摘要翻译：本发明包括从富含链烷烃或富烯烃的石蜡流中除去含氧化合物的方法，该方法包括将含有一个或多个C 10的进料流送入C 15 通过吸附床将含有一种或多种选自硅胶，活性氧化铝和吸附剂的吸附剂的烷烃或C 10向富含C 15的富烯烃链烷烃流和一种或多种含氧化合物进料，钠x沸石以除去基本上所有的含氧化合物; 并回收所述石蜡。可以使用第二吸附剂床来更彻底地除去这些含氧化合物。

5. 发明申请

US20100240941A1 New Catalyst for Higher Production Rates in Hydrocarbon Dehydrogenation 失效
标题翻译：用于烃脱氢的更高生产率的新催化剂
公开(公告)号：US20100240941A1
公开(公告)日：2010-09-23
申请号：US12406522
申请日：2009-03-18
申请人： Mark G. Riley , Bipin V. Vora
发明人： Mark G. Riley , Bipin V. Vora
IPC分类号： C07C5/333
CPC分类号： C07C5/3335 , C10G2400/20 , C10G2400/22
摘要： A process is presented for the dehydrogenation of hydrocarbons in a radial flow reactor. The process includes the continuous feeding of catalyst into the reactor and the continuous withdrawal of catalyst from the reactor, where the catalyst is modified to increase the increased density. The catalyst is a layered structure with a dense core and an active catalytic outer layer.
摘要翻译：提出了一种用于在径向流动反应器中烃的脱氢的方法。该方法包括将催化剂连续进料到反应器中，以及催化剂从反应器中连续排出，其中催化剂被改性以增加密度。催化剂是具有致密核心和活性催化外层的层状结构。

6. 发明授权

US07268265B1 Apparatus and process for light olefin recovery 有权
标题翻译：轻烯烃回收的设备和工艺
公开(公告)号：US07268265B1
公开(公告)日：2007-09-11
申请号：US10882531
申请日：2004-06-30
申请人： Douglas G. Stewart , Joseph E. Zimmermann , Angelo P. Furfaro , Bipin V. Vora
发明人： Douglas G. Stewart , Joseph E. Zimmermann , Angelo P. Furfaro , Bipin V. Vora
IPC分类号： C07C1/00 , C07C1/20
CPC分类号： C07C4/06 , C07C7/163 , C10G2400/20 , Y02P30/42 , C07C11/04 , C07C11/06 , C07C11/02
摘要： The present invention relates to a process and apparatus for the production of light olefins comprising olefins having from 2 to 3 carbon atoms per molecule from a feedstock containing heavier olefins. An intermediate cut from a fractionation column is used as olefinic feed to an olefin cracking process preferably after undergoing selective hydrogenation of diolefins. In one embodiment, a liquid side draw from a fractionation column is selectively hydrogenated and then returned to the fractionation column from which a vapor side draw containing olefins is cracked in the olefin cracking reactor.
摘要翻译：本发明涉及一种用于生产轻质烯烃的方法和设备，其包含每分子含有2至3个碳原子的烯烃，其含有较重的烯烃的原料。来自分馏塔的中间馏分用作烯烃裂化方法的烯烃进料，优选在进行二烯烃的选择性氢化之后。在一个实施方案中，从分馏塔抽出的液体侧被选择性氢化，然后返回到在烯烃裂解反应器中含有烯烃的蒸汽侧馏分从其分馏的分馏塔。

7. 发明授权

US07189885B1 Staged process for producing linear 2-phenyl-alkanes 有权
标题翻译：生产线性2-苯基烷烃的分阶段方法
公开(公告)号：US07189885B1
公开(公告)日：2007-03-13
申请号：US10680683
申请日：2003-10-07
申请人： Andrea G. Bozzano , R. Joe Lawson , Paul T. Barger , Bipin V. Vora , Kurt A. Detrick
发明人： Andrea G. Bozzano , R. Joe Lawson , Paul T. Barger , Bipin V. Vora , Kurt A. Detrick
IPC分类号： C07C2/64 , C07C2/66
CPC分类号： C07C2/66 , B01J21/12 , B01J29/18 , B01J35/0006 , B01J37/26 , B01J2229/42 , C07C2/68 , C07C2521/12 , C07C2527/12 , C07C2529/18 , C07C15/107
摘要： The process disclosed herein is a process for producing phenyl-alkanes by alkylation of an aryl compound with an olefinic compound and which uses a mordenite catalyst and a silica-alumina catalyst. The selectivity of the process to 2-phenyl-alkanes can be varied over a wide range.
摘要翻译：本文公开的方法是通过用烯烃化合物烷基化芳基化合物并使用丝光沸石催化剂和二氧化硅 - 氧化铝催化剂来生产苯基烷烃的方法。该方法对2-苯基 - 烷烃的选择性可以在很宽的范围内变化。

8. 发明授权

US06156947A Process for the production of butene-1 from a mixture of C.sub.4 olefins 有权
标题翻译：从C4烯烃混合物生产丁烯-1的方法
公开(公告)号：US06156947A
公开(公告)日：2000-12-05
申请号：US340622
申请日：1999-06-28
申请人： Bipin V. Vora
发明人： Bipin V. Vora
IPC分类号： C07C11/08 , C07C41/06 , C07C41/42 , C07C1/00
CPC分类号： C07C11/08 , C07C41/06 , C07C41/42 , C07C2529/85 , Y02P20/127
摘要： A simplified process for jointly producing butene-1 and ether in a catalytic distillation column which comprises an upper catalytic zone for etherification and a lower catalytic zone for isomerization of C.sub.4 plus olefins and conversion of butadiene. The process is especially useful when combined with a process for the production of light olefins including ethylene and propylene from methanol. According to the invention, the produced butene-1 stream is combined with ethylene to produce polyethylene.
摘要翻译：在催化蒸馏塔中共同生产丁烯-1和醚的简化方法，其包括用于醚化的上部催化区和用于C4加烯烃异构化的较低催化区和丁二烯的转化。当与用于从甲醇生产包括乙烯和丙烯的轻质烯烃的方法组合时，该方法是特别有用的。根据本发明，将生产的丁烯-1流与乙烯混合以制备聚乙烯。

9. 发明授权

US6015933A Process for removing polymeric by-products from acetylene hydrogenation product 失效
标题翻译：从乙炔氢化产物中除去聚合物副产物的方法
公开(公告)号：US6015933A
公开(公告)日：2000-01-18
申请号：US115481
申请日：1998-07-15
申请人： Hayim Abrevaya , Bipin V. Vora
发明人： Hayim Abrevaya , Bipin V. Vora
IPC分类号： C07C7/00 , C07C7/10
CPC分类号： C07C7/005 , C07C7/10
摘要： A process to remove polymeric by-products from the product of an acetylene selective hydrogenation reactor has been developed. The product is generated by introducing hydrogen and a liquid hydrocarbon stream containing largely butadiene and some acetylenes to a reactor containing a catalyst effective for the selective hydrogenation of acetylenes. The product contains at least hydrogen, butadiene, and polymeric by-products. The pressure of the product is reduced and the product cooled. The cooled product is conducted to a low pressure flash drum to produce a hydrogen enriched stream and a butadiene and polymeric by-product-enriched stream. The hydrogen-enriched stream is removed. The butadiene and polymeric by-product is passed to a knockout drum to produce a stream enriched in butadiene and polymeric by-products having less than about 12 carbon atoms and a stream enriched in polymeric by-products having about 12 or more carbon atoms. The stream enriched in polymeric by-products having about 12 or more carbon atoms is removed from the process. Polymeric by-products containing less than about 12 carbon atoms may be removed from the remaining stream by conducting a solvent and the stream enriched in butadiene and polymeric by-products containing less than about 12 carbon atoms to an extractive distillation column. In the extractive distillation column, the butadiene and polymeric by-products containing less than about 12 carbon atoms are carried with the solvent and removed in a bottoms stream as an extract mixture while the butanes and butenes are removed in an extractive distillation overhead stream. The bottoms extract stream is conducted to a stripper column where the solvent and the polymeric by-products are separated from the butadiene.
摘要翻译：已经开发了从乙炔选择性氢化反应器的产物中除去聚合物副产物的方法。该产物通过将含有大量丁二烯和一些乙炔的氢气和液体烃流引入含有对乙炔的选择性氢化有效的催化剂的反应器而产生。该产品至少含有氢，丁二烯和聚合副产物。产品的压力降低，产品冷却。冷却的产物被传导到低压闪蒸鼓以产生富氢流和丁二烯和聚合副产物富集流。除去富氢流。丁二烯和聚合副产物被传送到分离鼓中以产生富含丁二烯的流和具有小于约12个碳原子的聚合副产物和富含约12个或更多个碳原子的聚合副产物的物流。从该方法中除去富含约12个或更多个碳原子的聚合副产物的物流。含有少于约12个碳原子的聚合副产物可以通过将富含丁二烯的溶剂和含有少于约12个碳原子的聚合副产物的物流引入萃取蒸馏塔从剩余物流中除去。在萃取蒸馏塔中，含有少于约12个碳原子的丁二烯和聚合副产物与溶剂一起携带并在塔底物流中作为提取物混合物除去，同时在萃取蒸馏塔顶馏出物中除去丁烷和丁烯。将塔底提取物流引入汽提塔，其中溶剂和聚合副产物与丁二烯分离。

10. 发明授权

US5990369A Process for producing light olefins 失效
标题翻译：轻质烯烃的生产工艺
公开(公告)号：US5990369A
公开(公告)日：1999-11-23
申请号：US21044
申请日：1998-02-09
申请人： Paul T. Barger , R. Joe Lawson , Bipin V. Vora
发明人： Paul T. Barger , R. Joe Lawson , Bipin V. Vora
IPC分类号： C07C11/02 , C07C1/20 , C07C2/00 , C07C5/23
CPC分类号： C07C11/02 , C07C2529/85 , Y02P20/127
摘要： The present invention relates to a process for the production of light olefins comprising olefins having from 2 to 4 carbon atoms per molecule from an oxygenate feedstock. The process comprises passing the oxygenate feedstock to an oxygenate conversion zone containing a metal alumninophosphate catalyst to produce a light olefin stream. The light olefin stream is fractionated and a portion of the products are metathesized to enhance the yield of the ethylene, propylene, and/or butylene products. Propylene can be metathesized to produce more ethylene, or a combination of ethylene and butene can be metathesized to produce more propylene. This combination of light olefin production and metathesis, or disproportionation provides flexibility to overcome the equilibrium limitations of the metal aluminophosphate catalyst in the oxygenate conversion zone. In addition, the invention provides the advantage of extended catalyst life and greater catalyst stability in the oxygenate conversion zone.
摘要翻译：本发明涉及一种用于生产轻质烯烃的方法，其包含每分子含有2至4个碳原子的含氧原料。该方法包括使含氧化合物原料通入含有金属氨基磷酸盐催化剂的含氧化合物转化区以产生轻质烯烃流。将轻质烯烃流分馏，并将一部分产物复分解，以提高乙烯，丙烯和/或丁烯产物的产率。丙烯可以被复分解以产生更多的乙烯，或者乙烯和丁烯的组合可以被复分解以产生更多的丙烯。轻烯烃生产和复分解的组合或歧化提供了克服金属磷酸铝催化剂在含氧化合物转化区中的平衡限制的灵活性。此外，本发明提供了在含氧化合物转化区中延长的催化剂寿命和更大的催化剂稳定性的优点。

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