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    • 9. 发明授权
    • Methods and systems useful for drying ethanol
    • 用于干燥乙醇的方法和系统
    • US09221733B2
    • 2015-12-29
    • US13966843
    • 2013-08-14
    • Purdue Research FoundationArcher Daniels Midland Company
    • Youngmi KimRichard L. HendricksonNathan MosierMichael R. LadischAhmad K. Hilaly
    • B01D53/02C07C29/76B01J20/28B01J20/34C12P7/06
    • C07C29/76B01J20/28004B01J20/28019B01J20/28059B01J20/3433B01J20/3458B01J2220/4825C08L3/02C12P7/06Y02E50/17C07C31/08
    • Mixtures of ethanol and water are dehydrated using starch pearls to adsorb and remove water. Vapor-phase adsorption equilibrium capacities of cassava starch pellets (tapioca pearls) having different particle sizes are disclosed, and tapioca pearl particles are shown to be surprisingly more effective for dehydrating 88 to 97% w/w feed ethanol than corn grits. The adsorption equilibrium curve and BET surface area measurement show that the adsorption capacity of tapioca pearls is a function of surface area available to water molecules. SEM images demonstrate that the particle architecture required for the adsorption and dehydration properties is that of a core-shell configuration with pre-gel starch acting as a central scaffold holding together other particles to the outer layer of the particle. The outer surface area of the pearls, populated with dry starch granules, is the main factor determining the adsorption capacity of the pearls. Tapioca pearls are shown to possess a surprisingly higher adsorption capacity than corn grits of the same particle size. Pearls of 2 mm size in diameter gave 34% higher linear adsorption equilibrium constant (K) than grits of 1.7 mm.
    • 用淀粉珍珠脱水乙醇和水的混合物,吸附去除水分。 公开了具有不同粒度的木薯淀粉颗粒(木薯珍珠)的气相吸附平衡能力,并且显示木薯珍珠颗粒比玉米砂粒脱水88至97%w / w的进料乙醇更有效。 吸附平衡曲线和BET表面积测量显示,木薯珍珠的吸附能力是水分子可用表面积的函数。 SEM图像表明,吸附和脱水性质所需的颗粒结构是核 - 壳构型的结构,其中预凝胶淀粉作为将其它颗粒保持在颗粒的外层的中心支架。 珍珠的外表面积为干淀粉颗粒,是决定珍珠吸附能力的主要因素。 木薯珍珠与具有相同粒度的玉米砂粒相比具有惊人的更高的吸附能力。 直径2毫米的珍珠比1.7毫米的砂粒提高了34%的线性吸附平衡常数(K)。
    • 10. 发明授权
    • Gas separation device
    • 气体分离装置
    • US09144767B2
    • 2015-09-29
    • US14407552
    • 2013-06-14
    • Tomoya FujimineYoshifumi NakashimaJun IzumiNorio MiuraTadashi TaniuchiManabu Kuroki
    • Tomoya FujimineYoshifumi NakashimaJun IzumiNorio MiuraTadashi TaniuchiManabu Kuroki
    • B01D53/02B01D53/047C01B21/04B01J20/06
    • B01D53/047B01D53/0438B01D53/343B01D2253/1124B01D2256/10B01D2256/12B01D2257/104B01D2259/401B01D2259/402B01J20/041B01J20/06B01J20/3433B01J20/3458B01J20/3483B01J2220/606C01B13/0259C01B21/045C01B21/0455C01B2210/0045
    • A simple and inexpensive gas separation device is provided. The gas separation device (100) includes: an adsorption tower (110) having an adsorbent (120) that adsorbs oxygen in a prescribed pressure and temperature environment, with at least one section thereof being exposed to a higher temperature atmosphere than a normal temperature; a first feed passage (132) connected to the adsorption tower for guiding into the adsorption tower air that has been blown from a blower device (130); a second feed passage (136) for guiding air, at a lower flow rate than the first feed passage, into the adsorption tower; a separated gas discharge path (140) connected to the adsorption tower for discharging a separated gas; a first heat exchanging unit (150) for exchanging heat between the separated gas discharged from the adsorption tower and the air guided into the adsorption tower from the first feed passage; an oxygen discharge unit (160) for reducing a pressure inside the adsorption tower, causing oxygen to desorb from the adsorption agent, and discharging oxygen from the adsorption tower; and a second heat exchanging unit (170) for exchanging heat between oxygen and the air guided into the adsorption tower from the second feed passage.
    • 提供了一种简单而廉价的气体分离装置。 气体分离装置(100)包括:具有在规定的压力和温度环境中吸附氧气的吸附剂(120)的吸附塔(110),其中至少一个部分暴露于比正常温度更高的温度气氛; 连接到吸附塔的第一进料通道(132),用于引导已经从鼓风装置(130)吹出的吸附塔空气; 用于以比第一进料通道更低的流速将空气引导到吸附塔中的第二进料通道(136) 分离的气体排放路径(140),其连接到用于排出分离的气体的吸附塔; 第一热交换单元(150),用于在从所述吸附塔排出的分离气体与从所述第一供给通道引导到所述吸附塔中的空气之间进行热交换; 用于降低吸附塔内部的压力的氧气排出单元(160),使氧从吸附剂解吸,并从吸附塔排出氧气; 以及第二热交换单元(170),用于在从第二进料通道引导到吸附塔中的氧气和空气之间进行热交换。