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1. 发明授权

US06010841A Silver halide light sensitive emulsion layer having enhanced photographic sensitivity 失效
标题翻译：具有增强的照相感光度的卤化银感光乳剂层
公开(公告)号：US06010841A
公开(公告)日：2000-01-04
申请号：US739911
申请日：1996-10-30
申请人： Samir Y. Farid , Jerome R. Lenhard , Chin H. Chen , Annabel A. Muenter , Ian R. Gould , Stephen A. Godleski , Paul A. Zielinski
发明人： Samir Y. Farid , Jerome R. Lenhard , Chin H. Chen , Annabel A. Muenter , Ian R. Gould , Stephen A. Godleski , Paul A. Zielinski
IPC分类号： G03C1/12 , C09B23/04 , G03C1/16 , G03C1/28 , G03C1/08
CPC分类号： C09B23/04 , G03C1/16 , G03C2200/24
摘要： A photographic element comprises at least one silver halide emulsion layer in which the silver halide is sensitized with a compound of formulaZ-(L-XY).sub.kwherein:Z is a light absorbing group;L is a linking group containing a least one C, N, S, or O atom; andk is 1 or 2; andXY represents a fragmentable electron donor moiety wherein:1) XY has a an oxidation potential between 0 and about 1.4 V;2) X is an electron donor group;3) Y is a leaving group other than hydrogen; and4) the oxidized form of XY undergoes a bond cleavage reaction to give the radical X.sup..cndot. and the leaving fragment Y.In a preferred embodiment the radical X.sup..cndot. has an oxidation potential of .ltoreq.-0.7 V.
摘要翻译：照相元件包括至少一个卤化银乳剂层，其中卤化银与式Z-（L-XY）k化合物敏化，其中：Z是光吸收基团; L是含有至少一个C，N，S或O原子的连接基团; k为1或2; 并且XY表示可裂解的电子供体部分，其中：1）XY具有在0和约1.4V之间的氧化电位; 2）X是电子给体基团; 3）Y是氢以外的离去基团; 和4）XY的氧化形式经历键断裂反应，得到基团X.和离去片段Y.在优选的实施方案中，基团X.具有

2. 发明授权

US5747236A Silver halide light sensitive emulsion layer having enhanced photographic sensitivity 失效
标题翻译：具有增强的照相感光度的卤化银感光乳剂层
公开(公告)号：US5747236A
公开(公告)日：1998-05-05
申请号：US740536
申请日：1996-10-30
申请人： Samir Y. Farid , Jerome R. Lenhard , Chin H. Chen , Annabel A. Muenter , Ian R. Gould , Stephen A. Godleski , Paul A. Zielinski , Charles H. Weidner
发明人： Samir Y. Farid , Jerome R. Lenhard , Chin H. Chen , Annabel A. Muenter , Ian R. Gould , Stephen A. Godleski , Paul A. Zielinski , Charles H. Weidner
IPC分类号： G03C7/00 , G03C1/10 , G03C1/12 , G03C1/28 , G03C1/34 , G03C1/08
CPC分类号： G03C1/10 , G03C1/12 , G03C1/34 , G03C2200/24
摘要： A photographic element comprises a support and at least one silver halide emulsion layer in which the silver halide is sensitized with a fragmentable electron donor of the formula X--Y, wherein X is an electron donor moiety and Y is a leaving group other than hydrogen, and wherein: 1) X--Y has an oxidation potential between 0 and about 1.4 V; and 2) the oxidized form of X--Y undergoes a bond cleavage reaction to give the radical X.sup..cndot. and the leaving fragment Y. In a preferred embodiment of the invention, the radical X.sup..cndot. has an oxidation potential .ltoreq.-0.7V.
摘要翻译：照相元件包括载体和至少一个卤化银乳剂层，其中卤化银用式XY的可裂解电子给体致敏，其中X是电子给体部分，Y是除氢以外的离去基团，其中：1）XY具有介于0和约1.4V之间的氧化电位; 和2）X-Y的氧化形式经历键断裂反应，得到基团X.和离去片段Y.在本发明的一个优选实施方案中，基团X的氧化电势为-0.7V。

3. 发明授权

US5747235A Silver halide light sensitive emulsion layer having enhanced photographic sensitivity 失效
标题翻译：具有增强的照相感光度的卤化银感光乳剂层
公开(公告)号：US5747235A
公开(公告)日：1998-05-05
申请号：US739921
申请日：1996-10-30
申请人： Samir Y. Farid , Jerome R. Lenhard , Chin H. Chen , Annabel A. Muenter , Ian R. Gould , Stephen A. Godleski , Paul A. Zielinski
发明人： Samir Y. Farid , Jerome R. Lenhard , Chin H. Chen , Annabel A. Muenter , Ian R. Gould , Stephen A. Godleski , Paul A. Zielinski
IPC分类号： G03C1/08 , G03C1/09 , G03C1/10 , G03C1/12 , G03C1/28 , G03C1/34
CPC分类号： G03C1/09 , G03C1/10 , G03C2200/24
摘要： A photographic element comprising at least one silver halide emulsion layer in which the silver halide is sensitized with a compound of the formula: ##STR1## wherein A is a silver halide adsorptive group that contains at least one atom of N, S, Se, or Te that promotes adsorption to silver halide, and L represents a linking group containing at least one C, N, S or O atom, k is 1 or 2, and XY is an fragmentable electron donor moiety in which X is an electron donor group and Y is a leaving group other than hydrogen, and wherein: 1) XY has an oxidation potential between 0 and about 1-4 V; and 2) the oxidized form of XY undergoes a bond cleavage reaction to give the radical X.sup..cndot. and the leaving fragment Y. In a preferred embodiment of the invention, the radical X.sup..cndot. has an oxidation potential .ltoreq.-0.7V.
摘要翻译：一种照相元件，包括至少一个卤化银乳剂层，其中卤化银用下列化学式的化合物敏化：含有至少一个促进对卤化银吸附的N，S，Se或Te原子，L和表示含有至少一个C，N，S或O原子的连接基团，k为1或2，XY为可裂解的电子给体部分，其中X为电子给体基团，Y为氢以外的离去基团，其中：1）XY具有介于0和约1-4V之间的氧化电位; 和2）XY的氧化形式经历键断裂反应以得到基团X.和离去片段Y.在本发明的一个优选实施方案中，基团X的氧化势为-0.7V。

4. 发明授权

US6153371A Silver halide light sensitive emulsion layer having enhanced photographic sensitivity 失效
标题翻译：具有增强的照相感光度的卤化银感光乳剂层
公开(公告)号：US6153371A
公开(公告)日：2000-11-28
申请号：US118552
申请日：1998-07-17
申请人： Samir Y. Farid , Ian R. Gould , Stephen A. Godleski , Jerome R. Lenhard , Annabel A. Muenter , Paul A. Zielinski
发明人： Samir Y. Farid , Ian R. Gould , Stephen A. Godleski , Jerome R. Lenhard , Annabel A. Muenter , Paul A. Zielinski
IPC分类号： G03C1/10 , G03C1/12 , G03C1/29
CPC分类号： G03C1/12 , G03C1/10 , G03C1/29 , G03C2200/24
摘要： This invention comprises a photographic element comprising a support and at least one silver halide emulsion layer in which the silver halide is sensitized with a compound of the formula:Q-XYwherein Q represents the atoms necessary to form a chromophore comprising an amidinium-ion, a carboxyl-ion or dipolar-amidic chromophoric system when conjugated with XY, and XY is a fragmentable electron donor moiety in which X is an electron donor group and Y is a leaving group other than hydrogen, and wherein:1) XY has an oxidation potential between 0 and about 1.4 V;2) the oxidized form of XY undergoes a bond cleavage reaction to give the radical X.sup..cndot. and the leaving fragment Y.In a preferred embodiment of the invention, the radical X.cndot. has an oxidation potential
摘要翻译：本发明包括一种照相元件，其包括载体和至少一个卤化银乳剂层，其中卤化银用下式化合物敏化：Q-XY，其中Q表示形成包含脒鎓离子的发色团所需的原子，羧基离子或偶极 - 酰胺发色体系，XY为可裂解的电子给体部分，其中X为电子给体基团，Y为氢以外的离去基团，其中：1）XY具有氧化电位介于0和约1.4 V之间; 2）XY的氧化形式经历键断裂反应，得到基团X.和离去片段Y.在本发明的优选实施方案中，基团X的氧化势<-0.7V。

5. 发明授权

US06306570B1 Silver halide light sensitive emulsion layer having enhanced photographic sensitivity 失效
标题翻译：具有增强的照相感光度的卤化银感光乳剂层
公开(公告)号：US06306570B1
公开(公告)日：2001-10-23
申请号：US09536300
申请日：2000-03-27
申请人： Anthony Adin , Jerome J. Looker , Samir Y. Farid , Ian R. Gould , Stephen A. Godleski , Jerome R. Lenhard , Annabel A. Muenter , Lal C. Vishwakarma , Paul A. Zielinski
发明人： Anthony Adin , Jerome J. Looker , Samir Y. Farid , Ian R. Gould , Stephen A. Godleski , Jerome R. Lenhard , Annabel A. Muenter , Lal C. Vishwakarma , Paul A. Zielinski
IPC分类号： G03C110
CPC分类号： G03C1/10 , G03C1/12 , G03C2200/24
摘要： A photographic element comprising at least one silver halide emulsion layer in which the silver halide is sensitized with a compound of the formula: wherein A is a silver halide adsorptive group that contains at least one atom of N, S, Se, or Te that promotes adsorption to silver halide, and Z is a light absorbing group including for example cyanine dyes, complex cyanine dyes, merocyanine dyes, complex merocyanine dyes, homopolar cyanine dyes, styryl dyes, oxonol dyes, hemioxonol dyes, and hemicyanine dyes, and XY is an fragmentable electron donor moiety in which X is an electron donor group and Y is a leaving group other than hydrogen, and wherein: 1) XY has an oxidation potential between 0 and about 1.4 V; and 2) the oxidized form of XY undergoes a bond cleavage reaction to give the radical X• and the leaving fragment Y. In a preferred embodiment of the invention, the radical X• has an oxidation potential ≦−0.7 V.
摘要翻译：一种照相元件，包括至少一个卤化银乳剂层，其中卤化银用下式化合物致敏：其中A是含有至少一个促进的N，S，Se或Te原子的卤化银吸附基团 Z为吸光性基团，例如为花青染料，复合花青染料，部花菁染料，复色部花青染料，单极花青染料，苯乙烯基染料，氧杂菁染料，半氧杂菁染料，半花青染料，XY为其中X是电子给体基团，Y是除氢以外的离去基团，其中：1）XY具有介于0和约1.4V之间的氧化电位; 和2）XY的氧化形式经历键断裂反应以得到基团X.和离去片段Y.在本发明的优选实施方案中，基团X具有<= -0.7V的氧化电位。

6. 发明授权

US6054260A Silver halide light sensitive emulsion layer having enhanced photographic sensitivity 失效
标题翻译：具有增强的照相感光度的卤化银感光乳剂层
公开(公告)号：US6054260A
公开(公告)日：2000-04-25
申请号：US118714
申请日：1998-07-17
申请人： Anthony Adin , Jerome J. Looker , Samir Y. Farid , Ian R. Gould , Stephen A. Godleski , Jerome R. Lenhard , Annabel A. Muenter , Lal C. Vishwakarma , Paul A. Zielinski
发明人： Anthony Adin , Jerome J. Looker , Samir Y. Farid , Ian R. Gould , Stephen A. Godleski , Jerome R. Lenhard , Annabel A. Muenter , Lal C. Vishwakarma , Paul A. Zielinski
IPC分类号： G03C1/09 , G03C1/10 , G03C1/12
CPC分类号： G03C1/10 , G03C1/12 , G03C2200/24
摘要： A photographic element comprising at least one silver halide emulsion layer in which the silver halide is sensitized with a compound of the formula: ##STR1## wherein A is a silver halide adsorptive group that contains at least one atom of N, S, Se, or Te that promotes adsorption to silver halide, and Z is a light absorbing group including for example cyanine dyes, complex cyanine dyes, merocyanine dyes, complex merocyanine dyes, homopolar cyanine dyes, styryl dyes, oxonol dyes, hemioxonol dyes, and hemicyanine dyes, and XY is an fragmentable electron donor moiety in which X is an electron donor group and Y is a leaving group other than hydrogen, and wherein:1) XY has an oxidation potential between 0 and about 1.4 V; and2) the oxidized form of XY undergoes a bond cleavage reaction to give the radical X.sup..cndot. and the leaving fragment Y.In a preferred embodiment of the invention, the radical X.sup..cndot. has an oxidation potential .ltoreq.-0.7 V.
摘要翻译：一种照相元件，包括至少一个卤化银乳剂层，其中卤化银用下式化合物致敏：其中A是含有至少一个促进的N，S，Se或Te原子的卤化银吸附基团 Z为吸光性基团，例如为花青染料，复合花青染料，部花菁染料，复色部花青染料，单极花青染料，苯乙烯基染料，氧杂菁染料，半氧杂菁染料，半花青染料，XY为其中X是电子给体基团，Y是除氢以外的离去基团，其中：1）XY具有介于0和约1.4V之间的氧化电位; 和2）XY的氧化形式经历键断裂反应，得到基团X.和离去片段Y.在本发明的一个优选实施方案中，基团X的氧化电势为-0.7V。

7. 发明授权

US5994051A Silver halide light sensitive emulsion layer having enhanced photographic sensitivity 失效
标题翻译：具有增强的照相感光度的卤化银感光乳剂层
公开(公告)号：US5994051A
公开(公告)日：1999-11-30
申请号：US118536
申请日：1998-07-17
申请人： Ian R. Gould , Samir Farid , Stephen A. Godleski , Jerome R. Lenhard , Annabel A. Muenter , Paul A. Zielinski
发明人： Ian R. Gould , Samir Farid , Stephen A. Godleski , Jerome R. Lenhard , Annabel A. Muenter , Paul A. Zielinski
IPC分类号： G03C1/10 , G03C1/12 , G03C1/28 , G03C1/29 , G03C1/08
CPC分类号： G03C1/12 , G03C1/10 , G03C1/28 , G03C1/29 , G03C2200/24
摘要： This invention comprises a photographic element comprising at least one silver halide emulsion layer in which the silver halide is sensitized with a compound of the formula X--H, wherein X is an electron donor moiety to which a base, B.sup.-, is covalently linked and H is a leaving hydrogen atom, and wherein:1) X--H has an oxidation potential between 0 and about 1.4 V; and2) the oxidized form of X--H undergoes deprotonation reaction with the base B.sup.-, to give the radical X.sup..cndot. and the protonated base B-H.In a preferred embodiment of the invention, the radical X.cndot. has an oxidation potential
摘要翻译：本发明包括一种照相元件，其包含至少一个卤化银乳剂层，其中卤化银与式XH的化合物敏化，其中X是一个电子给体部分，其中B基共价连接，H是离去的氢原子，其中：1）XH的氧化电位在0至约1.4V之间; 和2）X-H的氧化形式与碱基B进行去质子化反应，得到基团X.和质子化的碱B-H。在本发明的优选实施方案中，基团X具有<-0.7V的氧化电位。

8. 发明授权

US06498004B1 Silver halide light sensitive emulsion layer having enhanced photographic sensitivity 失效
标题翻译：具有增强的照相感光度的卤化银感光乳剂层
公开(公告)号：US06498004B1
公开(公告)日：2002-12-24
申请号：US09750855
申请日：2000-12-28
申请人： Jerome R. Lenhard , Annabel A. Muenter , Stephen A. Godleski , Paul A. Zielinski , Deepak Shukla , Donald R. Diehl
发明人： Jerome R. Lenhard , Annabel A. Muenter , Stephen A. Godleski , Paul A. Zielinski , Deepak Shukla , Donald R. Diehl
IPC分类号： G03C108
CPC分类号： C07D207/416 , C07C233/47 , C07C255/25 , C07C271/58 , C07C309/42 , C07C317/18 , C07C323/25 , C07C2601/04 , C07D209/48 , C07D249/18 , C07D257/04 , C07D277/64 , C07D403/12 , C07D417/12 , G03C1/10 , G03C7/30511 , G03C7/30547 , G03C2200/24 , Y02P20/55
摘要： This invention provides a photographic element comprising at least one silver halide emulsion layer in which the silver halide is sensitized with a compound of the formula (a): &Dgr;−(t)m−XY′ (a) XY′−(t)m−&Dgr; (b) &Dgr;−(t)m−XY′−(t)m−&Dgr; (c) wherein &Dgr; is protective group that is eliminated during development of the photographic element, t is a timing group, m is an integer from 0 to 3, and XY′ is a fragmentable electron donor moiety in which X is an electron donor group and Y′ is a leaving proton H or a leaving group Y, with the proviso that if Y′ is a proton, a base, &bgr;−, is present in the emulsion or is covalently linked directly or indirectly to X, and wherein: 1) X—Y′ has an oxidation potential between 0 and about 1.4 V; 2) the oxidized form of X—Y′ undergoes a bond cleavage reaction to give the radical X• and the leaving fragment Y′, and 3) the radical X• has an oxidation potential ≦−0.7V.
摘要翻译：本发明提供了包含至少一种卤化银乳剂层的照相元件，其中卤化银与式（a）化合物敏化：其中DELTA是在照相元件显影过程中消除的保护基，t是定时基团，m为0至3的整数，XY'为可裂解的电子给体部分，其中X为电子给体基团，Y'为离子质子H或离去基团Y，条件是如果Y'为质子，碱，β-存在于乳液中或直接或间接地与X共价连接，并且其中：1）XY'具有0至约1.4V的氧化电位; 2）XY'的氧化形式，经历键断裂反应以得到基团X.和离开的片段Y'，和3）基团X的氧化势<= -0.7V。

9. 发明授权

US06531272B1 Color photographic element containing a fragmentable electron donor for improved photographic response 失效
标题翻译：含有可裂解电子供体的彩色照相元件，用于改善照相反应
公开(公告)号：US06531272B1
公开(公告)日：2003-03-11
申请号：US09236708
申请日：1999-01-25
申请人： James A. Friday , Joseph P. Pepe , Jeffrey C. Hansen , Annabel A. Muenter , Jerome R. Lenhard
发明人： James A. Friday , Joseph P. Pepe , Jeffrey C. Hansen , Annabel A. Muenter , Jerome R. Lenhard
IPC分类号： G03C108
CPC分类号： G03C7/3022 , G03C1/0051 , G03C1/10 , G03C2001/03594 , G03C2200/24
摘要： This invention comprises a multicolor photographic element comprising a support bearing a cyan dye image-forming unit comprising at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein at least one of said layers comprises large tabular grains having an average circular diameter of greater than 2 &mgr;m and contains a fragmentable electron donating compound is of the formula: X—Y′ or a compound which contains a moiety of the formula —X—Y′; wherein X is an electron donor moiety, Y′ is a leaving proton H or a leaving group Y, with the proviso that if Y′ is a proton, a base, &bgr;−, is covalently linked directly or indirectly to X, and wherein: 1) X—Y′ has an oxidation potential between 0 and about 1.4 V; and 2) the oxidized form of X—Y′ undergoes a bond cleavage reaction to give the radical X. and the leaving fragment Y′; and, optionally, 3) the radical X. has an oxidation potential ≦−0.7V (that is, equal to or more negative than about −0.7V).
摘要翻译：本发明包括一种多色照相元件，其包含支持青色染料成像单元的载体，该单元包含至少一种与其相关联的至少一种形成青色染料的成色剂的感红卤化银乳剂层，品红染料影像形成单元包括至少一种感绿卤化银乳剂层，其与至少一种品红色染料形成成色剂相关联，黄色染料影像形成单元，其包含至少一种蓝敏感卤化银乳剂层，其具有至少一种形成黄色染料的成色剂，其中所述层中的至少一个包括平均圆直径大于2μm的大片状颗粒，并且含有可分裂的给电子化合物具有下式：XY'或含有式-X-Y部分的化合物 '; 其中X是电子给体部分，Y'是离开质子H或离去基团Y，条件是如果Y'是质子，则碱，β - 与X直接或间接共价连接，并且其中：1 ）XY'具有介于0和约1.4V之间的氧化电位; 和2）X-Y'的氧化形式发生键断裂反应，得到X基团和离去片段Y'; 和任选地，3）基团X的氧化电位<= -0.7V（即等于或大于约-0.7V的负值）。

10. 发明授权

US06428947B1 Multicolor photographic element with improved latent image keeping 失效
标题翻译：具有改进的潜像保持的多色摄影元件
公开(公告)号：US06428947B1
公开(公告)日：2002-08-06
申请号：US09755419
申请日：2001-01-05
申请人： Sharon G. Johnston , Annabel A. Muenter , Steven P. Szatynski , Jerome R. Lenhard
发明人： Sharon G. Johnston , Annabel A. Muenter , Steven P. Szatynski , Jerome R. Lenhard
IPC分类号： G03C146
CPC分类号： G03C7/39208 , G03C1/12 , G03C7/3003 , G03C7/3041 , G03C2003/006 , G03C2200/24 , Y10S430/156
摘要： This invention comprises multicolor photographic element comprising a support bearing a cyan dye image-forming unit comprising at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein at least one of said red-sensitive or green-sensitive layers comprises a fragmentable electron donating compound of the formula: X—Y′ or a compound which contains a moiety of the formula —X—Y′; wherein the speed gain deriving from addition of said compound to said layer is less than or equal to 0.05 log sensitivity units and wherein X is an electron donor moiety, Y′ is a leaving proton H or a leaving group Y, with the proviso that if Y′ is a proton, a base, &bgr;−, is present in the emulsion layer, and wherein: 1) X—Y′ has an oxidation potential between 0 and about 1.4 V; 2) the oxidized form of X—Y′ undergoes a bond cleavage reaction to give the radical X· and the leaving fragment Y′, and 3) the radical X· has an oxidation potential ≦−0.7V.
摘要翻译：本发明包括多色照相元件，其包含支持青色染料成像单元的载体，该单元包括至少一种与其相关联的至少一种形成青色染料的成色剂的感红卤化银乳剂层，品红色染料影像形成单元至少包括一种感绿卤化银乳剂层，其具有与至少一种品红色染料形成成色剂相关联的黄色染料影像形成单元，其包含至少一种感蓝卤化银乳剂层，其具有至少一种形成黄色染料的成色剂，其中所述红敏敏感层或绿敏层中的至少一个包含下式的可裂解供电子化合物：XY'或含有式-X-Y'部分的化合物;其中来自添加的速度增益所述化合物与所述层的摩尔比小于或等于0.05log灵敏度单元，并且其中X是电子给体部分，Y'是离开质子H或离开组Y，条件是如果Y'是质子，则在乳剂层中存在碱，β - ，其中：1）XY'具有在0和约1.4V之间的氧化电位; 2）氧化形式的XY'经历键断裂反应以产生基团X.和离开的片段Y'，和3）基团X.具有氧化势<= -0.7V。

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