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1. 发明授权

US06531272B1 Color photographic element containing a fragmentable electron donor for improved photographic response 失效
标题翻译：含有可裂解电子供体的彩色照相元件，用于改善照相反应
公开(公告)号：US06531272B1
公开(公告)日：2003-03-11
申请号：US09236708
申请日：1999-01-25
申请人： James A. Friday , Joseph P. Pepe , Jeffrey C. Hansen , Annabel A. Muenter , Jerome R. Lenhard
发明人： James A. Friday , Joseph P. Pepe , Jeffrey C. Hansen , Annabel A. Muenter , Jerome R. Lenhard
IPC分类号： G03C108
CPC分类号： G03C7/3022 , G03C1/0051 , G03C1/10 , G03C2001/03594 , G03C2200/24
摘要： This invention comprises a multicolor photographic element comprising a support bearing a cyan dye image-forming unit comprising at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein at least one of said layers comprises large tabular grains having an average circular diameter of greater than 2 &mgr;m and contains a fragmentable electron donating compound is of the formula: X—Y′ or a compound which contains a moiety of the formula —X—Y′; wherein X is an electron donor moiety, Y′ is a leaving proton H or a leaving group Y, with the proviso that if Y′ is a proton, a base, &bgr;−, is covalently linked directly or indirectly to X, and wherein: 1) X—Y′ has an oxidation potential between 0 and about 1.4 V; and 2) the oxidized form of X—Y′ undergoes a bond cleavage reaction to give the radical X. and the leaving fragment Y′; and, optionally, 3) the radical X. has an oxidation potential ≦−0.7V (that is, equal to or more negative than about −0.7V).
摘要翻译：本发明包括一种多色照相元件，其包含支持青色染料成像单元的载体，该单元包含至少一种与其相关联的至少一种形成青色染料的成色剂的感红卤化银乳剂层，品红染料影像形成单元包括至少一种感绿卤化银乳剂层，其与至少一种品红色染料形成成色剂相关联，黄色染料影像形成单元，其包含至少一种蓝敏感卤化银乳剂层，其具有至少一种形成黄色染料的成色剂，其中所述层中的至少一个包括平均圆直径大于2μm的大片状颗粒，并且含有可分裂的给电子化合物具有下式：XY'或含有式-X-Y部分的化合物 '; 其中X是电子给体部分，Y'是离开质子H或离去基团Y，条件是如果Y'是质子，则碱，β - 与X直接或间接共价连接，并且其中：1 ）XY'具有介于0和约1.4V之间的氧化电位; 和2）X-Y'的氧化形式发生键断裂反应，得到X基团和离去片段Y'; 和任选地，3）基团X的氧化电位<= -0.7V（即等于或大于约-0.7V的负值）。

2. 发明授权

US06509144B1 Fragmentable electron donor compounds combined with broad blue spectral sensitization 失效
标题翻译：可分散的电子给体化合物与广泛的蓝色光谱增感相结合
公开(公告)号：US06509144B1
公开(公告)日：2003-01-21
申请号：US09236821
申请日：1999-01-25
申请人： Kenneth J. Reed , Joseph P. Pepe , James A. Friday , Jon N. Eikenberry , Yun C. Chang , Annabel A. Muenter , Jerome R. Lenhard
发明人： Kenneth J. Reed , Joseph P. Pepe , James A. Friday , Jon N. Eikenberry , Yun C. Chang , Annabel A. Muenter , Jerome R. Lenhard
IPC分类号： G03C110
CPC分类号： G03C1/10 , G03C1/0053 , G03C1/28 , G03C1/29
摘要： This invention comprises a photographic element comprising a support and at least one blue sensitive silver halide emulsion layer containing a tabular grain silver halide emulsion, or an emulsion in which the halide content is at least 50% chloride and no more than 5% iodide, wherein the emulsion is spectrally sensitized with at least one dye providing a peak sensitization between 446 and 500 nm and at least one dye providing a peak sensitization between 400 and 445 nm and additionally sensitized with a fragmentable electron donor of the formula: X—Y′. or an electron donor which contains an —XY′ moiety; wherein X is an electron donor moiety, Y′ is a leaving proton H or a leaving group Y, with the proviso that if Y′ is H a base, &bgr;−, is covalently linked directly or indirectly to X. and wherein: 1) X—Y′ has an oxidation potential between 0 and about 1.4 V; and 2) the oxidized form of X—Y′ fragments to give the radical X• and the leaving fragment Y′; and, optionally, 3) the radical X• has an oxidation potential ≦−0.7V (that is, equal to or more negative than about −0.7 V).
摘要翻译：本发明包括一种照相元件，其包括载体和至少一种含有片状银卤化银乳剂的蓝色感光卤化银乳剂层，或其中卤化物含量为至少50％氯化物和不超过5％碘化物的乳液，其中该乳液用至少一种提供446和500nm之间的峰敏感的染料和至少一种提供400和445nm之间的峰敏感的染料进行光谱增感，并用下式X-Y'的可裂解的电子给体进一步增感。或含有-XY'部分的电子给体;其中X是电子给体部分，Y'是离开质子H或离去基团Y，条件是如果Y'是H，则基团是共价连接的直接或间接地与X并且其中：1）XY'具有介于0和约1.4V之间的氧化电位; 和2）X-Y'片段的氧化形式，得到X基团和离去片段Y'; 和任选地，3）基团X的氧化电位<= -0.7V（即等于或大于约-0.7V的负）。

3. 发明授权

US06242170B1 Color photographic element containing a fragmentable electron donor in combination with a one equivalent coupler for improved photographic response 失效
标题翻译：含有可裂解的电子给体的彩色照相元件与一个等效的偶联剂结合以改善照相反应
公开(公告)号：US06242170B1
公开(公告)日：2001-06-05
申请号：US09468023
申请日：1999-12-20
申请人： Joseph P. Pepe , Jeffrey C. Hansen , James A. Friday , Annabel A. Muenter , David T. Southby
发明人： Joseph P. Pepe , Jeffrey C. Hansen , James A. Friday , Annabel A. Muenter , David T. Southby
IPC分类号： G03C108
CPC分类号： G03C1/0051 , G03C1/04 , G03C1/10 , G03C1/12 , G03C7/3022 , G03C7/30511 , G03C7/30547 , G03C7/392 , G03C2200/24 , Y10S430/156
摘要： This invention provides a multicolor photographic element comprising a support bearing a cyan dye image-forming unit comprising at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein at least one of said emulsion layers comprises large tabular grains having an average equivalent circular diameter of greater than 3 &mgr;m and contains a one equivalent image dye-forming coupler and a fragmentable electron donating compound of the formula: X—Y′ or a compound which contains a moiety of the formula —X—Y′; wherein X is an electron donor moiety, Y′ is a leaving proton H or a leaving group Y, with the proviso that if Y′ is a proton, a base, &bgr;−, is covalently linked directly or indirectly to X, and wherein: 1) X—Y′ has an oxidation potential between 0 and about 1.4 V; and 2) the oxidized form of X—Y′ undergoes a bond cleavage reaction to give the radical X• and the leaving fragment Y′; and, optionally, 3) the radical X• has an oxidation potential ≦−0.7 V (that is, equal to or more negative than about −0.7 V).
摘要翻译：本发明提供了一种多色照相元件，其包含载体，该支持体含有青色染料影像形成单元，该单元包含至少一种与其相关联的至少一种形成青色染料的成色剂的感红卤化银乳剂层，品红染料影像形成单元包括至少一种感绿卤化银乳剂层，其与至少一种品红色染料形成成色剂相关联，黄色染料影像形成单元，其包含至少一种蓝敏感卤化银乳剂层，其具有至少一种形成黄色染料的成色剂其中所述乳剂层中的至少一个包括平均当量圆直径大于3μm的大片状颗粒，并且含有一个等效的图像染料形成成色剂和下式的可裂解的给电子化合物：XY' 含有式-X-Y'的部分; 其中X是电子给体部分，Y'是离开质子H或离去基团Y，条件是如果Y'是质子，则碱，β - 与X直接或间接共价连接，并且其中：1 ）XY'具有介于0和约1.4V之间的氧化电位; 和2）X-Y'的氧化形式发生键断裂反应，得到X基团和离去片段Y'; 并且可选地，3）基团X具有氧化电位<= -0.7V（即等于或大于约-0.7V的负值）。

4. 发明授权

US4141897A N-dealkylation of N-alkyl-14-hydroxymorphinans and derivatives thereof 失效
标题翻译： N-烷基-14-羟基吗啡喃及其衍生物的N-脱烷基化
公开(公告)号：US4141897A
公开(公告)日：1979-02-27
申请号：US751570
申请日：1976-12-20
申请人： Roy A. Olofson , Joseph P. Pepe
发明人： Roy A. Olofson , Joseph P. Pepe
IPC分类号： C07D221/28 , C07D489/08
CPC分类号： C07D489/08 , C07D221/28
摘要： There is provided a novel, high yield, method of dealkylating N-alkylated 14-hydroxymorphinans and derivatives thereof including, inter alia, oxymorphone and oycodone. There are thus provided, inter alia, more efficient routes for the formation of naloxone, naltrexone, and nalbuphine. In the principal step of the process, the dealkylation using certain oxycarbonyl halides (or haloformates) is carried out on the N-alkyl-14-acyloxy-morphinan which it is desired to dealkylate.
摘要翻译：提供了一种新的，高产率的N-烷基化的14-羟基吗啡喃及其衍生物的烷基化方法，其中尤其包括羟吗啡酮和奥索酮。因此，尤其提供了用于形成纳洛酮，纳曲酮和纳布啡的更有效的途径。在该方法的主要步骤中，使用某些氧羰基卤化物（或卤代甲酸酯）进行脱烷基化在需要脱烷基化的N-烷基-14-酰氧基 - 吗啡喃上进行。

5. 发明授权

US4161597A N-alkyl-14-hydroxymorphinans and derivatives 失效
标题翻译： N-烷基-14-羟基吗啡喃及其衍生物
公开(公告)号：US4161597A
公开(公告)日：1979-07-17
申请号：US751571
申请日：1976-12-20
申请人： Roy A. Olofson , Joseph P. Pepe
发明人： Roy A. Olofson , Joseph P. Pepe
IPC分类号： C07D221/28 , C07D489/08
CPC分类号： C07D221/28 , C07D489/08
摘要： There is provided a novel and high yield procedure for transforming acid salts of 14-alkanoyloxymorphinans and derivatives thereof into the corresponding N-alkyl-14-hydroxymorphinans wherein the alkyl moiety on the nitrogen contains the same number of carbon atoms as that previously in the 14-alkanoyl moiety. In the process of the present invention, the acid is neutralized to the free base, the alkanoyl moiety at the 14-oxy then spontaneously shifts to the nitrogen and is subsequently reduced to the corresponding alkyl moiety. O-dealkylation at C-3, where an alkoxy group is originally present, is carried out in the usual manner. There is also provided a readily produced and readily disassociated adduct of the corresponding 14-hydroxy-N-alkanoyl morphinan-6-alkylene ketal with benzene, tetrahydrofuran, and the like.
摘要翻译：提供了用于将14-烷酰氧基吗啡喃及其衍生物的酸盐转化成相应的N-烷基-14-羟基吗啡喃的新颖且高产率的方法，其中氮上的烷基部分含有与之前在14中相同数量的碳原子 - 烷酰基部分。在本发明的方法中，将酸中和至游离碱，14-氧基上的烷酰基部分自发转移至氮气，随后还原成相应的烷基部分。最初存在烷氧基的C-3处的O-脱烷基化是以通常的方式进行的。还提供了相应的14-羟基-N-烷酰基吗啡喃-6-亚烷基缩酮与苯，四氢呋喃等的容易制备和容易分离的加合物。

6. 发明授权

US06686119B1 Blue-sensitive film for radiography and imaging assembly and method 失效
标题翻译：用于放射成像和成像组装的蓝色感光膜和方法
公开(公告)号：US06686119B1
公开(公告)日：2004-02-03
申请号：US10447786
申请日：2003-05-29
申请人： Mark P. Pavlik , Joseph P. Pepe , Susan K. Mroczek
发明人： Mark P. Pavlik , Joseph P. Pepe , Susan K. Mroczek
IPC分类号： G03C517
CPC分类号： G03C5/16 , G03C1/047 , G03C1/46 , G03C5/17 , G03C5/26 , G03C2001/0055 , G03C2001/03511 , G03C2001/03535 , G03C2007/3025 , G03C2200/27 , G03C2200/52 , Y10S430/167 , Y10S430/168
摘要： A blue-sensitive, radiographic silver halide film comprises a silver halide emulsion layer comprising predominantly tabular silver halide grains that have an aspect ratio of from 8 to 14.5, a grain thickness of from about 0.15 to about 0.3 &mgr;m, and comprise at least 90 mol % bromide and up to 6 mol % iodide, based on total silver halide. The tabular silver halide grains are dispersed in a hydrophilic polymeric vehicle mixture comprising at least 0.5% of oxidized gelatin, based on the total dry weight of the polymeric vehicle mixture in the emulsion layer.
摘要翻译：蓝色敏感的放射线卤化银膜包括卤化银乳剂层，其主要包含片状卤化银颗粒，其长宽比为8至14.5，颗粒厚度为约0.15至约0.3μm，并且包含至少90mol ％溴化物和高达6mol％碘化物，基于总卤化银。片状卤化银颗粒分散在包含至少0.5％氧化明胶的亲水性聚合物载体混合物中，基于乳液层中聚合物载体混合物的总干重。

7. 发明授权

US4310618A Silver halide photographic material and process utilizing blocked dye-forming couplers 失效
标题翻译：卤化银照相材料和使用阻挡染料成色剂的方法
公开(公告)号：US4310618A
公开(公告)日：1982-01-12
申请号：US154655
申请日：1980-05-30
申请人： Jose M. Fernandez , Joseph P. Pepe
发明人： Jose M. Fernandez , Joseph P. Pepe
IPC分类号： C07D231/38 , C07D231/40 , G03C7/32 , G03C7/00
CPC分类号： C07D231/38 , C07D231/40 , G03C7/3212
摘要： Novel dye-forming couplers have the structure: ##STR1## wherein: Z represents the atoms to complete, with the attached oxygen atom, the same or different 5-pyrazolone dye-forming coupler moiety, phenol dye-forming coupler moiety or naphthol dye-forming coupler moiety, the * in the ring completed by Z representing the coupling position;R is hydrogen or a coupling-off group;Bl is a blocking group removable, during development, from the coupler moiety completed by Z to which it is directly attached; andn is an integer of 2 to 4.
摘要翻译：新颖的成色成色剂具有以下结构：其中：Z表示完成的原子，具有连接的氧原子，相同或不同的5-吡唑啉酮染料形成成色剂部分，形成苯酚染料的成色剂部分或萘酚染料 - 形成成色剂部分，由Z表示的环中的*表示耦合位置; R是氢或偶合离去基团; B1是在开发期间从Z直接附着的成色剂部分可除去的封闭基团; n为2〜4的整数。

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