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1. 发明授权

US06695904B2 Surface coating composition comprising silicon compounds 失效
标题翻译：包含硅化合物的表面涂料组合物
公开(公告)号：US06695904B2
公开(公告)日：2004-02-24
申请号：US10227295
申请日：2002-08-26
申请人： Rosemarie Burger , Jaroslaw Monkiewicz , Roland Edelmann , Bjoern Borup
发明人： Rosemarie Burger , Jaroslaw Monkiewicz , Roland Edelmann , Bjoern Borup
IPC分类号： C09D18306
CPC分类号： C09D183/04 , C08G77/06 , C08K3/36 , C23C2222/20
摘要： A composition which retains a flash point of more than 21° C. even on storage and is obtainable by mixing and reacting (i) from 50 to 70% by weight of at least one alkyltrialkoxysilane, (ii) from 10 to 25% by weight of at least one alkoxysiloxane and/or at least one tetraalkoxysilane, (iii) from 15 to 25% by weight of at least one aqueous silica sol, (iv) from 0.1 to 5% by weight of at least one acid, and (v) from 0.1 to 60% by weight of at least one alcohol and/or glycol, the sum of the above components being not more than 100% by weight, by introducing components (i) and (ii) and also, if desired, a fraction of component (v) as an initial charge, adding component (iii), adjusting the mixture to a temperature in the range from −5 to 10° C., and subsequently adding component (iv), then allowing the mixture to continue reacting, thereafter distilling off hydrolysis alcohol under reduced pressure, and replacing it by adding component (v); which composition is useful for producing a coating on surfaces and also as a base material for paints; a process for preparing such a composition; and coatings and articles obtainable by applying such a composition.
摘要翻译：即使在储存时也保持闪点超过21℃的组合物，并且可通过混合并使（i）50至70重量％的至少一种烷基三烷氧基硅烷，（ii）10至25重量％的至少一种烷氧基硅氧烷和/或至少一种四烷氧基硅烷，（iii）15至25重量％的至少一种水性二氧化硅溶胶，（iv）0.1至5重量％的至少一种酸，和（v ）0.1至60重量％的至少一种醇和/或二醇，上述组分的总和不超过100重量％，通过引入组分（i）和（ii），并且如果需要，可以使用将组分（v）的馏分作为初始电荷，加入组分（iii），将混合物调节至-5至10℃的温度，随后加入组分（iv），然后使混合物继续反应然后在减压下蒸馏除去水解醇，并通过加入组分（v）代替; 该组合物可用于在表面上生产涂层以及用作涂料的基材; 制备这种组合物的方法; 以及通过应用这种组合物可获得的涂层和制品。

2. 发明授权

US06830816B2 Highly filled, pasty, composition containing silicoorganic nanohybrid and/or microhybrid capsules for scratch-resistant and/or abrasion-resistant coatings 失效
标题翻译：含有硅胶有机纳米混合和/或微混合胶囊的高填充，糊状组合物，用于耐刮擦和/或耐磨涂层
公开(公告)号：US06830816B2
公开(公告)日：2004-12-14
申请号：US10112042
申请日：2002-04-01
申请人： Reiner Mehnert , Hans-Juergen Glaesel , Helmut Langguth , Jaroslaw Monkiewicz , Roland Edelmann , Bjoern Borup
发明人： Reiner Mehnert , Hans-Juergen Glaesel , Helmut Langguth , Jaroslaw Monkiewicz , Roland Edelmann , Bjoern Borup
IPC分类号： C08K320
CPC分类号： C09C1/3081 , C01P2004/88 , C08K9/06 , C09C3/12 , Y10T428/2995 , Y10T428/31551 , Y10T428/31663 , Y10T428/31786 , Y10T428/31935
摘要： The present invention relates to a composition containing silico-organic nanohybrid and/or microhybrid capsules for scratch-resistant and/or abrasion-resistant coatings, wherein the silico-organic nanohybrid and/or microhybrid system includes one or more small metal oxide cores A and a substantially complete, silico-organic shell B, and the composition can be obtained by a reaction performed in situ, in a synthetic resin or in a synthetic-resin precursor compound, between metal oxide particles (KA-O) and at least one organofunctional silicon compound which contains an organofunctional group and at least one hydrolyzable group or at least one hydroxy group. The present invention also relates to the use of such compositions as the base for lacquers for producing a scratch-resistant and abrasion-resistant coating on a substrate as well as articles provided with corresponding scratch-resistant as well as abrasion-resistant coatings.
摘要翻译：本发明涉及包含用于耐刮擦和/或耐磨涂层的硅 - 有机纳米混合和/或微混合胶囊的组合物，其中硅 - 有机纳米混合和/或微混合系统包括一个或多个小金属氧化物核心A和基本上完全的硅 - 有机壳B，并且组合物可以通过在合成树脂或合成树脂前体化合物中原位进行的金属氧化物颗粒（KA-O）与至少一种有机官能团含有有机官能团和至少一个可水解基团或至少一个羟基的硅化合物。本发明还涉及这样的组合物作为基底用于在基材上生产耐刮擦和耐磨涂层以及具有相应的耐刮擦和耐磨涂层的制品的用途。

3. 发明授权

US08481654B2 Aqueous silane nanocomposites 有权
标题翻译：水性硅烷纳米复合材料
公开(公告)号：US08481654B2
公开(公告)日：2013-07-09
申请号：US11572691
申请日：2004-11-08
申请人： Roland Edelmann , Bjoern Borup , Jaroslaw Monkiewicz , Christian Wassmer , Kerstin Bibbo , Burkhard Standke
发明人： Roland Edelmann , Bjoern Borup , Jaroslaw Monkiewicz , Christian Wassmer , Kerstin Bibbo , Burkhard Standke
IPC分类号： C08G77/38 , C08G77/382 , C08L83/06
CPC分类号： C08G77/58 , B22C1/183 , C01P2004/62 , C01P2004/64 , C09C1/3054 , C09C1/3081 , C09C1/309 , C09D183/14 , Y10T428/31663
摘要： The present invention provides a composition based on the reaction at least of the following components: (i) a glycidyloxypropylalkoxysilane, (ii) an aqueous silica sol having an SiO2 content of >20% by weight, (iii) an organic acid hydrolysis catalyst, and (iv) n-propyl zirconate, butyl titanate or titanium acetylacetonate as crosslinker, a process for its preparation, and the use thereof, particularly as a composition for scratch resistant coatings, and also provides articles thus coated.
摘要翻译：本发明提供了至少以下组分的基于该反应的组合物：（i）缩水甘油氧基丙基烷氧基硅烷，（ii）SiO 2含量> 20重量％的水性硅溶胶，（iii）有机酸水解催化剂，和（iv）锆酸正丙酯，钛酸丁酯或乙酰丙酮钛作为交联剂，其制备方法及其用途，特别是作为耐划伤涂料的组合物，并且还提供如此涂覆的制品。

4. 发明授权

US07026398B2 Air-drying silane coating compositions 失效
标题翻译：风干硅烷涂料组合物
公开(公告)号：US07026398B2
公开(公告)日：2006-04-11
申请号：US10393067
申请日：2003-03-21
申请人： Jaroslaw Monkiewicz , Roland Edelmann , Andrea Edinger , Bjoern Borup
发明人： Jaroslaw Monkiewicz , Roland Edelmann , Andrea Edinger , Bjoern Borup
IPC分类号： C08L83/08
CPC分类号： C09D163/00 , C08K3/36 , C08K5/5415 , C08K2201/014 , C09D133/02 , Y10T428/31663 , C08L2666/28 , C08L2666/22
摘要： The present invention relates to an air-drying silane coating composition containing an epoxy or acrylic resin, an optional silicic ester or alkyl silicate, an aminoalkylsilane component, an optional organoalkyoxysilane, and possible auxiliaries; methods of use thereof, and articles and substrates coated accordingly.
摘要翻译：本发明涉及包含环氧树脂或丙烯酸树脂，任选的硅酸酯或烷基硅酸盐，氨基烷基硅烷组分，任选的有机烷氧基硅烷和可能的助剂的空气干燥硅烷涂料组合物; 使用方法，以及相应地涂覆的制品和基材。

5. 发明授权

US08043701B2 Polymerizable organosilicon nanocapsules 失效
标题翻译：可聚合的有机硅纳米胶囊
公开(公告)号：US08043701B2
公开(公告)日：2011-10-25
申请号：US11258025
申请日：2005-10-26
申请人： Roland Edelmann , Jaroslaw Monkiewicz
发明人： Roland Edelmann , Jaroslaw Monkiewicz
IPC分类号： B32B5/00 , B01J13/02
CPC分类号： C08K9/06 , B01J13/02 , B82Y30/00 , C01P2004/64 , C01P2006/12 , C09C1/00 , C09C1/3081 , C09C1/3684 , C09C1/407 , C09C3/12 , Y10T428/2984
摘要： The present invention provides a polymerizable organosilicon nanocapsule, which includes: a nanoscale core A, which includes: at least one particle comprising at least one oxide or mixed oxide, KA-O, of at least one metal or semimetal selected from the group including main groups 2 to 6 of the Periodic Table, transition groups 1 to 8 of the Periodic Table, lanthanides, and mixtures thereof; and an organosilicon shell B, which includes: at least one organosilicon compound having the formula (Ia): (Si′O—)xSi—R (Ia) wherein R is a vinyl or allyl group; wherein x is a number from 0 to 20; wherein remaining free valences of Si are each independently (KA-O)—, SiO— or —Z; wherein remaining free valences of Si′ are each independently (KA-O)—, SiO—, —R, or —Z; wherein the Z's are each independently hydroxyl or alkoxy radicals; and wherein each Si and Si′ in the shell B have not more than one R group attached thereto.
摘要翻译：本发明提供了一种可聚合的有机硅纳米胶囊，其包括：纳米级芯A，其包括：至少一种包含至少一种氧化物或混合氧化物的颗粒，KA-O，其至少一种金属或半金属选自包括主要元素周期表第2至6组，周期表第1至8族，镧系元素及其混合物; 和有机硅壳B，其包括：至少一种具有式（Ia）的有机硅化合物：（Si'O-）xSi-R（Ia）其中R是乙烯基或烯丙基; 其中x是0至20的数; 其中Si的剩余游离价各自独立地为（KA-O） - ， - SiO-或-Z; 其中Si'的剩余游离价各自独立地为（KA-O） - ， - SiO-，-R或-Z; 其中Z各自独立地为羟基或烷氧基; 并且其中壳体B中的每个Si和Si'具有不超过一个连接到其上的R基团。

6. 发明申请

US20070099004A1 Composition for producing a barrier layer for gases 审中-公开
标题翻译：用于制备气体阻挡层的组合物
公开(公告)号：US20070099004A1
公开(公告)日：2007-05-03
申请号：US10576467
申请日：2004-10-13
申请人： Roland Edelmann , Jaroslaw Monkiewicz , Bjorn Borup , Reiner Mehnert , Christian Elsner , Hubert Culik , Christian Breitwieser
发明人： Roland Edelmann , Jaroslaw Monkiewicz , Bjorn Borup , Reiner Mehnert , Christian Elsner , Hubert Culik , Christian Breitwieser
IPC分类号： B32B27/00 , C08G77/04 , C08L83/04
CPC分类号： C09D183/04 , C08G77/22 , C08G77/26 , C08G77/50 , C08K5/053 , C09D4/00 , Y10T428/31663 , C08G77/00
摘要： Organosilane-based composition for producing a barrier layer for gases, comprising (i) at least one organoalkoxysilane whose organofunctionality displays at least one unsaturated hydrocarbon group, (ii) at least one aminoalkylalkoxysilane, (iii) at least one polyol, (iv) optionally, another alkoxysilane or alkoxysiloxane, and (v) optionally, at least one nano- or microscale semimetal oxide or metal oxide, semimetal oxide hydroxide or metal oxide hydroxide, or sernimetal hydroxide or metal hydroxide, and/or (vi) at least one cocondensate composed of the components (i), (ii), (iii), and, optionally, (iv), and also, optionally, (v), and/or (vii) reaction products produced under hydrolysis conditions from the components (i), (ii), (iii), and, optionally, (iv), and also, optionally, (v) (viii) and organic solvent, with the proviso that there is a molar ratio (i):(ii):(iii) where (i)=1 and (ii)=from 0.5 to 1.5, and (iii)=from 0.3 to 1.1. The invention also relates to a process for producing, and the use of, the composition, and to packaging materials produced using the composition.
摘要翻译：包含（i）至少一种有机烷氧基硅烷，其有机官能团显示至少一个不饱和烃基，（ii）至少一个氨基烷基烷氧基硅烷，（iii）至少一种多元醇，（iv）任选地，（v）任选的至少一种纳米或微米级半金属氧化物或金属氧化物，半金属氧化物氢氧化物或金属氧化物氢氧化物或氢氧化金属或金属氢氧化物，和/或（vi）至少一种缩聚物由组分（i），（ii），（iii），和任选地（ⅳ），以及（ⅴ），（ⅴ），（Ⅴ）和/ ），（ⅱ），（ⅲ）和（ⅳ），（ⅳ），以及任选的（ⅴ）（Ⅷ）和有机溶剂，条件是摩尔比（ⅰ）（iii）其中（i）= 1和（ii）= 0.5至1.5，（iii）= 0.3至1.1。本发明还涉及一种用于生产和使用组合物以及使用该组合物生产的包装材料的方法。

7. 发明授权

US06395858B1 Aminopropyl-functional siloxane oligomers 有权
标题翻译：氨基丙基官能的硅氧烷低聚物
公开(公告)号：US06395858B1
公开(公告)日：2002-05-28
申请号：US09427479
申请日：1999-10-27
申请人： Helmut Mack , Dieter Barfurth , Roland Edelmann , Albert-Johannes Frings , Michael Horn , Peter Jenkner , Ralf Laven , Jaroslaw Monkiewicz , Burkhard Standke
发明人： Helmut Mack , Dieter Barfurth , Roland Edelmann , Albert-Johannes Frings , Michael Horn , Peter Jenkner , Ralf Laven , Jaroslaw Monkiewicz , Burkhard Standke
IPC分类号： C08G7726
CPC分类号： C08G77/045 , C07F7/21 , C08G77/26
摘要： The present invention relates to mixtures of catenate and cyclic siloxane oligomers of the formulae I and II where the substituents R consist of (i) aminopropyl-functional groups of the formula —(CH2)3—NH2 or —(CH2)3—NHR′ or —(CH2)3—NH(CH2)2—NH2 or —(CH2)3—NH(CH2)2—NH(CH2)2—NH2,in which R′ is a linear, branched or cyclic alkyl group of 1 to 18 carbon atoms or an aryl group of 6 to 12 carbon atoms, and (ii) methoxy, ethoxy, 2-methoxyethoxy and/or propoxy groups, and (iii) if desired, alkyl, alkenyl, isoalkyl or cycloalkyl groups of 1 to 18 carbon atoms and/or aryl groups of 6 to 12 carbon atoms, and where not more than one aminopropyl-functional group is attached to one silicon atom and the degree of oligomerization of compounds of the formula I is within the range 2
摘要翻译：本发明涉及式I和II的链状酯和环状硅氧烷低聚物的混合物，其中取代基R由（i）式 - （CH 2）3 -NH 2或 - （CH 2）3 -NHR'的氨基丙基官能团或 - （CH 2）3 -NH（CH 2）2 -NH 2或 - （CH 2）3 -NH（CH 2）2 -NH（CH 2）2 -NH 2，其中R'是直链，支链或环状烷基， 18个碳原子或6至12个碳原子的芳基，和（ii）甲氧基，乙氧基，2-甲氧基乙氧基和/或丙氧基，和（iii）如果需要，可以是1-18的烷基，烯基，异烷基或环烷基 6〜12个碳原子的碳原子和/或芳基，并且其中不超过一个氨基丙基官能团连接到一个硅原子上，并且式I化合物的低聚度在2 = 0.5的商。本发明还涉及制备所述混合物及其应用的特殊方法。

8. 发明授权

US6100418A Lessening residual halogen content and improving color number in alkoxysilanes or alkoxysilane-based compositions 有权
标题翻译：减少烷氧基硅烷或烷氧基硅烷类组合物中的残留卤素含量和提高色数
公开(公告)号：US6100418A
公开(公告)日：2000-08-08
申请号：US310145
申请日：1999-05-12
申请人： Burkhard Standke , Jaroslaw Monkiewicz , Albert-Johannes Frings , Ralf Laven , Roland Edelmann , Peter Jenkner , Helmut Mack , Michael Horn
发明人： Burkhard Standke , Jaroslaw Monkiewicz , Albert-Johannes Frings , Ralf Laven , Roland Edelmann , Peter Jenkner , Helmut Mack , Michael Horn
IPC分类号： C07F7/04 , C07F7/18 , C07F7/20 , C07F7/08
CPC分类号： C07F7/1836 , C07F7/20
摘要： The residual halogen content in alkoxysilanes and in alkoxysilane-based compositions is reduced by a process comprising, treating the alkoxysilane or the alkoxysilane-based composition with activated carbon.
摘要翻译：通过包括以活性炭处理烷氧基硅烷或烷氧基硅烷基组合物的方法，可以减少烷氧基硅烷和烷氧基硅烷类组合物中的残留卤素含量。

9. 发明授权

US09012538B2 Silane-containing binder for composite materials 有权
标题翻译：用于复合材料的含硅烷的粘合剂
公开(公告)号：US09012538B2
公开(公告)日：2015-04-21
申请号：US11995751
申请日：2006-06-14
申请人： Roland Edelmann , Burkhard Standke , Peter Jenkner , Alireza Kharazipour , Lars Kloeser , Jaroslaw Monkiewicz
发明人： Roland Edelmann , Burkhard Standke , Peter Jenkner , Alireza Kharazipour , Lars Kloeser , Jaroslaw Monkiewicz
IPC分类号： B29C47/00 , C09J161/00 , C09J193/00 , C08J5/04 , C08K5/544 , C08L61/20 , C08L97/02 , C09J161/06 , C09J161/24 , C09J161/28 , C09J189/00
CPC分类号： C09J161/00 , C08J5/045 , C08J2361/06 , C08K5/544 , C08L61/20 , C08L97/02 , C09J161/06 , C09J161/24 , C09J161/28 , C09J189/00 , C09J193/00 , Y10T428/31591 , Y10T428/31663 , Y10T428/31848 , C08L83/00 , C08L2666/16
摘要： The present invention relates to a binder for composite materials comprising cellulose- or lignocellulose-containing materials, which is based on the components (i) at least one binder from the series consisting of organic resins, isocyanates, natural or near-natural binders and (ii) at least one composition based on an aminoalkylsilane. The invention furthermore relates to a composite material which is at least based on a cellulose- or lignocellulose-containing material and the abovementioned binder, a process for the production of such a composite material and the use of the binder system according to the invention for the production of wood-based materials.
摘要翻译：本发明涉及一种用于复合材料的粘合剂，其包含含纤维素或木质素纤维素的材料，其基于组分（i）至少一种由有机树脂，异氰酸酯，天然或近天然粘合剂组成的系列的粘合剂和（ ii）至少一种基于氨基烷基硅烷的组合物。本发明还涉及至少基于含纤维素或木质素纤维素材料和上述粘合剂的复合材料，用于生产这种复合材料的方法以及根据本发明的粘合剂体系用于生产木质材料。

10. 发明授权

US08481165B2 Agent for providing substrates based on cellulose and/or starch with water repellent and simultaneously antifungal, antibacterial insect-repellent and antialgal properties 有权
标题翻译：用于提供基于纤维素和/或淀粉的基材具有防水性，同时具有抗真菌，抗菌驱虫和抗相反特性的试剂
公开(公告)号：US08481165B2
公开(公告)日：2013-07-09
申请号：US11572688
申请日：2005-06-03
申请人： Roland Edelmann , Christian Waβmer , Peter Jenkner , Jaroslaw Monkiewicz , Holger Militz , Carsten Mai , Steffen Donath
发明人： Roland Edelmann , Christian Waβmer , Peter Jenkner , Jaroslaw Monkiewicz , Holger Militz , Carsten Mai , Steffen Donath
IPC分类号： B32B9/02 , C09D5/14 , B05D3/10
CPC分类号： C09D183/08 , A01N55/00 , B27K3/0292 , B27K3/156 , Y10T428/31663
摘要： The invention relates to an agent for providing substrates based on cellulose and/or starch with water-repellent and simultaneously antifungal, antibacterial, insect-repellent and antialgal properties, which contains water and, as active substance, at least one linear, cyclic, branched or crosslinked co-oligomer or mixtures of co-oligomers from the series consisting of the alkyl-/aminoalkyl-/alkoxy- or hydroxy-siloxanes, the use of such agents and a special treatment process using such agents.
摘要翻译：本发明涉及一种用于提供基于纤维素和/或淀粉的基材，具有防水，同时具有抗真菌，抗菌，驱虫和抗反相性能的试剂，其含有水和活性物质至少一种直链，环状，支链状或交联的共聚低聚物或由低级烷基 - 氨基烷基 - /烷氧基 - 或羟基 - 硅氧烷组成的系列的共低聚物的混合物，使用这种试剂和使用这种试剂的特殊处理方法。

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