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1. 发明授权

US07679078B2 Bis-anthracenyl chiroptical compositions 失效
标题翻译：双蒽烯基手性组合物
公开(公告)号：US07679078B2
公开(公告)日：2010-03-16
申请号：US11078965
申请日：2005-03-10
申请人： Robert R. Schumaker , James J. Marek, Jr. , James Parakka
发明人： Robert R. Schumaker , James J. Marek, Jr. , James Parakka
IPC分类号： H01L29/08 , C07D339/02
CPC分类号： C07D339/00
摘要： Optoelectronic materials are provided that are bistable organic tautomeric compositions that intraconvert dithio or diseleno carbamate esters and cyclic 1,3-dithia- or -diselena-2-iminium salts of π-conjugated bis-anthracenyl compounds. Specifically disclosed are compounds having the formula: where X is sulfur or selenium; where the R and R1 groups are alkyl or alkyl that together form a ring of carbon atoms; where An is the anion of a strong acid; and where the Z element is a chiral ring-completing system of atoms that changes chirality on tautomerization. These molecules are in themselves molecular-sized optoelectronic switching devices.
摘要翻译：提供了光电材料，其是双稳态有机互变异构体，其包含二硫代氨基甲酸酯或二硒代氨基甲酸酯和环状1,3-二硫或 - 联苯胺-2-亚胺鎓盐和共轭双 - 蒽基化合物。具体公开的是具有下式的化合物：其中X是硫或硒; 其中R和R 1基团是一起形成碳原子环的烷基或烷基; 其中An是强酸的阴离子; 并且其中Z元素是在互变异构化上改变手性的原子的手性环完成体系。这些分子本身就是分子尺寸的光电开关器件。

2. 发明申请

US20140037711A1 PENDANT HYDROPHILE BEARING BIODEGRAADABLE COMPOSITIONS AND RELATED DEVICES 有权
标题翻译：供应商水泥轴承生物可降解组合物及相关设备
公开(公告)号：US20140037711A1
公开(公告)日：2014-02-06
申请号：US13880666
申请日：2011-10-20
申请人： James Parakka , Ananth Iyer
发明人： James Parakka , Ananth Iyer
IPC分类号： A61L31/06 , A61L31/16
CPC分类号： A61L31/06 , A61L15/22 , A61L15/24 , A61L15/26 , A61L15/28 , A61L15/44 , A61L15/50 , A61L15/58 , A61L15/64 , A61L26/009 , A61L31/041 , A61L31/048 , A61L31/148 , A61L31/16 , C08G63/664 , C08L71/02 , C08L39/06
摘要： The instant invention relates to a composition comprising at least one polymer having the structure A-B-A′, wherein A and A′ may be the same or different and each is a degradable polyester component and wherein B is the reaction product resulting from the reaction between a diol, having one or more pendant oligomeric or polymeric groups, and A and A′.Additionally, the invention also relates to the development of a bioresorbable patch comprising: (a) an adhesion barrier component comprising a composition according to the invention in the form of a film; and (b) an adhesive component comprising: (i) at least one synthetic adhesive polymer; and/or (ii) at least one polysaccharide. The present invention provides a method of wound healing, comprising administering the composition or patch.
摘要翻译：本发明涉及包含至少一种具有结构AB-A'的聚合物的组合物，其中A和A'可以相同或不同，并且各自是可降解的聚酯组分，其中B是由下列反应产生的反应产物：具有一个或多个侧链低聚或聚合基团的二醇，以及A和A'。另外，本发明还涉及生物可再吸收贴片的开发，其包括：（a）包含薄膜形式的根据本发明的组合物的粘合屏障组分; 和（b）粘合剂组分，其包含：（i）至少一种合成粘合剂聚合物; 和/或（ii）至少一种多糖。本发明提供一种伤口愈合的方法，包括施用所述组合物或贴剂。

3. 发明申请

US20110124772A1 ANTIMICROBIAL POLYMERS AND THEIR USES 审中-公开
标题翻译：抗微生物聚合物及其用途
公开(公告)号：US20110124772A1
公开(公告)日：2011-05-26
申请号：US12994836
申请日：2009-05-26
申请人： Shanger Wang , Robert S. Ward , Yuan Tian , Li Li , Keith Mccrea , James Parakka , Robert L. Jones, JR.
发明人： Shanger Wang , Robert S. Ward , Yuan Tian , Li Li , Keith Mccrea , James Parakka , Robert L. Jones, JR.
IPC分类号： C09D175/04 , C08G71/04
CPC分类号： A01N33/12 , A01N47/44 , A01N25/10 , A01N2300/00
摘要： Polymers with non-leaching antimicrobial activity and their use as surface coatings or bulk resins for medical devices. The antimicrobial polymers are prepared with antimicrobial moieties covalently bonded to a polymer chain end or to a polymer backbone at a side chain end. The antimicrobial moiety-containing endgroups include surface active (or surface assembling) moieties which promote enrichment of antimicrobial endgroups at the polymer surface and thus formation of an antimicrobially active surface. Polymers with built-in antimicrobial endgroups can be used as bulk resins, as antimicrobial additives, or as infection preventative coatings in the manufacture of medical devices (e.g., catheters, vascular access devices, peripheral lines, IV sites, drains, gastric feeding and tubes, and other implantable devices). Such materials can also be used as antimicrobial and antifouling coatings on structures in contact with microorganism in environments that require control of biofilm formation, such as marine products.
摘要翻译：具有非浸出抗菌活性的聚合物及其用作医疗器械的表面涂层或体积树脂。抗微生物聚合物通过共价键合到聚合物链末端的抗微生物部分或在侧链末端与聚合物主链一起制备。含抗微生物部分的端基包括表面活性（或表面组装）部分，其促进抗微生物端基在聚合物表面的富集，从而形成抗微生物活性表面。具有内置抗微生物端基的聚合物可用作散装树脂，作为抗微生物添加剂，或作为医疗器械制造中的感染预防性涂层（例如，导管，血管通路装置，外围线，IV部位，下水道，胃饲和管，和其他可植入装置）。在需要控制生物膜形成的环境中，例如海产品，这些材料也可用作与微生物接触的结构上的抗微生物和防污涂料。

4. 发明申请

US20060202193A1 Bis-anthracenyl chiroptical compositions 失效
标题翻译：双蒽烯基手性组合物
公开(公告)号：US20060202193A1
公开(公告)日：2006-09-14
申请号：US11078965
申请日：2005-03-10
申请人： Robert Schumaker , James Marek , James Parakka
发明人： Robert Schumaker , James Marek , James Parakka
IPC分类号： H01L29/08 , C07D339/02
CPC分类号： C07D339/00
摘要： Optoelectronic materials are provided that are bistable organic tautomeric compositions that intraconvert dithio or diseleno carbamate esters and cyclic 1,3-dithia- or -diselena-2-iminium salts of π-conjugated bis-anthracenyl compounds. Specifically disclosed are compounds having the formula: where X is sulfur or selenium; where the R and R1 groups are alkyl or alkyl that together form a ring of carbon atoms; where An is the anion of a strong acid; and where the Z element is a chiral ring-completing system of atoms that changes chirality on tautomerization. These molecules are in themselves molecular-sized optoelectronic switching devices.
摘要翻译：提供了光电子材料，其是双键有机互变异构体，其包含二硫代或二硒代氨基甲酸酯和π-共轭双 - 蒽基化合物的环状1,3-二硫或 - 二烯 - 亚胺鎓盐。具体公开的是具有下式的化合物：其中X是硫或硒; 其中R和R 1个基团是一起形成碳原子环的烷基或烷基; 其中A N是强酸的阴离子; 并且其中Z元素是在互变异构化上改变手性的原子的手性环完成体系。这些分子本身就是分子尺寸的光电开关器件。

5. 发明授权

US09181401B2 Phosphorylcholine-based amphiphilic silicones for medical applications 有权
标题翻译：用于医疗应用的基于磷酰胆碱的两亲性硅氧烷
公开(公告)号：US09181401B2
公开(公告)日：2015-11-10
申请号：US13378260
申请日：2010-06-07
申请人： James Parakka , Ananth V. Iyer , Anfeng Wang , Xuwei Jiang , Yuan Tian , Robert Ward
发明人： James Parakka , Ananth V. Iyer , Anfeng Wang , Xuwei Jiang , Yuan Tian , Robert Ward
IPC分类号： A61L15/24 , C08L83/08 , G02B1/04 , C08F30/02 , C08F230/02 , C07F7/02 , C07F9/02 , C08G77/395 , A61L31/10 , A61L15/26 , C07F9/6574 , A61L27/34 , C08F230/08 , C07F9/09 , A61F13/00 , A61L27/18 , C08L83/10 , A61L26/00
CPC分类号： C08G77/395 , A61F13/00017 , A61L15/26 , A61L26/0019 , A61L27/18 , A61L27/34 , A61L31/06 , A61L31/10 , C07F9/091 , C07F9/092 , C07F9/65742 , C07F9/65746 , C08F230/02 , C08F230/08 , C08L83/08 , C08L83/10 , G02B1/043 , C08L83/04
摘要： Amphiphilic biomimetic phosphorylcholine-containing silicone compounds for use in both topical and internal applications as components in biomedical devices. The silicone compounds, which include zwitterionic phosphorylcholine groups, may be polymerizable or non-polymerizable. Specific examples of applications include use as active functional components in ophthalmic lenses, ophthalmic lens care solutions, liquid bandages, wound dressings, and lubricious and anti-thrombogenic coatings.
摘要翻译：用于局部和内部应用的两亲仿生磷酰胆碱的硅氧烷化合物作为生物医学装置的组件。包含两性离子磷酰胆碱基团的硅氧烷化合物可以是可聚合的或不可聚合的。应用的具体实例包括用作眼科镜片中的活性功能组分，眼用晶状体护理溶液，液体绷带，伤口敷料以及润滑和抗血栓形成的涂层。

6. 发明申请

US20120136087A1 PHOSPHORYLCHOLINE-BASED AMPHIPHILIC SILICONES FOR MEDICAL APPLICATIONS 有权
标题翻译：用于医疗应用的基于磷酰胆碱的AMPHIPILILIC硅
公开(公告)号：US20120136087A1
公开(公告)日：2012-05-31
申请号：US13378260
申请日：2010-06-07
申请人： James Parakka , Ananth V. Iyer , Anfeng Wang , Xuwei Jiang , Yuan Tian , Robert Ward
发明人： James Parakka , Ananth V. Iyer , Anfeng Wang , Xuwei Jiang , Yuan Tian , Robert Ward
IPC分类号： C08L83/08 , C08F130/02 , C07F7/02 , A61L15/24
CPC分类号： C08G77/395 , A61F13/00017 , A61L15/26 , A61L26/0019 , A61L27/18 , A61L27/34 , A61L31/06 , A61L31/10 , C07F9/091 , C07F9/092 , C07F9/65742 , C07F9/65746 , C08F230/02 , C08F230/08 , C08L83/08 , C08L83/10 , G02B1/043 , C08L83/04
摘要： Amphiphilic biomimetic phosphorylcholine-containing silicone compounds for use in both topical and internal applications as components in biomedical devices. The silicone compounds, which include zwitterionic phosphorylcholine groups, may be polymerizable or non-polymerizable. Specific examples of applications include use as active functional components in ophthalmic lenses, ophthalmic lens care solutions, liquid bandages, wound dressings, and lubricious and anti-thrombogenic coatings.
摘要翻译：用于局部和内部应用的两亲仿生磷酰胆碱的硅氧烷化合物作为生物医学装置的组件。包含两性离子磷酰胆碱基团的硅氧烷化合物可以是可聚合的或不可聚合的。应用的具体实例包括用作眼科镜片中的活性功能组分，眼用晶状体护理溶液，液体绷带，伤口敷料以及润滑和抗血栓形成的涂层。

7. 发明申请

US20060229423A1 Process for the production of monodisperse and narrow disperse monofunctional silicones 审中-公开
标题翻译：用于生产单分散和窄分散单官能硅氧烷的方法
公开(公告)号：US20060229423A1
公开(公告)日：2006-10-12
申请号：US11377822
申请日：2006-03-16
申请人： James Parakka , Yuan Tian , Robert Ward , Wang Shanger
发明人： James Parakka , Yuan Tian , Robert Ward , Wang Shanger
IPC分类号： C08G77/06
CPC分类号： C08G77/045 , C07F7/0874 , C08G77/06 , C08G77/08 , C08G77/20 , C08G77/36 , C08G77/38 , G02B1/043 , C08L83/06
摘要： Synthesis and purification of mono and narrow disperse monofunctional polydimethylsiloxane methacrylate derivatives with different molecular weights are disclosed.
摘要翻译：公开了具有不同分子量的单分散和单分散单官能聚二甲基硅氧烷甲基丙烯酸酯衍生物的合成和纯化。

8. 发明授权

US08153728B2 PDMS-PVP block copolymers 有权
标题翻译： PDMS-PVP嵌段共聚物
公开(公告)号：US08153728B2
公开(公告)日：2012-04-10
申请号：US12531200
申请日：2008-03-13
申请人： James Parakka , Keith R. McCrea , Robert S. Ward
发明人： James Parakka , Keith R. McCrea , Robert S. Ward
IPC分类号： C08F30/08 , C08F293/00
CPC分类号： C08F293/00 , A61L15/26 , A61L27/18 , C08F8/10 , C08F8/14 , C08F2810/40 , C08G77/442 , C08G77/452 , C08L53/00 , C08L83/10 , G02B1/043 , C08L39/06 , C08L83/06 , C08L83/04 , C08F126/10 , C08L2666/02
摘要： Methods for preparing functionalized polyvinylpyrrolidones with polymerizable functions. Also, amphipathic polydimethylsiloxane-PVP block copolymers, such as and (meth)acrylated and (meth)acrylamide-functionalized polyvinylpyrrolidone compounds, such as The block copolymers are useful as biomaterial components in biomedical devices. They provide improved wettability, lubricity, and material compatibility to the biomedical device, e.g., ophthalmic lenses.
摘要翻译：制备具有可聚合功能的官能化聚乙烯吡咯烷酮的方法。此外，两亲性聚二甲基硅氧烷-PVP嵌段共聚物如（甲基）丙烯酸酯化和（甲基）丙烯酰胺官能化的聚乙烯吡咯烷酮化合物如嵌段共聚物可用作生物医学装置中的生物材料组分。它们为生物医学装置例如眼科镜片提供改善的润湿性，润滑性和材料相容性。

9. 发明申请

US20070265460A1 PROCESS FOR THE PRODUCTION OF (TRIMETHYLSILYLOXY)SILYLALKYLGLYCEROL METHACRYLATES 审中-公开
标题翻译：（三甲基硅氧烷）甲基丙烯酰氧基甲基丙烯酸酯的生产方法
公开(公告)号：US20070265460A1
公开(公告)日：2007-11-15
申请号：US11782727
申请日：2007-07-25
申请人： Shivkumar Mahadevan , Robert Ward , Shanger Wang , James Parakka , Yuan Tian , Frank Molock
发明人： Shivkumar Mahadevan , Robert Ward , Shanger Wang , James Parakka , Yuan Tian , Frank Molock
IPC分类号： C07F7/08
CPC分类号： C07F7/0879
摘要： The present invention relates to a process comprising the steps of reacting in the presence of a hydrosilylation catalyst, a first reaction mixture comprising a free radical reactive compound and a silicon containing compound to form a silicon substituted glyceryl (meth)acrylate.
摘要翻译：本发明涉及包括以下步骤的方法：在氢化硅烷化催化剂存在下，包含自由基反应性化合物和含硅化合物的第一反应混合物反应以形成硅取代的（甲基）丙烯酸甘油酯。

10. 发明申请

US20050282997A1 Control of polymer surface molecular architecture via amphipathic endgroups 有权
标题翻译：通过两亲性端基控制聚合物表面分子结构
公开(公告)号：US20050282997A1
公开(公告)日：2005-12-22
申请号：US11211734
申请日：2005-08-26
申请人： Robert Ward , Keith McCrea , Yuan Tian , James Parakka
发明人： Robert Ward , Keith McCrea , Yuan Tian , James Parakka
IPC分类号： A61L27/14 , A61L27/18 , A61L29/06 , A61L31/06 , C08F20060101 , C08F2/00 , C08G18/08 , C08G18/12 , C08G18/28 , C08G18/50 , C08G18/62 , C08G18/67 , C08G65/00 , C08G65/329 , C08G69/08 , C08J5/00 , C08L53/00
CPC分类号： C08G18/6287 , A61L27/18 , A61L29/06 , A61L31/06 , C08G18/0823 , C08G18/12 , C08G18/283 , C08G18/2865 , C08G18/289 , C08G18/5024 , C08G18/5039 , C08G18/6283 , C08G18/6795 , C08L75/04 , C08G18/3228
摘要： Polymers whose surfaces are modified by endgroups that include amphipathic surface-modifying moieties. An amphipathic endgroup of a polymer molecule is an endgroup that contains at least two moieties of significantly differing composition, such that the amphipathic endgroup spontaneously rearranges its positioning in a polymer body to position the moiety on the surface of the body, depending upon the composition of the medium with which the body is in contact, when that re-positioning causes a reduction in interfacial energy. An example of an amphipathic surface-modifying endgroup is one that has both a hydrophobic moiety and a hydrophilic moiety in a single endgroup. For instance, a hydrophilic poly(ethylene oxide) terminated with a hydrophilic hydroxyl group is not surface active in air when the surface-modifying endgroup is bonded to a more hydrophobic base polymer. If the hydroxyl group on the oligomeric poly(ethylene oxide) is replaced by a hydrophobic methoxy ether terminus, the poly(ethylene oxide) becomes surface active in air, and allows the poly(ethylene oxide) groups to crystallize in the air-facing surface. In this example, immersion in water destroys the crystallinity as the poly(ethylene oxide) sorbs water and the hydrophobic methoxy group retreats below the surface of the polymer. Also disclosed are methods and articles of manufacture that make use of these polymers.
摘要翻译：其表面被包括两亲表面改性部分的端基修饰的聚合物。聚合物分子的两亲端基是含有至少两个具有显着不同组成的部分的端基，使得两亲性端基在聚合物体中自发地重排其定位，以将该部分定位在身体的表面上，这取决于当该重新定位导致界面能量降低时，与身体接触的介质。两亲性表面改性端基的实例是在单个端基具有疏水部分和亲水部分的实例。例如，当表面改性端基键合到更疏水的基础聚合物上时，用亲水羟基封端的亲水性聚（环氧乙烷）在空气中不是表面活性的。如果低聚聚（环氧乙烷）上的羟基被疏水性甲氧基醚末端所代替，则聚（环氧乙烷）在空气中变得表面活性，并允许聚（环氧乙烷）基团在面向空气的表面中结晶。在该实施例中，当聚（环氧乙烷）吸附水和疏水性甲氧基在聚合物表面下方退缩时，浸入水中会破坏结晶度。还公开了利用这些聚合物的方法和制品。

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