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    • 3. 发明授权
    • Photographic imaging process and materials suitable therefor
    • 摄影成像过程和材料适合
    • US4269923A
    • 1981-05-26
    • US114296
    • 1980-01-22
    • Raymond A. RoosenRobert J. PolletAntoon L. Vandenberghe
    • Raymond A. RoosenRobert J. PolletAntoon L. Vandenberghe
    • G03C1/00G03C1/06G03C5/42G03C5/50G03C7/24G03C7/305G03C8/08
    • G03C8/08G03C5/42G03C5/50G03C7/24G03C7/305Y10S430/135Y10S430/156
    • Novel photographic imaging process and materials suitable therefor are provided, which can find their application in multi-color motion picture and simultaneous sound recording, in direct-positive image formation, in image-intensification processes, etc. A photographic silver image is formed in at least one hydrophilic colloid layer of a light-sensitive photographic material incorporating silver halide, by means of exposure and alkaline development steps, followed by bleaching of quantities of silver which are present in areas of said layer extraneous to those where imaging silver is required. A non-diffusible silver bleach inhibitor is initially present in said layer or is released therein during processing of the material but before the bleaching step to prevent bleaching of the required imaging silver in said layer in the bleaching step and the prevention of the bleaching of the silver by the bleach inhibitor in the areas extraneous to those where imaging silver is required is counteracted by the presence in the corresponding areas of such layer of a bleach accelerator which is caused to diffuse into such areas from an adjacent hydrophilic colloid layer during the development processing of the material.
    • 提供了适合于其的新型摄影成像工艺和材料,可以在图像强化处理等中,将其应用于多色运动图像和同时录音,直接成像,形成图像。 通过曝光和碱性显影步骤将含有卤化银的光敏照相材料的至少一个亲水胶体层,随后漂白出存在与需要成像银的那些层相邻的所述层的区域中的数量的银。 最初在所述层中存在非扩散性银漂白抑制剂,或者在处理材料期间但在漂白步骤之前释放其中,以防止漂白步骤中所需层中所需的成像银漂白,并防止漂白 通过漂白剂促进剂的这种层的相应区域的存在,在显影处理过程中由相邻的亲水胶体层扩散到这些区域中的那些区域中,通过漂白剂抑制剂与需要成像银的那些区域的银相抵消 的材料。
    • 4. 发明授权
    • Substituted triazolopyrimidines and their use in light-sensitive
photographic elements
    • 取代的三唑并嘧啶及其在感光照相材料中的用途
    • US4727017A
    • 1988-02-23
    • US823948
    • 1986-01-29
    • Robert J. PolletAntoon L. VandenbergheHendrik E. KokelenbergPiet Kok
    • Robert J. PolletAntoon L. VandenbergheHendrik E. KokelenbergPiet Kok
    • C07D487/04G03C1/34
    • C07D487/04G03C1/34Y10S430/15
    • Photographic element comprising a support and a silver halide emulsion layer comprising in said emulsion layer and/or in a water-permeable layer coated at the same side of the support as said emulsion layer a compound corresponding to the following general formula: ##STR1## wherein: each of R.sup.1, R.sup.2, and R.sup.3, which may be the same or different, can represent hydrogen, C.sub.1 -C.sub.8 alkyl, or Alk.sub.1 - X - Alk.sub.2 - Y -, wherein: Alk.sub.1 is C.sub.1 -C.sub.8 alkyl, which may be substituted, X is --O-- or --S--, Alk.sub.2 is C.sub.1 -C.sub.8 alkylene, which may be substituted, and Y is a single bond, --O--, --S--, --CONH--, --SO.sub.2 NH--, or --NHCONH--, R.sup.3 can alternatively represent C.sub.1 -C.sub.8 alkyl-thio, the C.sub.1 -C.sub.8 alkyl group of which can be substituted, at least one of R.sup.1, R.sup.2, and R.sup.3, however, being other than hydrogen and other than C.sub.1 -C.sub.8 alkyl.The invention disclosed includes compounds per se, which correspond to said general formula.
    • 包含载体和卤化银乳剂层的照相元件包括在所述乳剂层中和/或在与所述乳剂层的支持物的同一侧涂覆的透水层中,所述化合物对应于以下通式:其中 :可以相同或不同的R 1,R 2和R 3可以表示氢,C 1 -C 8烷基或Alk 1 -X-Alk 2 -Y-,其中:Alk1是可被取代的C 1 -C 8烷基,X 是-O-或-S-,Alk2是可以被取代的C1-C8亚烷基,Y是单键,-O - , - S - , - CONH - , - SO2NH-或-NHCONH-,R3可以 或者表示C1-C8烷基 - 硫基,其C1-C8烷基可以被取代,R 1,R 2和R 3中的至少一个,但不是氢并且不是C 1 -C 8烷基。 所公开的本发明包括对应于所述通式的化合物本身。
    • 6. 发明授权
    • Photographic silver halide emulsion material containing an antifoggant
precursor
    • 含有防雾剂前体的摄影卤化银乳剂材料
    • US4307175A
    • 1981-12-22
    • US185932
    • 1980-09-10
    • Robert J. PolletHendrik E. KokelenbergAntoon L. Vandenberghe
    • Robert J. PolletHendrik E. KokelenbergAntoon L. Vandenberghe
    • G03C7/00C07D257/04C07D307/46F02D41/02G03C1/34G03C8/00
    • C07D257/04C07C323/00C07D307/46G03C1/346G03C8/00
    • A photographic material comprising in at least one light-sensitive silver halide emulsion layer and/or in a hydrophilic colloid layer in water-permeable relationship with such an emulsion layer an antifoggant precursor corresponding to one of the following general formulae: ##STR1## wherein: each of Y.sup.1 and Y.sup.2 (same or different) is an acyl groupeach of Y.sup.10 and Y.sup.20 (same or different) is an aromatic acyl group,R is an alkyl group, an aryl group or a heterocyclic nitrogen-containing 5-, 6- or 7-membered ring,R.sup.1 is hydrogen, an alkyl group, an aryl group, a carboxyl group in free acid, salt or esterified form, a carbamoyl group or a N-substitued carbamoyl group,R.sup.2 is hydrogen, an alkyl group or an aryl group,R.sup.3 has the same meaning as Y.sup.10, or is hydrogen, or is an alkyl group or an aryl group, or is a R.sup.7 -S- group wherein R.sup.7 is an alkyl group, an aryl group, or a heterocyclic group,R.sup.4 is hydrogen, an aryl group or a heterocyclic group,R.sup.5 is hydrogen, an alkyl group, an aryl group or a heterocyclic group, andZ represents the necessary atoms to close a heterocyclic nitrogen-containing 5-, 6- or 7-membered ring.
    • 一种照相材料,其在至少一种感光卤化银乳剂层和/或亲水胶体层中与这种乳剂层具有水可渗透的关系,该防沫剂前体对应于以下通式之一:其中: Y1和Y2(相同或不同)分别为Y10和Y20(相同或不同)为酰基,芳基为酰基,R为烷基,芳基或杂环含氮的5-,6- 或7-元环,R 1是氢,烷基,芳基,游离酸中的羧基,盐或酯化形式,氨基甲酰基或N-取代的氨基甲酰基,R 2是氢,烷基或 芳基,R 3具有与Y 10相同的含义,或为氢原子,或为烷基或芳基,或为R 7 -S-基,其中R 7为烷基,芳基或杂环基,R 4 是氢,芳基或杂环基,R 5是氢,烷基,芳基或 杂环基,Z表示封闭杂环含氮的5-,6-或7-元环的必需原子。
    • 7. 发明授权
    • Diffusion transfer reversal process
    • 扩散转移反转过程
    • US4859565A
    • 1989-08-22
    • US186757
    • 1988-04-26
    • Rene M. De KeyzerRobert J. PolletLeon L. Vermeulen
    • Rene M. De KeyzerRobert J. PolletLeon L. Vermeulen
    • C07D487/04G03C7/00G03C8/04G03C8/06G03C8/26G03C8/36
    • C07D487/04G03C8/06Y10S430/166
    • Method for making images by image-wise exposing a silver halide emulsion layer, developing it with an alkaline processing solution in the presence of a silver halide solvent, development nuclei, and a density- and tone-controlling compound, transferring silver complexes from the emulsion layer to a non-light-sensitive image-receiving layer and forming an image therein, said density- and tone-controlling compound being contained in said image-receiving layer and/or in said processing solution and corresponding to the general formula: ##STR1## wherein R.sup.1, R.sup.2, and R.sup.3 (same or different) represent hydrogen, C.sub.1 -C.sub.8 alkyl, or Alk.sub.1 --X--Alk.sub.2 --Y--; Alk.sub.1 is (substituted) C.sub.1 -C.sub.8 alkyl; X is --O-- or --S--; Alk.sub.2 is (substituted) C.sub.1 -C.sub.8 alkylene; Y is a single bond, --O--, --S--, --CONH--, --SO.sub.2 NH--, or --NHCONH--; R.sup.3 can alternatively represent (substituted) C.sub.1 -C.sub.8 alkylthio; at least one of R.sup.1, R.sup.2, and R.sup.3 being other than hydrogen and other than C.sub.1 -C.sub.8 alkyl. The invention also provides an image-receiving layer and/or a processing solution incorporating such density- and tone-controlling compound.
    • 通过成像曝光卤化银乳剂层,在卤化银溶剂存在下用碱性处理溶液显影图像,显影核和密度和色调控制化合物,从乳液转移银络合物制备图像的方法 层到非感光图像接收层并在其中形成图像,所述密度和色调控制化合物包含在所述图像接收层和/或所述处理溶液中并且对应于以下通式:< IMAGE (I)其中R1,R2和R3(相同或不同)表示氢,C1-C8烷基或Alk1-X-Alk2-Y-; Alk1是(取代的)C1-C8烷基; X是-O-或-S-; Alk2是(取代的)C1-C8亚烷基; Y是单键,-O - , - S - , - CONH - , - SO 2 NH-或-NHCONH-; R3可以替代地代表(取代的)C 1 -C 8烷硫基; R 1,R 2和R 3中的至少一个不是氢而不是C 1 -C 8烷基。 本发明还提供一种包含这种密度和色调控制化合物的图像接收层和/或处理溶液。