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1. 发明授权

US4727017A Substituted triazolopyrimidines and their use in light-sensitive photographic elements 失效
标题翻译：取代的三唑并嘧啶及其在感光照相材料中的用途
公开(公告)号：US4727017A
公开(公告)日：1988-02-23
申请号：US823948
申请日：1986-01-29
申请人： Robert J. Pollet , Antoon L. Vandenberghe , Hendrik E. Kokelenberg , Piet Kok
发明人： Robert J. Pollet , Antoon L. Vandenberghe , Hendrik E. Kokelenberg , Piet Kok
IPC分类号： C07D487/04 , G03C1/34
CPC分类号： C07D487/04 , G03C1/34 , Y10S430/15
摘要： Photographic element comprising a support and a silver halide emulsion layer comprising in said emulsion layer and/or in a water-permeable layer coated at the same side of the support as said emulsion layer a compound corresponding to the following general formula: ##STR1## wherein: each of R.sup.1, R.sup.2, and R.sup.3, which may be the same or different, can represent hydrogen, C.sub.1 -C.sub.8 alkyl, or Alk.sub.1 - X - Alk.sub.2 - Y -, wherein: Alk.sub.1 is C.sub.1 -C.sub.8 alkyl, which may be substituted, X is --O-- or --S--, Alk.sub.2 is C.sub.1 -C.sub.8 alkylene, which may be substituted, and Y is a single bond, --O--, --S--, --CONH--, --SO.sub.2 NH--, or --NHCONH--, R.sup.3 can alternatively represent C.sub.1 -C.sub.8 alkyl-thio, the C.sub.1 -C.sub.8 alkyl group of which can be substituted, at least one of R.sup.1, R.sup.2, and R.sup.3, however, being other than hydrogen and other than C.sub.1 -C.sub.8 alkyl.The invention disclosed includes compounds per se, which correspond to said general formula.
摘要翻译：包含载体和卤化银乳剂层的照相元件包括在所述乳剂层中和/或在与所述乳剂层的支持物的同一侧涂覆的透水层中，所述化合物对应于以下通式：其中：可以相同或不同的R 1，R 2和R 3可以表示氢，C 1 -C 8烷基或Alk 1 -X-Alk 2 -Y-，其中：Alk1是可被取代的C 1 -C 8烷基，X 是-O-或-S-，Alk2是可以被取代的C1-C8亚烷基，Y是单键，-O - ， - S - ， - CONH - ， - SO2NH-或-NHCONH-，R3可以或者表示C1-C8烷基 - 硫基，其C1-C8烷基可以被取代，R 1，R 2和R 3中的至少一个，但不是氢并且不是C 1 -C 8烷基。所公开的本发明包括对应于所述通式的化合物本身。

2. 发明授权

US4307175A Photographic silver halide emulsion material containing an antifoggant precursor 失效
标题翻译：含有防雾剂前体的摄影卤化银乳剂材料
公开(公告)号：US4307175A
公开(公告)日：1981-12-22
申请号：US185932
申请日：1980-09-10
申请人： Robert J. Pollet , Hendrik E. Kokelenberg , Antoon L. Vandenberghe
发明人： Robert J. Pollet , Hendrik E. Kokelenberg , Antoon L. Vandenberghe
IPC分类号： G03C7/00 , C07D257/04 , C07D307/46 , F02D41/02 , G03C1/34 , G03C8/00
CPC分类号： C07D257/04 , C07C323/00 , C07D307/46 , G03C1/346 , G03C8/00
摘要： A photographic material comprising in at least one light-sensitive silver halide emulsion layer and/or in a hydrophilic colloid layer in water-permeable relationship with such an emulsion layer an antifoggant precursor corresponding to one of the following general formulae: ##STR1## wherein: each of Y.sup.1 and Y.sup.2 (same or different) is an acyl groupeach of Y.sup.10 and Y.sup.20 (same or different) is an aromatic acyl group,R is an alkyl group, an aryl group or a heterocyclic nitrogen-containing 5-, 6- or 7-membered ring,R.sup.1 is hydrogen, an alkyl group, an aryl group, a carboxyl group in free acid, salt or esterified form, a carbamoyl group or a N-substitued carbamoyl group,R.sup.2 is hydrogen, an alkyl group or an aryl group,R.sup.3 has the same meaning as Y.sup.10, or is hydrogen, or is an alkyl group or an aryl group, or is a R.sup.7 -S- group wherein R.sup.7 is an alkyl group, an aryl group, or a heterocyclic group,R.sup.4 is hydrogen, an aryl group or a heterocyclic group,R.sup.5 is hydrogen, an alkyl group, an aryl group or a heterocyclic group, andZ represents the necessary atoms to close a heterocyclic nitrogen-containing 5-, 6- or 7-membered ring.
摘要翻译：一种照相材料，其在至少一种感光卤化银乳剂层和/或亲水胶体层中与这种乳剂层具有水可渗透的关系，该防沫剂前体对应于以下通式之一：其中： Y1和Y2（相同或不同）分别为Y10和Y20（相同或不同）为酰基，芳基为酰基，R为烷基，芳基或杂环含氮的5-，6- 或7-元环，R 1是氢，烷基，芳基，游离酸中的羧基，盐或酯化形式，氨基甲酰基或N-取代的氨基甲酰基，R 2是氢，烷基或芳基，R 3具有与Y 10相同的含义，或为氢原子，或为烷基或芳基，或为R 7 -S-基，其中R 7为烷基，芳基或杂环基，R 4 是氢，芳基或杂环基，R 5是氢，烷基，芳基或杂环基，Z表示封闭杂环含氮的5-，6-或7-元环的必需原子。

3. 发明授权

US4292402A Light-sensitive silver halide materials containing fluorine-containing surfactants 失效
标题翻译：含有氟表面活性剂的感光卤化银材料
公开(公告)号：US4292402A
公开(公告)日：1981-09-29
申请号：US120111
申请日：1980-02-08
申请人： Robert J. Pollet , Hendrik E. Kokelenberg , Rafael P. Samijn , Francis J. Sels , Frans J. Ville , Nikolaas C. de Jaeger
发明人： Robert J. Pollet , Hendrik E. Kokelenberg , Rafael P. Samijn , Francis J. Sels , Frans J. Ville , Nikolaas C. de Jaeger
IPC分类号： C07C59/135 , C07C65/21 , C08G65/329 , C11D1/00 , G03C1/38 , G03C1/85 , G03C1/76
CPC分类号： C07C309/00 , C07C59/135 , C07C65/21 , C08G65/329 , C11D1/004 , C11D1/006 , G03C1/385 , Y10S430/151 , Y10S430/162
摘要： Fluorine-containing surfactants according to formula (Rf--X).sub.n --A--L--Z wherein Rf is a short-chain fluorine-containing group derived from hexafluoropropylene or trifluorochloroethylene, X is --O--, --S--, or --SO.sub.2 --, n is at least 2, the Rf groups being same or different, L is a monovalent bond or a bivalent bridging group such as --COO--alkylene, --CONR.sup.1 --alkylene, or --SO.sub.2 NR.sup.1 --alkylene, wherein R.sup.1 is hydrogen or C.sub.1 -C.sub.5 alkyl, and Z represents a hydrophilic polyoxyethylene group or a hydrophilic group such as ##STR1## wherein M is hydrogen, an alkali metal, ammonium, or organic ammonium, and R.sup.3 is alkyl; A is an aliphatic, aromatic, or aliphatic-aromatic group. These surfactants can be used in hydrophilic colloid layers, which may form part of light-sensitive silver halide materials.
摘要翻译：根据式（Rf-X）nALZ的含氟表面活性剂，其中Rf是衍生自六氟丙烯或三氟氯乙烯的短链含氟基团，X是-O - ， - S-或-SO 2 - ，n为至少2 Rf基团相同或不同，L为一价键或二价桥接基团，例如-COO-亚烷基，-CONR1-亚烷基或-SO2NR1-亚烷基，其中R1为氢或C1-C5烷基，Z为亲水性聚氧乙烯基团或亲水基团，例如其中M为氢，碱金属，铵或有机铵，R3为烷基; A是脂族，芳族或脂族 - 芳族基团。这些表面活性剂可用于亲水胶体层，其可形成感光卤化银材料的一部分。

4. 发明授权

US4263395A High intensity photon-image recording 失效
标题翻译：高强度光子图像记录
公开(公告)号：US4263395A
公开(公告)日：1981-04-21
申请号：US31151
申请日：1979-04-18
申请人： Gerard A. Delzenne , Hendrik E. Kokelenberg
发明人： Gerard A. Delzenne , Hendrik E. Kokelenberg
IPC分类号： G03C1/675 , G03C1/685 , G03C1/73 , G03C1/52 , G03C5/04 , G03C5/24
CPC分类号： G03C1/73 , G03C1/675 , G03C1/685 , Y10S430/146
摘要： A recording method for directly forming a visible image, which method comprises exposing a recording material information-wise to ultra-violet radiation having a wave-length in the range of 200 nm to 400 nm, with a radiation intensity of at least 5.times.10.sup.11 erg/sq.cm.s so that the recording material receives a radiation energy dose of at least 1.times.10.sup.7 erg/sq.cm, the said recording material containing in a layer in admixture with an organic binder medium:(A) at least one dye precursor compound, which is a spiropyran compound or a compound corresponding to one of the general formulae ##STR1## wherein: R represents hydrogen, a lower alkyl (C.sub.1 -C.sub.3) group, a lower alkyl group, a phenyl group or phenyloxy,R.sup.1 represents an organic group,Z.sup.1 represents the necessary atoms to close a homocyclic ring or ring system,Z.sup.2 represents the necessary atoms to close a homocyclic ring or ring system,R.sup.2 represents a lower alkyl (C.sub.1 -C.sub.5) group, and n is 1 or 2,(B) at least one organic UV-sensitive compound which is capable of splitting off halogen upon exposure to ultra-violet radiation in the range of 200 nm to 400 nm, andwhich is selected so that when present in a test recording material as defined in the specification and when said material is subjected to test (X) as defined in the specification a density increase at the wavelength of maximum absorption in the visible light range of not more than 0.15 is obtained, the density measurement being a totally diffuse density measurement and when said material is subjected to test (Y) as defined in the specification a white light specular density of at least 0.35 above inherent fog is obtained.
摘要翻译：一种用于直接形成可见图像的记录方法，该方法包括将记录材料信息地曝光于具有200nm至400nm范围内的波长的紫外辐射，其辐射强度为至少5×10 11个/ 平方厘米，使得记录材料接收至少1×107erg / sq.cm的辐射能量剂量，所述记录材料包含在与有机粘合剂介质混合的层中：（A）至少一种染料前体化合物（II）其中：R表示氢，低级烷基（C1-C3）基，低级烷基，低级烷基（C1-C3）苯基或苯氧基，R1表示有机基团，Z1表示封闭环状环或环系的必需原子，Z 2表示封闭环状或环状体系的必需原子，R2表示低级烷基（C1-C5）基团，和n为1或2，（B）至少一种有机UV敏感剂该化合物能够在暴露于200nm至400nm的范围内的紫外线辐射下分解卤素，并且被选择为使得当存在于本说明书中所定义的测试记录材料中时以及当所述材料经受为了测定（X），在可见光范围内的最大吸收波长处的密度增加不大于0.15时，密度测量是全扩散密度测量，并且当所述材料进行测试 Y），得到高于固有雾度的至少0.35以上的白光镜面密度。

5. 发明授权

US4810623A Development of photographic silver halide emulsion materials 失效
标题翻译：照相卤化银乳剂材料的开发
公开(公告)号：US4810623A
公开(公告)日：1989-03-07
申请号：US156750
申请日：1988-02-18
申请人： Hendrik E. Kokelenberg , Benedictus J. Jansen
发明人： Hendrik E. Kokelenberg , Benedictus J. Jansen
IPC分类号： G03C1/42 , G03C5/26 , G03C1/02 , G03C1/06 , G03C5/24 , G03C5/30
CPC分类号： G03C1/42 , G03C5/262 , Y10S430/167 , Y10S430/168
摘要： A process for developing a photographic material containing on a support an image-wise exposed silver halide emulsion layer of which the silver halide is substantially silver chloride and in which the photographic material before its exposure contains already at least one silver halide developing agent in a hydrophilic colloid binder in waterpermeable relationship with the silver halide, said process containing the step of contacting the exposed photographic material with an aqueous alkaline liquid, called activator liquid, being initially substantially free from developing agent(s), said contacting being not followed by a silver complex diffusion transfer processing, characterized in that said aqueous alkaline liquid contains a primary and/or secondary amine.

6. 发明授权

US4411978A Photoresist materials and processes of using with photosensitive naphthoquinone diazides and nitrones 失效
标题翻译：光敏材料和使用光敏萘醌二氮嗪和硝酮的方法
公开(公告)号：US4411978A
公开(公告)日：1983-10-25
申请号：US885998
申请日：1978-03-13
申请人： Urbain L. Laridon , Hendrik E. Kokelenberg , Rafael P. Samijn
发明人： Urbain L. Laridon , Hendrik E. Kokelenberg , Rafael P. Samijn
IPC分类号： G03C1/00 , G03C1/72 , G03F7/004 , G03F7/038 , G03F7/095 , G03F7/20 , H01L21/027 , H05K3/00 , G03C1/54 , G03C1/60 , G03C5/00
CPC分类号： G03F7/095
摘要： A photosensitive recording material which includes in a supported layer a mixture of photosensitive substances in admixture with one or more polymers that are soluble in an alkaline aqueous liquid, characterized in that such mixture of photosensitive substances essentially consists of:(A) at least one photosensitive nitrone of the formula: ##STR1## in which: R is an aromatic hydrocarbon group including a substituted aromatic hydrocarbon group,R.sup.1 is an aromatic or heterocyclic group including these groups in substituted form,n represents zero or 1, and(B) at least one photosensitive naphthoquinone-(1,2)-diazide (2) compound, that has a higher ultraviolet absorption in the wavelength range of 350 to 400 nm and a higher visible light absorption above 400 nm than each such nitrone has, the (A) and (B) compounds being present in such relative quantities to each other that the layer exhibits a relative decrease in solubility in an alkaline aqueous liquid upon a sufficient exposure to a UV-light and a relative increase in solubilty in such alkaline aqueous liquid upon a lesser exposure to visible light or to UV-light.
摘要翻译：一种感光记录材料，其在支撑层中包含与可溶于碱性含水液体的一种或多种聚合物混合的感光性物质的混合物，其特征在于，感光物质的这种混合物基本上由以下组成：（A）至少一种感光性硝基酮，其结构式如下：其中R为含有取代芳香族烃基的芳香族烃基，R 1为包含取代基的这些基团的芳香族或杂环基，n表示0或1，（B）至少（A）的光敏萘醌 - （1,2） - 二叠氮化物（2）化合物在350〜400nm的波长范围内具有较高的紫外线吸收，高于400nm的可见光吸收，和（B）化合物以彼此相对的量存在，使得当充分暴露于UV时，该层在碱性水性液体中表现出相对降低的溶解度并且在较少的可见光或紫外线照射下，这种碱性水性液体的溶解度相对增加。

7. 发明授权

US4181529A Hardening of proteinaceous materials 失效
标题翻译：蛋白质材料的硬化
公开(公告)号：US4181529A
公开(公告)日：1980-01-01
申请号：US904277
申请日：1978-05-09
申请人： Francis J. Sels , Hendrik E. Kokelenberg , George F. Van Veelen
发明人： Francis J. Sels , Hendrik E. Kokelenberg , George F. Van Veelen
IPC分类号： C08L89/00 , G03C1/30 , C09H7/00
CPC分类号： G03C1/305
摘要： A proteinaceous material such as gelatin is hardened by treatment with an aqueous solution of a partial hydrolysis product of cyanuric chloride that has been buffered with a water-soluble borate, e.g. sodium metaborate, potassium metaborate or ammonium metaborate.The proteinaceous material can be a proteinaceous coating such as a photographic silver halide emulsion layer, a backing layer, a protective layer, a filter layer or any other photographic auxiliary layer.
摘要翻译：通过用已经用水溶性硼酸盐缓冲的氰尿酰氯的部分水解产物的水溶液处理，例如明胶等蛋白质物质硬化。偏硼酸钠，偏硼酸钾或偏硼酸铵。蛋白质材料可以是蛋白质涂层，例如照相卤化银乳剂层，背衬层，保护层，过滤层或任何其它照相辅助层。

8. 发明授权

US4420553A Photosensitive recording material and photographic processes wherein said material is used 失效
标题翻译：使用所述材料的感光记录材料和照相方法
公开(公告)号：US4420553A
公开(公告)日：1983-12-13
申请号：US376596
申请日：1982-05-10
申请人： Jan F. Van Besauw , Luc H. Leenders , Dirk M. D'hont , Hendrik E. Kokelenberg , Rafael P. Samijn
发明人： Jan F. Van Besauw , Luc H. Leenders , Dirk M. D'hont , Hendrik E. Kokelenberg , Rafael P. Samijn
IPC分类号： G03C1/675 , C07D209/08 , G03C1/73 , G03C5/56 , G03F7/004 , G03F7/031 , G03C1/52 , G03C1/68
CPC分类号： C07D209/08 , G03C1/73 , G03F7/031 , Y10S430/117 , Y10S430/121 , Y10S430/156
摘要： Photographic material comprising a supported or self-supporting binder layer incorporating a photoradical precursor compound in operative relationship with an image-forming precursor compound which is capable of taking part in image formation by reaction with the photoradicals formed by photoexposing said photoradical precursor, wherein the image-forming compound is a reducing compound containing Zerewitinoff active hydrogen for forming a print-out image or an ethylenically unsaturated compound capable of free-radical addition polymerization, and the photoradical precursor compound is a di- or tri(2,3-aryl substituted indolyl) compound free of Zerewitinoff active hydrogen.
摘要翻译：照相材料包括一种载体或自支撑的粘合剂层，其包含与成像前体化合物有效关系的光致发光前体化合物，该成像前体化合物能够通过与通过光固化所述光自由基前体形成的光自由基反应而参与图像形成，其中图像形成化合物是含有Zerewitinoff活性氢的还原化合物，用于形成印刷图像或能够进行自由基加成聚合的烯属不饱和化合物，光伏前体化合物是二或三（2,3-芳基取代的吲哚基）化合物，不含Zerewitinoff活性氢。

9. 发明授权

US4255513A Photopolymerizable recording materials 失效
标题翻译：可光聚合记录材料
公开(公告)号：US4255513A
公开(公告)日：1981-03-10
申请号：US64895
申请日：1979-08-08
申请人： Urbain L. Laridon , August M. Marien , Walter F. De Winter , Hendrik E. Kokelenberg
发明人： Urbain L. Laridon , August M. Marien , Walter F. De Winter , Hendrik E. Kokelenberg
IPC分类号： C08F2/00 , C08F2/50 , G03F7/031 , H01L21/027 , G03C1/68
CPC分类号： C08F2/50 , G03F7/031 , Y10S430/111 , Y10S430/117 , Y10S430/12
摘要： A photosensitive material is described which comprises a base and a solid photosensitive layer comprising a photopolymerizable compound and a photopolymerization initiating mixture consisting of an oxime ester, a photopolymerization initiator and a p-dialkylaminobenzene of the formula ##STR1## wherein R.sup.1 and R.sup.2 are lower alkyl, R.sup.3 is hydrogen, alkyl, alkoxy or N(R.sup.1) (R.sup.2) and X is --CO--, --CS--, CH.sub.2, or --CH(OH)--.Synergistic photocuring sensitivity is obtained by said oxime ester in admixture with said p-dialkyl aminobenzene compound.
摘要翻译：描述了一种感光材料，其包含基底和包含可光聚合化合物的固体感光层和由肟酯，光聚合引发剂和下式的对二烷基氨基苯组成的光聚合引发混合物，其中R 1和R 2是低级烷基，R3是氢，烷基，烷氧基或N（R1）（R2），X是-CO-，-CS-，CH2或-CH（OH） - ，所述肟酯与所述对二烷基氨基苯化合物。

10. 发明授权

US4282309A Photosensitive composition containing an ethylenically unsaturated compound, initiator and sensitizer 失效
标题翻译：含有烯属不饱和化合物，引发剂和敏化剂的感光组合物
公开(公告)号：US4282309A
公开(公告)日：1981-08-04
申请号：US106166
申请日：1979-12-21
申请人： Urbain L. Laridon , Walter F. DeWinter , Hendrik E. Kokelenberg
发明人： Urbain L. Laridon , Walter F. DeWinter , Hendrik E. Kokelenberg
IPC分类号： G03C1/00 , C08F2/00 , C08F2/50 , G03F7/004 , G03F7/031 , G03F7/038 , G03C1/68
CPC分类号： C08F2/50 , G03F7/031 , Y10S430/121
摘要： A photosensitive composition of matter suited for the production of polymer resist images which composition comprises a mixture of:(1) a photopolymerizable ethylenically unsaturated compound,(2) at least one oxime ester photopolymerization initiator, and(3) at least one sensitizer increasing the photopolymerization rate of said composition said sensitizer being defined in two general formulae said formulae including respectively a merocyanine dye, a zeromethine merocyanine dye, a carbostyril compound, an aryl-substituted 2-pyrazoline compound, an aryl-substituted oxazole compound, an aryl-substituted 1,2,4-triazole compound, an aryl-substituted 1,3,4-oxadiazole compound or an aryl-substituted-4-oxazolin-2-one compound.
摘要翻译：适用于生产聚合物抗蚀剂图像的光敏组合物，其组成包含以下混合物：（1）可光聚合的烯键式不饱和化合物，（2）至少一种肟酯光聚合引发剂，和（3）至少一种增感剂所述组合物的光聚合速率，所述敏化剂在两个通式中定义，所述式包括分别为部花青染料，月桂酸亚菁染料，喹诺酮化合物，芳基取代的2-吡唑啉化合物，芳基取代的恶唑化合物，芳基取代的 1,2,4-三唑化合物，芳基取代的1,3,4-恶二唑化合物或芳基取代的-4-恶唑啉-2-酮化合物。

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