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    • 7. 发明授权
    • Polyamidopolyfunctional amine from lactam and ether amine
    • 来自内酰胺和醚胺的多胺多官能胺
    • US5254668A
    • 1993-10-19
    • US905699
    • 1992-06-29
    • Richard J. G. DominguezRichard J. Clark, IIRichele T. HoweltonGeorge P. Speranza
    • Richard J. G. DominguezRichard J. Clark, IIRichele T. HoweltonGeorge P. Speranza
    • C08G69/14C08G69/26C08G69/40C08G73/02
    • C08G73/028
    • Amidamines of the following formula are described: ##STR1## where R is independently hydrogen or lower alkyl of 1 to 4 carbon atoms;R' is an alkyl group if k is 1, or an alkylene group if k is greater than 1; where R' has 2 to 18 carbon atoms;R" is independently lower alkylene of 2 to 4 carbon atoms;R'" is independently straight or branched lower alkylene of 2 to 6 carbon atoms;x is independently 1 to 200;y is independently 1 to 300;z is independently 1 to 200;p is independently 2 to 11; andk is from 1 to 8; where the x and z groups may be distributed in blocks or randomly.These compositions are made by reacting a cyclic lactam with an etheramine. Incorporation of increasing quantities of the polyetherpolyamine did not decrease the crystalline melting point (T.sub.m) of the resulting copolymer. The polyamidopolyfunctional amines (poly(amide-ether-amide) triblock copolymers) have a relatively low modulus and retain higher use temperatures than current polyetheramide segment block copolymers. The polyamidopolyether amines may be further interconnected through reaction with dicarboxylic acids, esters and the like.
    • 描述下式的酰胺:其中R独立地是氢或1-4个碳原子的低级烷基; 如果k为1,R'为烷基,如果k大于1,则为亚烷基; 其中R'具有2至18个碳原子; R“独立地为2至4个碳原子的低级亚烷基; R“独立地为2至6个碳原子的直链或支链低级亚烷基; x独立地为1〜200; y独立地为1〜300; z独立地为1〜200; p独立为2〜11; k为1〜8; 其中x和z组可以以块或随机方式分布。 这些组合物是通过使环内酰胺与醚胺反应制得的。 结合增加量的聚醚多胺不会降低所得共聚物的结晶熔点(Tm)。 聚酰胺多官能胺(聚(酰胺 - 醚 - 酰胺)三嵌段共聚物)具有相对较低的模量并且保持比当前聚醚酰胺链段嵌段共聚物更高的使用温度。 聚酰胺聚醚胺可以通过与二羧酸,酯等反应进一步互连。