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    • 4. 发明授权
    • Process for the preparation of synthesis gas from black liquor
    • 从黑液制备合成气的方法
    • US08038906B2
    • 2011-10-18
    • US12431240
    • 2009-04-28
    • Poul Erik Højlund NielsenBodil Voss
    • Poul Erik Højlund NielsenBodil Voss
    • D21C11/00C10J3/46C01B3/24
    • C01B3/36C01B3/32C01B3/50C01B3/52C01B2203/0415C01B2203/047C01B2203/0475C07C41/01D21C11/125C07C43/043
    • A process for the adjustment of the composition of a synthesis gas produced in a high temperature black liquor gasifier. The process includes the steps of (a) generating a gasifier effluent stream from black liquor in the gasifier by a blast and optionally an atomising stream; (b) optionally quenching the gasifier effluent stream with a gas stream to form a gas quenched effluent stream; (c) quenching the gasifier effluent of step (a) or the gas quenched effluent gas stream of step (b) with a water stream to form a raw synthesis gas; (d) further cooling and cleaning and separating the raw synthesis gas to form a purified unprocessed synthesis gas with an appropriate H2/CO ratio; (e) partly converting the purified synthesis gas to dimethyl ether in a synthesis section, producing at least a product stream of DME and a hydrogen rich purge stream of processed; (f) splitting and recycling individual or combinations of split streams of the processed or the unprocessed synthesis gas to step a and/or step (b); and recycling a by-product stream of CO2 being further generated in step (e) in part or completely to step (a) and/or step (b).
    • 用于调节在高温黑液气化器中生产的合成气的组成的方法。 该方法包括以下步骤:(a)通过鼓风和任选的雾化流从气化器中的黑液生成气化器流出物流; (b)任选地用气流骤冷气化器流出物流以形成气体骤冷流出物流; (c)用水流淬火步骤(a)的气化器流出物或步骤(b)的气体骤冷流出物气流,以形成原始合成气; (d)进一步冷却和清洗并分离原始合成气以形成具有合适H 2 / CO比的纯化未加工合成气; (e)在合成部分中部分地将纯化的合成气转化为二甲醚,至少产生DME的产物流和加氢的富氢吹扫流; (f)将经处理或未经处理的合成气的分流或分离流分离和回收到步骤a和/或步骤(b); 并且在步骤(e)中再次产生副产物二氧化碳流,部分或完全是步骤(a)和/或步骤(b)。
    • 6. 发明授权
    • Process for the preparation of ethanol and higher alcohols
    • 乙醇和高级醇的制备方法
    • US08637580B2
    • 2014-01-28
    • US13808240
    • 2011-05-17
    • Poul Erik Højlund NielsenBurcin TemelPablo Beato
    • Poul Erik Højlund NielsenBurcin TemelPablo Beato
    • C07C27/00
    • C07C29/1516C07C29/1512C07C29/32C07C31/08C07C31/10C07C31/12C07C31/125
    • Process for the preparation of ethanol and/or higher alcohols comprising the steps of: (a) providing an alcohol synthesis gas comprising carbon monoxide and hydrogen in a molar ratio of higher than 0.5; (c) adding an amount of methanol and/or higher alcohols to the synthesis gas to obtain a synthesis gas mixture. (d) converting the synthesis gas mixture from step (c) in presence of one or more catalysts catalysing the conversion of the synthesis gas mixture into a ethanol and/or higher alcohols containing product; and (e) withdrawing the product from step (d), wherein the synthesis gas is purified by removing iron and nickel carbonyl compounds prior or after the addition methanol and/or higher alcohols to the synthesis gas and optionally (I) cooling the withdrawn product in step (e); and (g) contacting the cooled product with a hydrogenation catalyst.
    • 制备乙醇和/或高级醇的方法包括以下步骤:(a)提供摩尔比高于0.5的一氧化碳和氢气的醇合成气; (c)向合成气中加入一定量的甲醇和/或高级醇以得到合成气体混合物。 (d)在催化合成气混合物转化为乙醇和/或高级醇的产物的一种或多种催化剂的存在下,转化来自步骤(c)的合成气混合物; 和(e)从步骤(d)中取出产物,其中通过在向合成气中加入甲醇和/或高级醇之前或之后除去铁和镍羰基化合物来纯化合成气,并且任选地(I)冷却所提取的产物 在步骤(e)中; 和(g)使冷却的产物与氢化催化剂接触。
    • 8. 发明申请
    • COMBINED PRODUCTION OF HYDROCARBONS AND ELECTRICAL POWER
    • 联合生产碳氢化合物和电力
    • US20110314834A1
    • 2011-12-29
    • US12674272
    • 2008-08-13
    • Poul Erik Højlund NielsenThomas Rostrup-NielsenBodil VossFinn Joensen
    • Poul Erik Højlund NielsenThomas Rostrup-NielsenBodil VossFinn Joensen
    • F02C6/18
    • C07C29/1518C07C41/01C10G3/42C10G2300/1022C10G2400/02Y02E20/14Y02P30/20C07C31/04C07C43/043
    • A process for the preparation of hydrocarbon products and for the generation of power comprising the steps of (a) providing a synthesis gas having a hydrogen to carbon monoxide ratio of between 0.1 and 1; (b) contacting the synthesis gas with one or more catalysts which together catalyse a reaction of hydrogen and carbon monoxide to oxygenates comprising methanol and dimethyl ether with a dimethyl ether to methanol ratio of higher than 2 and a carbon dioxide content of above 20 mole %; (c) contacting the carbon dioxide containing oxygenate mixture at an inlet temperature of between 240 and 4000 C with a catalyst being active in the conversion of oxygenate to higher hydrocarbons and a tail gas being rich in carbon dioxide; (d) combusting the carbon dioxide rich tail gas, optionally admixed with fresh carbon monoxide rich synthesis gas in a gas turbine combustion chamber to flue gas; and (e) expanding the flue gas stream through a gas turbine for the generation of power.
    • 一种用于制备烃产物和产生动力的方法,包括以下步骤:(a)提供氢与一氧化碳比为0.1至1的合成气; (b)使合成气与一种或多种催化剂接触,这些催化剂一起催化氢和一氧化碳与包含甲醇和二甲醚的含氧化合物的反应,甲醚与甲醇的比例高于2,二氧化碳含量高于20摩尔% ; (c)在240至4000℃的入口温度下使含二氧化碳混合物与含氧化合物转化为高级烃和富含二氧化碳的尾气有活性的催化剂接触; (d)燃烧富含二氧化碳的尾气,任选地与燃气轮机燃烧室中的新鲜的富含一氧化碳的合成气混合成烟道气; 和(e)通过用于发电的燃气轮机扩大烟气流。