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    • 4. 发明授权
    • Surface modified colloidal abrasives, including stable bimetallic surface coated silica sols for chemical mechanical planarization
    • 表面改性胶体研磨剂,包括用于化学机械平面化的稳定的双金属表面涂层硅溶胶
    • US07429338B2
    • 2008-09-30
    • US11487443
    • 2006-07-17
    • Junaid Ahmed Siddiqui
    • Junaid Ahmed Siddiqui
    • B44C1/22
    • B24B37/044C09G1/02C09K3/1409C09K3/1463C23F3/04H01L21/3212
    • A composition and an associated method for chemical mechanical planarization (or other polishing) are described. The composition includes a surface-modified abrasive modified with at least one stabilizer and at least one catalyst differing from the at least one stabilizer. The composition can further include a medium containing the abrasive and an oxidizing agent (e.g., hydrogen peroxide), wherein the at least one catalyst is adapted to catalyze oxidation of a substrate by the oxidizing agent. Preferably, the abrasive is alumina, titania, zirconia, germania, silica, ceria and/or mixtures thereof, the stabilizer is B, W and/or Al, and the catalyst is Cu, Fe, Mn, Ti, W and/or V. Both the stabilizer and the catalyst are immobilized on the abrasive surface. The method includes applying the composition to a substrate to be polished, such as substrates containing W, Cu and/or dielectrics.
    • 描述了用于化学机械平面化(或其它抛光)的组合物和相关方法。 该组合物包括用至少一种稳定剂和至少一种不同于至少一种稳定剂的催化剂改性的表面改性磨料。 组合物还可以包括含有研磨剂和氧化剂(例如过氧化氢)的介质,其中所述至少一种催化剂适于催化由氧化剂氧化底物。 优选地,研磨剂是氧化铝,二氧化钛,氧化锆,氧化锗,二氧化硅,二氧化铈和/或其混合物,稳定剂是B,W和/或Al,催化剂是Cu,Fe,Mn,Ti,W和/或V 稳定剂和催化剂都固定在磨料表面上。 该方法包括将组合物施加到待抛光的基底,例如含有W,Cu和/或电介质的基底。
    • 10. 发明授权
    • Free radical-forming activator attached to solid and used to enhance CMP formulations
    • 自由基形成活化剂连接到固体上并用于增强CMP配方
    • US07513920B2
    • 2009-04-07
    • US11264027
    • 2005-11-02
    • Junaid Ahmed SiddiquiRobert J. SmallDaniel Hernandez Castillo
    • Junaid Ahmed SiddiquiRobert J. SmallDaniel Hernandez Castillo
    • C09G1/02C09G1/04
    • C09G1/02C03C19/00C09K3/1463C23F3/04G11B5/3163G11B5/3169H01L21/3212
    • A CMP composition having: a fluid comprising water and at least one oxidizing compound that produces free radicals when contacted with an activator; and a plurality of particles having a surface and comprising at least one activator selected from ions or compounds of Cu, Fe, Mn, Ti, or mixtures thereof disposed on said surface, wherein at least a portion of said surface comprises a stabilizer. Preferred activators are selected from inorganic oxygen-containing compounds of B, W, Al, and P, for example borate, tungstate, aluminate, and phosphate. The activators are preferably ions of Cu or Fe. Surprisingly, as little as 0.2 ppm and 12 ppm of activator is useful, if the activator-containing particles are suspended in the fluid as a slurry. Advantageously, certain organic acids, and especially dihydroxy enolic acids, are included in an amount less than about 4000 ppm. Advantageously, activator is coated onto abrasive particles after the particles have been coated with stabilizer.
    • 一种CMP组合物,其具有:包含水和至少一种在与活化剂接触时产生自由基的氧化化合物的流体; 以及多个具有表面并且包含至少一种选自Cu,Fe,Mn,Ti或其混合物的离子或化合物的活化剂的颗粒,其中所述表面的至少一部分包含稳定剂。 优选的活化剂选自B,W,Al和P的无机含氧化合物,例如硼酸盐,钨酸盐,铝酸盐和磷酸盐。 活化剂优选为Cu或Fe的离子。 令人惊奇的是,只要0.2ppm和12ppm的活化剂是有用的,如果含活化剂的颗粒作为浆料悬浮在流体中。 有利地,某些有机酸,特别是二羟基烯醇酸的含量小于约4000ppm。 有利地,在颗粒已经用稳定剂涂覆之后,将活化剂涂覆到磨料颗粒上。