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    • 8. 发明授权
    • Thermally-responsive dispersants for media formulations
    • 用于培养基配方的热响应分散剂
    • US08318853B2
    • 2012-11-27
    • US12665040
    • 2008-06-19
    • Andrew M. HoweTrevor J. WearAlan R. PittIan M. NewingtonJohn H. Hone
    • Andrew M. HoweTrevor J. WearAlan R. PittIan M. NewingtonJohn H. Hone
    • C08L39/00B05D3/02B41J2/15
    • B01F17/0057B41M5/52B41M5/5218C09D5/027C09D7/45C09D11/326
    • A thermally-responsive dispersant for an aqueous dispersion of positively- or negatively-charged or chargeable solid or liquid particulates, comprises a compound having an anchoring moiety linked to a thermally-responsive polymeric stabilizing moiety, other than a polyalkylene oxide, the polymeric moiety having a lower affinity for the surface than the anchoring group below the thermal transition temperature, the particulates being positively-charged or chargeable when the anchoring moiety contains an acid and/or hydroxy group and has a net acidity or neutrality and the particulates being negatively-charged or chargeable when the anchoring moiety has a basic group and has a net basicity, wherein the dispersion exhibits a change in sign from negative to positive and an increase in magnitude of a rheological property (viscosity at low shear and/or complex modulus at low amplitude oscillatory shear), on increasing the temperature from below to above the thermal transition temperature.
    • 用于带正电荷或带负电荷或带电荷的固体或液体颗粒的水性分散体的热响应性分散剂包括具有与热响应性聚合物稳定化部分连接的锚定部分的化合物,而不是聚环氧烷,所述聚合物部分具有 当锚定部分含有酸和/或羟基并且具有净酸度或中性并且颗粒带负电荷时,对于表面的亲和力低于锚定基团低于热转变温度的亲和力,所述颗粒被带正电或带电 或者当锚定部分具有碱性基团并且具有净碱度时可带电,其中分散体显示从负到正的变化和流变特性的大小(低剪切时的粘度和/或低振幅下的复数模量) 振荡剪切),将温度从低到高于热转变温度。
    • 10. 发明授权
    • Bis-poly(ethylene oxide) surfactants and their use as antistats in photographic materials
    • 双 - 聚(环氧乙烷)表面活性剂及其在照相材料中的抗静电剂用途
    • US06482975B1
    • 2002-11-19
    • US09857877
    • 2001-06-12
    • Alan R. PittTrevor J. Wear
    • Alan R. PittTrevor J. Wear
    • C07C6934
    • G03C1/895C07C69/34C07C69/63C07C323/52
    • Optionally fluorine-substituted alkyl or alkenyl poly(ethylene oxides) the compounds of the general formula in which R is an alkyl group with 10-20 carbon atoms, an alkenyl group with 10-20 carbon atoms or a fluoroalkyl or fluoroalkenyl group with f carbon atoms that each bear at least one fluorine atom and g carbon atoms that bear only hydrogen atoms, in which 1.5 f+g=10-20 and g may optionally be zero. R′ is an alkyl group with 1 to 4 carbon atoms, L is a linking group, a linking atom or a chemical bond, and p is at least 2, q is at least 2 and p+q=from 4 to 100, may be prepared by reacting maleic anhydride with a poly(ethylene glycol) alkyl. ether and reacting the resultant intermediate product with a compound of the formula RL′H in which L′ is a linking group or linking atom. Compounds of the formula (1) may also be prepared by reacting RL-substituted succinic anhydrides with a alkyl end-capped polyethylene glycol. The compounds of the formula (1) exhibit good solubility and surface activity and may be used as antistats, particularly in gelatin media, optionally in conjunction with lithium triflate or the like, in photographic coatings.
    • 任选氟取代的烷基或烯基聚(环氧乙烷),其中R为具有10-20个碳原子的烷基,具有10-20个碳原子的烯基或具有f个碳原子的氟代烷基或氟烯基的通式化合物 各自承担至少一个仅含有氢原子的氟原子和g个碳原子,其中1.5f + g = 10-20,g可以任选地为0.R'是具有1至4个碳原子的烷基,L是 连接基团,连接原子或化学键,并且p为至少2,q为至少2且p + q = 4至100,可以通过使马来酸酐与聚(乙二醇)烷基反应来制备。 醚,并使所得中间产物与其中L'为连接基团或连接原子的式RL'H化合物反应。 式(1)化合物也可以通过使RL取代的琥珀酸酐与烷基封端的聚乙二醇反应来制备。 式(1)的化合物表现出良好的溶解性和表面活性,并且可以用作抗静电剂,特别是在明胶介质中,任选地与三氟甲磺酸锂等一起在照相涂料中使用。