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1. 发明授权

US06171773B2 Color photographic print material 失效
标题翻译：彩色照相打印材料
公开(公告)号：US06171773B2
公开(公告)日：2001-01-09
申请号：US09304592
申请日：1999-05-04
申请人： Peter Bergthaller , J{umlaut over (u)}rgen Jung , Edgar Draber , Jörg Hagemann , Ulrich Nickel
发明人： Peter Bergthaller , J{umlaut over (u)}rgen Jung , Edgar Draber , Jörg Hagemann , Ulrich Nickel
IPC分类号： G03C108
CPC分类号： G03C7/383 , G03C7/3003 , G03C7/30535 , G03C7/3225 , G03C7/39276 , G03C2007/3015
摘要： A colour photographic material which contains at least one pyrrolo[1,2-b]-1,2,4-triazole cyan coupler of the formula (I) in which R1, X and Y have the meaning stated in the description, is distinguished by excellent reproduction of blue and cyan tones if a 2-equivalent yellow coupler is added to the layer containing the couplers of the formula (I).
摘要翻译：含有至少一种式（I）的吡咯并[1,2-b] -1,2,4-三唑青色成色剂的彩色照相材料，其中R1，X和Y具有说明书中所述的含义，其区别在于如果将2-当量的黄色成色剂加入到含有式（I）的成色剂的层中，则通过优异的蓝色和青色色调再现。

2. 发明授权

US06498001B1 Photographic silver halide emulsion 失效
标题翻译：摄影卤化银乳剂
公开(公告)号：US06498001B1
公开(公告)日：2002-12-24
申请号：US09911589
申请日：2001-07-24
申请人： Peter Bergthaller , Jörg Siegel , Hans-Ulrich Borst , Ralf Büscher , Ulrich Nickel
发明人： Peter Bergthaller , Jörg Siegel , Hans-Ulrich Borst , Ralf Büscher , Ulrich Nickel
IPC分类号： G03C1005
CPC分类号： G03C1/0053 , G03C1/08 , G03C1/10 , G03C1/28 , G03C2200/33
摘要： A spectrally sensitized photographic silver halide emulsion, characterized in that after precipitation at least one compound of formula is added to the emulsion, wherein R1 denotes alkyl, aryl, aralkyl, alkenyl or heterocyclyl; R2 denotes H, alkyl, aryl, heterocyclyl, amino or alkoxy; R3 denotes H, alkyl, aryl, aralkyl or heterocyclyl; D denotes —OH or —NR4R5; X denotes O or N—R6; R4 denotes H, alkyl, aryl, aralkyl, alkenyl or heterocyclyl; R5: denotes H, alkyl, aryl, aralkyl, alkenyl or heterocyclyl; R6: denotes H, alkyl, aryl, aralkyl, alkenyl, acyl, alkoxycarbonyl, carbamoyl or heterocyclyl, the aforementioned alkyl, aryl, aralkyl, alkenyl, heterocyclyl, amino, alkoxy, acyl, alkoxycarbonyl and carbamoyl groups can be substituted, and any two of the radicals R1 to R6 can together form a heterocyclic ring, such as a pyrrolidine, piperidine, perhydroazepine, piperazine, morpholine or thiomorpholine ring, for example; as well as a photographic material comprising a support and at least one silver halide emulsion layer which contains said emulsion, are distinguished by increased sensitivity, a high sensitivity/fogging ratio and a good shelf life, particularly when stored under humid climatic conditions.
摘要翻译：一种光谱增感的照相卤化银乳剂，其特征在于在沉淀后，将至少一种式的化合物加入乳液中，其中R1表示烷基，芳基，芳烷基，烯基或杂环基; R2表示H，烷基，芳基，杂环基，氨基或烷氧基; R3表示H，烷基，芳基，芳烷基或杂环基; D表示-OH或-NR4R5; X表示O或N-R6; R4表示H，烷基，芳基，芳烷基，烯基或杂环基; R5表示H，烷基，上述烷基，芳基，芳烷基，链烯基，杂环基，氨基，烷氧基，酰基，烷氧基羰基和氨基甲酰基; R 6表示H，烷基，芳基，芳烷基，烯基，酰基，烷氧基羰基，氨基甲酰基或杂环基可以被取代，并且任何两个基团R 1至R 6可以一起形成杂环，例如吡咯烷，哌啶，过氢氮杂，哌嗪，吗啉或硫代吗啉环; 以及包含载体和含有所述乳液的至少一种卤化银乳剂层的照相材料，特别是当在潮湿气候条件下储存时，具有增加的灵敏度，高灵敏度/起雾比和良好的保质期。

3. 发明授权

US06498003B2 Photographic silver halide material 失效
标题翻译：摄影卤化银材料
公开(公告)号：US06498003B2
公开(公告)日：2002-12-24
申请号：US09915687
申请日：2001-07-26
申请人： Peter Bergthaller , Jörg Siegel , Hans-Ulrich Borst
发明人： Peter Bergthaller , Jörg Siegel , Hans-Ulrich Borst
IPC分类号： G03C1005
CPC分类号： G03C1/28
摘要： A photographic material comprising a support and at least one layer which comprises at least one spectrally sensitised silver halide emulsion, characterised in that the material contains at least one compound of formula and/or wherein R1 denotes H, alkyl, aryl, aralkyl, alkenyl, heterocyclyl, R2 denotes OH, NH2, NHR7, NR8R9 or R1 together with R2, denotes the atoms necessary for the completion of a heteroaliphatic ring, R3 denotes OH, NH2, NHR7, NR8R9, R4 denotes H, alkyl, aryl, aralkyl, alkenyl, heterocyclyl, R5, R6 independently of each other, denote OH, NH2, NHR10, NR11R12, or R4 together with R5, or R4 together with R6, denote the atoms necessary for the completion of a heteroaliphatic ring, and the R5 or R6 radical, which is not part of a ring, denotes OH, NH2, NHR10 or NR11R12, R7, R10 denote alkyl, aryl, aralkyl, heterocyclyl, R8, R9 independently of each other, denote alkyl, aryl, aralkyl, heterocyclyl, or R8 together with R9, denotes the atoms necessary for the completion of a heteroaliphatic ring, and R11, R12 independently of each other, denote alkyl, aryl, aralkyl, heterocyclyl, or R11 together with R12, denote the atoms necessary for the completion of a heterocyclic ring, and wherein only one of the radicals R2 and R3 and only one of the radicals R5 and R6 can denote OH or NH2, is distinguished by increased spectral sensitivity, a high sensitivity/fogging ratio and a good shelf life under humid conditions.
摘要翻译：包含载体和至少一层包含至少一种光谱增感的卤化银乳剂的照相材料，其特征在于所述材料含有至少一种式和/或其中的R 1表示H，烷基，芳基，芳烷基，烯基，杂环基，R 2 表示OH，NH2，NHR7，NR8R9或R1与R2一起表示完成杂脂肪族环所需的原子，R3表示OH，NH2，NHR7，NR8R9，R4表示H，烷基，芳基，芳烷基，烯基，杂环基，R5 ，R6彼此独立地表示OH，NH2，NHR10，NR11R12或R4以及R5或R4与R6一起表示完成杂脂肪族环所必需的原子，以及不是部分的R5或R6基团表示OH，NH2，NHR10或NR11R12，R7，R10表示烷基，芳基，芳烷基，杂环基，R8，R9彼此独立地表示烷基，芳基，芳烷基，杂环基或R8与R9一起表示原子完成杂合子所必需的芳基，R 11，R 12彼此独立地表示烷基，芳基，芳烷基，杂环基或R 11与R 12一起表示完成杂环所必需的原子，并且其中仅一个基团R 2和R 3以及仅一个基团R5和R6可以表示OH或NH2，其特征在于增加的光谱灵敏度，高灵敏度/起雾比和在潮湿条件下的良好保质期。

4. 发明授权

US06261758B1 Production of silver halide emulsions 失效
标题翻译：生产卤化银乳剂
公开(公告)号：US06261758B1
公开(公告)日：2001-07-17
申请号：US09616445
申请日：2000-07-14
申请人： Ralf Wirowski , Hans-Ulrich Borst , Detlev Kapitza , Jörg Siegel , Peter Bergthaller , Heinrich Odenwälder
发明人： Ralf Wirowski , Hans-Ulrich Borst , Detlev Kapitza , Jörg Siegel , Peter Bergthaller , Heinrich Odenwälder
IPC分类号： G03C1035
CPC分类号： G03C1/07 , G03C1/0051 , G03C2001/0055 , G03C2001/0153 , G03C2200/33
摘要： The production of tabular silver bromide-iodide emulsions and silver bromide-chloride-iodide emulsions with an aspect ratio 32, an iodide content from 1 to 40 mol % and a chloride content from 0 to 20 mol %, by the process steps of (a) silver halide nucleus precipitation, and (b) at least one further precipitation of silver halide, wherein rein at least one aromatic five- or six-membered, heterocyclic compound, which is free from—SH—,—SSO2H— and—SSO2R groups, is added in an amount from 10−9 to 10−4 mol/mol silver during nucleus precipitation or during the precipitation of an inner zone of the silver halide grain which is different from the nucleus precipitate, results in an improved speed/grain size ratio and in an increased stability of a photographic material which contains an emulsion produced in this manner.
摘要翻译：通过（a）的方法步骤制备长宽比为32，碘化物含量为1至40摩尔％，氯化物含量为0至20摩尔％的片状溴化银碘化物乳液和溴化银 - 碘化碘化银乳剂）卤化银核沉淀，和（b）卤化银的至少一种进一步沉淀，其中保留至少一种不含-SH - ， - SSO2H和 - SSO2R基团的芳族五元或六元杂环化合物，在沉淀过程中或在不同于核沉淀物的卤化银颗粒的内部区域的析出过程中，其添加量为10-9至10-4mol / mol银，导致速度/晶粒尺寸的改善比例和增加的含有以这种方式生产的乳液的照相材料的稳定性。

5. 发明授权

US6150079A Color photographic recording material 失效
标题翻译：彩色摄影材料
公开(公告)号：US6150079A
公开(公告)日：2000-11-21
申请号：US227469
申请日：1999-01-08
申请人： Peter Bergthaller
发明人： Peter Bergthaller
IPC分类号： G03C7/38 , C09B57/00 , G03C7/305 , G03C7/32 , G03C1/08 , G03C7/26
CPC分类号： G03C7/30529 , G03C7/30541 , G03C7/3212 , G03C7/34 , G03C7/383 , Y10S430/156 , Y10S430/157 , Y10S430/158 , Y10S430/159
摘要： A color photographic material, the cyan coupler of which is of the formula ##STR1## in which R.sub.11 means an alkyl, aryl, acylamino, alkylcarbamoyl, arylcarbamoyl or a heterocyclic group,R.sub.12 means a group having electron-attracting characteristics,R.sub.13 means a group having electron-attracting characteristics,R.sub.14 means an alkyl or aryl group,R.sub.15 means a divalent linking member having 2 to 4 linking atoms,X means .dbd.O or .dbd.N--SO.sub.2 R.sub.21 andY means a group eliminable by hydrolytic or intramolecular (nucleophilic) attack,is distinguished by improved processing stability.
摘要翻译： R 11表示烷基，芳基，酰氨基，烷基氨基甲酰基，芳基氨基甲酰基或杂环基的R 1表示具有电子吸引特性的基团，R 13表示具有电子吸收特性的基团，吸引特性R14表示烷基或芳基，R15表示具有2〜4个连接原子的二价连接体，X表示= O或= N-SO 2 R 21，Y表示可通过水解或分子内（亲核）攻击消除的基团，通过改善加工稳定性。

6. 发明授权

US6043017A Color photographic silver halide material 失效
标题翻译：彩色照相卤化银材料
公开(公告)号：US6043017A
公开(公告)日：2000-03-28
申请号：US339623
申请日：1999-06-24
申请人： Peter Bergthaller
发明人： Peter Bergthaller
IPC分类号： C07D513/04 , G03C7/38 , G03C7/413 , G03C1/73
CPC分类号： C07D513/04 , G03C7/382 , G03C7/4136
摘要： The present invention relates to a new compound of formula (I) with the proviso that Y represents N, and also relates to a colour photographic silver halide material comprising at least one red-sensitive silver halide layer with which according to the invention a compound of formula (I) is associated, and also relates to a photographic colour development process in which couplers of formula (I) are reacted with colour developers of the phenylenediamine and/or diaminotoluene type to form coupling products which exhibit a strong absorption, particularly in the infrared region. The present invention further relates to the use of compounds of formula (I) as cyan and/or infrared couplers in colour photographic silver halide materials.
摘要翻译：本发明涉及新的式（I）化合物，条件是Y表示N，并且还涉及包含至少一种感红卤化物层的彩色照相卤化银材料，根据本发明，本发明的化合物式（I）相关联，并且还涉及其中式（I）的成色剂与苯二胺和/或二氨基甲苯型的显色剂反应以形成显示强吸收的偶联产物的照相显色方法，特别是在红外区域。本发明还涉及在彩色照相卤化银材料中式（I）化合物作为青色和/或红外成色剂的用途。

7. 发明授权

US5888717A Photographic silver halide emulsion 失效
标题翻译：摄影卤化银乳剂
公开(公告)号：US5888717A
公开(公告)日：1999-03-30
申请号：US970488
申请日：1997-11-14
申请人： Peter Bergthaller , Hans-Ulrich Borst , Jorg Siegel
发明人： Peter Bergthaller , Hans-Ulrich Borst , Jorg Siegel
IPC分类号： G03C1/005 , G03C1/09 , G03C1/34
CPC分类号： G03C1/09 , G03C1/0051 , G03C1/34
摘要： A photosensitive silver halide emulsion which is ripened with at least one compound of the formula (I)R.sub.1 --X--R.sub.2 (I)in whichR.sub.1 and R.sub.2 mutually independently mean groups which are linked to X via an element from periods 3 to 6 of main group 4 or 5 or via an element from sub-groups 4 to 8 of the periodic system of elements, wherein R.sub.1 and R.sub.2 may be attached together via a linking member and wherein the bonds R.sub.1 --X and R.sub.2 --X may mutually independently be single or double bonds, andX means Se or Te,is distinguished by elevated sensitivity, low grain and low fog.
摘要翻译：用至少一种式（I）化合物R1-X-R2（Ⅰ）熟化的感光卤化银乳剂，其中R 1和R 2相互独立地表示通过第3至6个主组4或5，或通过元素周期系统的亚组4至8的元素，其中R1和R2可以经由连接构件连接在一起，并且其中键R1-X和R2-X可以相互独立地为单键或双键，X表示Se或Te，通过提高灵敏度，低谷物和低雾来区分。

8. 发明授权

US5683863A Photographic silver halide material 失效
标题翻译：摄影卤化银材料
公开(公告)号：US5683863A
公开(公告)日：1997-11-04
申请号：US571408
申请日：1995-12-13
申请人： Peter Bergthaller , Hans-Ulrich Borst , Peter Bell , Ralf Buscher , Johannes Willsau , Thomas Stetzer
发明人： Peter Bergthaller , Hans-Ulrich Borst , Peter Bell , Ralf Buscher , Johannes Willsau , Thomas Stetzer
IPC分类号： G03C7/00 , C07D293/06 , C07D293/12 , G03C1/34 , G03C7/30 , G03C7/392 , G03C1/09
CPC分类号： C07D293/12 , C07D293/06 , G03C1/346 , G03C7/3924 , G03C7/39296 , G03C7/3022
摘要： A color photographic silver halide material having at least one silver halide emulsion layer, which is stabilized with a compound of formula (I) or (II) ##STR1## where X represents O or NR.sub.2 Y represents halogen, Z.sup..crclbar. represents an anion, R.sub.1 represents hydrogen or a substituent, or jointly with X represents the remaining members of a condensed ring R.sub.2 represents hydrogen or a substituent, and Q represents the atoms required for the completion of a 5- or 6-membered ring, is characterized by enhanced stability.
摘要翻译：具有至少一个卤化银乳剂层的彩色照相卤化银材料，其用X表示O或NR 2 Y的式（I）或（II）化合物稳定化，表示卤素，Z（ - ）表示阴离子，R1表示氢或取代基，或与X表示稠合环的其余成员R2表示氢或取代基，Q表示完成5-或 6元环的特征在于增强的稳定性。

9. 发明授权

US5021331A Color photographic recording material containing a DIR coupler 失效
标题翻译：含有DIR耦合器的彩色照相记录材料
公开(公告)号：US5021331A
公开(公告)日：1991-06-04
申请号：US528043
申请日：1990-05-23
申请人： Hans Vetter , Heinrich Odenwalder , Peter Bergthaller , Thomas Kruger
发明人： Hans Vetter , Heinrich Odenwalder , Peter Bergthaller , Thomas Kruger
IPC分类号： G03C7/305 , G03C7/32
CPC分类号： G03C7/305 , Y10S430/158
摘要： Highly active silver halide development inhibitors are released from DIR couplers corresponding to formula I during color development. Where DIR couplers are used in color photographic silver halide materials, high edge effects and high inter-image effects are obtained.A--(TIME).sub.n --Z IIn formula I,A is the residue of a coupler which couples with the oxidation product of a silver halide developing agent under the conditions of photographic development and, in doing so, releases a group corresponding to the following formula--(TIME).sub.n --ZTIME is a binding link which together with the group Z (a triazole ring) attached thereto is releases on reaction of the coupler with the oxidation product of a silver halide developing agent and which, in turn, releases the group Z with delay under the development conditions;n is 0 or 1;Z is a triazole ring corresponding to one of the following formulae ##STR1## R.sup.1 is alkylthio; R.sup.2 is H, alkyl, alkythio, aryl or a heterocyclic group; at least one of the substituents R.sup.1 and R.sup.2 contains at a distance of 2 to 4 atoms from the triazole ring a group --CO--OR.sup.3, --O--CO--OR.sup.3 or --O--CO--R.sup.3 hydrolyzable in aqueous alkali;R.sup.3 is alkyl, cycloalkyl or aryl.
摘要翻译：在显影期间，高活性卤化银显影抑制剂从对应于式I的DIR成色剂中释放出来。在彩色照相卤化银材料中使用DIR成色剂时，可获得高边缘效果和高图像效果。 A-（TIME）n-Z在式I中，A是在照相显影的条件下与卤化银显影剂的氧化产物偶联的成色剂的残基，并且在这样做时，释放相应于下列物质的基团式 - （TIME）nZ TIME是与连接到其上的组Z（三唑环）一起的结合链接，其与成色剂与卤化银显影剂的氧化产物反应释放，并且反过来释放基团 Z在发展条件下有延误; n为0或1; Z是对应于下式之一的三唑环：R 1是烷硫基; R2是H，烷基，链烯基，芳基或杂环基; 取代基R 1和R 2中的至少一个与三唑环在含水碱中可水解的基团-CO-OR3，-O-CO-OR3或-O-CO-R3的距离为2至4个原子; R3是烷基，环烷基或芳基。

10. 发明授权

US4546073A Photographic recording material containing a precursor of a photographically-active compound 失效
标题翻译：含有摄影活性化合物前体的摄影记录材料
公开(公告)号：US4546073A
公开(公告)日：1985-10-08
申请号：US610786
申请日：1984-05-16
申请人： Peter Bergthaller , Heinrich Odenwalder , Reinhard Matejec
发明人： Peter Bergthaller , Heinrich Odenwalder , Reinhard Matejec
IPC分类号： G03C7/00 , C07D249/18 , C07D257/04 , G03C7/305 , G03C7/32 , G03C7/26
CPC分类号： C07D257/04 , C07D249/18 , G03C7/30576 , Y10S430/156 , Y10S430/158
摘要： Precursor compounds from which photographically-active compounds are released with a time delay correspond to the following general formula ##STR1## wherein A represents the residue of a compound which undergoes oxidative coupling;X represents --O--, --S-- or --NR.sup.1 --;Y represents a releasable group which may consist of or contain the residue of a photographically-active compound; andR represents a group for controlling the kinetics of release.Advantageous pictorial properties (inter-image effect, edge effect, modulation transfer function) are obtained with compounds according to the present invention if the photographically-active residue is the residue of a development inhibitor.
摘要翻译：照相活性化合物以时间延迟释放的前体化合物对应于下列通式：其中A表示经历氧化偶联的化合物的残基; X表示-O - ， - S-或-NR1-; Y表示可以由摄影活性化合物的残基组成或含有的可释放基团; R表示用于控制释放动力学的基团。如果照相活性残基是显影抑制剂的残留物，则可以用根据本发明的化合物获得有利的图案性质（图像间效应，边缘效应，调制转移功能）。

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