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1. 发明授权

US06498002B2 Photographic silver halide material 失效
标题翻译：摄影卤化银材料
公开(公告)号：US06498002B2
公开(公告)日：2002-12-24
申请号：US09912835
申请日：2001-07-25
申请人： Peter Bergthaller , Jörg Siegel , Hans-Ulrich Borst
发明人： Peter Bergthaller , Jörg Siegel , Hans-Ulrich Borst
IPC分类号： G03C1005
CPC分类号： G03C1/28
摘要： A photographic material comprising a support and at least one at least one layer which comprises at least one spectrally sensitized silver halide emulsion, characterized in that the material contains at least one compound of formula wherein X denotes sulphur or selenium, R1 denotes aryl or heterocyclyl, R2 denotes alkyl, alkenyl, alkynyl, aralkyl or hetarylalkyl, R3 denotes alkyl, alkenyl, aryl, aralkyl, hetaryl or hetarylalkyl, and R4 denotes H, alkyl, alkenyl, aryl, aralkyl, hetaryl or hetaralkyl, or R3, together with R4, denotes the remaining atoms of a carbocyclic or heterocyclic ring, is distinguished by increased spectral sensitivity, a high sensitivity/fogging ratio and a good shelf life under humid conditions.
摘要翻译：一种照相材料，其包括载体和至少一层至少一层包含至少一种光谱增感的卤化银乳剂，其特征在于该材料含有至少一种化学式，其中X表示硫或硒，R 1表示芳基或杂环基，R 2表示烷基，烯基，炔基，芳烷基或杂芳基烷基，R 3表示烷基，烯基，芳基，芳烷基，杂芳基或杂芳基烷基，R 4表示H，烷基，烯基，芳基，芳烷基，杂芳基或杂芳烷基或R 3，的碳环或杂环，其特征在于增加的光谱灵敏度，高灵敏度/起雾比和在潮湿条件下的良好保质期。

2. 发明授权

US06498001B1 Photographic silver halide emulsion 失效
标题翻译：摄影卤化银乳剂
公开(公告)号：US06498001B1
公开(公告)日：2002-12-24
申请号：US09911589
申请日：2001-07-24
申请人： Peter Bergthaller , Jörg Siegel , Hans-Ulrich Borst , Ralf Büscher , Ulrich Nickel
发明人： Peter Bergthaller , Jörg Siegel , Hans-Ulrich Borst , Ralf Büscher , Ulrich Nickel
IPC分类号： G03C1005
CPC分类号： G03C1/0053 , G03C1/08 , G03C1/10 , G03C1/28 , G03C2200/33
摘要： A spectrally sensitized photographic silver halide emulsion, characterized in that after precipitation at least one compound of formula is added to the emulsion, wherein R1 denotes alkyl, aryl, aralkyl, alkenyl or heterocyclyl; R2 denotes H, alkyl, aryl, heterocyclyl, amino or alkoxy; R3 denotes H, alkyl, aryl, aralkyl or heterocyclyl; D denotes —OH or —NR4R5; X denotes O or N—R6; R4 denotes H, alkyl, aryl, aralkyl, alkenyl or heterocyclyl; R5: denotes H, alkyl, aryl, aralkyl, alkenyl or heterocyclyl; R6: denotes H, alkyl, aryl, aralkyl, alkenyl, acyl, alkoxycarbonyl, carbamoyl or heterocyclyl, the aforementioned alkyl, aryl, aralkyl, alkenyl, heterocyclyl, amino, alkoxy, acyl, alkoxycarbonyl and carbamoyl groups can be substituted, and any two of the radicals R1 to R6 can together form a heterocyclic ring, such as a pyrrolidine, piperidine, perhydroazepine, piperazine, morpholine or thiomorpholine ring, for example; as well as a photographic material comprising a support and at least one silver halide emulsion layer which contains said emulsion, are distinguished by increased sensitivity, a high sensitivity/fogging ratio and a good shelf life, particularly when stored under humid climatic conditions.
摘要翻译：一种光谱增感的照相卤化银乳剂，其特征在于在沉淀后，将至少一种式的化合物加入乳液中，其中R1表示烷基，芳基，芳烷基，烯基或杂环基; R2表示H，烷基，芳基，杂环基，氨基或烷氧基; R3表示H，烷基，芳基，芳烷基或杂环基; D表示-OH或-NR4R5; X表示O或N-R6; R4表示H，烷基，芳基，芳烷基，烯基或杂环基; R5表示H，烷基，上述烷基，芳基，芳烷基，链烯基，杂环基，氨基，烷氧基，酰基，烷氧基羰基和氨基甲酰基; R 6表示H，烷基，芳基，芳烷基，烯基，酰基，烷氧基羰基，氨基甲酰基或杂环基可以被取代，并且任何两个基团R 1至R 6可以一起形成杂环，例如吡咯烷，哌啶，过氢氮杂，哌嗪，吗啉或硫代吗啉环; 以及包含载体和含有所述乳液的至少一种卤化银乳剂层的照相材料，特别是当在潮湿气候条件下储存时，具有增加的灵敏度，高灵敏度/起雾比和良好的保质期。

3. 发明授权

US06498003B2 Photographic silver halide material 失效
标题翻译：摄影卤化银材料
公开(公告)号：US06498003B2
公开(公告)日：2002-12-24
申请号：US09915687
申请日：2001-07-26
申请人： Peter Bergthaller , Jörg Siegel , Hans-Ulrich Borst
发明人： Peter Bergthaller , Jörg Siegel , Hans-Ulrich Borst
IPC分类号： G03C1005
CPC分类号： G03C1/28
摘要： A photographic material comprising a support and at least one layer which comprises at least one spectrally sensitised silver halide emulsion, characterised in that the material contains at least one compound of formula and/or wherein R1 denotes H, alkyl, aryl, aralkyl, alkenyl, heterocyclyl, R2 denotes OH, NH2, NHR7, NR8R9 or R1 together with R2, denotes the atoms necessary for the completion of a heteroaliphatic ring, R3 denotes OH, NH2, NHR7, NR8R9, R4 denotes H, alkyl, aryl, aralkyl, alkenyl, heterocyclyl, R5, R6 independently of each other, denote OH, NH2, NHR10, NR11R12, or R4 together with R5, or R4 together with R6, denote the atoms necessary for the completion of a heteroaliphatic ring, and the R5 or R6 radical, which is not part of a ring, denotes OH, NH2, NHR10 or NR11R12, R7, R10 denote alkyl, aryl, aralkyl, heterocyclyl, R8, R9 independently of each other, denote alkyl, aryl, aralkyl, heterocyclyl, or R8 together with R9, denotes the atoms necessary for the completion of a heteroaliphatic ring, and R11, R12 independently of each other, denote alkyl, aryl, aralkyl, heterocyclyl, or R11 together with R12, denote the atoms necessary for the completion of a heterocyclic ring, and wherein only one of the radicals R2 and R3 and only one of the radicals R5 and R6 can denote OH or NH2, is distinguished by increased spectral sensitivity, a high sensitivity/fogging ratio and a good shelf life under humid conditions.
摘要翻译：包含载体和至少一层包含至少一种光谱增感的卤化银乳剂的照相材料，其特征在于所述材料含有至少一种式和/或其中的R 1表示H，烷基，芳基，芳烷基，烯基，杂环基，R 2 表示OH，NH2，NHR7，NR8R9或R1与R2一起表示完成杂脂肪族环所需的原子，R3表示OH，NH2，NHR7，NR8R9，R4表示H，烷基，芳基，芳烷基，烯基，杂环基，R5 ，R6彼此独立地表示OH，NH2，NHR10，NR11R12或R4以及R5或R4与R6一起表示完成杂脂肪族环所必需的原子，以及不是部分的R5或R6基团表示OH，NH2，NHR10或NR11R12，R7，R10表示烷基，芳基，芳烷基，杂环基，R8，R9彼此独立地表示烷基，芳基，芳烷基，杂环基或R8与R9一起表示原子完成杂合子所必需的芳基，R 11，R 12彼此独立地表示烷基，芳基，芳烷基，杂环基或R 11与R 12一起表示完成杂环所必需的原子，并且其中仅一个基团R 2和R 3以及仅一个基团R5和R6可以表示OH或NH2，其特征在于增加的光谱灵敏度，高灵敏度/起雾比和在潮湿条件下的良好保质期。

4. 发明授权

US06261758B1 Production of silver halide emulsions 失效
标题翻译：生产卤化银乳剂
公开(公告)号：US06261758B1
公开(公告)日：2001-07-17
申请号：US09616445
申请日：2000-07-14
申请人： Ralf Wirowski , Hans-Ulrich Borst , Detlev Kapitza , Jörg Siegel , Peter Bergthaller , Heinrich Odenwälder
发明人： Ralf Wirowski , Hans-Ulrich Borst , Detlev Kapitza , Jörg Siegel , Peter Bergthaller , Heinrich Odenwälder
IPC分类号： G03C1035
CPC分类号： G03C1/07 , G03C1/0051 , G03C2001/0055 , G03C2001/0153 , G03C2200/33
摘要： The production of tabular silver bromide-iodide emulsions and silver bromide-chloride-iodide emulsions with an aspect ratio 32, an iodide content from 1 to 40 mol % and a chloride content from 0 to 20 mol %, by the process steps of (a) silver halide nucleus precipitation, and (b) at least one further precipitation of silver halide, wherein rein at least one aromatic five- or six-membered, heterocyclic compound, which is free from—SH—,—SSO2H— and—SSO2R groups, is added in an amount from 10−9 to 10−4 mol/mol silver during nucleus precipitation or during the precipitation of an inner zone of the silver halide grain which is different from the nucleus precipitate, results in an improved speed/grain size ratio and in an increased stability of a photographic material which contains an emulsion produced in this manner.
摘要翻译：通过（a）的方法步骤制备长宽比为32，碘化物含量为1至40摩尔％，氯化物含量为0至20摩尔％的片状溴化银碘化物乳液和溴化银 - 碘化碘化银乳剂）卤化银核沉淀，和（b）卤化银的至少一种进一步沉淀，其中保留至少一种不含-SH - ， - SSO2H和 - SSO2R基团的芳族五元或六元杂环化合物，在沉淀过程中或在不同于核沉淀物的卤化银颗粒的内部区域的析出过程中，其添加量为10-9至10-4mol / mol银，导致速度/晶粒尺寸的改善比例和增加的含有以这种方式生产的乳液的照相材料的稳定性。

5. 发明授权

US5821044A Photographic silver halide emulsions 失效
标题翻译：摄影卤化银乳剂
公开(公告)号：US5821044A
公开(公告)日：1998-10-13
申请号：US896217
申请日：1997-07-17
申请人： Peter Bergthaller , Jorg Siegel , Hans-Ulrich Borst , Michael Missfeldt
发明人： Peter Bergthaller , Jorg Siegel , Hans-Ulrich Borst , Michael Missfeldt
IPC分类号： G03C7/00 , G03C1/18 , G03C1/28 , G03C1/09
CPC分类号： G03C1/28 , G03C1/18
摘要： A spectrally sensitised photographic silver halide emulsion which is super-sensitised with an aromatic complex having a central transition metal atom which is present in a valence state which is not the highest possible for the metal concerned and which complex contains at least one non-aromatic complex ligand, is distinguished by increased sensitivity.
摘要翻译：一种光谱增感的照相卤化银乳剂，其与具有中间过渡金属原子的芳族络合物超敏化，该中心过渡金属原子以有价金属不是最高可能的价态存在，并且该络合物含有至少一个非芳族络合物配体，通过增加灵敏度来区分。

6. 发明授权

US5908741A Photographic silver halide material 失效
标题翻译：摄影卤化银材料
公开(公告)号：US5908741A
公开(公告)日：1999-06-01
申请号：US701122
申请日：1996-08-21
申请人： Peter Bergthaller , Hans-Ulrich Borst , Johannes Willsau , Ralf Buscher , Peter Bell
发明人： Peter Bergthaller , Hans-Ulrich Borst , Johannes Willsau , Ralf Buscher , Peter Bell
IPC分类号： G03C7/00 , C07C391/02 , G03C1/34 , G03C7/392 , G03C1/09
CPC分类号： C07C391/02 , G03C1/346
摘要： A photographic silver halide material in which the silver halide emulsion layer of at least one silver halide emulsion layer is stabilized with a compound of the formula (I):Ar--Se--X (I)in whichAr means a carbocyclic or heterocyclic aromatic group which has an electron-attracting grouping in o-position relative to the Se andX means a further substituted heteroatom,exhibits a smaller reduction in sensitivity, in particular under tropical conditions of storage.
摘要翻译：一种照相卤化银材料，其中至少一种卤化银乳剂层的卤化银乳剂层用式（I）化合物稳定：Ar-Se-X（I），其中Ar表示碳环或杂环芳族基团其相对于Se具有在位置上的吸电子基团，X表示另外取代的杂原子，特别是在热带储藏条件下，灵敏度降低。

7. 发明授权

US5888717A Photographic silver halide emulsion 失效
标题翻译：摄影卤化银乳剂
公开(公告)号：US5888717A
公开(公告)日：1999-03-30
申请号：US970488
申请日：1997-11-14
申请人： Peter Bergthaller , Hans-Ulrich Borst , Jorg Siegel
发明人： Peter Bergthaller , Hans-Ulrich Borst , Jorg Siegel
IPC分类号： G03C1/005 , G03C1/09 , G03C1/34
CPC分类号： G03C1/09 , G03C1/0051 , G03C1/34
摘要： A photosensitive silver halide emulsion which is ripened with at least one compound of the formula (I)R.sub.1 --X--R.sub.2 (I)in whichR.sub.1 and R.sub.2 mutually independently mean groups which are linked to X via an element from periods 3 to 6 of main group 4 or 5 or via an element from sub-groups 4 to 8 of the periodic system of elements, wherein R.sub.1 and R.sub.2 may be attached together via a linking member and wherein the bonds R.sub.1 --X and R.sub.2 --X may mutually independently be single or double bonds, andX means Se or Te,is distinguished by elevated sensitivity, low grain and low fog.
摘要翻译：用至少一种式（I）化合物R1-X-R2（Ⅰ）熟化的感光卤化银乳剂，其中R 1和R 2相互独立地表示通过第3至6个主组4或5，或通过元素周期系统的亚组4至8的元素，其中R1和R2可以经由连接构件连接在一起，并且其中键R1-X和R2-X可以相互独立地为单键或双键，X表示Se或Te，通过提高灵敏度，低谷物和低雾来区分。

8. 发明授权

US5683863A Photographic silver halide material 失效
标题翻译：摄影卤化银材料
公开(公告)号：US5683863A
公开(公告)日：1997-11-04
申请号：US571408
申请日：1995-12-13
申请人： Peter Bergthaller , Hans-Ulrich Borst , Peter Bell , Ralf Buscher , Johannes Willsau , Thomas Stetzer
发明人： Peter Bergthaller , Hans-Ulrich Borst , Peter Bell , Ralf Buscher , Johannes Willsau , Thomas Stetzer
IPC分类号： G03C7/00 , C07D293/06 , C07D293/12 , G03C1/34 , G03C7/30 , G03C7/392 , G03C1/09
CPC分类号： C07D293/12 , C07D293/06 , G03C1/346 , G03C7/3924 , G03C7/39296 , G03C7/3022
摘要： A color photographic silver halide material having at least one silver halide emulsion layer, which is stabilized with a compound of formula (I) or (II) ##STR1## where X represents O or NR.sub.2 Y represents halogen, Z.sup..crclbar. represents an anion, R.sub.1 represents hydrogen or a substituent, or jointly with X represents the remaining members of a condensed ring R.sub.2 represents hydrogen or a substituent, and Q represents the atoms required for the completion of a 5- or 6-membered ring, is characterized by enhanced stability.
摘要翻译：具有至少一个卤化银乳剂层的彩色照相卤化银材料，其用X表示O或NR 2 Y的式（I）或（II）化合物稳定化，表示卤素，Z（ - ）表示阴离子，R1表示氢或取代基，或与X表示稠合环的其余成员R2表示氢或取代基，Q表示完成5-或 6元环的特征在于增强的稳定性。

9. 发明授权

US6040125A High-speed color photographic recording material having increased sensitivity in the blue spectral region 失效
标题翻译：在蓝色光谱区域具有增加的灵敏度的高速彩色照相记录材料
公开(公告)号：US6040125A
公开(公告)日：2000-03-21
申请号：US42401
申请日：1998-03-13
申请人： Jorg Siegel , Hans-Ulrich Borst , Peter Bell , Ralf Buscher , Heinz Reif , Jurgen Jung
发明人： Jorg Siegel , Hans-Ulrich Borst , Peter Bell , Ralf Buscher , Heinz Reif , Jurgen Jung
IPC分类号： G03C7/00 , G03C1/16 , G03C1/29 , G03C5/02 , G03C7/20 , G03C1/46
CPC分类号： G03C1/29 , G03C1/16 , G03C5/02
摘要： A color photographic recording material having at least one red-sensitive silver halide emulsion layer unit with which a cyan coupler is associated, at least one green-sensitive silver halide emulsion layer unit with which a magenta coupler is associated, at least one blue-sensitive silver halide emulsion layer unit with which a yellow coupler is associated, and optionally further light-insensitive layers, the blue-sensitive silver halide emulsion layer unit of which comprises at least two blue-sensitive partial layers which are sensitized with sensitizing dyes in such a way that a sensitivity curve ensues which is characterized by the following parameters:460 nm.ltoreq..lambda.(S.sub.max).ltoreq.480 nmb.sub.80 .gtoreq.24 nmb.sub.50 .gtoreq.91 nm,b.sub.20 .gtoreq.106 nm,wherein.lambda.(S.sub.max) denotes the wavelength of the sensitivity maximum (100 % sensitivity);b.sub.80 denotes the width of the sensitivity curve at 80% of the maximum sensitivity;b.sub.50 denotes the width of the sensitivity curve at 50% of the maximum sensitivity;b.sub.20 denotes the width of the sensitivity curve at 20% of the maximum sensitivity,has an increased blue sensitivity compared with conventional color photographic recording materials.
摘要翻译：至少一个与青色成色剂相关联的至少一个感红卤化银乳剂层单元的彩色照相记录材料，与品红色成色剂相关联的至少一个感绿卤化银乳剂层单元，至少一种蓝色敏感的卤化银乳剂层单元，其中与黄色成色剂相关联，以及任选的另外的不透光层，其感蓝卤化银乳剂层单元包含至少两个蓝敏敏部分层，其敏化染料在这种灵敏度曲线的特征在于以下参数：460nmλ=（Smax）= 480nm b80> / = 24nm b50> / = 91nm，b20> = 106nm，其中λ （Smax）表示灵敏度最大值（100％灵敏度）的波长; b80表示灵敏度曲线在最大灵敏度的80％处的宽度; b50表示灵敏度曲线在最大灵敏度的50％处的宽度; b20表示灵敏度曲线在最大灵敏度的20％处的宽度，与常规彩色照相记录材料相比具有增加的蓝色感光度。

10. 发明授权

US5853971A Color photographic silver halide material 失效
标题翻译：彩色照相卤化银材料
公开(公告)号：US5853971A
公开(公告)日：1998-12-29
申请号：US838084
申请日：1997-04-15
申请人： Peter Bell , Hans-Ulrich Borst , Ralf Buscher , Johannes Willsau , Jorg Siegel
发明人： Peter Bell , Hans-Ulrich Borst , Ralf Buscher , Johannes Willsau , Jorg Siegel
IPC分类号： G03C7/30 , G03C7/333 , G03C1/83
CPC分类号： G03C7/333 , G03C7/3029
摘要： A color photographic silver halide material contains on a support at least one red-sensitive, cyan-coupling, at least one green-sensitive, magenta-coupling and at least one blue-sensitive, yellow-coupling silver halide emulsion layer together with interlayers between layers of different colour sensitivity, wherein at least one of the stated interlayers contains at least one masking coupler, the masking coupler having a reaction rate constant for the coupling reaction with the developer oxidation product of .gtoreq.5000 1-mol.sup.- .cndot.s.sup.-1, is distinguished improved sensitivity without increase of granularity.
摘要翻译：彩色照相卤化银材料在载体上包含至少一种红色敏感性，青色偶联，至少一种绿色敏感，品红色偶联和至少一种蓝色敏感性黄色偶合卤化银乳剂层，以及中间层不同颜色敏感度的层，其中所述中间层中的至少一个含有至少一个掩蔽成色剂，所述掩蔽成色剂具有与显影剂氧化产物的偶联反应的反应速率常数> 1，提高灵敏度，不增加粒度。

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