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    • 1. 发明授权
    • Photographic silver halide material
    • 摄影卤化银材料
    • US06498002B2
    • 2002-12-24
    • US09912835
    • 2001-07-25
    • Peter BergthallerJörg SiegelHans-Ulrich Borst
    • Peter BergthallerJörg SiegelHans-Ulrich Borst
    • G03C1005
    • G03C1/28
    • A photographic material comprising a support and at least one at least one layer which comprises at least one spectrally sensitized silver halide emulsion, characterized in that the material contains at least one compound of formula wherein X denotes sulphur or selenium, R1 denotes aryl or heterocyclyl, R2 denotes alkyl, alkenyl, alkynyl, aralkyl or hetarylalkyl, R3 denotes alkyl, alkenyl, aryl, aralkyl, hetaryl or hetarylalkyl, and R4 denotes H, alkyl, alkenyl, aryl, aralkyl, hetaryl or hetaralkyl, or R3, together with R4, denotes the remaining atoms of a carbocyclic or heterocyclic ring, is distinguished by increased spectral sensitivity, a high sensitivity/fogging ratio and a good shelf life under humid conditions.
    • 一种照相材料,其包括载体和至少一层至少一层包含至少一种光谱增感的卤化银乳剂,其特征在于该材料含有至少一种化学式,其中X表示硫或硒,R 1表示芳基或杂环基,R 2表示 烷基,烯基,炔基,芳烷基或杂芳基烷基,R 3表示烷基,烯基,芳基,芳烷基,杂芳基或杂芳基烷基,R 4表示H,烷基,烯基,芳基,芳烷基,杂芳基或杂芳烷基或R 3, 的碳环或杂环,其特征在于增加的光谱灵敏度,高灵敏度/起雾比和在潮湿条件下的良好保质期。
    • 2. 发明授权
    • Photographic silver halide emulsion
    • 摄影卤化银乳剂
    • US06498001B1
    • 2002-12-24
    • US09911589
    • 2001-07-24
    • Peter BergthallerJörg SiegelHans-Ulrich BorstRalf BüscherUlrich Nickel
    • Peter BergthallerJörg SiegelHans-Ulrich BorstRalf BüscherUlrich Nickel
    • G03C1005
    • G03C1/0053G03C1/08G03C1/10G03C1/28G03C2200/33
    • A spectrally sensitized photographic silver halide emulsion, characterized in that after precipitation at least one compound of formula is added to the emulsion, wherein R1 denotes alkyl, aryl, aralkyl, alkenyl or heterocyclyl; R2 denotes H, alkyl, aryl, heterocyclyl, amino or alkoxy; R3 denotes H, alkyl, aryl, aralkyl or heterocyclyl; D denotes —OH or —NR4R5; X denotes O or N—R6; R4 denotes H, alkyl, aryl, aralkyl, alkenyl or heterocyclyl; R5: denotes H, alkyl, aryl, aralkyl, alkenyl or heterocyclyl; R6: denotes H, alkyl, aryl, aralkyl, alkenyl, acyl, alkoxycarbonyl, carbamoyl or heterocyclyl, the aforementioned alkyl, aryl, aralkyl, alkenyl, heterocyclyl, amino, alkoxy, acyl, alkoxycarbonyl and carbamoyl groups can be substituted, and any two of the radicals R1 to R6 can together form a heterocyclic ring, such as a pyrrolidine, piperidine, perhydroazepine, piperazine, morpholine or thiomorpholine ring, for example; as well as a photographic material comprising a support and at least one silver halide emulsion layer which contains said emulsion, are distinguished by increased sensitivity, a high sensitivity/fogging ratio and a good shelf life, particularly when stored under humid climatic conditions.
    • 一种光谱增感的照相卤化银乳剂,其特征在于在沉淀后,将至少一种式的化合物加入乳液中,其中R1表示烷基,芳基,芳烷基,烯基或杂环基; R2表示H,烷基,芳基,杂环基,氨基或烷氧基; R3表示H,烷基,芳基,芳烷基或杂环基; D表示-OH或-NR4R5; X表示O或N-R6; R4表示H,烷基,芳基,芳烷基,烯基或杂环基; R5表示H,烷基, 上述烷基,芳基,芳烷基,链烯基,杂环基,氨基,烷氧基,酰基,烷氧基羰基和氨基甲酰基; R 6表示H,烷基,芳基,芳烷基,烯基,酰基,烷氧基羰基,氨基甲酰基或杂环基 可以被取代,并且任何两个基团R 1至R 6可以一起形成杂环,例如吡咯烷,哌啶,过氢氮杂,哌嗪,吗啉或硫代吗啉环; 以及包含载体和含有所述乳液的至少一种卤化银乳剂层的照相材料,特别是当在潮湿气候条件下储存时,具有增加的灵敏度,高灵敏度/起雾比和良好的保质期。
    • 3. 发明授权
    • Photographic silver halide material
    • 摄影卤化银材料
    • US06498003B2
    • 2002-12-24
    • US09915687
    • 2001-07-26
    • Peter BergthallerJörg SiegelHans-Ulrich Borst
    • Peter BergthallerJörg SiegelHans-Ulrich Borst
    • G03C1005
    • G03C1/28
    • A photographic material comprising a support and at least one layer which comprises at least one spectrally sensitised silver halide emulsion, characterised in that the material contains at least one compound of formula and/or wherein R1 denotes H, alkyl, aryl, aralkyl, alkenyl, heterocyclyl, R2 denotes OH, NH2, NHR7, NR8R9 or R1 together with R2, denotes the atoms necessary for the completion of a heteroaliphatic ring, R3 denotes OH, NH2, NHR7, NR8R9, R4 denotes H, alkyl, aryl, aralkyl, alkenyl, heterocyclyl, R5, R6 independently of each other, denote OH, NH2, NHR10, NR11R12, or R4 together with R5, or R4 together with R6, denote the atoms necessary for the completion of a heteroaliphatic ring, and the R5 or R6 radical, which is not part of a ring, denotes OH, NH2, NHR10 or NR11R12, R7, R10 denote alkyl, aryl, aralkyl, heterocyclyl, R8, R9 independently of each other, denote alkyl, aryl, aralkyl, heterocyclyl, or R8 together with R9, denotes the atoms necessary for the completion of a heteroaliphatic ring, and R11, R12 independently of each other, denote alkyl, aryl, aralkyl, heterocyclyl, or R11 together with R12, denote the atoms necessary for the completion of a heterocyclic ring, and wherein only one of the radicals R2 and R3 and only one of the radicals R5 and R6 can denote OH or NH2, is distinguished by increased spectral sensitivity, a high sensitivity/fogging ratio and a good shelf life under humid conditions.
    • 包含载体和至少一层包含至少一种光谱增感的卤化银乳剂的照相材料,其特征在于所述材料含有至少一种式和/或其中的R 1表示H,烷基,芳基,芳烷基,烯基,杂环基,R 2 表示OH,NH2,NHR7,NR8R9或R1与R2一起表示完成杂脂肪族环所需的原子,R3表示OH,NH2,NHR7,NR8R9,R4表示H,烷基,芳基,芳烷基,烯基,杂环基,R5 ,R6彼此独立地表示OH,NH2,NHR10,NR11R12或R4以及R5或R4与R6一起表示完成杂脂肪族环所必需的原子,以及不是部分的R5或R6基团 表示OH,NH2,NHR10或NR11R12,R7,R10表示烷基,芳基,芳烷基,杂环基,R8,R9彼此独立地表示烷基,芳基,芳烷基,杂环基或R8与R9一起表示原子 完成杂合子所必需的 芳基,R 11,R 12彼此独立地表示烷基,芳基,芳烷基,杂环基或R 11与R 12一起表示完成杂环所必需的原子,并且其中仅一个基团R 2和R 3以及仅一个 基团R5和R6可以表示OH或NH2,其特征在于增加的光谱灵敏度,高灵敏度/起雾比和在潮湿条件下的良好保质期。