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    • 3. 发明申请
    • Castable shape memory polymers
    • 铸造形状记忆聚合物
    • US20060041089A1
    • 2006-02-23
    • US10965917
    • 2004-10-15
    • Patrick MatherChangdeng Liu
    • Patrick MatherChangdeng Liu
    • C08F4/06
    • C08F246/00
    • Shape memory polymers prepared by copolymerizing two monomers, which each separately produce polymers characterized by different glass transition temperatures in the presence of a difunctional monomer whereby the copolymer formed is cross-linked during the polymerization to form a theremoset network. The transition temperature of the final polymers is adjusted by the ratio of the monomers selected, to from about 20 to about 110° C., while the degree of cross-linking controls the rubbery modulus plateau. The shape memory polymers can be processed as castable formulations in the form of coatings and films. The copolymers are optically transparent and are useful as medical plastics. The invention also relates to the articles of manufacture thereof and methods of the preparation and use thereof.
    • 通过共聚两种单体制备的形状记忆聚合物,它们分别在双官能单体的存在下产生以不同玻璃化转变温度为特征的聚合物,由此形成的共聚物在聚合反应过程中交联以形成聚集体网络。 最终聚合物的转变温度通过所选单体的比例调节至约20至约110℃,而交联度控制橡胶模量平台。 形状记忆聚合物可以以涂料和薄膜的形式加工成可浇铸的制剂。 共聚物是光学透明的并且可用作医用塑料。 本发明还涉及其制造方法及其制备和使用方法。
    • 4. 发明申请
    • Crosslinked polycyclooctene
    • 交联多环辛烯
    • US20070142562A1
    • 2007-06-21
    • US11651276
    • 2007-01-09
    • Patrick MatherChangdeng LiuSeung ChunE. Coughlin
    • Patrick MatherChangdeng LiuSeung ChunE. Coughlin
    • C08F259/00
    • C08G18/3893C08G61/08C08G2230/00C08L65/00
    • Chemically crosslinked polycyclooctene having excellent shape recovery properties and a method for its synthesis via ring-opening metathesis polymerization of cyclooctene using the dihydroimidazolylidene-modified Grubbs catalyst are disclosed. The polycyclooctene products, following curing with dicumyl peroxide can be shaped, the shape memorized, a new shape imparted with the original shape being recoverable by suitable temperature adjustment. The dependence of shape memory characteristics on degree of crosslinking was established. In addition to polycyclooctene, blends thereof with other materials such as SBR, EVA, polyurethane rubbers, and inorganic fillers can be utilized to provide chemically crosslinked products having excellent and tailored shape memory properties.
    • 公开了具有优异的形状恢复性能的化学交联的多环辛烯和通过使用二氢咪唑基改性的Grubbs催化剂的环辛烯的开环易位聚合合成方法。 多环辛烯产物在用过氧化二异丙苯固化后可以成型,形状记忆,赋予原始形状的新形状可通过适当的温度调节而恢复。 形状记忆特性对交联度的依赖性已被确立。 除了聚环辛烯之外,可以使用其与其它材料如SBR,EVA,聚氨酯橡胶和无机填料的共混物来提供具有优良和定制形状记忆性质的化学交联产物。