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1. 发明申请

US20050245719A1 Shape memory polymers based on semicrystalline thermoplastic polyurethanes bearing nanostructured hard segments 有权
标题翻译：基于具有纳米结构硬链段的半结晶热塑性聚氨酯的形状记忆聚合物
公开(公告)号：US20050245719A1
公开(公告)日：2005-11-03
申请号：US11111388
申请日：2005-04-21
申请人： Patrick Mather , Changdeng Liu , Qing Ge
发明人： Patrick Mather , Changdeng Liu , Qing Ge
IPC分类号： C08G18/38 , C08G18/61 , C08G61/08 , C08L65/00 , C08G18/10
CPC分类号： C08G18/3893 , C08G18/4277 , C08G18/428 , C08G18/4833 , C08G18/61 , C08G61/08 , C08G2230/00 , C08G2280/00 , C08L65/00
摘要： Thermoplastic polyurethanes having an alternating sequence of hard and soft segments in which a nanostructured polyhedral oligosilsesquioxane diol is used as a chain extender to form a crystalline hard segment constituting SMPs. The polyurethanes are formed by reacting a polyol, a chain extender dihydroxyl-terminated polyhedral oligosilsesquioxane and a diisocyanate. The polyurethanes have multiple applications including for example, implants for human health care, drug delivery matrices, superabsorbant hydrogels, coatings, adhesives, temperature and moisture sensors, etc.
摘要翻译：具有硬链段和软链段的交替序列的热塑性聚氨酯，其中使用纳米结构多面体寡聚倍半硅氧烷二醇作为扩链剂以形成构成SMP的结晶硬链段。聚氨酯通过使多元醇，扩链剂二羟基封端的多面体寡聚倍半硅氧烷和二异氰酸酯反应而形成。聚氨酯具有多种应用，包括例如用于人体保健的植入物，药物递送基质，超吸收水凝胶，涂层，粘合剂，温度和湿度传感器等。

2. 发明申请

US20050251249A1 Endoprostheses 有权
标题翻译：内假体
公开(公告)号：US20050251249A1
公开(公告)日：2005-11-10
申请号：US11111509
申请日：2005-04-21
申请人： Ronald Sahatjian , Francisca Tan , Patrick Mather , Changdeng Liu , Qing Ge
发明人： Ronald Sahatjian , Francisca Tan , Patrick Mather , Changdeng Liu , Qing Ge
IPC分类号： A61F2/00 , A61F2/06 , A61L31/10
CPC分类号： A61L31/10 , A61F2250/0067 , A61L31/022 , A61L31/04 , A61L31/16 , A61L2300/402 , Y10T428/24926 , C08L75/04 , C08L83/04
摘要： Endoprostheses are disclosed.
摘要翻译：公布内裤假体。

3. 发明申请

US20070135578A1 BLENDS OF AMORPHOUS AND SEMICRYSTALLINE POLYMERS HAVING SHAPE MEMORY PROPERTIES 失效
标题翻译：具有形状记忆性质的非晶态和半结晶聚合物的共混物
公开(公告)号：US20070135578A1
公开(公告)日：2007-06-14
申请号：US11624952
申请日：2007-01-19
申请人： Patrick Mather , Changdeng Liu , Cheryl Campo
发明人： Patrick Mather , Changdeng Liu , Cheryl Campo
IPC分类号： C08L27/12
CPC分类号： C08G18/3893 , C08G61/08 , C08G2230/00 , C08J3/005 , C08L27/16 , C08L31/04 , C08L33/12 , C08L65/00 , C08L67/04 , C08L2666/04
摘要： Blends of amorphous and semicrystalline polymers having shape memory properties were prepared by blending a crystalline polymer such as poly(vinylidene fluoride), polylactide, poly(hydroxxybutyrate), poly(ethylene glycol) polyethylene, polyethylene-co-vinyl acetate, poly(vinyl chloride), poly(vinylidene chloride) and copolymers of poly(vinylidene chloride) and poly(vinyle chloride) and an amorphous polymer such as poly(vinyl acetate), poly methyl acrylate, poly ethyl acrylate, atactic poly methyl methacrylate, isotactic poly methyl methacrylate, syndiotactic poly methyl methacrylate and other poly alkyl methacrylates. The method for preparing the polymeric materials and applications thereof, for example, as smart medical devices, are also disclosed.
摘要翻译：通过混合结晶聚合物如聚（偏二氟乙烯），聚丙交酯，聚（羟基丁酸酯），聚（乙二醇）聚乙烯，聚乙烯 - 共 - 乙酸乙烯酯，聚（氯乙烯）等制备具有形状记忆性质的无定形和半结晶聚合物的共混物），聚（偏二氯乙烯）和聚（偏二氯乙烯）和聚（氯乙烯）的共聚物和无定形聚合物如聚（乙酸乙烯酯），聚甲基丙烯酸酯，聚丙烯酸乙酯，无规立构聚甲基丙烯酸甲酯，全同立构聚甲基丙烯酸甲酯间同立构聚甲基丙烯酸甲酯和其他聚甲基丙烯酸烷基酯。还公开了制备聚合物材料的方法及其应用，例如智能医疗装置。

4. 发明申请

US20060154195A1 Shape memory polymer orthodontic appliances, and methods of making and using the same 审中-公开
标题翻译：形状记忆聚合物正畸矫治器及其使用方法
公开(公告)号：US20060154195A1
公开(公告)日：2006-07-13
申请号：US11301795
申请日：2005-12-12
申请人： Patrick Mather , Charles Burstone , Changdeng Liu
发明人： Patrick Mather , Charles Burstone , Changdeng Liu
IPC分类号： A61C3/00
CPC分类号： A61C7/00 , A61C2201/007 , B82Y30/00 , F03G7/065
摘要： Described are fixed and removable orthodontic appliances and components thereof fabricated from shape memory polymer compositions. The preparation and use of such appliances are also disclosed.
摘要翻译：描述了由形状记忆聚合物组合物制成的固定和可移除的矫正器具及其部件。还公开了这种电器的制备和使用。

5. 发明申请

US20060041089A1 Castable shape memory polymers 审中-公开
标题翻译：铸造形状记忆聚合物
公开(公告)号：US20060041089A1
公开(公告)日：2006-02-23
申请号：US10965917
申请日：2004-10-15
申请人： Patrick Mather , Changdeng Liu
发明人： Patrick Mather , Changdeng Liu
IPC分类号： C08F4/06
CPC分类号： C08F246/00
摘要： Shape memory polymers prepared by copolymerizing two monomers, which each separately produce polymers characterized by different glass transition temperatures in the presence of a difunctional monomer whereby the copolymer formed is cross-linked during the polymerization to form a theremoset network. The transition temperature of the final polymers is adjusted by the ratio of the monomers selected, to from about 20 to about 110° C., while the degree of cross-linking controls the rubbery modulus plateau. The shape memory polymers can be processed as castable formulations in the form of coatings and films. The copolymers are optically transparent and are useful as medical plastics. The invention also relates to the articles of manufacture thereof and methods of the preparation and use thereof.
摘要翻译：通过共聚两种单体制备的形状记忆聚合物，它们分别在双官能单体的存在下产生以不同玻璃化转变温度为特征的聚合物，由此形成的共聚物在聚合反应过程中交联以形成聚集体网络。最终聚合物的转变温度通过所选单体的比例调节至约20至约110℃，而交联度控制橡胶模量平台。形状记忆聚合物可以以涂料和薄膜的形式加工成可浇铸的制剂。共聚物是光学透明的并且可用作医用塑料。本发明还涉及其制造方法及其制备和使用方法。

6. 发明申请

US20070142562A1 Crosslinked polycyclooctene 失效
标题翻译：交联多环辛烯
公开(公告)号：US20070142562A1
公开(公告)日：2007-06-21
申请号：US11651276
申请日：2007-01-09
申请人： Patrick Mather , Changdeng Liu , Seung Chun , E. Coughlin
发明人： Patrick Mather , Changdeng Liu , Seung Chun , E. Coughlin
IPC分类号： C08F259/00
CPC分类号： C08G18/3893 , C08G61/08 , C08G2230/00 , C08L65/00
摘要： Chemically crosslinked polycyclooctene having excellent shape recovery properties and a method for its synthesis via ring-opening metathesis polymerization of cyclooctene using the dihydroimidazolylidene-modified Grubbs catalyst are disclosed. The polycyclooctene products, following curing with dicumyl peroxide can be shaped, the shape memorized, a new shape imparted with the original shape being recoverable by suitable temperature adjustment. The dependence of shape memory characteristics on degree of crosslinking was established. In addition to polycyclooctene, blends thereof with other materials such as SBR, EVA, polyurethane rubbers, and inorganic fillers can be utilized to provide chemically crosslinked products having excellent and tailored shape memory properties.
摘要翻译：公开了具有优异的形状恢复性能的化学交联的多环辛烯和通过使用二氢咪唑基改性的Grubbs催化剂的环辛烯的开环易位聚合合成方法。多环辛烯产物在用过氧化二异丙苯固化后可以成型，形状记忆，赋予原始形状的新形状可通过适当的温度调节而恢复。形状记忆特性对交联度的依赖性已被确立。除了聚环辛烯之外，可以使用其与其它材料如SBR，EVA，聚氨酯橡胶和无机填料的共混物来提供具有优良和定制形状记忆性质的化学交联产物。

7. 发明申请

US20050216074A1 Implantable medical devices 有权
标题翻译：可植入医疗器械
公开(公告)号：US20050216074A1
公开(公告)日：2005-09-29
申请号：US10958435
申请日：2004-10-05
申请人： Ronald Sahatjian , Francisca Tan , Patrick Mather , Changdeng Liu , Cheryl Campo
发明人： Ronald Sahatjian , Francisca Tan , Patrick Mather , Changdeng Liu , Cheryl Campo
IPC分类号： A61L29/14 , A61L31/14 , C08G18/38 , C08G61/08 , C08L65/00 , A61F2/06
CPC分类号： C08G61/08 , A61F2/88 , A61F2/91 , A61F2/915 , A61F2002/8483 , A61F2002/91541 , A61F2002/9528 , A61F2220/0016 , A61F2250/0039 , A61F2250/0068 , A61L29/14 , A61L31/14 , A61M25/1027 , C08G18/3893 , C08G18/4277 , C08G18/4833 , C08G2230/00 , C08L65/00
摘要： A medical device includes a balloon catheter having an expandable member, e.g., an inflatable balloon, at its distal end and a stent or other endoprosthesis. The stent is, for example, an apertured tubular member formed of a polymer and is assembled about the balloon. The stent has an initial diameter for delivery into the body and can be expanded to a larger diameter by inflating the balloon.
摘要翻译：医疗装置包括球囊导管，其具有在其远端处具有可膨胀构件，例如可膨胀气囊，以及支架或其他内置假体。支架是例如由聚合物形成的多孔管状构件，并围绕气囊组装。支架具有用于输送到身体中的初始直径，并且可以通过使气囊膨胀而扩展到更大的直径。

8. 发明申请

US20050075625A1 Medical devices 审中-公开
标题翻译：医疗设备
公开(公告)号：US20050075625A1
公开(公告)日：2005-04-07
申请号：US10891286
申请日：2004-07-14
申请人： Kinh-Luan Dao , Changdeng Liu , Patrick Mather , Ronald Sahatjian , Sheng-Ping Zhong
发明人： Kinh-Luan Dao , Changdeng Liu , Patrick Mather , Ronald Sahatjian , Sheng-Ping Zhong
IPC分类号： A61B17/00 , A61B17/12 , A61B19/00 , A61M25/00 , A61M25/01 , A61M25/16 , A61M29/00
CPC分类号： A61B17/12022 , A61B17/12113 , A61B17/1214 , A61B90/39 , A61B2017/00292 , A61B2017/00867 , A61B2017/1205 , A61B2090/3925 , A61B2090/3954 , A61M25/0041 , A61M25/0043 , A61M25/0074 , A61M25/0158
摘要： A medical device, such as, for example, a catheter, includes a tubular member having a first portion having a shape memory polymer.
摘要翻译：医疗装置，例如导管，包括具有第一部分的管状部件，该第一部分具有形状记忆聚合物。

9. 发明申请

US20050010275A1 Implantable medical devices 审中-公开
公开(公告)号：US20050010275A1
公开(公告)日：2005-01-13
申请号：US10683314
申请日：2003-10-10
申请人： Ronald Sahatjian , Francisca Tan , Patrick Mather , Changdeng Liu
发明人： Ronald Sahatjian , Francisca Tan , Patrick Mather , Changdeng Liu
IPC分类号： A61F2/00 , A61F2/84 , A61F2/88 , A61L29/14 , A61L31/14 , C08G18/38 , C08G18/48 , C08G18/61 , C08G18/71 , C08G61/08 , C08G65/336 , C08J3/00 , C08L65/00 , C08L71/02 , A61F2/04 , A61F2/06 , B29C35/02
CPC分类号： A61F2/88 , A61F2/958 , A61F2002/8483 , A61F2220/0016 , A61F2250/0037 , A61L31/14 , A61M27/008 , C08G18/3893 , C08G18/4833 , C08G18/61 , C08G18/718 , C08G61/08 , C08G65/336 , C08G2230/00 , C08J3/005 , C08L65/00 , C08L71/02 , C08L2205/05 , C08L83/00
摘要： A medical device includes a balloon catheter having an expandable member, e.g., an inflatable balloon, at its distal end and a stent or other endoprosthesis. The stent is, for example, an apertured tubular member formed of a polymer and is assembled about the balloon. The stent has an initial diameter for delivery into the body and can be expanded to a larger diameter by inflating the balloon.

10. 发明申请

US20120213969A1 Functionally Graded Shape Memory Polymer 审中-公开
标题翻译：功能分级形状记忆聚合物
公开(公告)号：US20120213969A1
公开(公告)日：2012-08-23
申请号：US13401606
申请日：2012-02-21
申请人： Patrick Mather , Pine Yang , Xiaofan Luo , Andrew M. DiOrio
发明人： Patrick Mather , Pine Yang , Xiaofan Luo , Andrew M. DiOrio
IPC分类号： B32B7/02 , C08F220/14 , C08G65/08 , C08G63/127 , C08F12/08 , C08G18/06 , C08F14/06 , C08F220/12 , C08F2/48 , C08J3/28 , C08G63/78 , C08G18/08 , B32B27/08 , B32B15/08 , B32B33/00 , C08G65/34
CPC分类号： B29C61/06 , C08F220/12 , C08F220/14 , C08G2280/00 , C08L63/00 , C08L71/02 , C08L75/04 , C08L2205/05 , Y10T428/24479 , Y10T428/24628 , Y10T428/24983 , C08L33/04
摘要： A functionally graded shape memory polymer (SMP) that has a range of transition temperatures that are spatially distributed in a gradient fashion within one single article. The SMP is formed by post-curing a pre-cured glassy SMP in a linear temperature gradient that imposes different vitrification temperature limits at different positions along the gradient. Utilizing indentation-based surface shape memory coupled with optical measurements of photoelastic response, the capability of this material to respond over a wide range of thermal triggers is correlated with the graded glass transition behavior. This new class of SMP offers great potential for such applications as passive temperature sensing and precise control of shape evolution during a thermally triggered shape recovery.
摘要翻译：功能梯度的形状记忆聚合物（SMP），其具有在一个单一制品内以梯度方式空间分布的转变温度范围。 SMP通过在线性温度梯度下固化预固化的玻璃状SMP而形成，该梯度在梯度的不同位置施加不同的玻璃化温度极限。利用基于压痕的表面形状记忆耦合光弹性响应的光学测量，该材料在宽范围的热触发器上的响应能力与渐变玻璃化转变行为相关。这种新型的SMP在热触发形状恢复期间为诸如被动温度感测和形状演化的精确控制等应用提供了巨大的潜力。

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