专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

1. 发明授权

US5233100A Process for producing alcohol 失效
标题翻译：生产酒精的方法
公开(公告)号：US5233100A
公开(公告)日：1993-08-03
申请号：US813918
申请日：1991-12-27
申请人： Osamu Tabata , Atsuhito Mori , Takahiro Kawakami , Kunizo Hashiba , Kiyoshi Tsukada
发明人： Osamu Tabata , Atsuhito Mori , Takahiro Kawakami , Kunizo Hashiba , Kiyoshi Tsukada
IPC分类号： C07C29/149 , C07C29/17
CPC分类号： C07C29/177 , C07C29/149 , Y02P20/132
摘要： A process for producing an alcohol from a fatty acid ester, a fatty acid triglyceride or a fatty acid by continuously catalytically reducing the starting material in the presence of a hydrogenation catalyst is disclosed. In the process of the present invention, two reactors (i.e., the main reactor located upstream and the after reactor located downstream) being located in series are employed. In the process of the present invention, two reactors are employed and the temperatures thereof are individually controlled, whereby the conversion ratio is elevated while suppressing the formation of hydrocarbon and aldehyde by-products. Thus, an alcohol of extremely high quality and high purity can be produced. Further, the process of the present invention makes it possible to omit any post-treatment for eliminating the by-products. Furthermore, the active life of the hydrogenation catalyst can be remarkably prolonged by using three reactors (i.e., the guard reactor, the main reactor and the after reactor).
摘要翻译：公开了一种通过在氢化催化剂的存在下连续催化还原原料从脂肪酸酯，脂肪酸甘油三酯或脂肪酸制备醇的方法。在本发明的方法中，使用两个反应器（即，位于下游的位于反应器的主反应器和位于下游的反应器）串联。在本发明的方法中，使用两个反应器，并且单独控制其温度，由此转化率提高同时抑制烃和醛副产物的形成。因此，可以生产出高质量和高纯度的醇。此外，本发明的方法使得可以省略用于消除副产物的任何后处理。此外，通过使用三个反应器（即保护反应器，主反应器和后反应器），氢化催化剂的活性寿命可以显着延长。

2. 发明授权

US5250713A Process for producing desulfurized fats and oils or fatty acid esters and process for producing alcohols by using said desulfurized fats and oils or fatty acid esters 失效
标题翻译：用于生产脱硫脂肪和油或脂肪酸酯的方法和通过使用所述脱硫脂肪和脂肪酸酯制备醇的方法
公开(公告)号：US5250713A
公开(公告)日：1993-10-05
申请号：US849187
申请日：1992-03-11
申请人： Hiroyuki Tamura , Yasuyuki Hattori , Kunizo Hashiba , Osamu Tabata , Kiyoshi Tsukada , Noriaki Fukuoka
发明人： Hiroyuki Tamura , Yasuyuki Hattori , Kunizo Hashiba , Osamu Tabata , Kiyoshi Tsukada , Noriaki Fukuoka
IPC分类号： C07C29/149 , C11B3/02 , C07C51/36
CPC分类号： C11B3/02 , C07C29/149
摘要： A process for producing desulfurized fats and oils or fatty acid esters is disclosed, which comprises treating fats and oils or fatty acid esters under hydrogen or a mixture of hydrogen and an inert gas atmosphere at a pressure of from 0.1 to 500 kg/cm.sup.2 in the absolute pressure at a temperature of from 100.degree. to 350.degree. C. in the presence of a catalyst of the following formula (I):Cu.multidot.X.sub.x .multidot.Y.sub.y .multidot.O.sub.z (I)wherein all symbols are defined in the disclosure. A process for producing an alcohols using desulfurized fats and oils or fatty acid esters is also disclosed. According to the process for producing an alcohol of the present invention, an alcohol of a high purity and good qualities can efficiently and effectively be produced.
摘要翻译：公开了一种生产脱硫脂肪和油或脂肪酸酯的方法，其包括在氢气或氢气和惰性气体气氛下以0.1-500kg / cm 2的压力下在脂肪和油或脂肪酸酯中的处理在下式（I）的催化剂存在下，在100℃至350℃的温度下的绝对压力：其中所有符号在本公开中定义的CuxXxxYyxOz（I）。还公开了使用脱硫脂肪和油或脂肪酸酯制备醇的方法。根据本发明的醇的制造方法，可以有效且高效地制造纯度高，品质好的醇。

3. 发明授权

US5120885A Process for producing alcohol 失效
标题翻译：生产酒精的方法
公开(公告)号：US5120885A
公开(公告)日：1992-06-09
申请号：US757053
申请日：1991-09-09
申请人： Kiyoshi Tsukada , Yasuyuki Hattori , Hiroyuki Tamura , Akira Yamamuro , Kunizo Hashiba , Osamu Tabata
发明人： Kiyoshi Tsukada , Yasuyuki Hattori , Hiroyuki Tamura , Akira Yamamuro , Kunizo Hashiba , Osamu Tabata
IPC分类号： C07C29/149
CPC分类号： C07C29/149
摘要： A process for producing alcohols comprising catalytically reducing fats and oils or fatty acid esters with hydrogen in the presence of a catalyst for ester reduction is disclosed, wherein the starting oils are first treated at a temperature of from 50.degree. to 200.degree. C. in hydrogen gas or a mixed gas of hydrogen and an inert gas in the presence of a nickel catalyst to yield a sulfur content at not more than 0.6 ppm an acid value (KOH mg/g) of not more than 2. By use of the thus purified starting oils, the catalyst for ester reduction exhibits a prolonged duration.
摘要翻译：公开了一种制备醇的方法，其包括在用于酯还原的催化剂的存在下用氢气催化降低脂肪和油或脂肪酸酯，其中起始油首先在50℃至200℃的温度下在氢气气体或氢气和惰性气体的混合气体，在镍催化剂的存在下得到不大于0.6ppm的硫含量，酸值（KOH mg / g）不大于2.通过使用如此纯化的起始油，用于酯还原的催化剂表现出延长的持续时间。

4. 发明授权

US4918248A Process for preparation of alcohols 失效
标题翻译：醇的制备方法
公开(公告)号：US4918248A
公开(公告)日：1990-04-17
申请号：US355292
申请日：1989-05-22
申请人： Yasuyuki Hattori , Noriaki Fukuoka , Shigeru Tamura , Kunizo Hashiba , Kiyoshi Tsukada , Makoto Misono
发明人： Yasuyuki Hattori , Noriaki Fukuoka , Shigeru Tamura , Kunizo Hashiba , Kiyoshi Tsukada , Makoto Misono
IPC分类号： B01J23/72 , B01J23/80 , C07B61/00 , C07C27/00 , C07C29/136 , C07C29/149 , C07C67/00
CPC分类号： C07C29/149
摘要： An alcohol is effective produced by catalytically reducing an organic carboxylic acid ester with hydrogen in the presence of a catalyst obtained by reducing a catalyst precursor comprising (A) copper oxide and (B) titanium oxide and/or titanium hydroxide at a weight ratio of (A) to (B) in the range between 15/85 and 65/35. The component (A) may be alternatively a composite metal oxide comprises copper oxide and up to 20 wt. % of zinc oxide.
摘要翻译：在通过将包含（A）氧化铜和（B）氧化钛和/或氢氧化钛的催化剂前体以（A）氧化铜和/或氢氧化钛的重量比为（A））催化还原的催化剂存在下，通过催化还原有机羧酸酯而产生的醇是有效的， A）到（B）在15/85和65/35之间的范围内。组分（A）可以是复合金属氧化物，其包含氧化铜和至多20wt。％的氧化锌。

5. 发明授权

US5229346A Process for producing hydrogenation reaction catalyst precursor 失效
标题翻译：生产氢化反应催化剂前体的方法
公开(公告)号：US5229346A
公开(公告)日：1993-07-20
申请号：US886398
申请日：1992-05-21
申请人： Atsuhito Mori , Yasuyuki Hattori , Kiyoshi Tsukada , Noriaki Fukuoka
发明人： Atsuhito Mori , Yasuyuki Hattori , Kiyoshi Tsukada , Noriaki Fukuoka
IPC分类号： B01J21/06 , B01J23/78 , B01J23/80 , B01J23/83 , B01J23/887 , B01J37/02 , C07C29/149
CPC分类号： B01J21/063 , B01J23/78 , B01J23/80 , B01J23/83 , B01J23/8873 , B01J37/0209 , C07C29/149
摘要： A process for producing a hydrogenation reaction catalyst precursor is disclosed, including the steps of:(i) coating the outer surface of at least one of a first titanium oxide and a first titanium hydroxide having an outer surface area of at least 15 m.sup.2 /g with at least one of a second titanium oxide and a second titanium hydroxide formed by hydrolyzing at least one of a titanium alkoxide represented by Formula (I) and a titanium alkoxo acid represented by Formula (II) to prepare a catalyst carrier (A);Ti(OR).sub.4 (I) wherein R represents an alkyl group having from 1 to 18 carbon atoms or an aryl group,H.sub.2 [Ti(OR).sub.6 ] (II) wherein R has the same meaning as above;(ii) applying a metal oxide composition (B) onto the catalyst carrier (A) obtained in step (i), or mixing the metal oxide composition (B) with the catalyst carrier (A) to obtain a hydrogenation reaction catalyst precursor. Also, a process for producing an alcohol is described, including catalytically reducing an organic carboxylic acid ester with hydrogen in the presence of a catalyst obtained by reducing the hydrogenation reaction catalyst precursor produced by the process described above.
摘要翻译：公开了一种制备氢化反应催化剂前体的方法，包括以下步骤：（i）涂覆外表面积至少为15m 2 / g的第一氧化钛和第一氢氧化钛中的至少一种的外表面与由式（I）表示的钛醇盐和由式（II）表示的钛烷氧基化物中的至少一种形成的第二氧化钛和第二氢氧化钛中的至少一种以制备催化剂载体（A）; Ti（OR）4（I）其中R表示具有1至18个碳原子的烷基或芳基，H 2 [Ti（OR）6]（II）其中R具有与上述相同的含义; （ii）将金属氧化物组合物（B）施加到步骤（i）中得到的催化剂载体（A）上，或将金属氧化物组合物（B）与催化剂载体（A）混合，得到氢化反应催化剂前体。此外，描述了一种制备醇的方法，包括在通过还原由上述方法制备的氢化反应催化剂前体获得的催化剂的存在下，用氢催化还原有机羧酸酯。

6. 发明授权

US5658843A Method for preparing copper-containing hydrogenation reaction catalyst and method for producing alcohol 失效
标题翻译：制备含铜加氢反应催化剂的方法及其制备方法
公开(公告)号：US5658843A
公开(公告)日：1997-08-19
申请号：US448580
申请日：1995-06-06
申请人： Kiyoshi Tsukada , Yasuyuki Hattori , Taku Mimura , Osamu Tabata , Futoshi Nishigaki
发明人： Kiyoshi Tsukada , Yasuyuki Hattori , Taku Mimura , Osamu Tabata , Futoshi Nishigaki
IPC分类号： B01J23/72 , B01J23/60 , B01J23/70 , B01J23/745 , B01J23/80 , B01J23/86 , B01J37/00 , B01J37/16 , B01J37/18 , C07B61/00 , C07C29/149 , C07C31/125
CPC分类号： B01J37/18 , B01J23/60 , B01J23/72 , B01J23/80 , B01J23/868 , B01J37/16 , C07C29/149 , B01J23/745 , B01J37/0009
摘要： A method for preparing a copper-containing hydrogenation reaction catalyst includes the step of reducing a formed precursor of a copper-containing hydrogenation reaction catalyst with hydrogen gas or a mixture of hydrogen and inert gas by liquid phase reduction in a stream of a solvent. The reductive activation is carried out by the two steps of performing the first stage of liquid phase reduction by which the catalyst precursor is activated in the temperature range of from 20.degree. to 140.degree. C. so that at least 10% by weight of the copper oxide contained in the catalyst precursor can be reduced by the time when the temperature passes 140.degree. C., and then performing the second stage of liquid phase reduction by which the catalyst precursor is further activated in the temperature range of from 140.degree. to 250.degree. C. The catalyst thus obtained has markedly improved catalytic activity and selectivity. An alcohol of high quality can be obtained at a high productivity using the catalyst in a fixed bed continuous reaction system.
摘要翻译： PCT No.PCT / JP94 / 00077 Sec。 371日期：1995年6月6日 102（e）日期1995年6月6日PCT 1994年1月20日PCT PCT。公开号WO95 / 19844 日期：1995年7月27日制备含铜氢化反应催化剂的方法包括以下步骤：用氢气或氢气和惰性气体的混合物在流中通过液相还原将还原形成的含铜氢化反应催化剂的前体的溶剂。还原活化通过进行第二阶段的液相还原的两个步骤进行，催化剂前体在20℃至140℃的温度范围内被活化，因此至少10重量％的铜包含在催化剂前体中的氧化物可以在温度达到140℃时降低，然后进行第二阶段的液相还原，催化剂前体在140°至250°的温度范围内进一步活化因此得到的催化剂显着地改善了催化活性和选择性。使用固定床连续反应体系中的催化剂可以以高生产率获得高质量的醇。

7. 发明授权

US4846991A Novel fatty acid-lactic acid ester 失效
标题翻译：新型脂肪酸乳酸酯
公开(公告)号：US4846991A
公开(公告)日：1989-07-11
申请号：US152493
申请日：1988-02-05
申请人： Shigetoshi Suzue , Akio Kimura , Kiyoshi Tsukada , Kozo Noda , Hidekazu Ogino , Jun Kamegai
发明人： Shigetoshi Suzue , Akio Kimura , Kiyoshi Tsukada , Kozo Noda , Hidekazu Ogino , Jun Kamegai
IPC分类号： A61K8/30 , A61K8/00 , A61K8/37 , A61K8/40 , A61K8/41 , A61Q5/02 , A61Q5/12 , B01F17/00 , C07C69/52 , C07C69/68 , C11C3/00 , C11D1/00 , C11D1/04 , C11D3/20
CPC分类号： B01F17/0028 , A61K8/37 , A61Q5/02 , A61Q5/12 , B01F17/0021
摘要： Lactic acid esters of an .alpha.-branched fatty acid possessing an excellent hair conditioning effect are disclosed. Typical example is sodium 2-heptylundecanoyl acid lactate prepared by the reaction of 2-heptylundecanoic acid and lactic acid in the presence of an alkali such as sodium hydroxide. This compound gives a shampoo composition in conjunction with an anionic surface active agent, and a hair rinse composition when a quaternary ammonium salt is formulated. The compositions have excellent conditioning effects on use such as good slipperiness and hair curling formation or retention performance.

8. 发明授权

US06977034B2 Capillary array and electrophoresis apparatus 有权
标题翻译：毛细管阵列和电泳仪
公开(公告)号：US06977034B2
公开(公告)日：2005-12-20
申请号：US10239765
申请日：2000-12-04
申请人： Tomonari Morioka , Yasushi Shimizu , Seiichi Ugai , Toshiaki Kita , Kiyoshi Tsukada
发明人： Tomonari Morioka , Yasushi Shimizu , Seiichi Ugai , Toshiaki Kita , Kiyoshi Tsukada
IPC分类号： G01N27/447 , G01N27/453 , G01N30/02
CPC分类号： G01N27/44782 , G01N27/44721
摘要： A capillary array comprising multiple capillaries and two holding substrates for arranging the aforementioned multiple capillaries in a substantially plane surface by sandwiching at least some of these capillaries mutually. One of the holding substrates has a detection window for transmitting the detected light emitted by a test sample by irradiation of light. Especially, this detection window comprises multiple light transmission areas provided to correspond to each capillary to transmit the detected light, and light cut-off areas provided between these light transmission areas to cut off the detected light. These light cut-off areas cut off light reflected from the surface of capillaries and hence improve the SN ratio, thereby ensuring high-precision detection.
摘要翻译：毛细管阵列，其包括多个毛细管和两个保持基板，用于通过相互夹住这些毛细管中的至少一些来将上述多个毛细管布置在基本上平面的表面中。保持基板中的一个具有用于通过照射光透射由测试样品发射的检测到的光的检测窗口。特别地，该检测窗口包括多个透光区域，其设置为对应于每个毛细管以透射检测到的光，以及设置在这些光透射区域之间的遮光区域以切断检测到的光。这些遮光区域切断从毛细管表面反射的光，从而提高SN比，从而确保高精度检测。

9. 发明授权

US5642140A Rotational arm assembly for a printing mechanism of a recorder and copy machine incorporating same 失效
标题翻译：用于记录器的打印机构的旋转臂组件和包含其的复印机
公开(公告)号：US5642140A
公开(公告)日：1997-06-24
申请号：US337813
申请日：1994-11-08
申请人： Yukio Sawano , Mamoru Mizunokura , Kiyoshi Tsukada
发明人： Yukio Sawano , Mamoru Mizunokura , Kiyoshi Tsukada
IPC分类号： B41J25/304 , B41J2/315 , B41J2/32 , B41J3/54 , G01D15/10 , G01D15/24 , G01D15/16
CPC分类号： G01D15/24 , B41J2/315 , B41J3/54 , G01D15/10
摘要： A thermally sensitive recording head comprising, a two bases 2 moving with its attitude being kept along a guide shaft 5, an attachment 3 rotatably provided on the base 2 so that the base 2 extends to an right angle direction with the guide shaft 5 and contacts on or separates from a platen 8, and a heating head 4, which is rotatably provided on the attachment 3, and on front surface of which a heating body train is formed in a right angle direction with the guide shaft 5 and extends in opposite direction to an extending direction of the attachment 3 from the tip end of the attachment 3 to contact on or separate from the platen 8, whereby the attachment 3 and the heating head 4 are pressed on the thermally Sensitive paper placed on back-side of the platen 8. In this arrangement, a clear image can be obtained without generation of irregularity of photographic density because the heating head 4 presses the thermally sensitive papers while being kept always in parallel with the platen 8.
摘要翻译：一种热敏记录头，包括：沿着导向轴5保持其姿态移动的两个基座2;可旋转地设置在基座2上的安装件3，使得基座2与导向轴5成直角的方向延伸，与压板8分开或分离;以及可旋转地设置在附件3上的加热头4，并且其前表面上与导向轴5成直角方向形成加热体列，并沿相反方向延伸从连接件3的前端延伸到连接件3的延伸方向上，以与台板8接触或分离，从而将附件3和加热头4按压在放置在压盘背面的热敏纸上在这种布置中，可以获得清晰的图像而不会产生不均匀的照相密度，因为加热头4在保持总是与压板8保持平行的同时按压热敏纸。

10. 发明授权

US5481048A Method for preparing copper-containing hydrogenation reaction catalyst and method for producing alcohol 失效
公开(公告)号：US5481048A
公开(公告)日：1996-01-02
申请号：US357173
申请日：1994-12-13
申请人： Kiyoshi Tsukada , Yasuyuki Hattori , Taku Mimura
发明人： Kiyoshi Tsukada , Yasuyuki Hattori , Taku Mimura
IPC分类号： B01J23/72 , B01J23/745 , B01J23/80 , B01J23/86 , B01J37/18 , C07B61/00 , C07C29/149 , C07C31/02 , C07C29/36 , C07C31/125
CPC分类号： C07C29/149 , B01J23/72 , B01J23/80
摘要： A copper-containing hydrogenation reaction catalyst is prepared by reducing a precursor of a copper-containing catalyst usable in hydrogenation reaction with hydrogen gas or a mixture of hydrogen and an inert gas by liquid phase reduction in a stream of a solvent in the temperature range of from 50.degree. to 140.degree. C. An alcohol is produced using the catalyst thus obtained in a fixed bed continuous reaction system.

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式