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1. 发明授权

US5658843A Method for preparing copper-containing hydrogenation reaction catalyst and method for producing alcohol 失效
标题翻译：制备含铜加氢反应催化剂的方法及其制备方法
公开(公告)号：US5658843A
公开(公告)日：1997-08-19
申请号：US448580
申请日：1995-06-06
申请人： Kiyoshi Tsukada , Yasuyuki Hattori , Taku Mimura , Osamu Tabata , Futoshi Nishigaki
发明人： Kiyoshi Tsukada , Yasuyuki Hattori , Taku Mimura , Osamu Tabata , Futoshi Nishigaki
IPC分类号： B01J23/72 , B01J23/60 , B01J23/70 , B01J23/745 , B01J23/80 , B01J23/86 , B01J37/00 , B01J37/16 , B01J37/18 , C07B61/00 , C07C29/149 , C07C31/125
CPC分类号： B01J37/18 , B01J23/60 , B01J23/72 , B01J23/80 , B01J23/868 , B01J37/16 , C07C29/149 , B01J23/745 , B01J37/0009
摘要： A method for preparing a copper-containing hydrogenation reaction catalyst includes the step of reducing a formed precursor of a copper-containing hydrogenation reaction catalyst with hydrogen gas or a mixture of hydrogen and inert gas by liquid phase reduction in a stream of a solvent. The reductive activation is carried out by the two steps of performing the first stage of liquid phase reduction by which the catalyst precursor is activated in the temperature range of from 20.degree. to 140.degree. C. so that at least 10% by weight of the copper oxide contained in the catalyst precursor can be reduced by the time when the temperature passes 140.degree. C., and then performing the second stage of liquid phase reduction by which the catalyst precursor is further activated in the temperature range of from 140.degree. to 250.degree. C. The catalyst thus obtained has markedly improved catalytic activity and selectivity. An alcohol of high quality can be obtained at a high productivity using the catalyst in a fixed bed continuous reaction system.
摘要翻译： PCT No.PCT / JP94 / 00077 Sec。 371日期：1995年6月6日 102（e）日期1995年6月6日PCT 1994年1月20日PCT PCT。公开号WO95 / 19844 日期：1995年7月27日制备含铜氢化反应催化剂的方法包括以下步骤：用氢气或氢气和惰性气体的混合物在流中通过液相还原将还原形成的含铜氢化反应催化剂的前体的溶剂。还原活化通过进行第二阶段的液相还原的两个步骤进行，催化剂前体在20℃至140℃的温度范围内被活化，因此至少10重量％的铜包含在催化剂前体中的氧化物可以在温度达到140℃时降低，然后进行第二阶段的液相还原，催化剂前体在140°至250°的温度范围内进一步活化因此得到的催化剂显着地改善了催化活性和选择性。使用固定床连续反应体系中的催化剂可以以高生产率获得高质量的醇。

2. 发明授权

US06982340B2 Process for producing an ester 有权
公开(公告)号：US06982340B2
公开(公告)日：2006-01-03
申请号：US10384596
申请日：2003-03-11
申请人： Taku Mumura , Hidetoshi Kadowaki , Futoshi Nishigaki
发明人： Taku Mumura , Hidetoshi Kadowaki , Futoshi Nishigaki
IPC分类号： C07C51/36 , C07C67/02 , C07C27/04
CPC分类号： C11C3/003 , C07C29/149 , C07C67/56 , C11C1/08 , C07C69/24 , C07C69/52 , C07C31/125
摘要： There is provided a process wherein a lower alkyl ester of a fatty acid derived from natural fats and oils and a lower alcohol containing 1 to 4 carbon atoms is produced in a lower sulfur content at lower costs without causing a reduction in yield and a deterioration in selectivity, as well as a process for producing an alcohol without reducing the activity of a catalyst. The process comprises the step of adsorption treatment of an ester with at least one adsorbent selected from clay and activated carbon. Further are provided a process for producing an ester which further comprises adsorption treatment with a hydrogenating decomposition-type adsorbent containing Ni and/or Cu, in hydrogen or a mixed gas atmosphere of hydrogen and an inert gas, and a process for producing an alcohol which comprises hydrogenation reaction with an ester produced by any one of these processes as the starting material.

3. 发明授权

US6002054A Method for producing alcohol 失效
标题翻译：酒精生产方法
公开(公告)号：US6002054A
公开(公告)日：1999-12-14
申请号：US973743
申请日：1997-12-22
申请人： Hideaki Ueoka , Futoshi Nishigaki , Osamu Tabata
发明人： Hideaki Ueoka , Futoshi Nishigaki , Osamu Tabata
IPC分类号： C07C29/149
CPC分类号： C07C29/149
摘要： A method for producing an alcohol comprising the steps of continuously feeding starting materials of an alcohol; and carrying out catalytic reduction reaction of the starting materials in the presence of a hydrogenation catalyst, wherein said starting materials of an alcohol and a hydrogen gas are fed in a gaseous state or a mixture of liquid and gaseous states in a reduction reactor, and wherein said catalytic reduction reaction of the starting materials is carried out under temperature conditions, pressure conditions, and conditions of a molar ratio of hydrogen ((hydrogen molecules/(acyl groups in the starting materials)), sufficient to give an evaporation ratio of the starting materials of from 20 to 80% by weight, and wherein a ratio of VG to VL satisfies the following relationship in the reduction reactor: 100.ltoreq.VG/VL.ltoreq.10000, wherein "VG" stands for the superficial velocity at a gas phase portion of a mixture of the starting materials of an alcohol fed and hydrogen gas; and "VL" stands for the superficial velocity at a liquid phase portion of the mixture.
摘要翻译： PCT No.PCT / JP96 / 01601 Sec。 371 1997年12月22日第 102（e）日期1997年12月22日PCT提交1996年6月12日PCT公布。公开号WO97 / 00841 日本1997年1月9日一种醇的制造方法，其特征在于，包括连续供给醇的原料的工序; 并在氢化催化剂存在下进行原料的催化还原反应，其中所述醇和氢气的原料在还原反应器中以气态或液态和气态的混合物进料，其中所述起始原料的所述催化还原反应在温度条件，压力条件和氢（（氢原子/（原料中的酰基）的摩尔比）的条件下进行，足以使起始材料为20〜80重量％，并且其中VG与VL的比例在还原反应器中满足以下关系：100 VG / VL = 10000，其中“VG”表示a 醇的原料与氢气的混合物的气相部分;“VL”表示混合物的液相部分的表观速度。

4. 发明授权

US06331645B2 Process for preparing powdery alkyl sulfates 有权
公开(公告)号：US06331645B2
公开(公告)日：2001-12-18
申请号：US09725250
申请日：2000-11-29
申请人： Futoshi Nishigaki , Osamu Tabata
发明人： Futoshi Nishigaki , Osamu Tabata
IPC分类号： C07C30300
CPC分类号： C07C303/44 , C07C305/06
摘要： A process for preparing a powdery alkyl sulfate, comprising drying aqueous slurry having a solid content of 60 to 85% by weight and containing an alkyl sulfate and an alkali metal carbonate in a ratio of 0.05 to 10 parts by weight of the alkali metal carbonate based on 100 parts by weight of the alkyl sulfate. This process is capable of stably preparing a powdery alkyl sulfate without deteriorating the quality of aqueous slurry of an alkyl sulfate and powder obtainable from the aqueous slurry.

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