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1. 发明授权

US5948232A Method of manufacturing passive elements using conductive polypyrrole formulations 失效
标题翻译：使用导电聚吡咯制剂制造无源元件的方法
公开(公告)号：US5948232A
公开(公告)日：1999-09-07
申请号：US881107
申请日：1997-06-23
申请人： Oliver J. Murphy , G. Duncan Hitchens , Dalibor Hodko , Eric T. Clarke , David L. Miller , Donald L. Parker
发明人： Oliver J. Murphy , G. Duncan Hitchens , Dalibor Hodko , Eric T. Clarke , David L. Miller , Donald L. Parker
IPC分类号： C08G61/12 , C23C26/00 , C25D5/54 , G03F7/004 , G03F7/027 , H01B1/12 , H01C7/00 , H01C17/242 , H01G9/02 , H01G9/025 , H05K1/09 , H05K1/16 , H05K3/10 , H05K3/42 , H05K9/00 , C25D5/02 , B05D3/02 , C08F2/48
CPC分类号： H01G9/025 , C08G61/124 , C23C26/00 , C25D5/54 , G03F7/0045 , G03F7/027 , H01B1/12 , H01C17/242 , H01C7/005 , H05K1/167 , H05K1/095 , H05K1/162 , H05K1/165 , H05K2201/0329 , H05K2203/0514 , H05K3/105 , H05K3/424
摘要： The present invention provides electronically conducting polymer films formed from formulations of pyrrole and an electron acceptor. The formulations may include photoinitiators, flexibilizers, solvents and the like. These formulations can be used to manufacture multichip modules on typical multichip module substrates, such as alumina, fiberglass epoxy, silicon and polyimide. The formulations and methods of the invention enable the formation of passive electronic circuit elements such as resistors, capacitors and inductors in multichip modules or printed wiring boards.
摘要翻译：本发明提供由吡咯和电子受体的制剂形成的电子导电聚合物膜。制剂可以包括光引发剂，柔韧剂，溶剂等。这些配方可用于在典型的多芯片模块衬底（例如氧化铝，玻璃纤维环氧树脂，硅和聚酰亚胺）上制造多芯片模块。本发明的配方和方法能够在多芯片模块或印刷电路板中形成无源电子电路元件，例如电阻器，电容器和电感器。

2. 发明授权

US06210537B1 Method of forming electronically conducting polymers on conducting and nonconducting substrates 失效
标题翻译：在导电和非导电基材上形成电子导电聚合物的方法
公开(公告)号：US06210537B1
公开(公告)日：2001-04-03
申请号：US08492235
申请日：1995-06-19
申请人： Oliver J. Murphy , G. Duncan Hitchens , Dalibor Hodko , Eric T. Clarke , David L. Miller , Donald L. Parker
发明人： Oliver J. Murphy , G. Duncan Hitchens , Dalibor Hodko , Eric T. Clarke , David L. Miller , Donald L. Parker
IPC分类号： C07C100
CPC分类号： H01G9/025 , C08G61/124 , C23C26/00 , C25D5/54 , G03F7/027 , H01B1/12 , H01C7/005 , H01C17/242 , H05K1/095 , H05K1/16 , H05K1/162 , H05K1/165 , H05K1/167 , H05K3/105 , H05K3/185 , H05K3/188 , H05K9/0081 , H05K2201/0329 , H05K2203/0514
摘要： The present invention provides electronically conducting polymer films formed from photosensitive formulations of pyrrole and an electron acceptor that have been selectively exposed to UV light, laser light, or electron beams. The formulations may include photoinitiators, flexibilizers, solvents and the like. These solutions can be used in applications including printed circuit boards and through-hole plating and enable direct metallization processes on non-conducting substrates. After forming the conductive polymer patterns, a printed wiring board can be formed by sensitizing the polymer with palladium and electrolytically depositing copper.
摘要翻译：本发明提供了由已经选择性地暴露于紫外光，激光或电子束的吡咯和电子受体的光敏剂形成的电子导电聚合物膜。制剂可以包括光引发剂，柔韧剂，溶剂等。这些解决方案可用于包括印刷电路板和通孔电镀在内的应用，并可在非导电基板上进行直接金属化处理。在形成导电聚合物图案之后，可以通过使用钯和电沉积铜使聚合物敏化来形成印刷线路板。

3. 发明授权

US5855755A Method of manufacturing passive elements using conductive polypyrrole formulations 失效
标题翻译：使用导电聚吡咯制剂制造无源元件的方法
公开(公告)号：US5855755A
公开(公告)日：1999-01-05
申请号：US630063
申请日：1996-04-12
申请人： Oliver J. Murphy , G. Duncan Hitchens , Dalibor Hodko , Eric T. Clarke , David L. Miller , Donald L. Parker
发明人： Oliver J. Murphy , G. Duncan Hitchens , Dalibor Hodko , Eric T. Clarke , David L. Miller , Donald L. Parker
IPC分类号： C08F2/48 , C08G61/12 , C23C26/00 , C25D5/54 , G03F7/027 , H01B1/12 , H01C7/00 , H01C17/242 , H01G9/02 , H01G9/025 , H05K1/09 , H05K1/16 , H05K3/10 , H05K3/18 , H05K3/42 , H05K9/00 , C25D5/02 , B21F41/00
CPC分类号： H01G9/025 , C08G61/124 , C23C26/00 , C25D5/54 , G03F7/027 , H01B1/12 , H01C17/242 , H01C7/005 , H05K1/095 , H05K1/16 , H05K1/167 , H05K3/105 , H05K3/185 , H05K3/188 , H05K9/0083 , H05K1/162 , H05K1/165 , H05K2201/0329 , H05K2203/0514 , H05K3/424 , Y10T29/417
摘要： The present invention provides electronically conducting polymer films formed from photosensitive formulations of pyrrole and an electron acceptor that have been selectively exposed to UV light, laser light, or electron beams. The formulations may include photoinitiators, flexibilizers, solvents and the like. These formulations can be used to manufacture multichip modules on typical multichip module substrates, such as alumina, fiberglass epoxy, silicon and polyimide. The formulations and methods of the invention enable the formation of passive electronic circuit elements such as resistors, capacitors and inductors in multichip modules or printed wiring boards.
摘要翻译：本发明提供了由已经选择性地暴露于紫外光，激光或电子束的吡咯和电子受体的光敏剂形成的电子导电聚合物膜。制剂可以包括光引发剂，柔韧剂，溶剂等。这些配方可用于在典型的多芯片模块衬底（例如氧化铝，玻璃纤维环氧树脂，硅和聚酰亚胺）上制造多芯片模块。本发明的配方和方法能够在多芯片模块或印刷电路板中形成无源电子电路元件，例如电阻器，电容器和电感器。

4. 发明授权

US5545308A Method of using conductive polymers to manufacture printed circuit boards 失效
标题翻译：使用导电聚合物制造印刷电路板的方法
公开(公告)号：US5545308A
公开(公告)日：1996-08-13
申请号：US491625
申请日：1995-06-19
申请人： Oliver J. Murphy , G. Duncan Hitchens , Dalibor Hodko , Eric T. Clarke , David L. Miller , Donald L. Parker
发明人： Oliver J. Murphy , G. Duncan Hitchens , Dalibor Hodko , Eric T. Clarke , David L. Miller , Donald L. Parker
IPC分类号： C08G61/12 , C23C26/00 , C23C28/00 , C25D5/54 , G03F7/027 , H01B1/12 , H01C7/00 , H01C17/242 , H01G9/02 , H01G9/025 , H05K1/16 , H05K3/10 , H05K3/18 , H05K3/42 , H05K9/00 , C25D5/02
CPC分类号： H01G9/025 , C08G61/124 , C23C26/00 , C23C28/00 , C25D5/54 , G03F7/027 , H01B1/12 , H01C17/242 , H01C7/005 , H05K1/16 , H05K1/167 , H05K3/188 , H05K1/162 , H05K1/165 , H05K2201/0329 , H05K2203/0514 , H05K3/105 , H05K3/424
摘要： The present invention provides electronically conducting polymer films formed from photosensitive formulations of pyrrole and an electron acceptor that have been selectively exposed to UV light, laser light, or electron beams. The formulations may include photoinitiators, flexibilizers, solvents and the like. These solutions can be used in applications including printed circuit boards and through-hole plating and enable direct metallization processes on non-conducting substrates. After forming the conductive polymer patterns, a printed wiring board can be formed by sensitizing the polymer with palladium and electrolytically depositing copper.
摘要翻译：本发明提供了由已经选择性地暴露于紫外光，激光或电子束的吡咯和电子受体的光敏剂形成的电子导电聚合物膜。制剂可以包括光引发剂，柔韧剂，溶剂等。这些解决方案可用于包括印刷电路板和通孔电镀在内的应用，并可在非导电基板上进行直接金属化处理。在形成导电聚合物图案之后，可以通过使用钯和电沉积铜使聚合物敏化来形成印刷线路板。

5. 发明授权

US5859085A Stable powders made from photosensitive polycrystalline complexes of heterocyclic monomers and their polymers 失效
标题翻译：由杂环单体的光敏多晶配合物及其聚合物制成的稳定粉末
公开(公告)号：US5859085A
公开(公告)日：1999-01-12
申请号：US787270
申请日：1997-01-24
申请人： Dalibor Hodko , Oliver J. Murphy , G. Duncan Hitchens
发明人： Dalibor Hodko , Oliver J. Murphy , G. Duncan Hitchens
IPC分类号： C08F2/48 , C08G61/12 , C23C26/00 , C25D5/54 , G03F7/027 , H01B1/12 , H01C7/00 , H01C17/242 , H01G9/02 , H01G9/025 , H05K1/09 , H05K1/16 , H05K3/10 , H05K3/18 , H05K3/42 , H05K9/00 , C08G73/06
CPC分类号： H01G9/025 , C08G61/124 , C23C26/00 , C25D5/54 , G03F7/027 , H01B1/12 , H01C17/242 , H01C7/005 , H05K1/095 , H05K1/16 , H05K1/167 , H05K3/185 , H05K3/188 , H05K9/0083 , H05K1/162 , H05K1/165 , H05K2201/0329 , H05K2203/0514 , H05K3/105 , H05K3/424
摘要： The present invention relates to a low electronic conductivity polymer composition having well dispersed metal granules, a stable powder made from photosensitive polycrystalline complexes of pyrrole, or its substituted derivatives and silver cations for making the polymer composition, and methods of forming the stable powder and polymer composition, respectively. A polycrystalline complex of silver and a monomer, such as pyrrole, its substituted derivatives or combinations thereof, is precipitated in the form of a stable photosensitive powder upon addition of the monomer to a solvent solution, such as toluene containing an electron acceptor. The photosensitive powder can be stored in the dark until needed. The powder may be dissolved in a solvent, cast onto a substrate and photopolymerized.
摘要翻译：本发明涉及具有良好分散的金属颗粒的低电子导电性聚合物组合物，由吡咯的光敏多晶配合物制成的稳定的粉末或其取代的衍生物和用于制备聚合物组合物的银阳离子，以及形成稳定的粉末和聚合物的方法组成。当将单体添加到溶剂溶液（例如含有电子受体的甲苯）时，银和单体如吡咯，其取代的衍生物或其组合的多晶复合物以稳定的感光性粉末的形式沉淀。光敏粉末可以在黑暗中储存，直至需要。粉末可以溶解在溶剂中，浇铸到基材上并进行光聚合。

6. 发明授权

US06265205B1 Enhancement of soil and groundwater remediation 失效
标题翻译：加强土壤和地下水的修复
公开(公告)号：US06265205B1
公开(公告)日：2001-07-24
申请号：US09013729
申请日：1998-01-27
申请人： G. Duncan Hitchens , Drahomira Brejchova , Alan J. Cisar , Dalibor Hodko , Oliver J. Murphy
发明人： G. Duncan Hitchens , Drahomira Brejchova , Alan J. Cisar , Dalibor Hodko , Oliver J. Murphy
IPC分类号： C12S1300
CPC分类号： C12P5/02 , B09C1/08 , B09C1/10 , Y02E50/343
摘要： This invention is a novel method for bioremediation of soil and ground water based on supplying hydrogen (H2) to naturally occurring anaerobic bacteria in the soil or ground water. These organisms use the hydrogen as an electron donor to perform adventitious chemical reactions including the dehalogenation of chlorinated organic compounds. The hydrogen can be supplied from a number of sources, including; stored hydrogen, hydrogen generated above ground on site, either electrochemically or by reforming a fuel source, or by electrolysis in the soil, either using an electric current supplied from above ground or an electric current generated by the corrosion of metal particles in the ground. For the last of these cases, a novel multi-metallic particle especially useful for the generation of hydrogen, and a method for making these particles, are disclosed.
摘要翻译：本发明是一种基于向土壤或地下水中的天然存在的厌氧细菌供应氢（H2）的土壤和地下水生物修复的新方法。这些生物体使用氢作为电子给体来进行不定期的化学反应，包括氯化有机化合物的脱卤。氢可以从许多来源提供，包括：储存的氢气，现场地面上产生的氢气，电化学或通过燃料源重整，或通过土壤中的电解，使用从地面提供的电流或由地下金属颗粒的腐蚀产生的电流。对于这些情况中的最后一种，公开了特别可用于产生氢的新型多金属颗粒和制造这些颗粒的方法。

7. 发明授权

US06221224B1 Fluid management system for electrokinetic remediation 失效
标题翻译：用于电动修复的流体管理系统
公开(公告)号：US06221224B1
公开(公告)日：2001-04-24
申请号：US09124549
申请日：1998-07-29
申请人： G. Duncan Hitchens , Dalibor Hodko
发明人： G. Duncan Hitchens , Dalibor Hodko
IPC分类号： C02F146
CPC分类号： B01D61/56 , B09C1/085 , C02F1/469 , C02F2201/4612
摘要： A system for managing fluids used during electroremediation of contaminants in a porous medium, such as soil is disclosed. The system monitors the fluid gain and loss from the electrode wells and maintains optimal fluid levels in the wells on an individual basis. The system may use a sensor element for measuring the metal ion content of the electrode well fluid. A method for using the fluid management system is also disclosed.
摘要翻译：公开了一种用于管理多孔介质（例如土壤）中的污染物的电修复中使用的流体的系统。该系统监测来自电极井的流体增益和损失，并且在各个基础上保持井中的最佳流体水平。该系统可以使用传感器元件来测量电极井液的金属离子含量。还公开了一种使用流体管理系统的方法。

8. 发明授权

US5779912A Photocatalytic oxidation of organics using a porous titanium dioxide membrane and an efficient oxidant 失效
标题翻译：使用多孔二氧化钛膜和有效的氧化剂对有机物进行光催化氧化
公开(公告)号：US5779912A
公开(公告)日：1998-07-14
申请号：US791599
申请日：1997-01-31
申请人： Anuncia Gonzalez-Martin , Oliver J. Murphy , Dalibor Hodko
发明人： Anuncia Gonzalez-Martin , Oliver J. Murphy , Dalibor Hodko
IPC分类号： B01D53/86 , B01J8/00 , B01J19/12 , B01J19/24 , B01J35/00 , C01B3/38 , C02F1/30 , C02F1/32 , C02F1/467 , C02F1/72 , C02F1/78
CPC分类号： C02F1/325 , B01D53/864 , B01D53/8668 , B01J19/123 , B01J19/127 , B01J19/2415 , B01J19/2475 , B01J35/002 , B01J35/004 , B01J8/009 , C01B3/38 , C02F1/725 , B01D2251/104 , B01D2251/106 , B01D2255/20707 , B01J2219/00067 , B01J2219/00144 , B01J2219/00162 , B01J2219/00164 , B01J2219/0883 , C02F1/4672 , C02F1/722 , C02F1/78 , C02F2101/303 , C02F2101/322 , C02F2101/363 , C02F2201/009 , C02F2201/3223 , C02F2201/328 , C02F2305/10 , Y02P20/52 , Y02W10/37
摘要： A method and apparatus for mineralizing organic contaminants in water or air provides photochemical oxidation in a unique two-phase or three-phase boundary system formed in each pore of a TiO.sub.2 membrane in a photocatalytic reactor. In the three-phase system, gaseous oxidant, liquid contaminant, and solid semiconductor photocatalyst meet and engage in an efficient oxidation reaction. The porous membrane has pores which have a region wherein the meniscus of the liquid varies from the molecular diameter of water to that o f a capillary tube resulting in a diffusion layer that is several orders of magnitude smaller than the closest known reactors. The photocatalytic reactor operates effectively at ambient temperature and low pressures.
摘要翻译：用于矿化水或空气中的有机污染物的方法和装置在光催化反应器中在TiO 2膜的每个孔中形成的独特的两相或三相边界系统中提供光化学氧化。在三相系统中，气态氧化剂，液体污染物和固体半导体光催化剂相遇并进行有效的氧化反应。多孔膜具有其中液体的弯液面从毛细管的分子直径到毛细管的弯曲面的区域的孔，导致扩散层比最近的已知反应器小几个数量级。光催化反应器在环境温度和低压下有效运行。

9. 发明授权

US06334965B1 Electronically conductive polymers 有权
标题翻译：电子导电聚合物
公开(公告)号：US06334965B1
公开(公告)日：2002-01-01
申请号：US09390194
申请日：1999-09-07
申请人： Waheguru Pal Singh , Dalibor Hodko , Suchitra Chepin , Oliver J. Murphy
发明人： Waheguru Pal Singh , Dalibor Hodko , Suchitra Chepin , Oliver J. Murphy
IPC分类号： H01B100
CPC分类号： H01B1/127 , H01B1/128 , H05K3/424
摘要： The present invention provides a formulation for forming an electronically conducting polymer. The formulation contains an electron acceptor comprising a dopant anion and a metal cation selected from Ag+, Fe3+, Cu2+ or combinations thereof. The preferred electron acceptor is a silver salt, preferably selected from AgNO3, AgClO4 and AgNO2. The formulation also contains between 2 and 100 moles of a polymerizable component per mole of the electron acceptor, the polymerizable component being selected from pyrrole, aniline, their oligomers, or combinations thereof. In addition, the formulation includes an aqueous solvent selected from acetonitrile, acetone, and combinations thereof, the aqueous solvent having up to 30 volume percent water.
摘要翻译：本发明提供了一种用于形成电子导电聚合物的配方。该制剂含有包含掺杂剂阴离子和选自Ag +，Fe 3+，Cu 2+或其组合的金属阳离子的电子受体。优选的电子受体是银盐，优选选自AgNO 3，AgClO 4和AgNO 2。该配方还含有每摩尔电子受体2至100摩尔可聚合组分，可聚合组分选自吡咯，苯胺，其低聚物或其组合。此外，该制剂包括选自乙腈，丙酮及其组合的水性溶剂，所述水性溶剂具有至多30体积％的水。

10. 发明授权

US6117337A Enhanced photocatalytic oxidation of organics using a porous titanium dioxide membrane 失效
标题翻译：使用多孔二氧化钛膜增强有机物的光催化氧化
公开(公告)号：US6117337A
公开(公告)日：2000-09-12
申请号：US96277
申请日：1998-06-11
申请人： Anuncia Gonzalez-Martin , Oliver J. Murphy , Dalibor Hodko , Carlos Salinas
发明人： Anuncia Gonzalez-Martin , Oliver J. Murphy , Dalibor Hodko , Carlos Salinas
IPC分类号： B01D53/86 , B01J8/00 , B01J19/12 , B01J19/24 , B01J35/00 , C01B3/38 , C02F1/30 , C02F1/32 , C02F1/467 , C02F1/72 , C02F1/78 , B01J19/08
CPC分类号： B01D53/864 , B01D53/8668 , B01J19/123 , B01J19/127 , B01J19/2415 , B01J19/2475 , B01J35/002 , B01J35/004 , B01J8/009 , C01B3/38 , C02F1/325 , C02F1/725 , B01D2251/104 , B01D2251/106 , B01D2255/20707 , B01J2219/00067 , B01J2219/00144 , B01J2219/00162 , B01J2219/00164 , B01J2219/0883 , C02F1/4672 , C02F1/722 , C02F1/78 , C02F2101/303 , C02F2101/322 , C02F2101/363 , C02F2201/009 , C02F2201/3223 , C02F2201/328 , C02F2305/10 , Y02P20/52 , Y02W10/37
摘要： A method and apparatus for mineralizing organic contaminants in water or air provides photochemical oxidation in a unique two-phase or three-phase boundary system formed in each pore of a TiO.sub.2 membrane in a photocatalytic reactor. In the three-phase system, gaseous oxidant, liquid contaminant, and solid semiconductor photocatalyst having a metal catalyst disposed thereon meet and engage in an efficient oxidation reaction. The porous membrane has pores which have a region wherein the meniscus of the liquid varies from the molecular diameter of water to that of a capillary tube resulting in a diffusion layer that is several orders of magnitude smaller than the closest known reactors. The photocatalytic reactor operates effectively at ambient temperature and low pressures.
摘要翻译：用于矿化水或空气中的有机污染物的方法和装置在光催化反应器中在TiO 2膜的每个孔中形成的独特的两相或三相边界系统中提供光化学氧化。在三相系统中，具有设置在其上的金属催化剂的气态氧化剂，液体污染物和固体半导体光催化剂满足并参与有效的氧化反应。多孔膜具有这样的孔，其中液体的弯月面从水的分子直径变化到毛细管的弯液面，导致比最近的已知反应器小几个数量级的扩散层。光催化反应器在环境温度和低压下有效运行。

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