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1. 发明授权

US08889758B2 Dental materials containing hydrophobic nanoparticulate silicic acid co-condensates and use thereof 有权
标题翻译：含有疏水性纳米颗粒硅酸共缩合物的牙科材料及其用途
公开(公告)号：US08889758B2
公开(公告)日：2014-11-18
申请号：US12226129
申请日：2007-03-27
申请人： Norbert Moszner , Volker Rheinberger , Simone Klapdohr , Urs Karl Fischer
发明人： Norbert Moszner , Volker Rheinberger , Simone Klapdohr , Urs Karl Fischer
IPC分类号： C08F283/12 , C08F30/08 , A61K6/083 , A61K6/00 , C08G77/12 , C08G77/20
CPC分类号： A61K6/0005 , A61K6/0017 , A61K6/083 , C08G77/12 , C08G77/20 , C08L51/085
摘要： The present invention relates to dental materials comprising liquid, nanoparticulate functionalized hydrophobic co-condensates of tetraalkyl silicates with functionalized trialkoxysilanes of the formula I P—(CH2)n—Si(OR)3 where P, R and n independently of one another have the following meanings: P=a polymerizable CH2═CH—, CH2═CH—O—, styryl, (meth)acrylic or (meth)acrylamide group or an SH group capable of polyaddition, R=methyl, ethyl or propyl and n=from 3 to 15, which can be prepared by co-condensation of tetraalkyl silicates with alkyltrialkoxysilanes functionalized in the ω position and subsequent end group functionalization with trimethylsilyl groups; The invention further relates to the use of the dental materials for filling composites, fixing cements or materials for coatings.
摘要翻译：本发明涉及包含液体，纳米颗粒官能化的四烷基硅酸盐的疏水性共缩合物与式IP-（CH 2）n -Si（OR）3的官能化三烷氧基硅烷的牙科材料，其中P，R和n彼此独立地具有以下含义：P =可聚合CH 2 = CH-，CH 2 = CH-O-，苯乙烯基，（甲基）丙烯酸或（甲基）丙烯酰胺基团或能够加成的SH基团，R =甲基，乙基或丙基，n = 3 至15，其可以通过四烷基硅酸盐与在ω位官能化的烷基三烷氧基硅烷和随后的三甲基甲硅烷基基团官能化的共缩合制备; 本发明还涉及牙科材料用于填充复合材料，固定水泥或涂层材料的用途。

2. 发明申请

US20090043004A1 Dental Materials Containing Hydrophobic Nanoparticulate Silicic Acid Co-Condensates and Use Thereof 有权
标题翻译：含疏水性纳米微粒硅酸共冷凝物及其用途的牙科材料
公开(公告)号：US20090043004A1
公开(公告)日：2009-02-12
申请号：US12226129
申请日：2007-03-27
申请人： Norbert Moszner , Volker Rheinberger , Simone Klapdohr , Urs Karl Fischer
发明人： Norbert Moszner , Volker Rheinberger , Simone Klapdohr , Urs Karl Fischer
IPC分类号： A61K8/72 , C08F230/08 , C08F283/12
CPC分类号： A61K6/0005 , A61K6/0017 , A61K6/083 , C08G77/12 , C08G77/20 , C08L51/085
摘要： The present invention relates to dental materials comprising liquid, nanoparticulate functionalized hydrophobic co-condensates of tetraalkyl silicates with functionalized trialkoxysilanes of the formula I P—(CH2)n—Si(OR)3 where P, R and n independently of one another have the following meanings: P=a polymerizable CH2═CH—, CH2═CH—O—, styryl, (meth)acrylic or (meth)acrylamide group or an SH group capable of polyaddition, R=methyl, ethyl or propyl and n=from 3 to 15, which can be prepared by co-condensation of tetraalkyl silicates with alkyltrialkoxysilanes functionalized in the ω position and subsequent end group functionalization with trimethylsilyl groups; The invention further relates to the use of the dental materials for filling composites, fixing cements or materials for coatings.
摘要翻译：本发明涉及牙科材料，其包括液体，纳米颗粒官能化的四烷基硅酸盐的疏水性共缩合物与式I的官能化三烷氧基硅烷<？in-line-formula description =“In-line formula”end =“lead”→> P- （CH2）n-Si（OR）3 <？in-line-formula description =“In-line Formulas”end =“tail”？>其中P，R和n彼此独立地具有以下含义：P = a 可聚合的CH 2 -CH-，CH 2 -CH-O-，苯乙烯基，（甲基）丙烯酸或（甲基）丙烯酰胺基团或能够加成的SH基团，R =甲基，乙基或丙基，n = 3至15，通过硅烷四烷基酯与在ω位置官能化的烷基三烷氧基硅烷的共缩合制备，随后用三甲基甲硅烷基进行末端官能化; 本发明还涉及牙科材料用于填充复合材料，固定水泥或涂层材料的用途。

3. 发明授权

US06900251B2 Dental materials based on acrylic-ester phosphonic acids 有权
标题翻译：基于丙烯酸酯膦酸的牙科材料
公开(公告)号：US06900251B2
公开(公告)日：2005-05-31
申请号：US10606142
申请日：2003-06-25
申请人： Norbert Moszner , Ulrich Salz , Frank Zeuner , Jörg Zimmermann , Volker Rheinberger , Jorg Angermann , Urs Karl Fischer
发明人： Norbert Moszner , Ulrich Salz , Frank Zeuner , Jörg Zimmermann , Volker Rheinberger , Jorg Angermann , Urs Karl Fischer
IPC分类号： A61C13/087 , A61K6/00 , A61K6/083 , C07F9/38 , C08F30/02 , C08F220/54 , C08F230/02 , C09J4/00 , C09J4/02 , C09J11/04 , C09J11/06 , A61K8/00 , C07F9/09 , C08F2/46
CPC分类号： A61K6/0023 , A61K6/083 , C07F9/3808 , C08F30/02 , C08L33/00 , C08L43/02 , C08L39/06
摘要： Acrylic ester phosphonic acids of general formula (I), stereoisomers thereof and mixtures of these, wherein n is 1 or 2, on the condition that for n=1 R1 has the meaning and for n=2 R1 has the meaning R2 is a C1 to C12 alkylene radical, C4-C8 cycloalkylene radical or C7 to C15 alkylene phenylene radical; R3 is hydrogen, a C1 to C5 alkyl radical or a C1 to C5 O-alkyl radical; and R4, R5, independently of each other, each stand for a C1 to C5 alkyl radical or a C1 to C5 O-alkyl radical.
摘要翻译：在通式（I）的丙烯酸酯膦酸，其立体异构体和它们的混合物，其中n为1或2，条件是对于n = 1的R 1具有含义，n = 2 R 1具有R 2是C 1至C 12亚烷基的C 1至C 4亚烷基，C 4 C 1 -C 8亚环烷基或C 7至C 15亚烷基亚苯基; R 3是氢，C 1至C 5烷基或C 1至C 6烷基， 5 O - 烷基; 和R 4，R 5，R 5彼此独立地代表C 1至C 5烷基自由基或C 1至C 5 - O-烷基。

4. 发明授权

US06653375B2 Urethane di(meth)acrylate derivatives of 1,3-bis(1-isocyanato-1-methylethyl)benzene 有权
标题翻译：苯乙烯的聚氨酯二（甲基）丙烯酸酯衍生物，1,3-双（1-异氰酸基-1-甲基乙基）苯
公开(公告)号：US06653375B2
公开(公告)日：2003-11-25
申请号：US09236787
申请日：1999-01-25
申请人： Norbert Moszner , Volker Rheinberger , Thomas Völkel , Urs Karl Fischer
发明人： Norbert Moszner , Volker Rheinberger , Thomas Völkel , Urs Karl Fischer
IPC分类号： A61K6083
CPC分类号： A61K6/0023 , A61K6/0017 , A61K6/09 , C07C271/20 , C08L75/16
摘要： The invention relates to urethane di(meth)acrylate derivatives of 1-3-bis(1-isocyanato-1-methylethyl)benzene according to Formula (I) in which R is hydrogen or a straight-chained C1-C8 alkyl radical; X and Y independently of each other stand for R1 being a substituted or unsubstituted C6- to C12-aryl or C7- to C16-alkyl aryl radical; R2 hydrogen, a C1- to C5-alkyl or a substituted or unsubstituted C6- to C12-aryl radical; R3 hydrogen or a methyl radical; R4 a C1- to C8-alkylene radical which can be broken by oxygen atoms, or a phenylene radical; R5 hydrogen or a methyl radical; R6 a substituted or unsubstituted C6- to C12-aryl or C7- to C16-alkyl aryl radical; Z being —CO— or a chemical bond and W standing for oxygen, sulphur or NR7, R7 being hydrogen or a straight-chained C1- to C6-alkyl radical. The substances are suitable in particular for the production of dental materials.
摘要翻译：本发明涉及式（I）的1,3-双（1-异氰酸基-1-甲基乙基）苯的氨基甲酸酯二（甲基）丙烯酸酯衍生物，其中R为氢或直链C1-C8烷基; X和Y彼此独立地代表R 1是取代或未取代的C 6 -C 12 - 芳基或C 7 -C 16烷基芳基; R 2为氢，C 1至C 5 - 烷基或取代或未取代的C 6至C 12 - 芳基; R 3氢或甲基; R 4可以被氧原子断裂的C1-至C8-亚烷基或亚苯基; R 5氢或甲基; R 6取代或未取代的C 6 -C 12 - 芳基或C 7 -C 16烷基芳基; Z是-CO-或化学键，W代表氧，硫或NR 7，R 7是氢或直链C 1至C 6烷基。这些物质特别适用于生产牙科材料。

5. 发明授权

US06353039B1 Polymerizable composite material 有权
标题翻译：可聚合复合材料
公开(公告)号：US06353039B1
公开(公告)日：2002-03-05
申请号：US09209905
申请日：1998-12-11
申请人： Volker Rheinberger , Ulrich Salz , Wolfram Höland , André Rumphorst , Kurt Grabher , Urs Karl Fischer , Marcel Schweiger , Norbert Moszner
发明人： Volker Rheinberger , Ulrich Salz , Wolfram Höland , André Rumphorst , Kurt Grabher , Urs Karl Fischer , Marcel Schweiger , Norbert Moszner
IPC分类号： A61K6083
CPC分类号： A61K6/0276 , A61K6/083 , A61K6/09 , C08F2/44 , C08K3/40 , C08K9/08 , C08L33/00 , C08L75/16
摘要： A composite material is described which contains polymerizable monomers plus a special transparent glass having high release of calcium ions and fluorine ions and, because of this release property and in particular of its optical properties, can be used as a restoration material in dentistry.
摘要翻译：描述了一种复合材料，其包含可聚合单体加上具有高释放的钙离子和氟离子的特殊透明玻璃，并且由于该释放性质，特别是其光学性质，可用作牙科中的修复材料。

6. 发明授权

US08921450B2 Dental materials based on dimer acid derivatives with ring opening polymerizable groups 有权
标题翻译：基于具有开环聚合基团的二聚酸衍生物的牙科材料
公开(公告)号：US08921450B2
公开(公告)日：2014-12-30
申请号：US13175988
申请日：2011-07-05
申请人： Norbert Moszner , Jörg Angermann , Urs Karl Fischer , Volker Rheinberger
发明人： Norbert Moszner , Jörg Angermann , Urs Karl Fischer , Volker Rheinberger
IPC分类号： A61K6/08 , A61K6/083 , C07D339/00 , A61K6/00
CPC分类号： C07D339/00 , A61K6/0023 , A61K6/083 , C08L33/08 , C08L33/10 , C08L65/00
摘要： The invention relates to a radically polymerizable monomer of formula (I) wherein W1 and W2 in each case independently represent H or X—R—Y—PG, wherein at least one of W1 and W2 represents X—R—Y—PG, X in each case independently is missing or represents an ether, ester, amide, urethane or urea group, Y in each case independently is missing or represents an ether, ester, amide, urethane or urea group, R in each case independently is missing or represents a C1-C16 alkylene radical which can be interrupted by one or more O atoms, wherein R can be missing only if X and/or Y is simultaneously also missing, and PG in each case independently represents a cyclic, ring-opening polymerizable group, a, b, c and d independently of each other can take the values 3 to 10. The invention also relates to polymerizable compositions which comprise the monomers according to the invention, as well as their use as dental materials and for the preparation of dental materials, in particular composites, cements, adhesives or coatings.
摘要翻译：本发明涉及式（I）的自由基聚合性单体，其中W1和W2各自独立地表示H或X-R-Y-PG，其中W1和W2中的至少一个表示X-R-Y-PG，X 在每种情况下都独立地缺失或表示醚，酯，酰胺，氨基甲酸酯或脲基，Y在每种情况下独立地缺失或表示醚，酯，酰胺，氨基甲酸酯或脲基，R各自独立地缺失或表示可以被一个或多个O原子中断的C1-C16亚烷基，其中只有当X和/或Y同时缺失时，R只能缺失，并且每种情况下PG都独立地表示环状的开环聚合基团， a，b，c和d可以取值为3至10.本发明还涉及包含根据本发明的单体的可聚合组合物，以及它们作为牙科材料和用于制备牙科材料的用途，特别是composi 水泥，粘合剂或涂料。

7. 发明申请

US20070287792A1 Dental materials based on ring-opening polymerizable acid monomers 审中-公开
标题翻译：基于开环聚合酸单体的牙科材料
公开(公告)号：US20070287792A1
公开(公告)日：2007-12-13
申请号：US11585280
申请日：2006-10-24
申请人： Norbert Moszner , Jorg Angermann , Frank Zeuner , Armin de Mejere , Urs Karl Fischer , Volker Rheinberger
发明人： Norbert Moszner , Jorg Angermann , Frank Zeuner , Armin de Mejere , Urs Karl Fischer , Volker Rheinberger
IPC分类号： C08L31/00
CPC分类号： A61K6/0023 , A61K6/0017 , A61K6/083 , C08L33/00
摘要： Dental material which contains at least one radically polymerizable monomer according to the general formula (I): in which PG is a cyclic, ring-opening polymerizable group; X1 is absent, O, S, is an ester, amide or urethane group; X2 is absent with, O, S, is an ester, amide or urethane group; Y is absent, O, S, is an ester, amide or urethane group; R is an organic radical with a valency of (n+m), with 1 to 35 carbon atoms and 0 to 8 heteroatoms, the H atoms of which can be wholly or partially substituted by F atoms; R1 is absent or is a C1-C16 alkylene radical which can be interrupted by O atoms; R2 is absent or is a C1-C16 alkylene radical which can be interrupted by O atoms; n is 1, 2, 3, 4, 5 or 6; m is 1, 2 or 3; HG is —P═O(OH)2; —P═O(OH)(OR14); —O—P═O(OH)2, —O—P═O(OH)(OR15) or —SO2OH, wherein R14 is a C1-C15 alkyl radical, phenyl or benzyl radical; and R15 is a C1-C15 alkyl radical, phenyl or benzyl radical.
摘要翻译：含有至少一种根据通式（I）的可自由基聚合的单体的牙科材料：其中PG是环状可开环聚合基团; X 1不存在，O，S是酯，酰胺或氨基甲酸酯基; O，S不是酯，酰胺或氨基甲酸酯基; Y不存在，O，S是酯，酰胺或氨基甲酸酯基; R为化合价为（n + m），有1至35个碳原子和0至8个杂原子的有机基团，其H原子可以被F原子全部或部分取代; R 1不存在或可被O原子间断的C 1 -C 16亚烷基; R 2不存在或可被O原子间隔的C 1 -C 16亚烷基; n为1,2,3,4,5或6; m为1,2或3; HG是-P-O（OH）2; -P-O（OH）（OR 14）; -OPO（OH）2，-OPO（OH）（OR 15）或-SO 2 OH，其中R 14， CH 2是C 1 -C 15烷基，苯基或苄基; R 15是C 1 -C 15烷基，苯基或苄基。

8. 发明授权

US07078446B2 (Meth) acrylate-substituted iminooxidiazine dione derivatives 有权
标题翻译：（甲基）丙烯酸酯取代的亚氨氧亚氨基二酮衍生物
公开(公告)号：US07078446B2
公开(公告)日：2006-07-18
申请号：US10361961
申请日：2003-02-10
申请人： Norbert Moszner , Thomas Völkel , Urs Karl Fischer , Volker Rheinberger
发明人： Norbert Moszner , Thomas Völkel , Urs Karl Fischer , Volker Rheinberger
IPC分类号： A61K6/083 , A61C5/00 , C08G18/04
CPC分类号： A61K6/083 , A61K6/0023 , C07D273/04 , C08L33/00
摘要： The invention relates to iminooxadiazine dione derivatives with the formula (I) in which X, Y and Z represent a (meth)acrylic acid radical of the formula (II) in which R1 is hydrogen, an aliphatic hydrocarbon radical with 1 to 14 carbon atoms, which can be interrupted by oxygen atoms, or an aromatic hydrocarbon radical with to 16 carbon atoms; R2 is hydrogen, an aliphatic hydrocarbon radical with 1 to 5 carbon atoms or an aromatic hydrocarbon radical with 6 carbon atoms, n is 1 or 2; where the (meth)acrylic acid radical of formula (II) is bound to the radical of formula (I) by R1 or R2 and the binding point remaining at R2 or R1 is saturated by hydrogen and X, Y and Z can be the same or different; the individual radicals R being able to be the same or different and selected from alicyclic or aromatic hydrocarbon radicals with 5 to 10 or aliphatic hydrocarbon radicals with 1 to 10 carbon atoms.
摘要翻译：本发明涉及式（I）的亚氨基恶二嗪二酮衍生物，其中X，Y和Z表示式（II）的（甲基）丙烯酸基，其中R 1是氢，脂族可以被氧原子中断的具有1至14个碳原子的烃基或具有16个碳原子的芳族烃基; R 2是氢，具有1至5个碳原子的脂族烃基或具有6个碳原子的芳族烃基，n是1或2; 其中式（II）的（甲基）丙烯酸基团通过R 1或R 2 2与式（I）的基团结合，并且R H 2和R 1可以被氢饱和，X，Y和Z可以相同或不同; 各个基团R能够相同或不同，并且选自具有5-10个碳原子的脂族或芳族烃基或具有1-10个碳原子的脂族烃基。

9. 发明授权

US06180688B2 Ion-releasing composite material 有权
标题翻译：离子释放复合材料
公开(公告)号：US06180688B2
公开(公告)日：2001-01-30
申请号：US09210510
申请日：1998-12-11
申请人： Volker Rheinberger , Ulrich Salz , Andr{acute over (e)} Rumphorst , Kurt Grabher , Urs Karl Fischer , Norbert Moszner
发明人： Volker Rheinberger , Ulrich Salz , Andr{acute over (e)} Rumphorst , Kurt Grabher , Urs Karl Fischer , Norbert Moszner
IPC分类号： A61K6083
CPC分类号： A61K6/083
摘要： The invention relates to ion-releasing composite materials on the basis of polymerizable monomers. The material is characterized in that it contains one or more non-acid, non-ionic, hydrophilic crosslinker monomers, one or more non-acid, non-ionic, hydrophilic dilution monomers having a viscosity of ≦1 Pas and at least one ion-releasing filler. The materials are suitable in particular for use as dental materials.
摘要翻译：本发明涉及基于可聚合单体的离子释放复合材料。该材料的特征在于其含有一种或多种非酸性，非离子型亲水性交联剂单体，一种或多种非酸性，非离子型亲水稀释单体，其粘度为≥1Pa·s和至少一种离子释放填料这些材料特别适合用作牙科材料。

10. 发明授权

US6136887A Vinylcyclopropane-(meth)acrylates and their use 有权
标题翻译：乙烯基环丙烷 - （甲基）丙烯酸酯及其用途
公开(公告)号：US6136887A
公开(公告)日：2000-10-24
申请号：US266509
申请日：1999-03-11
申请人： Norbert Moszner , Volker Rheinberger , Thomas Voelkel , Urs Karl Fischer
发明人： Norbert Moszner , Volker Rheinberger , Thomas Voelkel , Urs Karl Fischer
IPC分类号： A61K6/00 , A61K6/083 , C07C69/743 , C08F22/10
CPC分类号： A61K6/0023 , A61K6/083 , C07C69/743 , C08F22/105
摘要： The invention relates to vinylcyclopropane derivatives according to the formula ##STR1## in which A is --[--Y--CO--C(.dbd.CH.sub.2)R.sup.4 ].sub.m or --C(.dbd.CH.sub.2)CO--O--C.sub.1-4 -alkyl, U and X, independently of each other, stand for CO, COO or CONH; Y and Z stand for O or NH or are absent, but Y and Z cannot be absent at the same time; n, m stand for a whole number from 0 to 4, but n and m are not 0 at the same time; R.sup.1 is H, CH.sub.3 or Cl; R.sup.2, R.sup.3 stand for H, a C.sub.1 - to C.sub.10 -alkyl or alkylene radical, which can be interrupted by O, S or NH, for a C.sub.6 - to C.sub.14 -aryl or arylene, C.sub.7 - to C.sub.14 -alkylaryl or alkylarylene or a C.sub.5 - to C.sub.8 -cycloalkyl or cycloalkylene radical; and R.sup.4 is H or a C.sub.1 - to C.sub.10 -alkyl radical, and to processes for their production. The compounds are suitable in particular for the production of adhesives, cements, composites and mouldings.
摘要翻译：本发明涉及下式的乙烯基环丙烷衍生物，其中A为 - [ - Y-CO-C（= CH2）R4] m或-C（= CH2）CO-O-C1-4烷基，U和X，独立于代表CO，COO或CONH; Y和Z代表O或NH或不存在，但Y和Z不能同时不存在; n，m表示从0到4的整数，但n和m不同时为0; R1是H，CH3或Cl; R2，R3代表H，C 1至C 10 - 烷基或亚烷基，其可被O，S或NH中断，用于C 6至C 14 - 芳基或亚芳基，C 7至C 14 - 烷基芳基或烷基亚芳基或 C5至C8-环烷基或环亚烷基; 并且R4是H或C1-至C10-烷基，并且用于其制备。该化合物特别适用于粘合剂，水泥，复合材料和模制品的生产。

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