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1. 发明授权

US06900251B2 Dental materials based on acrylic-ester phosphonic acids 有权
标题翻译：基于丙烯酸酯膦酸的牙科材料
公开(公告)号：US06900251B2
公开(公告)日：2005-05-31
申请号：US10606142
申请日：2003-06-25
申请人： Norbert Moszner , Ulrich Salz , Frank Zeuner , Jörg Zimmermann , Volker Rheinberger , Jorg Angermann , Urs Karl Fischer
发明人： Norbert Moszner , Ulrich Salz , Frank Zeuner , Jörg Zimmermann , Volker Rheinberger , Jorg Angermann , Urs Karl Fischer
IPC分类号： A61C13/087 , A61K6/00 , A61K6/083 , C07F9/38 , C08F30/02 , C08F220/54 , C08F230/02 , C09J4/00 , C09J4/02 , C09J11/04 , C09J11/06 , A61K8/00 , C07F9/09 , C08F2/46
CPC分类号： A61K6/0023 , A61K6/083 , C07F9/3808 , C08F30/02 , C08L33/00 , C08L43/02 , C08L39/06
摘要： Acrylic ester phosphonic acids of general formula (I), stereoisomers thereof and mixtures of these, wherein n is 1 or 2, on the condition that for n=1 R1 has the meaning and for n=2 R1 has the meaning R2 is a C1 to C12 alkylene radical, C4-C8 cycloalkylene radical or C7 to C15 alkylene phenylene radical; R3 is hydrogen, a C1 to C5 alkyl radical or a C1 to C5 O-alkyl radical; and R4, R5, independently of each other, each stand for a C1 to C5 alkyl radical or a C1 to C5 O-alkyl radical.
摘要翻译：在通式（I）的丙烯酸酯膦酸，其立体异构体和它们的混合物，其中n为1或2，条件是对于n = 1的R 1具有含义，n = 2 R 1具有R 2是C 1至C 12亚烷基的C 1至C 4亚烷基，C 4 C 1 -C 8亚环烷基或C 7至C 15亚烷基亚苯基; R 3是氢，C 1至C 5烷基或C 1至C 6烷基， 5 O - 烷基; 和R 4，R 5，R 5彼此独立地代表C 1至C 5烷基自由基或C 1至C 5 - O-烷基。

2. 发明申请

US20060135719A1 Self-etching dental materials based on (METH) acrylamide phosphates 有权
标题翻译：基于（METH）丙烯酰胺磷酸盐的自蚀牙科材料
公开(公告)号：US20060135719A1
公开(公告)日：2006-06-22
申请号：US11211938
申请日：2005-08-25
申请人： Norbert Moszner , Iris Lamparth , Frank Zeuner , Ulrich Salz , Angela Mucke , Jorg Zimmermann , Jorg Angermann , Volker Rheinberger
发明人： Norbert Moszner , Iris Lamparth , Frank Zeuner , Ulrich Salz , Angela Mucke , Jorg Zimmermann , Jorg Angermann , Volker Rheinberger
IPC分类号： C08F120/54
CPC分类号： A61K6/0017 , A61K6/0023 , A61K6/0029 , A61K6/083 , A61K6/09 , C08L33/26 , C08L33/04 , C08L75/04
摘要： Polymerizable dental material, characterized in that it contains at least one (meth)acrylamide phosphate of the following general formula (I): in which R1 is H or CH3; R2 is H or a C1-C4 alkyl radical or forms together with the nitrogen atom to which it is bonded and one or more atoms which belong to R3 or R3′ a heterocyclic ring; R3, R3′ independently of each other are a linear or branched aliphatic C1-C50 radical with a valency of m+n or p+n, an aromatic C6-C18 radical with a valency of m+n or p+n, or a cycloaliphatic, araliphatic or heterocyclic C3-C18 radical with a valency of m+n or p+n, wherein the carbon chains of the radical or radicals can be interrupted by O, S, CONR4, OCONH, or form together with one or more atoms which belong to R2 and the nitrogen atom, to which the R2 is bonded a heterocyclic ring, R3′ being H if p=0, and R4 being H, C1-C10 alkyl, C6-C12 aryl, C6-C10 aralkyl or a bicylic C4-C12 radical; n is 1, 2, 3 or 4 if p=0, and is 1 or 2 if p≠0; m is 1, 2, 3 or 4; p is 0, 1, 2, 3 or 4; x is 0 or S.
摘要翻译：可聚合的牙科材料，其特征在于它含有至少一种下列通式（I）的（甲基）丙烯酰胺磷酸酯：其中R 1是H或CH 3; R 2是H或C 1 -C 4烷基，或与其键合的氮原子一起形成一个或多个属于R 3或R 3'杂原子的杂原子; R 3，R 3，R 3'彼此独立地是直链或支链的脂族C 1 -C 50 - 基团具有m + n或p + n的化合价，m + n或p + n的芳族C 6 -C 18 - 基团，或脂环族基团，芳烷基或杂环C 3 -C 18 - 基团，其价态为m + n或p + n，其中基团或基团的碳链可以被O， S，CONR 4，OCONH，或与一个或多个属于R 2的原子和氮原子一起形成，R 2 O 2 >键合杂环，如果p = 0，则R 3'为H，R 4为H，C 1 -C 3 C 10 -C 12烷基，C 6 -C 12芳基，C 6 -C 10芳烷基或C 6 -C 12烷基二元C 4 -C 12 - 基团; 如果p = 0，则n为1,2,3或4，如果p <0，则为1或2; m为1,2,3或4; p是0，1，2，3或4; x是0或S.

3. 发明授权

US06353039B1 Polymerizable composite material 有权
标题翻译：可聚合复合材料
公开(公告)号：US06353039B1
公开(公告)日：2002-03-05
申请号：US09209905
申请日：1998-12-11
申请人： Volker Rheinberger , Ulrich Salz , Wolfram Höland , André Rumphorst , Kurt Grabher , Urs Karl Fischer , Marcel Schweiger , Norbert Moszner
发明人： Volker Rheinberger , Ulrich Salz , Wolfram Höland , André Rumphorst , Kurt Grabher , Urs Karl Fischer , Marcel Schweiger , Norbert Moszner
IPC分类号： A61K6083
CPC分类号： A61K6/0276 , A61K6/083 , A61K6/09 , C08F2/44 , C08K3/40 , C08K9/08 , C08L33/00 , C08L75/16
摘要： A composite material is described which contains polymerizable monomers plus a special transparent glass having high release of calcium ions and fluorine ions and, because of this release property and in particular of its optical properties, can be used as a restoration material in dentistry.
摘要翻译：描述了一种复合材料，其包含可聚合单体加上具有高释放的钙离子和氟离子的特殊透明玻璃，并且由于该释放性质，特别是其光学性质，可用作牙科中的修复材料。

4. 发明授权

US06180688B2 Ion-releasing composite material 有权
标题翻译：离子释放复合材料
公开(公告)号：US06180688B2
公开(公告)日：2001-01-30
申请号：US09210510
申请日：1998-12-11
申请人： Volker Rheinberger , Ulrich Salz , Andr{acute over (e)} Rumphorst , Kurt Grabher , Urs Karl Fischer , Norbert Moszner
发明人： Volker Rheinberger , Ulrich Salz , Andr{acute over (e)} Rumphorst , Kurt Grabher , Urs Karl Fischer , Norbert Moszner
IPC分类号： A61K6083
CPC分类号： A61K6/083
摘要： The invention relates to ion-releasing composite materials on the basis of polymerizable monomers. The material is characterized in that it contains one or more non-acid, non-ionic, hydrophilic crosslinker monomers, one or more non-acid, non-ionic, hydrophilic dilution monomers having a viscosity of ≦1 Pas and at least one ion-releasing filler. The materials are suitable in particular for use as dental materials.
摘要翻译：本发明涉及基于可聚合单体的离子释放复合材料。该材料的特征在于其含有一种或多种非酸性，非离子型亲水性交联剂单体，一种或多种非酸性，非离子型亲水稀释单体，其粘度为≥1Pa·s和至少一种离子释放填料这些材料特别适合用作牙科材料。

5. 发明授权

US09668946B2 Dental materials based on monomers having debonding-on-demand properties 有权
公开(公告)号：US09668946B2
公开(公告)日：2017-06-06
申请号：US14343297
申请日：2012-09-10
申请人： Norbert Moszner , Iris Lamparth , Thorsten Bock , Urs Karl Fischer , Ulrich Salz , Volker Rheinberger , Robert Liska
发明人： Norbert Moszner , Iris Lamparth , Thorsten Bock , Urs Karl Fischer , Ulrich Salz , Volker Rheinberger , Robert Liska
IPC分类号： A61K6/083 , A61K6/00 , C07D239/47 , C07F3/06 , C08F122/22
CPC分类号： A61K6/0835 , A61K6/0002 , A61K6/0023 , A61K6/083 , C07D239/47 , C07F3/06 , C08F122/22 , C08L33/00
摘要： The invention relates to a dental restorative material which comprises a thermolabile or photolabile polymerizable compound of Formula I: [(Z1)m-Q1-X)]k-T-[Y-Q2-(Z2)n]l Formula I, in which T represents a thermolabile or photolabile group, Z1 and Z2 in each case independently represent a polymerizable group selected from vinyl groups, CH2═CR1—CO—O— and CH2═CR1—CO—NR2— or an adhesive group selected from —Si(OR)3, —COOH, —O—PO(OH)2, —PO(OH)2, —SO2OH and —SH, wherein at least one Z1 or Z2 is a polymerizable group, Q1 in each case independently is missing or represents an (m+1)-valent linear or branched aliphatic C1-C20 radical which can be interrupted by —O—, —S—, —CO—O—, —O—CO—, —CO—NR3—, —NR3—CO—, —O—CO—NR3—, —NR3—CO—O— or —NR3—CO—NR3—, Q2 in each case independently is missing or represents an (n+1)-valent linear or branched aliphatic C1-C20 radical which can be interrupted by —O—, —S—, —CO—O—, —O—CO—, —CO—NR3—, —NR3—CO—, —O—CO—NR3—, —NR3—CO—O— or —NR3—CO—NR3—, X and Y in each case independently are missing or represent —O—, —S—, CO—O—, —O—CO—, —CO—NR3—, —NR3—CO—, —O—CO—NR3—, —NR3—CO—O— or —NR3—CO—NR3—, R, R1, R2 and R3 in each case independently represent H or a C1-C7 alkyl radical and k, l, m and n in each case independently are 1, 2 or 3.

6. 发明申请

US20140329929A1 DENTAL MATERIALS BASED ON MONOMERS HAVING DEBONDING-ON-DEMAND PROPERTIES 有权
公开(公告)号：US20140329929A1
公开(公告)日：2014-11-06
申请号：US14343297
申请日：2012-09-10
申请人： Norbert Moszner , Iris Lamparth , Thorsten Bock , Urs Karl Fischer , Ulrich Salz , Volker Rheinberger , Robert Liska
发明人： Norbert Moszner , Iris Lamparth , Thorsten Bock , Urs Karl Fischer , Ulrich Salz , Volker Rheinberger , Robert Liska
IPC分类号： A61K6/083
CPC分类号： A61K6/0835 , A61K6/0002 , A61K6/0023 , A61K6/083 , C07D239/47 , C07F3/06 , C08F122/22 , C08L33/00
摘要： The invention relates to a dental restorative material which comprises a thermolabile or photolabile polymerizable compound of Formula I: [(Z1)m-Q1-X)]k-T-[Y-Q2-(Z2)n]1 Formula I, in which T represents a thermolabile or photolabile group, Z1 and Z2 in each case independently represent a polymerizable group selected from vinyl groups, CH2═CR1—CO—O— and CH2═CR1—CO—NR2— or an adhesive group selected from —Si(OR)3, —COOH, —O—PO(OH)2, —PO(OH)2, —SO2OH and —SH, wherein at least one Z1 or Z2 is a polymerizable group, Q1 in each case independently is missing or represents an (m+1)-valent linear or branched aliphatic C1-C20 radical which can be interrupted by —O—, —S—, —CO—O—, —O—CO—, —CO—NR3—, —NR3—CO—, —O—CO—NR3—, —NR3—CO—O— or —NR3—CO—NR3—, Q2 in each case independently is missing or represents an (n+1)-valent linear or branched aliphatic C1-C20 radical which can be interrupted by —O—, —S—, —CO—O—, —O—CO—, —CO—NR3—, —NR3—CO—, —O—CO—NR3—, —NR3—CO—O— or —NR3—CO—NR3—, X and Y in each case independently are missing or represent —O—, —S—, CO—O—, —O—CO—, —CO—NR3—, —NR3—CO—, —O—CO—NR3—, —NR3—CO—O— or —NR3—CO—NR3—, R, R1, R2 and R3 in each case independently represent H or a C1-C7 alkyl radical and k, l, m and n in each case independently are 1, 2 or 3.

7. 发明授权

US07622538B2 Self-etching dental materials based on (METH) acrylamide phosphates 有权
标题翻译：基于（METH）丙烯酰胺磷酸盐的自蚀牙科材料
公开(公告)号：US07622538B2
公开(公告)日：2009-11-24
申请号：US11211938
申请日：2005-08-25
申请人： Norbert Moszner , Iris Lamparth , Frank Zeuner , Ulrich Salz , Angela Mucke , Jorg Zimmermann , Jorg Angermann , Volker M. Rheinberger
发明人： Norbert Moszner , Iris Lamparth , Frank Zeuner , Ulrich Salz , Angela Mucke , Jorg Zimmermann , Jorg Angermann , Volker M. Rheinberger
IPC分类号： C08F20/58 , C08F20/60
CPC分类号： A61K6/0017 , A61K6/0023 , A61K6/0029 , A61K6/083 , A61K6/09 , C08L33/26 , C08L33/04 , C08L75/04
摘要： Polymerizable dental material, characterized in that it contains at least one (meth)acrylamide phosphate of the following general formula (I): in which R1 is H or CH3; R2 is H or a C1-C4 alkyl radical or forms together with the nitrogen atom to which it is bonded and one or more atoms which belong to R3 or R3′ a heterocyclic ring; R3, R3′ independently of each other are a linear or branched aliphatic C1-C50 radical with a valency of m+n or p+n, an aromatic C6-C18 radical with a valency of m+n or p+n, or a cycloaliphatic, araliphatic or heterocyclic C3-C18 radical with a valency of m+n or p+n, wherein the carbon chains of the radical or radicals can be interrupted by O, S, CONR4, OCONH, or form together with one or more atoms which belong to R2 and the nitrogen atom, to which the R2 is bonded a heterocyclic ring, R3′ being H if p=0, and R4 being H, C1-C10 alkyl, C6-C12 aryl, C6-10 aralkyl or a bicylic C4-C12 radial; n is 1, 2, 3 or 4 if p=0, and is 1 or 2 if p ≠0; m is 1, 2, 3 or 4; p is 0, 1, 2, 3 or 4; x is 0 or S.
摘要翻译：可聚合牙科材料，其特征在于其含有至少一种下列通式（I）的（甲基）丙烯酰胺磷酸酯：其中R1是H或CH3; R2是H或C1-C4烷基或与其键合的氮原子一起形成一个或多个属于R3或R3'杂原子的原子; R 3，R 3'彼此独立地为具有m + n或p + n价的直链或支链脂族C 1 -C 50基团，价数为m + n或p + n的芳族C 6 -C 18基团或脂环族，芳脂族或杂环C 3 -C 18基，其价态为m + n或p + n，其中基团或基团的碳链可被O，S，CONR 4，OCONH中断，或与一个或多个原子一起形成属于R2和氮原子，R 2与杂环结合，如果p = 0，则R3'为H，R4为H，C1-C10烷基，C6-C12芳基，C6-10芳烷基或双 C4-C12径向; 如果p = 0，则n为1,2,3或4，如果p为0，则为1或2; m为1,2,3或4; p是0，1，2，3或4; x是0或S.

8. 发明申请

US20060130701A1 Hydrolysis-stable self-etching single-component dental adhesive 有权
标题翻译：水解稳定自腐蚀单组份牙科粘合剂
公开(公告)号：US20060130701A1
公开(公告)日：2006-06-22
申请号：US11212065
申请日：2005-08-25
申请人： Ulrich Salz , Angela Mucke , Jorg Zimmermann , Norbert Moszner , Frank Zeuner , Volker Rheinberger
发明人： Ulrich Salz , Angela Mucke , Jorg Zimmermann , Norbert Moszner , Frank Zeuner , Volker Rheinberger
IPC分类号： C09K3/00
CPC分类号： A61K6/083 , A61K6/0017 , A61K6/0023 , A61K6/0835 , C08L33/00
摘要： Dental composition containing (i) at least one acid (meth)acrylamide monomer which has two or more polymerizable groups, (ii) at least one acid monomer which has only one polymerizable group and (iii) at least one polymerization initiator.
摘要翻译：含有（i）至少一种具有两个或多个可聚合基团的酸（甲基）丙烯酰胺单体，（ii）至少一种仅具有一个可聚合基团的酸单体和（iii）至少一种聚合引发剂）的牙科组合物。

9. 发明授权

US07851515B2 Hydrolysis-stable self-etching single-component dental adhesive 有权
标题翻译：水解稳定自腐蚀单组份牙科粘合剂
公开(公告)号：US07851515B2
公开(公告)日：2010-12-14
申请号：US11212065
申请日：2005-08-25
申请人： Ulrich Salz , Angela Mucke , Jorg Zimmermann , Norbert Moszner , Frank Zeuner , Volker Rheinberger
发明人： Ulrich Salz , Angela Mucke , Jorg Zimmermann , Norbert Moszner , Frank Zeuner , Volker Rheinberger
IPC分类号： C07F9/06 , C07F9/113 , C07F9/143 , A61K6/083 , A61K6/08 , A61K6/00 , A61C5/00 , C08F20/58 , C08F220/54
CPC分类号： A61K6/083 , A61K6/0017 , A61K6/0023 , A61K6/0835 , C08L33/00
摘要： Dental composition containing (i) at least one acid (meth)acrylamide monomer which has two or more polymerizable groups, (ii) at least one acid monomer which has only one polymerizable group and (iii) at least one polymerization initiator.
摘要翻译：含有（i）至少一种具有两个或多个可聚合基团的酸（甲基）丙烯酰胺单体，（ii）至少一种仅具有一个可聚合基团的酸单体和（iii）至少一种聚合引发剂）的牙科组合物。

10. 发明申请

US20080277814A1 Polymerizable compositions with acylgermanium compounds 有权
标题翻译：具有酰基锗化合物的可聚合组合物
公开(公告)号：US20080277814A1
公开(公告)日：2008-11-13
申请号：US11902865
申请日：2007-09-26
申请人： Norbert Moszner , Ulrich Salz , Urs Karl Fischer , Robert Liska , Heinrich Gruber , Beate Ganster
发明人： Norbert Moszner , Ulrich Salz , Urs Karl Fischer , Robert Liska , Heinrich Gruber , Beate Ganster
IPC分类号： A61C13/087
CPC分类号： C08F2/50 , A61K6/083 , C08F4/72 , Y10S522/908 , C08L33/00
摘要： Composition with at least one polymerizable binder and at least one polymerization initiator, which contains at least one acylgermanium compound according to general Formula (I), in which R0 is a substituted or unsubstituted C1-18-alkyl radical or an acyl group; R1 and R2 are H, an acyl group or have one of the meanings given for R3; R3 is a branched or linear C1-18-alkyl radical which can be unsubstituted or substituted one or more times by —O—, —NH—, —NR—, —S— or interrupted by other groups, trimethylsilyl, hal-(CH3)2Si—[OSi(CH3)2]r−, (CH3)3Si—[OSi(CH3)2]r—, —COOH, —COO—R10, —CO—NR11R12, —CO-vinyl, —CO-phenyl, phenyl-C1-4-alkyl, phenyl, naphthyl or biphenyl, C5-12 cycloalkyl, a 5 or 6-membered O, S or N-containing heterocyclic ring, halogen, OH, an aromatic C6-30 radical which can be substituted or unsubstituted and/or interrupted by O, S or —NR—, or a branched, cyclic or linear C1-20 alkyl, -alkenyl, -alkoxy or -alkenoxy radical; m is 1, 2 or 3; n is 0 or 1 and p is 0 or 1; wherein in each case two of the radicals R0, R1, R2 or R3 can be connected to each other accompanied by the formulation of a 5 to 8 member ring; and the use of acylegermanium compounds of Formula (I), for example, as initiator for radical polymerization.
摘要翻译：含有至少一种可聚合粘合剂和至少一种聚合引发剂的组合物，其含有至少一种根据通式（I）的酰基锗化合物，其中R 0是取代或未取代的C 1 -18-烷基或酰基; R 1和R 2均为H，酰基或具有R 3给出的含义之一; R 3是支链或直链C 1-18 - 烷基，其可以是未取代的或被-O - ， - NH-，-NR- ，-S-或被其它基团中断，三甲基甲硅烷基，卤代（CH 3）2 Si- [OSi（CH 3）3）（CH 3）3 Si- [OSi（CH 3）3） -COOH，-COO-R 10，-CO-NR， - ， - SO 2 - ， - 11- 12，-CO-乙烯基，-CO-苯基，苯基-C 1-4 - 烷基，苯基，萘基或联苯基，C

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