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1. 发明授权

US4542086A Color diffusion transfer element with hydroquinone type compound 失效
标题翻译：彩色扩散转移元件与氢醌类化合物
公开(公告)号：US4542086A
公开(公告)日：1985-09-17
申请号：US266781
申请日：1981-05-26
申请人： Nobutaka Ohki , Motohiko Tsubota , Masakazu Morigaki , Tsutomu Hamaoka
发明人： Nobutaka Ohki , Motohiko Tsubota , Masakazu Morigaki , Tsutomu Hamaoka
IPC分类号： G03C8/36 , G03C8/00 , G03C1/40 , G03C5/54
CPC分类号： G03C8/00
摘要： A color diffusion transfer photographic element comprising (a) a light sensitive component containing at least one light sensitive silver halide emulsion layer associated with a dye releasing redox compound, (b) a dye image receiving component and (c) an alkaline processing composition component, wherein the improvement comprises at least one of said components (a), (b) and (c) containing a diffusible hydroquinone type compound having the half wave potential of polarography in the range of from -300 mV to -380 mV measured using a saturated calomel electrode as a reference electrode in a buffer solution having a pH of 13.0.degree. at 25.degree. C. The diffusible hydroquinone type compound has excellent gradation control properties and is particularly suitable for controlling gradation of the toe part in a photographic characteristic curve of a color diffusion transfer photograph. A typical example of a diffusible hydroquinone compound of the invention is: ##STR1##
摘要翻译：一种彩色扩散转印照相材料，包括（a）含有至少一种与释放染料的氧化还原化合物相关的感光卤化银乳剂层的光敏组分，（b）染料影像接收组分和（c）碱性处理组合物组分，其中所述改进包括至少一种所述组分（a），（b）和（c）中的至少一种，其含有具有-300mV至-380mV范围内极谱半波电位的可扩散氢醌型化合物，其使用饱和甘汞电极作为参考电极，在25℃下pH为13.0的缓冲溶液中。可扩散氢醌型化合物具有优异的灰度控制性能，特别适用于控制颜色的照相特征曲线中的脚趾部分的灰度扩散转印照片。本发明的可扩散氢醌化合物的典型实例是：

2. 发明授权

US4429031A Color diffusion transfer photographic element 失效
标题翻译：彩色扩散转印照相材料
公开(公告)号：US4429031A
公开(公告)日：1984-01-31
申请号：US193495
申请日：1980-10-03
申请人： Motohiko Tsubota , Masakazu Morigaki , Tsutomu Hamaoka , Nobutaka Ohki
发明人： Motohiko Tsubota , Masakazu Morigaki , Tsutomu Hamaoka , Nobutaka Ohki
IPC分类号： G03C5/29 , G03C5/30 , G03C7/00 , G03C8/36 , G03C5/54
CPC分类号： G03C5/3021 , G03C8/36
摘要： A color diffusion transfer photographic element is disclosed, comprising (a) a photosensitive component containing at least one photosensitive silver halide emulsion layer combined with a DRR compound, (b) a dye image receiving component and (c) an alkaline processing composition component, wherein the improvement comprises at least one of said components (a), (b), and (c) containing a compound represented by the formula (I) ##STR1## wherein R represents a substituted or unsubstituted alkyl group having from 1 to 18 carbon atoms.
摘要翻译：公开了一种彩色扩散转印照相材料，其包含（a）含有至少一种与DRR化合物组合的感光卤化银乳剂层的感光组分，（b）染料影像接收组分和（c）碱性处理组合物组分，其中改进包括含有式（I）表示的化合物的所述组分（a），（b）和（c）中的至少一种：其中R表示取代或未取代的烷基，其具有1至 18个碳原子。

3. 发明授权

US4264720A Color photographic light-sensitive material 失效
标题翻译：彩色摄影感光材料
公开(公告)号：US4264720A
公开(公告)日：1981-04-28
申请号：US108091
申请日：1979-12-28
申请人： Tsutomu Hamaoka , Masakazu Morigaki , Satoru Sawada , Nobutaka Ohki , Kotaro Nakamura
发明人： Tsutomu Hamaoka , Masakazu Morigaki , Satoru Sawada , Nobutaka Ohki , Kotaro Nakamura
IPC分类号： G03C7/26 , C07D311/60 , C07D311/72 , G03C7/38 , G03C7/392 , G03C1/40 , G03C7/00
CPC分类号： G03C7/39268 , C07D311/72
摘要： A silver halide color photographic light-sensitive material which contains a 3-anilino-5-pyrazolone type of magenta coupler and a novel dye image-stabilizing agent of the general formula (I) as hereinafter defined.
摘要翻译：含有3-苯胺基-5-吡唑啉酮型品红成色剂的卤化银彩色照相感光材料和下文定义的通式（I）的新型染料影像稳定剂。

4. 发明授权

US4770987A Silver halide color photographic materials containing an antisain agent and a magenta coupler in lipophilic fine particles 失效
标题翻译：在亲脂性细颗粒中含有防锈剂和品红色成色剂的卤化银彩色照相材料
公开(公告)号：US4770987A
公开(公告)日：1988-09-13
申请号：US943035
申请日：1986-12-17
申请人： Osamu Takahashi , Hideaki Naruse , Masakazu Morigaki , Nobutaka Ohki , Tadahisa Sato
发明人： Osamu Takahashi , Hideaki Naruse , Masakazu Morigaki , Nobutaka Ohki , Tadahisa Sato
IPC分类号： G03C7/26 , G03C7/32 , G03C7/38 , G03C7/388 , G03C7/392 , G03C1/06
CPC分类号： G03C7/39236
摘要： A silver halide color photographic material is disclosed, comprising a support having provided thereon at least one silver halide emulsion layer having dispersed therein lipophilic fine particles containing an image dye forming lipophilic coupler, wherein the lipophilic fine particles further contain at least one lipophilic compound having a water-solubility of not more than 1% by weight at 25.degree. C. and represented by formula (I):R.sub.0 SO.sub.2 X (I)wherein R.sub.0 represents a substituted or unsubstituted alkyl, aryl or heterocyclic group having 8 or more total carbon atoms; and X represents a hydrogen atom, an alkali metal atom, an alkaline earth metal atom, a nitrogen-containing organic base, ammonium or a group represented by formula (A): ##STR1## wherein R.sub.1 represents a hydrogen atom or a substituted or unsubstituted alkyl, aryl or heterocyclic group; R.sub.2 represents a hydrogen atom, a halogen atom or a substituted or unsubstituted alkyl, aryl, acyloxy or sulfonyl group; and R.sub.3 represents a hydrogen atom or a hydrolyzable group.The material prevents stain formation on the non-color-developed areas due to aging and the like after processing.
摘要翻译：公开了一种卤化银彩色照相材料，其包括其上提供有至少一个卤化银乳剂层的载体，所述卤化银乳剂层分散有含有形成亲脂性成色剂的图像染料的亲脂性微粒，其中亲脂性微粒还含有至少一种亲脂性化合物，在25℃下水溶性不超过1重量％，由式（I）表示：R 0 SO 2 X（I）其中R 0表示具有8个或更多总碳原子的取代或未取代的烷基，芳基或杂环基; X表示氢原子，碱金属原子，碱土金属原子，含氮有机碱，铵或式（A）表示的基团：其中R 1表示氢原子或取代或未取代的烷基，芳基或杂环基; R 2表示氢原子，卤素原子或取代或未取代的烷基，芳基，酰氧基或磺酰基; 并且R 3表示氢原子或可水解基团。该材料防止由于加工后的老化等而在非显色区域上形成污斑。

5. 发明授权

US4983507A Silver halide color photographic materials 失效
公开(公告)号：US4983507A
公开(公告)日：1991-01-08
申请号：US262603
申请日：1988-10-26
申请人： Osamu Takahashi , Hideaki Naruse , Masakazu Morigaki , Nobutaka Ohki , Nobuo Furutachi
发明人： Osamu Takahashi , Hideaki Naruse , Masakazu Morigaki , Nobutaka Ohki , Nobuo Furutachi
IPC分类号： G03C7/26 , G03C7/38 , G03C7/392
CPC分类号： G03C7/3805 , G03C7/39252
摘要： The present invention provides silver halide color photographic materials having a layer which contains at least one magenta color image-forming oleophilic coupler of the following formulae (I) and/or (II) and at least one of the following formula (III): ##STR1## in which Ar represents a phenyl group which is substituted by at least one substituent selected from the group consisting of a halogen atom, an alkyl group, an alkoxy group, an alkoxycarbonyl group and a cyano group; Y represents an acylamino group or an anilino group; and Z.sub.1 represents a group capable of being removed by coupling, ##STR2## in which X represents a hydrogen atom or a substituent; Z.sub.2 represents a hydrogen atom or a group capable of being removed by coupling;W represents a hydrogen atom, an acyl group or an aliphatic or aromatic sulfonyl group;Za and Zb each represent a methine group, a substituted methine group or --N.dbd.; andX, Z.sub.2 or the substituted methine of Za or Zb may form a dimer or higher polymer, ##STR3## in which A represents an alkyl group, an aryl group, a heterocyclic group, an acyl group, an alkoxy group, an aryloxy group, a heterocyclic oxy group, an alkylthio group, an arylthio group or an amino group, which may be substituted or unsubstituted; R.sub.1 and R.sub.2 each independently represents a hydrogen atom or a substituted or unsubstituted alkyl group; R.sub.3a and R.sub.3b each represents a hydrogen atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group or an arylthio group; R.sub.4 represents an alkyl group, an aryl group or a heterocyclic group; and D represents an oxygen atom or a sulfur atom.The use of the combination of the magenta coupler(s) of the formulae (I) and/or (II) and the stain-inhibitory additive(s) of the formula (II) provides photographic light-sensitive materials that are almost free from stains when such materials are preserved for a long period of time after having been exposed, developed and then photographically processed.

6. 发明授权

US4704350A Silver halide color photographic material 失效
标题翻译：卤化银彩色照相材料
公开(公告)号：US4704350A
公开(公告)日：1987-11-03
申请号：US947305
申请日：1986-12-29
申请人： Masakazu Morigaki , Nobutaka Ohki , Osamu Takahashi , Hideaki Naruse
发明人： Masakazu Morigaki , Nobutaka Ohki , Osamu Takahashi , Hideaki Naruse
IPC分类号： G03C7/30 , G03C7/392 , G03C7/38
CPC分类号： G03C7/301 , G03C7/39228
摘要： A silver halide color photographic material is disclosed, comprising a support having provided thereon at least one silver halide emulsion layer having dispersed therein lipophilic fine particles containing a certain type of lipophilic pyrazoloazole coupler, and said lipophilic fine particles further contain at least one lipophilic mercapto compound represented by formula (II)R--SH (II)wherein R represents a substituted or unsubstituted alkyl, alkenyl, or aryl group, and said compound of formula (II) has a water solubility of not more than 1% by weight at 25.degree. C.The material is prevented from forming color stain caused by processing solution components that become incorporated into the materials during development processing.
摘要翻译：公开了一种卤化银彩色照相材料，其包括其上提供有至少一个卤化银乳剂层的载体，其中分散有含有某种亲油性吡唑并唑成色剂的亲脂性微粒，并且所述亲脂性细颗粒还含有至少一种亲脂性巯基化合物由式（II）表示的R-SH（II）其中R表示取代或未取代的烷基，烯基或芳基，所述式（II）化合物在25℃下的水溶解度不超过1重量％ C.防止材料在显影处理过程中由加工溶液成分引起的材料形成色斑。

7. 发明授权

US5041365A Silver halide color photographic materials 失效
标题翻译：卤化银彩色照相材料
公开(公告)号：US5041365A
公开(公告)日：1991-08-20
申请号：US555676
申请日：1990-07-19
申请人： Osamu Takahashi , Hideaki Naruse , Masakazu Morigaki , Nobutaka Ohki , Nobuo Furutachi
发明人： Osamu Takahashi , Hideaki Naruse , Masakazu Morigaki , Nobutaka Ohki , Nobuo Furutachi
IPC分类号： G03C7/26 , G03C7/38 , G03C7/392
CPC分类号： G03C7/3805 , G03C7/39252
摘要： The present invention provides silver halide color photographic materials having a layer which contains at least one magenta color image-forming oleophilic coupler of the following formulae (I) and/or (II) and at least one of the following formula (III): ##STR1## in which Ar represents a phenyl group which is substituted by at least one substituent selected from the group consisting of a halogen atom, an alkyl group, an alkoxy group, an alkoxycarbonyl group and a cyano group; Y represents an acylamino group or an anilino group; and Z.sub.1 represents a group capable of being removed by coupling, ##STR2## in which X represents a hydrogen atom or a substituent; Z.sub.2 represents a hydrogen atom or a group capable of being removed by coupling;W represents a hydrogen atom, an acyl group or an aliphatic or aromatic sulfonyl group;Za and Zb each represent a methine group, a substituted methine group or --N.dbd.; andX, Z.sub.2 or the substituted methine of Za or Zb may form a dimer or higher polymer, ##STR3## in which A represents an alkyl group, an aryl group, a heterocyclic group, an acyl group, an alkoxy group, an aryloxy group, a heterocyclic oxy group, an alkylthio group, an arylthio group or an amino group, which may be substituted or unsubstituted; R.sub.1 and R.sub.2 each independently represents a hydrogen atom or a substituted or unsubstituted alkyl group; R.sub.3a and R.sub.3b each represents a hydrogen atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group or an arylthio group; R.sub.4 represents an alkyl group, an aryl group or a heterocyclic group; and D represents an oxygen atom or a sulfur atom.The use of the combination of the magenta couplers(s) of the formulae (I) and/or (II) and the stain-inhibitory additive(s) of the formula (III) provides photographic light-sensitive materials that are almost free from stains when such materials are preserved for a long period of time after having been exposed, developed and then photographically processed.

8. 发明授权

US4366226A Color photographic sensitive material with sulfonamidophenol scavenger 失效
标题翻译：具有磺酰胺酚清除剂的彩色感光材料
公开(公告)号：US4366226A
公开(公告)日：1982-12-28
申请号：US285721
申请日：1981-07-22
申请人： Tsutomu Hamaoka , Osamu Takahashi , Tooru Harada , Minoru Sakai , Nobutaka Ohki
发明人： Tsutomu Hamaoka , Osamu Takahashi , Tooru Harada , Minoru Sakai , Nobutaka Ohki
IPC分类号： G03C7/26 , C07C67/00 , C07C301/00 , C08F28/00 , G03C7/392 , G03C8/08 , G03C8/10 , G03C1/40 , G03C1/10 , G03C5/54
CPC分类号： G03C7/39216 , G03C8/10
摘要： A color photographic silver halide light-sensitive material is described comprising a compound represented by formula (I) ##STR1## wherein R.sup.1 and R.sup.3 can each represent an unsubstituted or substituted alkyl group or an unsubstituted or substituted aryl group, R.sup.2 can represent an unsubstituted or substituted alkyl group, R.sup.4 and R.sup.5 can each represent a hydrogen atom, an unsubstituted or substituted alkyl group, an unsubstituted or substituted aryloxy group, an unsubstituted or substituted alkylthio group, an unsubstituted or substituted arylthio group, a halogen atom, or an acylamino group, and R.sup.1 and R.sup.2, R.sup.1 and R.sup.4, or R.sup.2 and R.sup.5 together can represent atoms forming a condensed ring structure together with the benzene ring of formula (I), provided that the total of carbon atom numbers in R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 is at least 16.
摘要翻译：描述了一种彩色照相卤化银感光材料，其包含由式（I）表示的化合物（I），其中R 1和R 3各自表示未取代或取代的烷基或未取代或取代的芳基，R 2可以表示未取代或取代的烷基，R4和R5各自表示氢原子，未取代或取代的烷基，未取代或取代的芳氧基，未取代或取代的烷硫基，未取代或取代的芳硫基，卤素原子或酰基氨基，R1和R2，R1和R4，或R2和R5一起可以表示与式（I）的苯环一起形成稠环结构的原子，条件是R1，R2， R3，R4和R5至少为16。

9. 发明授权

US5478704A Method for forming color images 失效
标题翻译：彩色图像形成方法
公开(公告)号：US5478704A
公开(公告)日：1995-12-26
申请号：US291459
申请日：1994-08-17
申请人： Masato Taniguchi , Nobutaka Ohki , Mitsuru Yamamoto , Akimitsu Haijima
发明人： Masato Taniguchi , Nobutaka Ohki , Mitsuru Yamamoto , Akimitsu Haijima
IPC分类号： G03C7/305 , G03C1/035 , G03C7/00 , G03C7/30 , G03C7/413 , G03C5/18 , G03C5/26
CPC分类号： G03C7/413 , G03C7/3022 , G03C7/3029 , G03C7/305 , Y10S430/158
摘要： i) A method of forming color images improved in color reproducibility and sharpness, which comprises providing a silver halide color photographic material which has on a support at least one emulsion layer unit constituted of at least two silver halide emulsion layers having the same color sensitivity and different photographic speeds, and which contains at least one DIR compound represented by the following general formula (II) in at least one layer selected from said emulsion layer unit and other constituent layers; exposing said color photographic material, and processing said color photographic material with a color developer containing at least one compound represented by the following general formula (I): ##STR1## wherein R.sub.1 represents an alkyl group or a hydroxyalkyl group containing; R.sub.2 represents an alkylene group containing, or a straight-chain or branched hydroxyalkyiene group containing 3 to 6 carbon atoms; R.sub.3 represents a substituent group; n represents 0 or an integer from 1 to 4;A--Q (II)with the substituents as defined herein the specification.
摘要翻译： i）形成颜色再现性和锐度提高的彩色图像的方法，其包括提供卤化银彩色照相材料，所述卤化银彩色照相材料在支持体上具有由至少两个具有相同颜色敏感度的卤化银乳剂层构成的乳剂层单元，不同的摄影速度，并且在选自所述乳剂层单元和其它构成层中的至少一层中含有至少一种由以下通式（II）表示的DIR化合物; 曝光所述彩色照相材料，并用含有至少一种由以下通式（I）表示的化合物的显色剂处理所述彩色照相材料：其中R 1表示烷基或含有羟基烷基; R2表示含有或含有3〜6个碳原子的直链或支链羟基亚烷基的亚烷基; R3表示取代基; n表示0或1至4的整数; 具有如本说明书所定义的取代基的A-Q（II）。

10. 发明授权

US5356763A Silver halide color photographic material 失效
标题翻译：卤化银彩色照相材料
公开(公告)号：US5356763A
公开(公告)日：1994-10-18
申请号：US24437
申请日：1993-03-01
申请人： Osamu Takahashi , Nobutaka Ohki
发明人： Osamu Takahashi , Nobutaka Ohki
IPC分类号： G03C1/035 , G03C7/30 , G03C7/38 , G03C7/392 , G03C7/407 , G03C1/46
CPC分类号： G03C7/3003
摘要： A silver halide color photographic material enables rapid processing, provides a high quality image and has excellent light fastness under extensive conditions, even under high humidity comprises a support, provided thereon at least three silver halide emulsion layers each containing at least one different coupler for forming a different dye by a coupling reaction with the oxidation product of an aromatic primary amine developing agent and each having a different light sensitivity, and at least one anti-color mixing layer provided between each of the emulsion layers and comprising a light-insensitive layer, wherein at least one of the above silver halide emulsion layers contains silver halide grains having a silver chloride content of 90 mole % or more and a magenta coupler represented by the following formula (I) and at least two of the anti-color mixing layers contain at least one anti-color mixing agent having a molecular weight of 350 or more and at least one high boiling organic solvent having the dielectric constant of 5.0 or more: ##STR1## wherein R.sub.1 represents a hydrogen atom or a substituent; Z.sub.a, Z.sub.b, and Z.sub.c each represent methine, substituted methine, .dbd.N--, or --NH--; Y represents a hydrogen atom or a group capable of splitting off upon a coupling reaction with the oxidation product of a developing agent; provided that a dimer or polymer may be formed via R.sub., Y or Z.sub.a, Z.sub.b or Z.sub.c each of which is a substituted methine.
摘要翻译：卤化银彩色照相材料能够快速加工，提供高质量的图像并且在广泛的条件下具有优异的耐光性，即使在高湿度下也包含一个载体，其上设置有至少三个卤化银乳剂层，每个卤化银乳剂层含有至少一个不同的成色剂通过与芳族伯胺显影剂的氧化产物的偶联反应并且各自具有不同的光敏感性的不同的染料，以及设置在每个乳剂层之间并包含不透光层的至少一个防混色层，其中上述卤化银乳剂层中的至少一种含有氯化银含量为90摩尔％以上的卤化银颗粒和由下式（I）表示的品红色偶联剂，并且至少两种防混色层含有至少一种分子量为350以上的至少一种抗混色剂和至少一种高沸点有机物介电常数为5.0以上的醇类：其中R1表示氢原子或取代基;（I） Za，Zb和Zc各自表示次甲基，取代的次甲基，= N-或-NH-; Y表示氢原子或与显影剂的氧化产物偶联反应时可分解的基团; 条件是可以经由R，Y或Za，Zb或Zc形成二聚体或聚合物，其各自为取代的次甲基。

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