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1. 发明授权

US4914002A Silver halide photographic material 失效
标题翻译：卤化银照相材料
公开(公告)号：US4914002A
公开(公告)日：1990-04-03
申请号：US267469
申请日：1988-11-04
申请人： Nobuaki Inoue , Hisashi Okada , Shigeo Hirano , Kimitaka Kameoka , Tetsuo Yoshida , Morio Yagihara
发明人： Nobuaki Inoue , Hisashi Okada , Shigeo Hirano , Kimitaka Kameoka , Tetsuo Yoshida , Morio Yagihara
IPC分类号： G03C1/06 , G03C1/16
CPC分类号： G03C1/061 , G03C1/16
摘要： A silver halide negative photographic material comprising a support having thereon at least one silver halide emulsion layer, at least one hydrophilic colloidal layer thereof containing (1) a hydrazine derivative, (2) a compound substantially having no absorption maximum in the visible light region represented by formula (I): ##STR1## wherein Z.sup.11, Z.sup.12, R.sup.11, R.sup.12 X and n are as defined in the specification, and (3) at least one compound represented by formula (II) or (III): ##STR2## wherein R.sub.1, R.sub.2, R.sub.3 and Q are as defined in the specification; and ##STR3## wherein R.sub.21, R.sub.22, R.sub.23, and R.sub.24, are as defined in the specification. The photographic material can be processed with a stable developer to provide an ultra-high contrast image without reduction in sensitivity, gamma or maximum density or the appearance of black pepper. The photographic material is excellent in pressure properties and anti-blocking properties.
摘要翻译：一种卤化银负型照相材料，其包含其上具有至少一个卤化银乳剂层的载体，至少一种亲水性胶体层，其含有（1）肼衍生物，（2）在可见光区域中基本上不具有最大吸收的化合物通式（I）：其中Z11，Z12，R11，R12X和n如说明书中所定义，其中（I）至少一种由式（II）或（III）表示的化合物：（II）其中R1，R2，R3和Q如说明书中所定义; 和（III）其中R 21，R 22，R 23和R 24如说明书中所定义。可以用稳定的显影剂处理照相材料以提供超高对比度图像，而不降低灵敏度，γ或最大密度或黑胡椒的外观。照相材料的压力特性和防粘连性优异。

2. 发明授权

US5142029A Silver halide photographic material containing a compound with variable development restraining ability 失效
标题翻译：含有可变发展限制能力的化合物的银色摄影材料
公开(公告)号：US5142029A
公开(公告)日：1992-08-25
申请号：US741229
申请日：1991-08-05
申请人： Keiichi Adachi , Shingo Sato , Shigeo Hirano , Koki Nakamura , Morio Yagihara , Isamu Ito , Tadashi Ikeda , Kenichi Kuwabara
发明人： Keiichi Adachi , Shingo Sato , Shigeo Hirano , Koki Nakamura , Morio Yagihara , Isamu Ito , Tadashi Ikeda , Kenichi Kuwabara
IPC分类号： C07C51/15 , C07C65/17 , C07D249/20 , C07D257/04 , C07D403/06 , G03C1/43 , G03C7/305
CPC分类号： C07D257/04 , C07C317/00 , C07C51/15 , C07C65/17 , C07D249/20 , C07D403/06 , G03C1/43 , G03C7/305 , G03C2005/168 , G03C7/30541 , Y10S430/156 , Y10S430/158
摘要： The compounds in a preferred form are represented by general formula (I): ##STR1## wherein A and A' are each a group which can be hydrolyzed by hydrogen or alkali; X, Y and Z are each hydrogen, a halogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryl group, a thioalkyl group or an electron-withdrawing group; PUG is a group released by a reaction with a light-exposed silver halide and/or the oxidized product of the developing agent, Time is a timing group; Time.sub.t PUG is a group released as .crclbar.TimePUG first when the oxidation-reduction moiety causes a cross reaction during the development and becomes an oxidized product, and is bonded to the benzene nucleus via a sulfur atom, a nitrogen atom or a selenium atom; and t is 0 or 1.
摘要翻译：优选形式的化合物由通式（I）表示：其中A和A'各自是可以被氢或碱水解的基团; X，Y和Z各自为氢，卤素原子，取代或未取代的烷基，取代或未取代的烷氧基，取代或未取代的芳基，硫代烷基或吸电子基团; PUG是通过与曝光的卤化银和/或显影剂的氧化产物反应释放的基团，时间是定时组; TimetPUG是当氧化还原部分在显影期间引起交叉反应而变成氧化产物时首先发布为（ - ）TimePUG的基团，并且通过硫原子，氮原子或硒原子与苯核键合; t为0或1。

3. 发明授权

US4767692A Silver halide photographic material 失效
公开(公告)号：US4767692A
公开(公告)日：1988-08-30
申请号：US484
申请日：1987-01-05
申请人： Yoshio Inagaki , Morio Yagihara , Shigeo Hirano
发明人： Yoshio Inagaki , Morio Yagihara , Shigeo Hirano
IPC分类号： C07D295/215 , G03C1/06 , G03C1/485 , G03C1/42
CPC分类号： C07D295/215 , G03C1/061 , G03C1/48561
摘要： A novel silver halide photographic material is provided comprising a support and at least one silver halide photographic emulsion layer formed thereon and containing in said photographic emulsion layer or at least one hydrophilic colloid layer a compound represented by formula (I): ##STR1## wherein R.sup.1 and R.sup.2 may be the same or different and each represents a hydrogen atom, an aliphatic residual group, an aromatic residual group, or a heterocyclic residual group; R.sup.3 represents a hydrogen atom or an aliphatic residual group; L.sub.1 represents a divalent aliphatic group, a divalent aromatic group, or a divalent heterocyclic group; L.sub.2 represents --O--, --CONR--, --NRCO--, --SO.sub.2 NR--, --NRSO.sub.2 --, --OCO--, --COO--, --S--, --NR--, --CO--, --SO--, --SO.sub.2 --, --OCOO--, --NRCONR'--, --NRCOO--, --OCONR--, or --NRSO.sub.2 NR'-- (in which R and R' each represents a hydrogen atom, an alkyl group or an aryl group); l and m each represents an integer of 1 or 2; n represents an integer of 0 or 1; and A represents a residual group which is obtained by removing hydrogen atoms from Ar or B in a compound represented by formula (II), provided that when m=1, one hydrogen atom is removed; when m=2, two hydrogen atoms are removed: ##STR2## wherein Ar represents an aryl group; B represents a formyl group, an acyl group, an alkyl or arylsulfonyl group, an alkyl or arylsulfinyl group, a carbamoyl group, a sulfamoyl group, an alkoxy or aryloxycarbonyl group, a sulfinamoyl group, an alkoxysulfonyl group, a thioacyl group, a thiocarbamoyl group, or a heterocyclic group; and R.sub.0 and R.sub.00 each represents a hydrogen atom or one of R.sub.0 and R.sub.00 represents a hydrogen atom and the other represents a substituted or unsubstituted alkylsulfonyl group, a substituted or unsubstituted arylsulfonyl group or a substituted or unsubstituted acyl group, with the proviso that B, R.sub.00 and the nitrogen atom to which B and R.sub.00 are bonded may together form a partial structure of hydrazone (--N.dbd.C

4. 发明授权

US4740453A Silver halide photosensitive material containing a compound capable of releasing a photographically useful group 失效
标题翻译：含有能释放摄影有用基团的化合物的卤化银感光材料
公开(公告)号：US4740453A
公开(公告)日：1988-04-26
申请号：US813308
申请日：1985-12-24
申请人： Koki Nakamura , Shigeo Hirano , Tadashi Ikeda , Keiji Mihayashi , Mitsunori Ono , Toshiro Takahashi , Ken-ichi Kuwabara , Morio Yagihara , Isamu Itoh
发明人： Koki Nakamura , Shigeo Hirano , Tadashi Ikeda , Keiji Mihayashi , Mitsunori Ono , Toshiro Takahashi , Ken-ichi Kuwabara , Morio Yagihara , Isamu Itoh
IPC分类号： G03C1/43 , G03C7/305 , G03C1/40 , G03C5/54
CPC分类号： G03C1/43 , G03C7/305 , G03C2005/168 , Y10S430/156 , Y10S430/158 , Y10S430/16
摘要： A silver halide photosensitive material is described, comprising a support and at least one silver halide emulsion layer, wherein said emulsion layer or another layer contains a compound represented by formula (I) ##STR1## wherein X represents an atomic group forming a redox center of benzene type having substituents by linking with C.sub.A and C.sub.B, and which does not enable Time-PUG to be released until the redox center is oxidized during development processing; EWG represents an electron withdrawing group having a Hammet's .sigma. para value exceeding 0.3; C.sub.A and C.sub.B each represents a carbon atom; R.sub.1 and R.sub.2 each represents a hydrogen atom or a suitable substituent; Time represents a timing group connecting to C.sub.B through a sulfur, nitrogen, or selenium atom thereof, t is an integer of 0 or 1, and when t=0, Time is a chemical bond; PUG represents a photographically useful group and connects to C.sub.B through a sulfur, nitrogen, or selenium atom thereof when t=0; and n is an integer of 0 or 1.
摘要翻译：描述了卤化银感光材料，其包括载体和至少一种卤化银乳剂层，其中所述乳剂层或另一层含有由式（I）表示的化合物（I），其中X表示形成通过与CA和CB连接而具有取代基的苯类氧化还原中心，并且不能使Time-PUG释放直到氧化还原中心在显影处理期间被氧化; EWG代表Hammet sigma值超过0.3的吸电子基团; CA和CB各自表示碳原子; R1和R2各自表示氢原子或适当的取代基; 时间表示通过其硫，氮或硒原子与CB连接的定时基团，t为0或1的整数，当t = 0时，为化学键; PUG表示当t = 0时，通过其硫，氮或硒原子连接CB; n为0或1的整数。

5. 发明授权

US4987052A Silver halide photographic material and method for forming superhigh contrast negative images using the same 失效
标题翻译：卤化银照相材料和使用其形成超高对比度负像的方法
公开(公告)号：US4987052A
公开(公告)日：1991-01-22
申请号：US139230
申请日：1987-12-29
申请人： Shigeo Hirano , Kazunobu Katoh , Yoshio Inagaki , Nobuaki Inoue
发明人： Shigeo Hirano , Kazunobu Katoh , Yoshio Inagaki , Nobuaki Inoue
IPC分类号： G03C1/06 , G03C1/12
CPC分类号： G03C1/12 , G03C1/061
摘要： A silver halide photographic material is disclosed, which comprises at least one silver halide emulsion layer on a support, at least one of the emulson layer and other layers contains at least one hydrazine derivative and at least one of these layers contains at least one compound having both a silver halide adsorbing group and an acid group represented by the general formula (I):C-L-D (I)wherein C represents a group that enhances adsorption to silver halide, D represents an acid group, and L represents a divalent linking group,and possessing substantially no absorption maximum in the visible region. A method for forming superhigh contrast negative images is also disclosed, comprising imagewise exposing this silver halide photographic material, followed by developing with a developing solution containing sulfite ions in an amount of about 0.15 mol or more per liter and having a pH of about 10.5 to about 12.3.
摘要翻译：公开了一种卤化银照相材料，其包含至少一个卤化银乳剂层，其中至少一个乳化剂层和其它层含有至少一个肼衍生物，并且这些层中的至少一个含有至少一种具有卤化银吸附基团和由通式（I）表示的酸基团：CLD（I）其中C表示增强对卤化银的吸附的基团，D表示酸基，L表示二价连接基团，在可见区域基本上没有吸收最大值。还公开了一种用于形成超高对比度负像的方法，包括成像曝光该卤化银照相材料，然后用含有约0.15摩尔或更高/升每升的量的亚硫酸根离子的显影溶液显影，并具有约10.5的pH至约12.3。

6. 发明授权

US06120983A Photothermographic material, novel 2,3-dihydrothiazole derivative, and photographic silver halide photosensitive material 失效
标题翻译：光热成像材料，新型2,3-二氢噻唑衍生物和照相卤化银感光材料
公开(公告)号：US06120983A
公开(公告)日：2000-09-19
申请号：US956134
申请日：1997-10-22
申请人： Hisashi Okada , Ryo Suzuki , Naoki Asanuma , Tadashi Ikeda , Shigeo Hirano
发明人： Hisashi Okada , Ryo Suzuki , Naoki Asanuma , Tadashi Ikeda , Shigeo Hirano
IPC分类号： C09B55/00 , G03C1/498
CPC分类号： G03C1/49845
摘要： A photothermographic material contains an organic silver salt, a photosensitive silver halide, a reducing agent, a binder, and a compound of the formula: X--L.sub.1 --D wherein D is an electron donative group of atoms, X is an adsorption promoting group to silver halide, and L.sub.1 is a valence bond or a linking group. It has high sensitivity in the red to infrared region and experiences a minimal change of photographic properties under different developing conditions.
摘要翻译：光热成像材料包含有机银盐，感光卤化银，还原剂，粘合剂和下式的化合物：X-L1-D其中D是原子的给电子基团，X是吸附促进基团卤化银，L1是价键或连接基团。它在红色到红外区域具有高灵敏度，并且在不同的显影条件下经历摄影性能的最小变化。

7. 发明授权

US5744279A Silver halide photographic material 失效
标题翻译：卤化银照相材料
公开(公告)号：US5744279A
公开(公告)日：1998-04-28
申请号：US595478
申请日：1996-02-01
申请人： Toshihide Ezoe , Toshiaki Kubo , Hiroshi Takeuchi , Kazunobu Katoh , Shigeo Hirano , Kazuki Yamazaki , Takashi Hoshimiya , Minoru Sakai , Tetsuo Yoshida
发明人： Toshihide Ezoe , Toshiaki Kubo , Hiroshi Takeuchi , Kazunobu Katoh , Shigeo Hirano , Kazuki Yamazaki , Takashi Hoshimiya , Minoru Sakai , Tetsuo Yoshida
IPC分类号： G03C1/06 , G03C1/295 , G03C5/30
CPC分类号： G03C1/295 , G03C1/061 , G03C5/30
摘要： A silver halide photographic material is disclosed, comprising a support having provided thereon at least one silver halide emulsion layer, at least one layer of the emulsion layer and other hydrophilic colloid layers containing at least one hydrazine-type nucleating agent having, in the vicinity of the hydrazine group, an anionic group or a nonionic group which forms an intramolecular hydrogen bond with a hydrogen atom of the hydrazine, and also containing at least one of the onium salt compounds represented by formulae (a), (b) and (c), or at least one of the amine compounds represented by formulae (d), (e), (f), (g), (h), (i) and (j). Also disclosed is a method for processing, after exposure, the silver halide photographic material described above with a developer containing a reductone-type developing agent and having a pH of 12 or less.
摘要翻译：公开了一种卤化银照相材料，其包括在其上设置有至少一个卤化银乳剂层的支撑体，至少一层乳剂层和其它含有至少一种肼型成核剂的亲水胶体层，所述肼型成核剂在肼基，与肼的氢原子形成分子内氢键的阴离子基团或非离子基团，还含有由式（a），（b）和（c）表示的至少一种鎓盐化合物，，或者由式（d），（e），（f），（g），（h），（i）和（j）表示的至少一种胺化合物。还公开了一种在曝光后用含有还原酮型显影剂并且pH为12以下的显影剂处理上述卤化银照相材料的方法。

8. 发明授权

US06593069B2 Photothermographic material and method for forming images 失效
标题翻译：光热成像材料和形成图像的方法
公开(公告)号：US06593069B2
公开(公告)日：2003-07-15
申请号：US09809024
申请日：2001-03-16
申请人： Toyohisa Oya , Kazunobu Katoh , Shigeo Hirano
发明人： Toyohisa Oya , Kazunobu Katoh , Shigeo Hirano
IPC分类号： G03C134
CPC分类号： G03C1/49845 , G03C1/49827 , G03C7/305 , Y10S430/166
摘要： A photothermographic material comprising at least (a) a photosensitive silver halide, (b) a reducible silver salt, (c) a reducing compound represented by the following formula (1) or (2), (d) a binder and (e) a coupler compound on the same side of a support: wherein, in the formula (1), V1 to V4 each independently represent hydrogen atom or a substituent, and V5 represents a substituted or unsubstituted alkyl group, aryl group or heterocyclic group: Q1—NHNH—V6 (2) wherein, in the formula (2), Q1 represents a 5- to 7-membered unsaturated ring bonding to NHNH—V6 at a carbon atom, and V6 represents a carbamoyl group, an acyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, a sulfonyl group or a sulfamoyl group. The photothermographic material of the present invention shows good photographic properties including sensitivity, fog and so forth, and enables control of color tone of the photothermographic material in an arbitrary wavelength region even as a monosheet type photothermographic material.
摘要翻译：一种光热成像材料，其至少包含（a）感光卤化银，（b）可还原的银盐，（c）由下式（1）或（2）表示的还原化合物，（d）粘合剂和（e）其中在式（1）中，V1至V4各自独立地表示氢原子或取代基，V5表示取代或未取代的烷基，芳基或杂环基：其中，在式（2）中，Q1表示在碳原子上与NHNH-V6键合的5至7元不饱和环，V 6表示氨基甲酰基，酰基，烷氧基羰基，芳氧基羰基，磺酰基或氨磺酰基。本发明的光热敏成像材料显示出良好的照相性质，包括灵敏度，雾度等，并且即使作为单片型光热敏成像材料也能够控制光热成像材料在任意波长区域中的色调。

9. 发明授权

US06358677B1 Heat-developable recording material 有权
标题翻译：热显影记录材料
公开(公告)号：US06358677B1
公开(公告)日：2002-03-19
申请号：US09528450
申请日：2000-03-17
申请人： Masahiko Taniguchi , Katsuyuki Watanabe , Shigeo Hirano , Minoru Sakai
发明人： Masahiko Taniguchi , Katsuyuki Watanabe , Shigeo Hirano , Minoru Sakai
IPC分类号： G03C1498
CPC分类号： G03C1/49845
摘要： A heat-developable recording material having, at least on one side and the same side of the support, (a) reducible silver salt, (b) a reducing agent other than a compound represented by the general formula (1) below, (c) a binder, and (d) at least one compound represented by the general formula (1) below; content of the compound represented by the general formula (1) being 0.01 to 100 mol % with respect to the reducing agent: [where in the general formula (1), R1, R2, R3, X1 and X2 independently represent a hydrogen atom; halogen atom; or substituent which is bound to the benzene ring via a carbon atom, oxygen atom, nitrogen atom, sulfur atom or phosphorus atom. At least either X1 or X2 represents a group represented as —NR4R5, where R4 and R5 independently represent a group selected from a hydrogen atom, alkyl group and the like.]
摘要翻译：（a）可还原银盐，（b）除了下述通式（1）表示的化合物以外的还原剂，（c）的可热显影记录材料，至少在一个侧面和同一侧上，（c））粘合剂，和（d）至少一种由下述通式（1）表示的化合物; 通式（1）表示的化合物的含量相对于还原剂为0.01〜100摩尔％[其中，在通式（1）中，R 1，R 2，R 3，X 1和X 2独立地表示氢原子; 卤素原子; 或通过碳原子，氧原子，氮原子，硫原子或磷原子与苯环结合的取代基。 X 1或X 2中至少有一个表示为-NR 4 R 5的基团，其中R 4和R 5独立地表示选自氢原子，烷基等的基团。

10. 发明授权

US6165707A Photothermographic or thermographic image-forming material 失效
标题翻译：光热成像或热成像成像材料
公开(公告)号：US6165707A
公开(公告)日：2000-12-26
申请号：US333271
申请日：1999-06-15
申请人： Shigeo Hirano , Satoru Toda , Masahiko Taniguchi , Hiroyuki Suzuki
发明人： Shigeo Hirano , Satoru Toda , Masahiko Taniguchi , Hiroyuki Suzuki
IPC分类号： G03C1/498 , G03C1/34
CPC分类号： G03C1/49845
摘要： An image-forming material comprising a support and a constituent layer(s) comprising at least (a) a thermographic image-forming layer containing a reducible silver salt, a reducing agent of the reducible silver salt and a binder or (b) a photothermographic image-forming layer containing a light-sensitive silver halide as a photocatalyst, reducible silver salt, a reducing agent of the reducible silver salt and a binder, wherein the image-forming material comprises a compound represented by formula (I-1) or (II-1) in at least one constituent layer: ##STR1## wherein R represents a secondary alkyl group or a cycloalkyl group; and M.sup.1 and M.sup.2 each represents a hydrogen atom, a metal ion or an ammonium ion; ##STR2## wherein R.sup.1 represents a secondary alkyl group, a cycloalkyl group, an aryl group, or a primary alkyl group substituted with a substituent bonded via a hetero atom; and M.sup.1 and M.sup.2 each represents a hydrogen atom, a metal ion or an ammonium ion.
摘要翻译：一种成像材料，其包括载体和构成层，其至少包含（a）含有可还原银盐的热成像图像形成层，可还原银盐的还原剂和粘合剂或（b）光热敏成像含有感光卤化银作为光催化剂的成像层，可还原银盐，可还原银盐的还原剂和粘合剂，其中成像材料包含由式（I-1）或（ II-1）至少一个构成层：其中R表示仲烷基或环烷基; M1和M2各自表示氢原子，金属离子或铵离子; 其中R1表示被通过杂原子键合的取代基取代的仲烷基，环烷基，芳基或伯烷基; M1和M2各自表示氢原子，金属离子或铵离子。

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