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    • 4. 发明授权
    • Lead-free and cadmium-free glass compositions for glazing, enameling and
decorating glass of glass-ceramics
    • 玻璃陶瓷玻璃,搪瓷和装饰玻璃的无铅和无镉玻璃组合物
    • US6043171A
    • 2000-03-28
    • US81468
    • 1998-05-19
    • Friedrich SiebersOttmar BeckerWaldemar WeinbergPetra Auchter-Krummel
    • Friedrich SiebersOttmar BeckerWaldemar WeinbergPetra Auchter-Krummel
    • C04B41/86C03C3/083C03C3/091C03C8/02C03C8/04C03C8/06C03C8/14C03C10/14C03C17/04
    • C03C8/02C03C10/0018C03C10/0027C03C10/0054C03C17/04C03C2217/72
    • The lead- and cadmium-free glass composition for glazing, enameling and decorating glass or glass-ceramic articles contains high quartz and/or keatite solid solution crystals as principal crystalline phases after crystallization and a low thermal expansion coefficient of less than 2.times.10.sup.-6 /K at temperatures between 20 and 700.degree. C. This glass composition contains Li.sub.2 O, 0 to 5% by weight; Na.sub.2 O, 0 to 5% by weight; K.sub.2 O, less than 2% by weight; MgO, 0 to 3% by weight; CaO, 0 to 4% by weight; SrO, 0 to 4% by weight; BaO, 0 to 4% by weight; ZnO, 0 to 4% by weight; B.sub.2 O.sub.3, 15 to 27% by weight; Al.sub.2 O.sub.3, 10 to 20% by weight; SiO.sub.2, 43 to 58% by weight; TiO.sub.2, 0 to 3% by weight and ZrO.sub.2, 0 to 4% by weight, Sb.sub.2 O.sub.3, 0 to 2% by weight; F, 0 to 3% by weight in exchange for oxygen and up to 30% by weight of at least one inorganic pigment resistant to a burning-in temperature on the glass or the glass-ceramics. The sum total amount of Li.sub.2 O, Na.sub.2 O and K.sub.2 O must be from 1 to 10% by weight. An average bending tensile strength of a glass-ceramic or glass article completely coated with the glass composition after burning-in is greater than 30 MPa.
    • 用于玻璃,搪瓷和装饰玻璃或玻璃陶瓷制品的无铅和无镉玻璃组合物在结晶后含有高石英和/或酮钾固溶体晶体作为主要晶相,低热膨胀系数小于2×10 -6 / K的温度在20和700℃之间。该玻璃组合物含有0至5重量%的Li 2 O, Na 2 O,0〜5重量% K2O,小于2重量%; 0〜3重量%的MgO, CaO,0〜4重量% 0-4%(重量); BaO,0〜4重量% 0〜4重量%的ZnO, B 2 O 3,15〜27重量% 10〜20重量%; SiO 2,43〜58重量% TiO 2,0〜3重量%,ZrO 2,0〜4重量%,Sb 2 O 3,0〜2重量% F,0至3重量%以换取氧气和至多30重量%的至少一种耐玻璃或玻璃陶瓷上的燃烧温度的无机颜料。 Li2O,Na2O和K2O的总量必须为1〜10重量%。 烧结后玻璃组合物完全涂覆的玻璃陶瓷或玻璃制品的平均弯曲拉伸强度大于30MPa。
    • 5. 发明授权
    • Device for applying decors and/or characters on glass, glass ceramics and ceramics products
    • 用于在玻璃,玻璃陶瓷和陶瓷制品上使用装饰和/或字符的装置
    • US06487386B1
    • 2002-11-26
    • US09830278
    • 2001-06-18
    • Michael ZimmerWaldemar WeinbergPetra Auchter-KrummelDieter Jung
    • Michael ZimmerWaldemar WeinbergPetra Auchter-KrummelDieter Jung
    • G03G1516
    • G03G15/1625
    • The device for applying decorations and characters on glass, glass ceramic or ceramic products includes an image roller (5) provided with an electrostatically chargeable photoconductive layer; a photo-exposure assembly (6) for generating an electrostatic charge image corresponding to at least one of decorations and characters to be applied; a supply container (8) for a toner with a device (8a) for developing the electrostatic charge image with the toner; a dimensionally stable transfer roller (7) for receiving the toner image, which is in direct contact with the image roller on one side and with the product (2) on its other side; at least two coronas (9, 10) including a first corona (9) arranged on the transfer roller (7) and a second corona (10) arranged under the product near the transfer roller (7) and a heater for burning the toner image onto the product, after electrostatically transferring the toner image to the product by means of the coronas.
    • 用于在玻璃,玻璃陶瓷或陶瓷产品上施加装饰和字符的装置包括设置有可静电电荷的光电导层的图像辊(5) 用于产生对应于要施加的装饰和字符中的至少一个的静电荷图像的照相曝光组件(6); 用于调色剂的供应容器(8),具有用于利用调色剂显影静电荷图像的装置(8a); 用于接收与一侧的图像辊直接接触并且在另一侧上与产品(2)直接接触的调色剂图像的尺寸稳定的转印辊(7) 包括布置在转印辊(7)上的第一电晕(9)和布置在转印辊附近的产品下面的第二电晕(10)的至少两个冠(9,10)和用于燃烧调色剂图像的加热器 在通过冠状物将调色剂图像静电转印到产品之后,到产品上。