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1. 发明授权

US06339167B2 Process for preparing organohalosilanes 有权
标题翻译：制备有机卤代硅烷的方法
公开(公告)号：US06339167B2
公开(公告)日：2002-01-15
申请号：US09782190
申请日：2001-02-14
申请人： Mikio Aramata , Kazutoshi Fujioka , Masahiro Yuyama
发明人： Mikio Aramata , Kazutoshi Fujioka , Masahiro Yuyama
IPC分类号： C07F716
CPC分类号： C07F7/16
摘要： Organohalosilanes are prepared by reacting metallic silicon with a halogenated hydrocarbon in the presence of a copper or copper compound catalyst and an activated aluminum, aluminum alloy or aluminum carbide promotor. The reaction is carried out at a temperature of 250-400° C. in a stirred tank reactor or a fluidized bed reactor. The inventive process shortens the time required for activation in the Rochow reaction and increases the selectivity for desirable diorganodihalosilanes. The steady state is thus prolonged and conversion of the silicon enhanced, resulting in an improved reaction performance.
摘要翻译：有机卤代硅烷通过在铜或铜化合物催化剂和活化的铝，铝合金或碳化铝促进剂的存在下使金属硅与卤代烃反应来制备。反应在250-400℃的温度下在搅拌釜反应器或流化床反应器中进行。本发明的方法缩短了Rochow反应中活化所需的时间，并增加了对所需二有机二卤代硅烷的选择性。稳定状态因此延长，硅的转化率提高，从而提高了反应性能。

2. 发明授权

US06685906B2 Silicon oxide containing active silicon and its evaluation 有权
标题翻译：含有活性硅的氧化硅及其评估
公开(公告)号：US06685906B2
公开(公告)日：2004-02-03
申请号：US09773521
申请日：2001-02-02
申请人： Hirofumi Fukuoka , Mikio Aramata , Kazutoshi Fujioka , Susumu Ueno , Takeshi Fukuda
发明人： Hirofumi Fukuoka , Mikio Aramata , Kazutoshi Fujioka , Susumu Ueno , Takeshi Fukuda
IPC分类号： C01B33113
CPC分类号： H01M4/485 , C01B33/113 , H01M4/131 , H01M10/0525 , H01M2004/021 , H01M2004/027 , Y10T436/24
摘要： Silicon oxide containing active silicon represented by the general formula: SiOx wherein x is from 0.8 to 1.9, when analyzed by solid state NMR (29Si DD/MAS) with a sufficient relaxation time set, exhibits a spectrum having two separate peaks, a broad peak (A1) centered at −70 ppm and a broad peak (A2) centered at −110 ppm, the area ratio A1/A2 being in the range of 0.1≦A1/A2≦1.0.
摘要翻译：当通过固态NMR（29SiDD / MAS）以足够的弛豫时间设定分析时，由通式SiO x表示的含氧化硅的活性硅，其中x为0.8至1.9，表现出具有两个单独峰的光谱，宽峰（A1）以-70ppm为中心，以-1.0ppm为中心的宽峰（A2），面积比A1 / A2在0.1 <= A1 / A2＆LE; 1.0的范围内。

3. 发明授权

US06242629B1 Preparation of organohalosilanes 有权
标题翻译：有机硅烷的制备
公开(公告)号：US06242629B1
公开(公告)日：2001-06-05
申请号：US09657282
申请日：2000-09-07
申请人： Susumu Ueno , Toshio Shinohara , Mikio Aramata , Yoichi Tanifuji , Tetsuya Inukai , Kazutoshi Fujioka
发明人： Susumu Ueno , Toshio Shinohara , Mikio Aramata , Yoichi Tanifuji , Tetsuya Inukai , Kazutoshi Fujioka
IPC分类号： C07F716
CPC分类号： C07F7/16
摘要： When oganohalosilanes are prepared by charging a reactor with a contact mass containing a metallic silicon powder and a copper catalyst, and introducing an organohalide-containing gas into the reactor to effect the direct reaction, a poly(organo)phosphino compound is added to the contact mass. The invention is successful in producing organohalosilanes at a significantly improved production rate without reducing the selectivity of useful silane.
摘要翻译：当通过向包含金属硅粉末和铜催化剂的接触物质填充反应器并且将含有机卤化物的气体引入反应器以进行直接反应来制备原料卤代硅烷时，向接触物中加入聚（有机）膦基化合物质量本发明成功地以显着提高的生产速率生产有机卤代硅烷，而不降低有用硅烷的选择性。

4. 发明授权

US06215012B1 Preparation of organohalosilanes 有权
标题翻译：有机硅烷的制备
公开(公告)号：US06215012B1
公开(公告)日：2001-04-10
申请号：US09657458
申请日：2000-09-07
申请人： Susumu Ueno , Toshio Shinohara , Mikio Aramata , Yoichi Tanifuji , Tetsuya Inukai , Kazutoshi Fujioka
发明人： Susumu Ueno , Toshio Shinohara , Mikio Aramata , Yoichi Tanifuji , Tetsuya Inukai , Kazutoshi Fujioka
IPC分类号： C07F716
CPC分类号： C07F7/16
摘要： When oganohalosilanes are prepared by charging a reactor with a contact mass containing a metallic silicon powder and a copper catalyst, and introducing an organohalide-containing gas into the reactor to effect the direct reaction, a metal complex of an organophosphino compound is added to the contact mass. The invention is successful in producing organohalosilanes at a significantly improved production rate without reducing the selectivity of useful silane.
摘要翻译：当通过向包含金属硅粉末和铜催化剂的接触物质填充反应器并且将含有机卤化物的气体引入反应器以进行直接反应来制备原料卤代硅烷时，将有机膦基化合物的金属络合物加入到接触质量本发明成功地以显着提高的生产速率生产有机卤代硅烷，而不降低有用硅烷的选择性。

5. 发明授权

US5527837A Heat-curable silicone elastomer compositions 失效
标题翻译：可热固化的硅氧烷弹性体组合物
公开(公告)号：US5527837A
公开(公告)日：1996-06-18
申请号：US426697
申请日：1995-04-24
申请人： Takashi Kondou , Takeo Yoshida , Kazutoshi Fujioka
发明人： Takashi Kondou , Takeo Yoshida , Kazutoshi Fujioka
IPC分类号： C08K9/10 , C08K9/12 , C08K9/00
CPC分类号： C08K9/10 , C08K9/12
摘要： In a heat-curable silicone elastomer composition comprising (A) an organopolysiloxane having at least two aliphatic-unsaturated hydrocarbon groups each bonded to a silicon atom and (B) an organohydrogenpolysiloxane having at least two hydrogen atoms each bonded to a silicon atom, there is blended (C) a hydrosilylating catalyst in the form of a hydrosilylation-promoting compound on a porous filler having a mean particle size of 0.1-100 .mu.m and a pore volume of 0.5-5 cm.sup.3 /g. The composition is stable during storage at room temperature, but quickly curable at elevated temperatures through hydrosilylation reaction.
摘要翻译：在可热固化的硅氧烷弹性体组合物中，其包含（A）具有至少两个与硅原子键合的脂族不饱和烃基的有机聚硅氧烷和（B）具有至少两个键合到硅原子上的氢原子的有机氢聚硅氧烷，将（C）氢化硅烷化促进化合物形式的氢化硅烷化催化剂混合在平均粒度为0.1-100μm，孔体积为0.5-5cm 3 / g的多孔填料上。该组合物在室温储存期间是稳定的，但通过氢化硅烷化反应在高温下快速固化。

6. 发明授权

US5391588A Curable organopolysiloxane compositions 失效
标题翻译：可固化的有机聚硅氧烷组合物
公开(公告)号：US5391588A
公开(公告)日：1995-02-21
申请号：US166077
申请日：1993-12-14
申请人： Takafumi Sakamoto , Masatoshi Arai , Kazutoshi Fujioka
发明人： Takafumi Sakamoto , Masatoshi Arai , Kazutoshi Fujioka
IPC分类号： C08F299/08 , C08F2/46 , C08F290/00 , C08K5/5425 , C08L83/06 , C08L83/07
CPC分类号： C08L83/06
摘要： Curable compositions comprising (A) an organopolysiloxane of the following general formula (1): ##STR1## wherein R.sup.1 is hydrogen or methyl, R.sup.2 and R.sup.3 are monovalent hydrocarbon groups, and R.sup.4 is a divalent organic group, (B) a silane having an .alpha.-silylester group, (C) a photoinitiator, and (D) a curing catalyst. The compositions are both photo-curable and room-temperature-curable. When cured by irradiation with light, the compositions give cured products having good rubber properties.
摘要翻译：（A）下述通式（1）的有机聚硅氧烷的固化性组合物：其中R1是氢或甲基，R2和R3是一价烃基，R4是二价有机基团，（B）具有α-甲硅烷基酯基团的硅烷，（C）光引发剂和（D）固化催化剂。组合物都是可光固化的和室温可固化的。当通过光照射固化时，组合物产生具有良好橡胶性能的固化产物。

7. 发明授权

US5266631A Process of producing room temperature curable organopolysiloxane composition 失效
标题翻译：生产室温可固化的有机聚硅氧烷组合物的方法
公开(公告)号：US5266631A
公开(公告)日：1993-11-30
申请号：US897853
申请日：1992-06-12
申请人： Masatoshi Arai , Kazutoshi Fujioka , Yuki Tateyama
发明人： Masatoshi Arai , Kazutoshi Fujioka , Yuki Tateyama
IPC分类号： C08K3/36 , C08L83/04 , C09K3/10
CPC分类号： C09K3/1018 , C08K3/36 , C08L83/04 , C08G77/14 , C08G77/16 , C08G77/18 , C08G77/20
摘要： The present process of producing a room temperature curable organopolysiloxane composition is characterized in that an organopolysiloxane represented by the following general formula (1) or (2): ##STR1## wherein X represents a hydrolyzable group such as an alkoxy group, R.sup.1 and R.sup.2 each represent a monovalent hydrocarbon group such as an alkyl group and a phenyl group, n is a positive integer, and a is 2 or 3, and a finely divided silica are mixed and thereafter a condensation catalyst is mixed. According to the present process, a curable composition which will not slump can be obtained without using a slump preventive.
摘要翻译：本发明的室温固化型有机基聚硅氧烷组合物的制造方法的特征在于，由下述通式（1）或（2）表示的有机聚硅氧烷：其中，X表示水解性基团，作为烷氧基，R 1和R 2各自表示一价烃基如烷基和苯基，n是正整数，a是2或3，并且将细碎的二氧化硅混合，然后将缩合催化剂混合根据本方法，可以在不使用防塌陷的情况下获得不会塌陷的可固化组合物。

8. 发明授权

US4943613A Photocurable organopolysiloxane composition 失效
标题翻译：光固化有机聚硅氧烷组合物
公开(公告)号：US4943613A
公开(公告)日：1990-07-24
申请号：US357977
申请日：1989-05-26
申请人： Masatoshi Arai , Kazutoshi Fujioka , Masaharu Satou
发明人： Masatoshi Arai , Kazutoshi Fujioka , Masaharu Satou
IPC分类号： C08F2/48 , C08F290/00 , C08F290/06 , C08F299/08 , C08K5/09 , C08K5/5425 , C08K5/544 , C08L83/04 , C08L83/07 , C09D4/06 , C09J4/06
CPC分类号： C09D4/06 , C08F290/068 , C08K5/09 , C08K5/5425 , C08K5/544 , C09J4/06
摘要： The photocurable organopolysiloxane composition is curable by irradiation with ultraviolet light into a rubbery elastomer which is excellently adhesive to the surface of the substrate on which it has been cured. The composition comprises an organopolysiloxane having, in a molecule, at least one acryloxy-functional group represented by the general formula[CH.sub.2 .dbd.CR.sup.1 --CO--O--(CH.sub.2).sub.a --SiR.sub.2 --O--].sub.b (R).sub.3-b Si--R.sup.2 --,in which R.sup.1 is a hydrogen atom or a methyl group, each R is a monovalent hydrocarbon group, R.sup.2 is an oxygen atom or a divalent hydrocarbon group and each of the subscripts a and b is 1, 2 or 3, as the principal ingredient together with an acryloxy-containing trialkoxy silane represented by the general formula(R.sup.3 O).sub.3 Si--R.sup.4 --(NH--CO--O--R.sup.4).sub.c --O--CO--CR.sup.1 .dbd.CH.sub.2,in which each R.sup.3 is a monovalent hydrocarbon group, each R.sup.4 is a divalent hydrocarbon group having 1 to 20 carbon atoms, R.sup.1 has the same meaning as defined above and the subscript c is zero or 1, acrylic or methacrylic acid and a photosensitizer.
摘要翻译：可光固化的有机基聚硅氧烷组合物可通过紫外线照射而固化成橡胶状弹性体，该橡胶状弹性体与已经固化的基材表面非常粘合。该组合物包含在分子中具有至少一个由通式[CH 2 = CR 1 -CO-O-（CH 2）a -SiR 2 -O-] b（R）3-b-Si（O）2）表示的丙烯酰氧基官能团的有机聚硅氧烷， R2-，其中R1是氢原子或甲基，每个R是一价烃基，R2是氧原子或二价烃基，并且每个下标a和b是1,2或3，作为主要成分与由通式（R3O）3Si-R4-（NH-CO-O-R4）cO-CO-CR1 = CH2表示的含丙烯酰氧基的三烷氧基硅烷，其中每个R 3是一价烃基， R4是具有1-20个碳原子的二价烃基，R 1具有与上述相同的含义，下标c为0或1，丙烯酸或甲基丙烯酸和光敏剂。

9. 发明授权

US4861908A Organosilicon compound 失效
标题翻译：有机硅化合物
公开(公告)号：US4861908A
公开(公告)日：1989-08-29
申请号：US216023
申请日：1988-07-07
申请人： Shinichi Satoh , Kazutoshi Fujioka
发明人： Shinichi Satoh , Kazutoshi Fujioka
IPC分类号： C08F299/08 , C07F7/18 , C08F290/00 , C08K5/5455
CPC分类号： C07F7/1836 , C08K5/5455
摘要： An organosilicon compound represented by the general formula (I): ##STR1## wherein R.sup.1 may be the same or different and represents an alkyl group having 1 to 8 carbon atoms; R.sup.2 and R.sup.3 may be the same or different and represents an alkylene group having 1 to 8 carbon atoms; and R.sup.4 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms,and a process for preparing the same. This compound is useful for improving adhesive properties of UV curable silicone compositions and the like.

10. 发明授权

US5985371A Primer compositions 失效
标题翻译：底漆组合物
公开(公告)号：US5985371A
公开(公告)日：1999-11-16
申请号：US985084
申请日：1997-12-04
申请人： Kazutoshi Fujioka , Takashi Kondou
发明人： Kazutoshi Fujioka , Takashi Kondou
IPC分类号： C09D183/04 , B05D3/02
CPC分类号： C09D183/04
摘要： The invention provides a primer composition comprising (I) an organoalkoxysilane or siloxane, (II) an organohydrogensiloxane having an SiH group and an alkoxysilyl group, and (III) an organic titanate. Also provided is a primer composition comprising (A) an alkenyl-containing organopolysiloxane, (B) an organopolysiloxane, (C) an organoalkoxysilane or siloxane, (D) an organohydrogensiloxane having an SiH group and an alkoxysilyl group, (E) a platinum catalyst, (F) an organic titanate, and (G) an organic peroxide. The primer compositions have sufficient adhesion to join thermoset silicone rubber to various substrates.
摘要翻译：本发明提供一种底漆组合物，其包含（I）有机烷氧基硅烷或硅氧烷，（II）具有SiH基和烷氧基甲硅烷基的有机氢硅氧烷，和（III）有机钛酸酯。还提供了包含（A）含链烯基的有机聚硅氧烷，（B）有机聚硅氧烷，（C）有机烷氧基硅烷或硅氧烷，（D）具有SiH基和烷氧基甲硅烷基的有机氢硅氧烷，（E）铂催化剂，（F）有机钛酸酯，和（G）有机过氧化物。底漆组合物具有足够的粘合性以将热固性硅橡胶加入到各种基材中。

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