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    • 3. 发明授权
    • Halogenated photopolymerizable adhesives
    • 卤化光聚合粘合剂
    • US4134814A
    • 1979-01-16
    • US682629
    • 1976-05-03
    • Michel De PoortereMarc ColpaertPaul DufourAugust Vrancken
    • Michel De PoortereMarc ColpaertPaul DufourAugust Vrancken
    • C08F2/00C08F2/44C08F2/48C08F2/50C08F291/00C09J4/00C09J4/02C09J4/06C09J167/00G03F7/032C08F4/00
    • G03F7/032C09J167/00C09J4/06Y10T428/31794
    • Halogenated photopolymerizable adhesive, which comprises: (a) 20 to 70% by weight of at least one halogenated polymer, which: (1) has a chain interrupted by at least one oxygen or nitrogen atom, (2) contains from 4 to 70% by weight of halogen atoms attached to carbon atoms having the electronic configuration sp.sup.2, (called "active halogen atoms"), (3) has an average molecular weight between 700 and 10,000 and (4) has a glass transition temperature (Tg) between -80.degree. C and 20.degree. C; (b) 5 to 30% by weight of at least one organic monomer compound containing at least two acrylic and/or methacrylic acid radicals and containing from 0 to 65% by weight of active halogen atoms; (c) 20 to 70% by weight of at least one organic monomer compound containing an acrylic or methacrylic acid radical and containing from 0 to about 65% by weight of active halogen atoms; (d) about 1 to about 25% by weight of a photo-initiator system comprising: (1) 0.5 to 100% by weight of at least one aromatic ketone, (2) 0 to 99.5% by weight of at least one tertiary amine, at least one carbon atom of which, in the alpha position with regard to the nitrogen atom, carries at least one hydrogen atom, (3) 0 to 90% by weight of an aromatic or nonaromatic alpha-dione, the sum of (1) + (2) + (3) representing 100% by weight of the photo-initiator system, the total content of active halogen atoms amonting to 3 to 50% by weight of the total halogenated photopolymerizable adhesive and lamination or contact adhesives based on said halogenated photopolymerizable adhesive.
    • 卤化光聚合性粘合剂,其包含:(a)20至70重量%的至少一种卤化聚合物,其:(1)具有被至少一个氧或氮原子间隔的链,(2)含有4-70% (称为“活性卤素原子”)的碳原子上连接的卤素原子,(3)的平均分子量为700〜10,000,(4)玻璃化转变温度(Tg)为 80℃,20℃; (b)5至30重量%的至少一种含有至少两个丙烯酸和/或甲基丙烯酸基团并且含有0至65重量%活性卤素原子的有机单体化合物; (c)20至70重量%的至少一种含丙烯酸或甲基丙烯酸基团并含有0至约65重量%活性卤素原子的有机单体化合物; (d)约1至约25重量%的光引发剂体系,其包含:(1)0.5至100重量%的至少一种芳族酮,(2)0至99.5重量%的至少一种叔胺 ,至少一个碳原子在相对于氮原子的α位置携带至少一个氢原子,(3)0至90重量%的芳族或非芳族α-二酮,(1 )+(2)+(3)代表光引发剂体系的100重量%,活性卤素原子的总含量占总卤化光聚合性粘合剂的3〜50重量%,并且基于所述 卤化光聚合粘合剂。
    • 4. 发明授权
    • Halogenated photopolymerizable compositions
    • 卤化光聚合组合物
    • US4134811A
    • 1979-01-16
    • US682630
    • 1976-05-03
    • Michel De PoortereMarc ColpaertPaul DufourAugust Vrancken
    • Michel De PoortereMarc ColpaertPaul DufourAugust Vrancken
    • G03F7/004C08F2/00C08F2/44C08F2/48C08F2/50C08F20/00C08F20/22C08F283/00C08F283/01C08F299/00C08F299/04C08G63/00C08G63/682C08G63/685C09D11/00C09D11/10C09D151/00C09D167/06G03F7/032G03F7/038C08F4/00
    • C09D11/101C08F283/00C08F299/0421C09D167/06G03F7/032Y10T428/31794
    • A film-forming halogenated photopolymerizable composition, which comprises: a) 20 to 70% by weight of at least one halogenated polymer, which (1) has a chain interrupted by at least one oxygen or nitrogen atom, (2) contains from 4 to 70% by weight halogen atoms attached to carbon atoms having the electronic configuration sp.sup.2, (called active halogen atoms), (3) has an average molecular weight between 700 and 10,000, (4) has a glass transition temperature (Tg) between 20.degree. C and the thermal decomposition point of the polymer; b) 20 to 60% by weight of at least one monomeric organic compound containing at least two acrylic acid and/or methacrylic acid radicals and containing from 0 to 65% by weight of active halogen atoms; c) 0 to about 40% by weight of at least one monomeric organic compound containing an acrylic acid or methacrylic acid radical and containing from 0 to about 65% by weight active halogen atoms; d) about 1 to about 25% by weight of a photoinitiator system comprising 1) 0.5 to 100% by weight of at least one aromatic ketone, 2) 0 to 99.5% by weight of at least one tertiary amine, at least one carbon atom of which, in the alpha position with regard to the nitrogen atom, carries at least one hydrogen atom; 3) 0 to 90% by weight of an aromatic or non-aromatic alpha-dione, the sum of 1) + 2) + 3) representing 100% by weight of the photoinitiator system; and the total content of active halogen atoms representing about 3 to about 50% by weight of the total halogenated photopolymerizable composition and printing inks, paints and varnishes based on said halogenated photopolymerizable composition, particularly suitable, inter alia, for the manufacture of printed circuits.
    • 一种成膜卤化光聚合组合物,其包含:a)20至70重量%的至少一种卤化聚合物,其中(1)具有被至少一个氧原子或氮原子间隔的链,(2)含有4至 连接到具有电子构型sp2的碳原子(称为活性卤素原子)的70重量%的卤素原子,(3)的平均分子量为700至10,000,(4)玻璃化转变温度(Tg)为20℃ C和聚合物的热分解点; b)20至60重量%的至少一种含有至少两个丙烯酸和/或甲基丙烯酸基团并含有0至65重量%活性卤素原子的单体有机化合物; c)0至约40重量%的至少一种含有丙烯酸或甲基丙烯酸基团并且含有0至约65重量%的活性卤素原子的单体有机化合物; d)约1至约25重量%的光引发剂体系,其包含1)0.5至100重量%的至少一种芳族酮,2)0至99.5重量%的至少一种叔胺,至少一个碳原子 其中在相对于氮原子的α位置上携带至少一个氢原子; 3)表示100重量%的光引发剂体系的0至90重量%的芳族或非芳族α-二酮,1)+2)+ 3)的总和; 并且占卤化光聚合组合物总量的约3至约50重量%的活性卤素原子的总含量和基于所述卤化光聚合组合物的印刷油墨,油漆和清漆,特别适用于制造印刷电路。