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    • 1. 发明授权
    • Semi-telechelic olefinically-unsaturated organic polymers
    • 半遥爪烯属不饱和有机聚合物
    • US4312726A
    • 1982-01-26
    • US3479
    • 1979-01-12
    • August VranckenPaul Dufour
    • August VranckenPaul Dufour
    • C08F8/00C08F8/14
    • C08F8/00
    • Organic polymer compounds having semi-telechelic olefinic unsaturation, which correspond to the general formula: ##STR1## in which V is the radical of an organic compound containing at least one polymerizable ##STR2## group and another group capable of reacting with the functional groups of organic compounds having radicals represented by W and Y; W is the radical of a chain transfer agent RSH, R being an organic radical having at least one hydroxyl or carboxyl group; X is the radical of an organic compound containing a polymerizable ##STR3## group; Y is the radical of an organic compound containing a polymerizable ##STR4## group and at least one other reactive group selected from hydroxyl, carboxyl, acid anhydride and epoxy groups; y is 0 or a whole number of from 1 to 10; x is the number of moles of X necessary to enable the chain --(X).sub.x -- (Y).sub.y -- to have a molecular weight from 1000 to 10,000 and H is the hydrogen atom detached from the chain transfer agent RSH, the radical RS of which is represented by W in the above general formula; the radicals X and the radicals Y being distributed statistically along the polymer chain --(X).sub.x --(Y).sub.y -- in accordance with the polymerization kinetics; a process for the preparation thereof, compositions comprising them and coatings or mouldings comprising these compounds or compositions.
    • 具有半遥爪烯属不饱和键的有机聚合物化合物,其对应于以下通式:其中V是含有至少一个可聚合基团的有机化合物的基团,另一个能够与官能团反应的基团 具有由W和Y表示的自由基的有机化合物; W是链转移剂RSH的基团,R是具有至少一个羟基或羧基的有机基团; X是含有可聚合基团的有机化合物的基团; Y是含有可聚合基团的有机化合物和至少一种选自羟基,羧基,酸酐和环氧基团的其它反应性基团的基团; y为0或1〜10的整数; x是使链 - (X)x-(Y)y-具有1000至10,000的分子量和H是从链转移剂RSH分离的氢原子所需的X的摩尔数,基团RS 在上述通式中由W表示; 根据聚合动力学,基团X和基团Y沿着聚合物链 - (X)x-(Y)y-统计分布; 其制备方法,包含它们的组合物和包含这些化合物或组合物的涂层或模制品。
    • 2. 发明授权
    • Semi-telechelic olefinically-unsaturated organic polymers
    • 半遥爪烯属不饱和有机聚合物
    • US4177338A
    • 1979-12-04
    • US517822
    • 1974-10-24
    • August VranckenPaul Dufour
    • August VranckenPaul Dufour
    • C08F8/00C08F8/14
    • C08F8/00
    • Organic polymer compounds having semi-telechelic olefinic unsaturation, which correspond to the general formula: ##STR1## in which V is the radical of an organic compound containing at least one polymerizable ##STR2## group and another group capable of reacting with the functional groups of organic compounds having radicals represented by W and Y; W is the radical of a chain transfer agent RSH, R being an organic radical having at least one hydroxyl or carboxyl group; X is the radical of an organic compound containing a polymerizable ##STR3## group; Y is the radical of an organic compound containing a polymerizable ##STR4## group and at least one other reactive group selected from hydroxyl, carboxyl, acid anhydride and epoxy groups; y is 0 or a whole number of from 1 to 10; x is the number of moles of X necessary to enable the chain --(X).sub.x --(Y).sub.y -- to have a molecular weight from 1000 to 10,000 and H is the hydrogen atom detached from the chain transfer agent RSH, the radical RS of which is represented by W in the above general formula; the radicals X and the radicals Y being distributed statistically along the polymer chain --(X).sub.x --(Y).sub.y -- in accordance with the polymerization kinetics; a process for the preparation thereof, compositions comprising them and coatings or mouldings comprising these compounds or compositions.
    • 具有半遥爪烯属不饱和键的有机聚合物化合物,其对应于以下通式:其中V是含有至少一个可聚合基团的有机化合物的基团,另一个能够与官能团反应的基团 具有由W和Y表示的自由基的有机化合物; W是链转移剂RSH的基团,R是具有至少一个羟基或羧基的有机基团; X是含有可聚合基团的有机化合物的基团; Y是含有可聚合基团的有机化合物和至少一种选自羟基,羧基,酸酐和环氧基团的其它反应性基团的基团; y为0或1〜10的整数; x是使链 - (X)x-(Y)y-具有1000至10,000的分子量和H是从链转移剂RSH分离的氢原子所需的X的摩尔数,基团RS 在上述通式中由W表示; 根据聚合动力学,基团X和基团Y沿着聚合物链 - (X)x-(Y)y-统计分布; 其制备方法,包含它们的组合物和包含这些化合物或组合物的涂层或模制品。
    • 4. 发明授权
    • Radio-hardenable acrylic polyesters
    • 无线电硬化丙烯酸聚酯
    • US4206025A
    • 1980-06-03
    • US940512
    • 1978-09-05
    • August VranckenPaul Dufour
    • August VranckenPaul Dufour
    • C08G63/52C08G63/676C08F8/00C08G18/00
    • C08G63/676C08G63/52
    • Radio-hardenable acrylic polyesters of the general formula:[A][B--C--D.sub.m ].sub.2 (I)wherein A is the radical of a linear polyester of the general formula:--O--[R.sub.1 --R.sub.2 ].sub.x R.sub.1 --O-- (II)wherein R.sub.1 is a radical derived from at least one dihydroxylated compound, R.sub.2 a radical derived from at least one dicarboxylic acid and x an integer from 1 to 20; wherein B has the same meaning as R.sub.2, C is a radical derived from at least one aliphatic polyhydroxylated compound, D a radical derived from acrylic acid and m is an integer from 2 to 7.Manufacture of said polyesters and use as binders in radio-hardenable compositions.
    • 通式为:[A] [BC-Dm] 2(I)的放射性硬化性丙烯酸类聚酯,其中A为下列通式的直链聚酯基团:-O- [R 1 -R 2] x R 1 -O-(II )其中R 1是衍生自至少一种二羟基化化合物的基团,R 2是衍生自至少一种二羧酸的基团,x是1-20的整数; 其中B具有与R 2相同的含义,C为至少一种脂族多羟基化合物衍生的基团,D为衍生自丙烯酸的基团,m为2-7的整数。所述聚酯的制造和用作无线电设备中的粘合剂, 可硬化组合物。
    • 7. 发明授权
    • Halogenated photopolymerizable adhesives
    • 卤化光聚合粘合剂
    • US4134814A
    • 1979-01-16
    • US682629
    • 1976-05-03
    • Michel De PoortereMarc ColpaertPaul DufourAugust Vrancken
    • Michel De PoortereMarc ColpaertPaul DufourAugust Vrancken
    • C08F2/00C08F2/44C08F2/48C08F2/50C08F291/00C09J4/00C09J4/02C09J4/06C09J167/00G03F7/032C08F4/00
    • G03F7/032C09J167/00C09J4/06Y10T428/31794
    • Halogenated photopolymerizable adhesive, which comprises: (a) 20 to 70% by weight of at least one halogenated polymer, which: (1) has a chain interrupted by at least one oxygen or nitrogen atom, (2) contains from 4 to 70% by weight of halogen atoms attached to carbon atoms having the electronic configuration sp.sup.2, (called "active halogen atoms"), (3) has an average molecular weight between 700 and 10,000 and (4) has a glass transition temperature (Tg) between -80.degree. C and 20.degree. C; (b) 5 to 30% by weight of at least one organic monomer compound containing at least two acrylic and/or methacrylic acid radicals and containing from 0 to 65% by weight of active halogen atoms; (c) 20 to 70% by weight of at least one organic monomer compound containing an acrylic or methacrylic acid radical and containing from 0 to about 65% by weight of active halogen atoms; (d) about 1 to about 25% by weight of a photo-initiator system comprising: (1) 0.5 to 100% by weight of at least one aromatic ketone, (2) 0 to 99.5% by weight of at least one tertiary amine, at least one carbon atom of which, in the alpha position with regard to the nitrogen atom, carries at least one hydrogen atom, (3) 0 to 90% by weight of an aromatic or nonaromatic alpha-dione, the sum of (1) + (2) + (3) representing 100% by weight of the photo-initiator system, the total content of active halogen atoms amonting to 3 to 50% by weight of the total halogenated photopolymerizable adhesive and lamination or contact adhesives based on said halogenated photopolymerizable adhesive.
    • 卤化光聚合性粘合剂,其包含:(a)20至70重量%的至少一种卤化聚合物,其:(1)具有被至少一个氧或氮原子间隔的链,(2)含有4-70% (称为“活性卤素原子”)的碳原子上连接的卤素原子,(3)的平均分子量为700〜10,000,(4)玻璃化转变温度(Tg)为 80℃,20℃; (b)5至30重量%的至少一种含有至少两个丙烯酸和/或甲基丙烯酸基团并且含有0至65重量%活性卤素原子的有机单体化合物; (c)20至70重量%的至少一种含丙烯酸或甲基丙烯酸基团并含有0至约65重量%活性卤素原子的有机单体化合物; (d)约1至约25重量%的光引发剂体系,其包含:(1)0.5至100重量%的至少一种芳族酮,(2)0至99.5重量%的至少一种叔胺 ,至少一个碳原子在相对于氮原子的α位置携带至少一个氢原子,(3)0至90重量%的芳族或非芳族α-二酮,(1 )+(2)+(3)代表光引发剂体系的100重量%,活性卤素原子的总含量占总卤化光聚合性粘合剂的3〜50重量%,并且基于所述 卤化光聚合粘合剂。
    • 8. 发明授权
    • Halogenated photopolymerizable compositions
    • 卤化光聚合组合物
    • US4134811A
    • 1979-01-16
    • US682630
    • 1976-05-03
    • Michel De PoortereMarc ColpaertPaul DufourAugust Vrancken
    • Michel De PoortereMarc ColpaertPaul DufourAugust Vrancken
    • G03F7/004C08F2/00C08F2/44C08F2/48C08F2/50C08F20/00C08F20/22C08F283/00C08F283/01C08F299/00C08F299/04C08G63/00C08G63/682C08G63/685C09D11/00C09D11/10C09D151/00C09D167/06G03F7/032G03F7/038C08F4/00
    • C09D11/101C08F283/00C08F299/0421C09D167/06G03F7/032Y10T428/31794
    • A film-forming halogenated photopolymerizable composition, which comprises: a) 20 to 70% by weight of at least one halogenated polymer, which (1) has a chain interrupted by at least one oxygen or nitrogen atom, (2) contains from 4 to 70% by weight halogen atoms attached to carbon atoms having the electronic configuration sp.sup.2, (called active halogen atoms), (3) has an average molecular weight between 700 and 10,000, (4) has a glass transition temperature (Tg) between 20.degree. C and the thermal decomposition point of the polymer; b) 20 to 60% by weight of at least one monomeric organic compound containing at least two acrylic acid and/or methacrylic acid radicals and containing from 0 to 65% by weight of active halogen atoms; c) 0 to about 40% by weight of at least one monomeric organic compound containing an acrylic acid or methacrylic acid radical and containing from 0 to about 65% by weight active halogen atoms; d) about 1 to about 25% by weight of a photoinitiator system comprising 1) 0.5 to 100% by weight of at least one aromatic ketone, 2) 0 to 99.5% by weight of at least one tertiary amine, at least one carbon atom of which, in the alpha position with regard to the nitrogen atom, carries at least one hydrogen atom; 3) 0 to 90% by weight of an aromatic or non-aromatic alpha-dione, the sum of 1) + 2) + 3) representing 100% by weight of the photoinitiator system; and the total content of active halogen atoms representing about 3 to about 50% by weight of the total halogenated photopolymerizable composition and printing inks, paints and varnishes based on said halogenated photopolymerizable composition, particularly suitable, inter alia, for the manufacture of printed circuits.
    • 一种成膜卤化光聚合组合物,其包含:a)20至70重量%的至少一种卤化聚合物,其中(1)具有被至少一个氧原子或氮原子间隔的链,(2)含有4至 连接到具有电子构型sp2的碳原子(称为活性卤素原子)的70重量%的卤素原子,(3)的平均分子量为700至10,000,(4)玻璃化转变温度(Tg)为20℃ C和聚合物的热分解点; b)20至60重量%的至少一种含有至少两个丙烯酸和/或甲基丙烯酸基团并含有0至65重量%活性卤素原子的单体有机化合物; c)0至约40重量%的至少一种含有丙烯酸或甲基丙烯酸基团并且含有0至约65重量%的活性卤素原子的单体有机化合物; d)约1至约25重量%的光引发剂体系,其包含1)0.5至100重量%的至少一种芳族酮,2)0至99.5重量%的至少一种叔胺,至少一个碳原子 其中在相对于氮原子的α位置上携带至少一个氢原子; 3)表示100重量%的光引发剂体系的0至90重量%的芳族或非芳族α-二酮,1)+2)+ 3)的总和; 并且占卤化光聚合组合物总量的约3至约50重量%的活性卤素原子的总含量和基于所述卤化光聚合组合物的印刷油墨,油漆和清漆,特别适用于制造印刷电路。