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1. 发明授权

US5155193A Suspension polymerization processes 失效
标题翻译：悬浮聚合方法
公开(公告)号：US5155193A
公开(公告)日：1992-10-13
申请号：US548328
申请日：1990-07-02
申请人： Michael K. Georges , Peter G. Odell , Lupu Alexandru
发明人： Michael K. Georges , Peter G. Odell , Lupu Alexandru
IPC分类号： C08F2/18 , C08F4/28 , C08F4/34
CPC分类号： C08F4/34
摘要： Process for the preparation of polymers which comprises a suspension free radical polymerization of monomers in the presence of the initiator O,O-t-amyl-O-(2-ethylhexyl)monoperoxycarbonate.

2. 发明授权

US4894309A Processes for the preparation of crosslinked copolymers 失效
标题翻译：制备交联共聚物的方法
公开(公告)号：US4894309A
公开(公告)日：1990-01-16
申请号：US246070
申请日：1988-09-19
申请人： Michael K. Georges , Lupu Alexandru , William J. Dale , Paul D. Szabo , Robert A. Nelson
发明人： Michael K. Georges , Lupu Alexandru , William J. Dale , Paul D. Szabo , Robert A. Nelson
IPC分类号： C08F212/08 , G03G9/087
CPC分类号： G03G9/08793 , C08F212/08 , G03G9/08737
摘要： A free radical suspension polymerization process for obtaining crosslinked styrene butadiene ternary copolymers which comprises the polymerization of styrene monomers, butadiene monomers, and crosslinking components in the presence of a surfactant, a stabilizer, and a first and second initiator; and wherein the aforementioned components are present in an aqueous phase; heating the resulting aqueous mixture at a temperature of from about 50.degree. C. to about 110.degree. C.; thereafter heating the mixture at a temperature of from about 110.degree. C. to about 150.degree. C.; followed by cooling and isolating the desired product.
摘要翻译：一种用于获得交联的苯乙烯丁二烯三元共聚物的自由基悬浮聚合方法，其包括在表面活性剂，稳定剂和第一和第二引发剂存在下苯乙烯单体，丁二烯单体和交联组分的聚合; 并且其中所述组分存在于水相中; 在约50℃至约110℃的温度下加热得到的含水混合物; 然后在约110℃至约150℃的温度下加热该混合物; 然后冷却并分离所需的产物。

3. 发明授权

US4770968A Polysiloxane-styrene-butadiene terpolymers and use in toners 失效
标题翻译：聚硅氧烷 - 苯乙烯 - 丁二烯三元共聚物，用于调色剂
公开(公告)号：US4770968A
公开(公告)日：1988-09-13
申请号：US78123
申请日：1987-07-27
申请人： Michael K. Georges , Lupu Alexandru
发明人： Michael K. Georges , Lupu Alexandru
IPC分类号： C08F290/06 , C08G77/20 , C08G77/442 , G03G9/087 , G03G9/10 , C08F230/08 , G03G9/08
CPC分类号： C08G77/20 , C08F290/068 , C08G77/442 , G03G9/08773
摘要： A branched polysiloxane styrene butadiene polymer of the following formula ##STR1## wherein m is a number of from about 2 to about 10; z is the number 3,4 or 5; n is a number of from about 10 to about 1,000; k, l and o are weight fraction numbers with k being from about 0.35 to about 0.95, l being from 0.1 to about 0.2, and o is from about 0.05 to about 0.5; R is an aromatic substituent, alkyl-CR"C(O)O, and alkylene-CR"C(O)O, wherein R" is hydrogen or an alkyl substituent, and R' is an alkyl substituent or a trialkylsilylether substituent.
摘要翻译：具有下列结构式的分支聚硅氧烷苯乙烯丁二烯聚合物：其中m为约2至约10; z是3,4或5; n为约10至约1,000的数; k，l和o是重量分数，其中k为约0.35至约0.95，l为0.1至约0.2，o为约0.05至约0.5; R是芳基取代基，烷基-C'C（O）O和亚烷基-CR''C（O）O，其中R“是氢或烷基取代基，R'是烷基取代基或三烷基甲硅烷基醚取代基。

4. 发明授权

US5114820A Polyalkyl styrene butadiene toner compositions 失效
标题翻译：聚烷基苯乙烯丁二烯调色剂组合物
公开(公告)号：US5114820A
公开(公告)日：1992-05-19
申请号：US428134
申请日：1989-10-27
申请人： Michael K. Georges , Lupu Alexandru
发明人： Michael K. Georges , Lupu Alexandru
IPC分类号： G03G9/087
CPC分类号： G03G9/08737 , Y10S430/105
摘要： A toner composition comprised of pigment particles and a branched polyalkyl/styrene/butadiene copolymer of the following formula ##STR1## wherein m, n and o are weight fraction numbers, p represents the number of CH.sub.2 groups, R is hydrogen or alkyl, and R' is carbonyloxy or aryl.
摘要翻译：由颜料颗粒和下式（IMAGE）的支链多烷基/苯乙烯/丁二烯共聚物组成的调色剂组合物，其中m，n和o是重量分数，p表示CH 2基数，R是氢或烷基，R '是羰氧基或芳基。

5. 发明授权

US5274057A Bead suspension polymerization process 失效
标题翻译：珠悬浮聚合工艺
公开(公告)号：US5274057A
公开(公告)日：1993-12-28
申请号：US812082
申请日：1991-12-23
申请人： Michael K. Georges , Robert D. Bayley , Lupu Alexandru
发明人： Michael K. Georges , Robert D. Bayley , Lupu Alexandru
IPC分类号： C08F2/20 , C08F236/10
CPC分类号： C08F2/20 , C08F236/10
摘要： An improved process for producing resin particles by a bead suspension polymerization reaction, and a polymer formed by the process wherein the process comprises: providing a liquid reaction medium suitable for conducting the polymerization; forming a suspension agent system in the reaction medium by an in situ interaction of at least two components in the reaction medium, for example, certain water soluble metal halides and polyvinylacetate derived polymers; adding at least one polymerizable monomer compound to the resulting reaction medium having the suspension agent system dispersed therein; and effecting polymerization of the monomer in the reaction medium to form low ash content beads of the polymer.A second embodiment comprises conducting a bead suspension polymerization process utilizing the suspension agent system formed in situ to limit the amount of fine particles of less than about 100 microns produced during the process comprising: providing a reaction medium suitable for conducting the polymerization in the reaction system; utilizing a suspension agent system which is appropriate for forming polymer beads having a desired size and for minimizing fine particle formation; adding at least one polymerizable monomer compound to the resulting reaction medium having the suspension agent system dispersed therein; effecting polymerization of the monomer in the reaction medium to form the beads of the polymer; and separating resin particles from the reaction followed by optional washing and drying.
摘要翻译：通过珠粒悬浮聚合反应制备树脂颗粒的改进方法和通过该方法形成的聚合物，其中所述方法包括：提供适于进行聚合的液体反应介质; 在反应介质中通过反应介质中至少两种组分的原位相互作用形成悬浮剂体系，例如某些水溶性金属卤化物和聚乙酸乙烯酯衍生的聚合物; 向其中分散有悬浮剂体系的所得反应介质中加入至少一种可聚合单体化合物; 并且在反应介质中进行单体的聚合以形成聚合物的低灰分珠粒。第二实施方案包括使用原位形成的悬浮剂体系进行珠粒悬浮聚合方法，以限制在该方法期间产生的小于约100微米的细颗粒的量，其包括：提供适于在反应体系中进行聚合的反应介质 ; 利用适于形成具有所需尺寸的聚合物珠粒并用于最小化细颗粒形成的悬浮剂体系; 向其中分散有悬浮剂体系的所得反应介质中加入至少一种可聚合单体化合物; 在反应介质中进行单体的聚合以形成聚合物的珠粒; 并从反应中分离树脂颗粒，然后任选地洗涤和干燥。

6. 发明授权

US06472485B2 Polymerization process for the preparation of a resin 失效
标题翻译：用于制备树脂的聚合方法
公开(公告)号：US06472485B2
公开(公告)日：2002-10-29
申请号：US09976992
申请日：2001-10-12
申请人： Paula J. MacLeod , Peter G. Odell , Francisco E. Torres , Michael K. Georges
发明人： Paula J. MacLeod , Peter G. Odell , Francisco E. Torres , Michael K. Georges
IPC分类号： C08F222
CPC分类号： C08F2/38 , C08F2/30
摘要： A process for the preparation of a thermoplastic resin, or thermoplastic resins comprising: forming, or providing a miniemulsion comprised of a mixture of an oligomeric compound of the formula R-SFR, wherein R is an oligomeric compound comprised of from about 1 to about 30 monomer units and optionally a covalently bonded free radical initiator compound, -SFR is a covalently bound stable free radical end group, and at least one free radical polymerizable monomer compound, and a surfactant; and heating the miniemulsion wherein there results a latex thermoplastic resin or a latex of thermoplastic resins with a high monomer to polymer conversion of about 85 to about 100 percent and a narrow polydispersity of from about 1.1 to about 2.0.
摘要翻译：一种制备热塑性树脂或热塑性树脂的方法，包括：形成或提供由式R-SFR的低聚化合物的混合物组成的细乳液，其中R为约1至约30的低聚化合物单体单元和任选的共价键合的自由基引发剂化合物，-SFR是共价结合的稳定的自由基端基，以及至少一种可自由基聚合的单体化合物和表面活性剂; 加热微乳液，其中产生胶乳热塑性树脂或具有约85至约100％的高单体至聚合物转化率和约1.1至约2.0的窄多分散性的热塑性树脂胶乳。

7. 发明授权

US06469094B1 Polymerization processes 失效
标题翻译：聚合工艺
公开(公告)号：US06469094B1
公开(公告)日：2002-10-22
申请号：US09561208
申请日：2000-04-28
申请人： Barkev Keoshkerian , Paula J. MacLeod , Peter G. Odell , Michael K. Georges
发明人： Barkev Keoshkerian , Paula J. MacLeod , Peter G. Odell , Michael K. Georges
IPC分类号： C08J307
CPC分类号： C08F4/00 , C08F293/005
摘要： A process for latex preparation including: a first heating of a mixture of at least one free radical polymerizable monomer compound, a free radical initiator compound, and a stable free radical compound to form a latomer mixture with from about 1 to about 8 percent conversion of the monomer compound to an oligomeric compound of the formula I—R′—SFR, wherein R′ is an oligomer comprised of from about 1 to about 30 monomer units, I— is a covalently bonded free radical initiator fragment arising from the free radical initiator compound, and —SFR is a covalently bound stable free radical group; dispersing the resulting latomer mixture in water with high shear to form a miniemulsion; and a second heating of the miniemulsion, wherein there results a high stability polymer particle latex which contains a polymer with a high monomer to polymer conversion of from about 98 to about 100 weight percent and a narrow polydispersity of from about 1.1 to about 2.0.
摘要翻译：一种用于胶乳制备的方法，包括：首先加热至少一种可自由基聚合的单体化合物，自由基引发剂化合物和稳定的自由基化合物的混合物以形成卡波姆混合物，其中约1至约8％的转化率单体化合物与式I-R'-SFR的低聚化合物反应，其中R'是由约1至约30个单体单元组成的低聚物，I-是自由基引发剂产生的共价键合的自由基引发剂片段化合物，-SFR是共价结合的稳定自由基; 将所得的卡波姆混合物以高剪切力分散在水中以形成细乳液; 和小乳液的第二次加热，其中产生高稳定性聚合物颗粒胶乳，其包含具有约98至约100重量％的高单体与聚合物转化率和约1.1至约2.0的窄多分散性的聚合物。

8. 发明授权

US06365675B1 Polymerization processes 失效
标题翻译：聚合工艺
公开(公告)号：US06365675B1
公开(公告)日：2002-04-02
申请号：US09592188
申请日：2000-06-12
申请人： Paula J. MacLeod , Peter G. Odell , Francisco E. Torres , Michael K. Georges
发明人： Paula J. MacLeod , Peter G. Odell , Francisco E. Torres , Michael K. Georges
IPC分类号： C08F400
CPC分类号： C08F2/38 , C08F2/30
摘要： A process for the preparation of a thermoplastic resin, or thermoplastic resins comprising: forming, or providing a miniemulsion comprised of a mixture of an oligomeric compound of the formula R—SFR, wherein R is an oligomeric compound comprised of from about 1 to about 30 monomer units and optionally a covalently bonded free radical initiator compound, —SFR is a covalently bound stable free radical end group, and at least one free radical polymerizable monomer compound, and a surfactant; and heating the miniemulsion wherein there results a latex thermoplastic resin or a latex of thermoplastic resins with a high monomer to polymer conversion of about 85 to about 100 percent and a narrow polydispersity of from about 1.1 to about 2.0.
摘要翻译：一种制备热塑性树脂或热塑性树脂的方法，包括：形成或提供由式R-SFR的低聚化合物的混合物组成的细乳液，其中R为约1至约30的低聚化合物单体单元和任选的共价键合的自由基引发剂化合物，-SFR是共价结合的稳定的自由基端基，以及至少一种可自由基聚合的单体化合物和表面活性剂; 加热微乳液，其中产生胶乳热塑性树脂或具有约85至约100％的高单体至聚合物转化率和约1.1至约2.0的窄多分散性的热塑性树脂胶乳。

9. 发明授权

US5608023A Rate enhanced polymerization processes 失效
标题翻译：速率增强的聚合过程
公开(公告)号：US5608023A
公开(公告)日：1997-03-04
申请号：US413663
申请日：1995-03-30
申请人： Peter G. Odell , Richard P. N. Veregin , Gordon K. Hamer , Michael K. Georges
发明人： Peter G. Odell , Richard P. N. Veregin , Gordon K. Hamer , Michael K. Georges
IPC分类号： C08F2/00 , C08F2/38 , C08F4/04 , C08F4/28 , C08F4/40
CPC分类号： C08F4/40
摘要： A polymerization process for the preparation of thermoplastic resin or resins comprising heating a mixture comprised of a free radical initiator, a stable free radical agent, at least one polymerizable monomer compound, and a sulfonic acid salt polymerization rate enhancing compound, to form a thermoplastic resin or resins with a high monomer to polymer conversion and a narrow polydispersity.
摘要翻译：一种用于制备热塑性树脂或树脂的聚合方法，包括加热由自由基引发剂，稳定的自由基试剂，至少一种可聚合单体化合物和磺酸盐聚合速率增强化合物组成的混合物，以形成热塑性树脂或具有高单体与聚合物转化率和窄多分散性的树脂。

10. 发明授权

US6121397A Polymerization processes using oligomeric compound, monomer and surfactant 失效
标题翻译：使用低聚化合物，单体和表面活性剂的聚合方法
公开(公告)号：US6121397A
公开(公告)日：2000-09-19
申请号：US892860
申请日：1997-07-14
申请人： Paula J. MacLeod , Peter G. Odell , Francisco E. Torres , Michael K. Georges
发明人： Paula J. MacLeod , Peter G. Odell , Francisco E. Torres , Michael K. Georges
IPC分类号： C08F2/22 , C08F2/16 , C08F2/30 , C08F2/38 , C08F4/00 , C08F297/00
CPC分类号： C08F2/38 , C08F2/30
摘要： A process for the preparation of a thermoplastic resin, or thermoplastic resins comprising:forming, or providing a miniemulsion comprised of a mixture of an oligomeric compound of the formula R-SFR, wherein R is an oligomeric compound comprised of from about 1 to about 30 monomer units and optionally a covalently bonded free radical initiator compound, -SFR is a covalently bound stable free radical end group, and at least one free radical polymerizable monomer compound, and a surfactant; andheating the miniemulsion wherein there results a latex thermoplastic resin or a latex of thermoplastic resins with a high monomer to polymer conversion of about 85 to about 100 percent and a narrow polydispersity of from about 1.1 to about 2.0.
摘要翻译：一种制备热塑性树脂或热塑性树脂的方法，包括：形成或提供由式R-SFR的低聚化合物的混合物组成的细乳液，其中R为约1至约30的低聚化合物单体单元和任选的共价键合的自由基引发剂化合物，-SFR是共价结合的稳定的自由基端基，以及至少一种可自由基聚合的单体化合物和表面活性剂; 并加热微乳液，其中产生胶乳热塑性树脂或具有约85至约100％的高单体与聚合物转化率和约1.1至约2.0的窄多分散性的热塑性树脂胶乳。

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