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    • 4. 发明授权
    • Aqueous suspension polymerization process
    • 水悬浮聚合法
    • US4558108A
    • 1985-12-10
    • US658719
    • 1984-10-09
    • Lupu AlexandruPeter G. Odell
    • Lupu AlexandruPeter G. Odell
    • C08F2/18C08F212/08G03G9/08
    • C08F2/18C08F212/08G03G9/08
    • A process for forming a copolymer of styrene and butadiene is disclosed including providing an aqueous phase comprising an aqueous mixture comprising water, styrene monomer, butadiene monomer, a suspension stabilizing agent, and a chain propogating amount of one or more free radical polymerization initiators, the ratio of the styrene monomer and the butadiene monomer being between about 80:20 and about 95:5 by weight, the weight proportion of water to the combination of styrene monomer and butadiene monomer being between about 0.8:1 and about 2:1 and a vapor phase comprising an inert gas and butadiene monomer, heating the aqueous phase and the vapor phase to a temperature between about 50.degree. C. and about 130.degree. C. at a pressure between about 20 psi and about 140 psi, removing butadiene monomer from the vapor phase after at least about 75 percent by weight of the butadiene monomer and the styrene monomer in the aqueous phase are converted to a copolymer and prior to conversion of more than about 98 percent by weight of the butadiene monomer and the styrene monomer to a copolymer in the aqueous phase, and heating the aqueous phase at a temperature between about 50.degree. C. and about 130.degree. C. at a pressure between about 20 psi and about 140 psi until at least about 90 percent by weight of the styrene monomer and butadiene monomer are copolymerized to form an aqueous suspension of discrete copolymer particles.
    • 公开了一种形成苯乙烯和丁二烯的共聚物的方法,其包括提供含有水,苯乙烯单体,丁二烯单体,悬浮稳定剂和链传递量的一种或多种自由基聚合引发剂的水性混合物的水相, 苯乙烯单体和丁二烯单体的重量比在约80:20至约95:5之间,水与苯乙烯单体和丁二烯单体的组合的重量比例在约0.8:1和约2:1之间,和 蒸汽相包含惰性气体和丁二烯单体,在约20psi至约140psi之间的压力下将水相和气相加热至约50℃至约130℃之间的温度,从而将丁二烯单体从 至少约75重量%的丁二烯单体和水相中的苯乙烯单体之间的气相转化为共聚物,并且在更多的转化之前 约98重量%的丁二烯单体和苯乙烯单体与水相中的共聚物反应,并在约50psi至约130℃的温度下在约20psi至约130psi的压力下加热该水相, 约140psi,直到至少约90重量%的苯乙烯单体和丁二烯单体共聚以形成离散共聚物颗粒的水悬浮液。
    • 5. 发明授权
    • Polymerization processes
    • 聚合工艺
    • US06365675B1
    • 2002-04-02
    • US09592188
    • 2000-06-12
    • Paula J. MacLeodPeter G. OdellFrancisco E. TorresMichael K. Georges
    • Paula J. MacLeodPeter G. OdellFrancisco E. TorresMichael K. Georges
    • C08F400
    • C08F2/38C08F2/30
    • A process for the preparation of a thermoplastic resin, or thermoplastic resins comprising: forming, or providing a miniemulsion comprised of a mixture of an oligomeric compound of the formula R—SFR, wherein R is an oligomeric compound comprised of from about 1 to about 30 monomer units and optionally a covalently bonded free radical initiator compound, —SFR is a covalently bound stable free radical end group, and at least one free radical polymerizable monomer compound, and a surfactant; and heating the miniemulsion wherein there results a latex thermoplastic resin or a latex of thermoplastic resins with a high monomer to polymer conversion of about 85 to about 100 percent and a narrow polydispersity of from about 1.1 to about 2.0.
    • 一种制备热塑性树脂或热塑性树脂的方法,包括:形成或提供由式R-SFR的低聚化合物的混合物组成的细乳液,其中R为约1至约30的低聚化合物 单体单元和任选的共价键合的自由基引发剂化合物,-SFR是共价结合的稳定的自由基端基,以及至少一种可自由基聚合的单体化合物和表面活性剂; 加热微乳液,其中产生胶乳热塑性树脂或具有约85至约100%的高单体至聚合物转化率和约1.1至约2.0的窄多分散性的热塑性树脂胶乳。
    • 8. 发明授权
    • Polymerization processes
    • 聚合工艺
    • US06469094B1
    • 2002-10-22
    • US09561208
    • 2000-04-28
    • Barkev KeoshkerianPaula J. MacLeodPeter G. OdellMichael K. Georges
    • Barkev KeoshkerianPaula J. MacLeodPeter G. OdellMichael K. Georges
    • C08J307
    • C08F4/00C08F293/005
    • A process for latex preparation including: a first heating of a mixture of at least one free radical polymerizable monomer compound, a free radical initiator compound, and a stable free radical compound to form a latomer mixture with from about 1 to about 8 percent conversion of the monomer compound to an oligomeric compound of the formula I—R′—SFR, wherein R′ is an oligomer comprised of from about 1 to about 30 monomer units, I— is a covalently bonded free radical initiator fragment arising from the free radical initiator compound, and —SFR is a covalently bound stable free radical group; dispersing the resulting latomer mixture in water with high shear to form a miniemulsion; and a second heating of the miniemulsion, wherein there results a high stability polymer particle latex which contains a polymer with a high monomer to polymer conversion of from about 98 to about 100 weight percent and a narrow polydispersity of from about 1.1 to about 2.0.
    • 一种用于胶乳制备的方法,包括:首先加热至少一种可自由基聚合的单体化合物,自由基引发剂化合物和稳定的自由基化合物的混合物以形成卡波姆混合物,其中约1至约8%的转化率 单体化合物与式I-R'-SFR的低聚化合物反应,其中R'是由约1至约30个单体单元组成的低聚物,I-是自由基引发剂产生的共价键合的自由基引发剂片段 化合物,-SFR是共价结合的稳定自由基; 将所得的卡波姆混合物以高剪切力分散在水中以形成细乳液; 和小乳液的第二次加热,其中产生高稳定性聚合物颗粒胶乳,其包含具有约98至约100重量%的高单体与聚合物转化率和约1.1至约2.0的窄多分散性的聚合物。