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1. 发明授权

US06956141B1 Method for preparing acetylene alcohols and their secondary products 失效
标题翻译：乙炔醇及其次要产物的制备方法
公开(公告)号：US06956141B1
公开(公告)日：2005-10-18
申请号：US09913979
申请日：2000-02-22
申请人： Melanie Maas-Brunner , Jochem Henkelmann , Gerd Kaibel , Alois Kindler , Christian Knoll , Harald Rust , Christian Tragut , Manfred Stroezel , Udo Rheude , Rudolf Erich Lorenz , Juan Aiscar
发明人： Melanie Maas-Brunner , Jochem Henkelmann , Gerd Kaibel , Alois Kindler , Christian Knoll , Harald Rust , Christian Tragut , Manfred Stroezel , Udo Rheude , Rudolf Erich Lorenz , Juan Aiscar
IPC分类号： C07C29/17 , C07C29/42 , C07C33/042 , C07C33/04 , C07C33/044 , C07C33/046
CPC分类号： C07C29/42 , C07C29/172 , Y02P20/582 , C07C33/044 , C07C33/042 , C07C31/20
摘要： A process for preparing at least one unsaturated alcohol (B) comprises the steps (I) to (III) below: (I) reaction of at least one alkali metal hydroxide or alkaline earth metal hydroxide with at least one alcohol (A) in at least one organic solvent (L) to give a mixture (G-I) comprising at least the alcohol (A), the solvent (L) and an alkoxide (AL); (II) reaction of at least one carbonyl compound of the formula R—CO—R′ with at least one alkyne of the formula R″—C≡C—H and the mixture (G-I) obtained in step (I) to give a mixture (G-II) comprising at least the alcohol (A), the solvent (L) and an unsaturated alcohol (B); (III) distillation of the mixture (G-II) obtained in step (II) to give the alcohol or alcohols (B) and a mixture (G-III) comprising the solvent (L) and the alcohol (A), wherein the solvent (L) obtained in step (III) and the alcohol (A) obtained in step (III) are recycled as a mixture to step (I).
摘要翻译：一种制备至少一种不饱和醇（B）的方法包括下列步骤（I）至（III）：（I）至少一种碱金属氢氧化物或碱土金属氢氧化物与至少一种醇（A）在至少一种有机溶剂（L），得到至少包含醇（A），溶剂（L）和醇盐（AL）的混合物（GI）（II）至少一种式R-CO-R'的羰基化合物与至少一种式R'-C≡CH的炔和步骤（I）中获得的混合物（GI）的反应，得到混合物至少包含醇（A），溶剂（L）和不饱和醇（B）的化合物（G-II）; （II）中获得的混合物（G-II）的蒸馏（III），得到醇或醇（B）和包含溶剂（L）和醇（A）的混合物（G-III），其中将步骤（III）中获得的溶剂（L）和步骤（III）中获得的醇（A）作为步骤（I）的混合物再循环。

2. 发明授权

US06300524B1 Process for preparing higher unsaturated ketones 失效
标题翻译：制备高级不饱和酮的方法
公开(公告)号：US06300524B1
公开(公告)日：2001-10-09
申请号：US09440281
申请日：1999-11-15
申请人： Carsten Oost , Manfred Stroezel , Heinz Etzrodt , Dietmar Weller , Udo Rheude , Gerd Kaibel , Thomas Krug , Luise Spiske , Hagen Jaedicke
发明人： Carsten Oost , Manfred Stroezel , Heinz Etzrodt , Dietmar Weller , Udo Rheude , Gerd Kaibel , Thomas Krug , Luise Spiske , Hagen Jaedicke
IPC分类号： C07C4500
CPC分类号： C07C45/676 , Y02P20/582 , C07C49/255 , C07C49/203
摘要： The present invention relates to an improved process for preparing higher unsaturated ketones by reacting the corresponding &agr;,&bgr;-unsaturated alcohols with alkyl acetoacetates in a Carroll reaction , in a reactor system with fitted fractionation column, wherein A the &agr;,&bgr;-unsaturated alcohol is introduced into the reaction vessel together with the organic aluminum compound in the absence of effective amounts of a solvent, and the alkyl acetoacetate is metered into this mixture, B a reaction temperature which is as constant as possible at between 175° C. and 220° C., preferably between 180° C. and 200° C., is adjusted and C during the reaction the content of alkyl acetoacetate in the reaction mixture is adjusted to a value which is as constant as possible at between 1 and 3% by weight. It is advantageous in this process for the reaction temperature defined under B to be controlled by suitable variation of the heat input and/or by variation of the rate of addition of the alkyl acetoacetate, and for adequate mixing of the reaction mixture in the reaction vessel to be ensured This can be achieved with the aid of a stirrer, by pumping the reaction mixture through an external liquid circulation, by introducing the alkyl acetoacetate by means of a mixing nozzle or else by passing in a stream of inert gas. The process according to the invention is particularly suitable for the Carroll reaction of higher alcohols such as 3,7-dimethyl-1,6-octadien-3-ol (linalool), 3,7-dimethyl-1-octen-3-ol, 3,7,11-trimethyl-1,6,10-dodecatrien-3-ol (nerolidol), 3,7,11-trimethyl-1-dodecen-3-ol or 3,7,11-trimethyl-1,6-dodecadien-3-ol (dihydronerolidol).
摘要翻译：本发明涉及一种改进的制备高级不饱和酮的方法，该方法通过在具有合适分馏塔的反应器系统中，在卡罗尔反应中使相应的α，β-不饱和醇与烷基乙酰乙酸酯反应，其中引入α，β-不饱和醇在没有有效量的溶剂的情况下，将有机铝化合物与有机铝化合物一起加入到反应容器中，并将乙酰乙酸烷基酯计量加入到该混合物中，B在175℃和220℃之间的反应温度尽可能恒定在反应过程中，优选在180℃和200℃之间调节和C，将反应混合物中乙酰乙酸烷基酯的含量调节至1至3重量％之间尽可能恒定的值。在该方法中，通过适当变化的热输入和/或通过烷基的加成速率的变化来控制在B下限定的反应温度，乙酰乙酸酯，并使反应混合物在反应容器中充分混合以确保这可以借助于搅拌器，通过泵送反应混合物通过外部液体循环，通过引入烷基乙酰乙酸酯通过混合喷嘴或者通过流入惰性气体流。根据本发明的方法特别适用于高级醇如3,7-二甲基-1,6-辛二烯-3-醇（芳樟醇），3， 7,7-二甲基-1-辛烯-3-醇，3,7,11-三甲基-1,6,10-十二碳三烯-3-醇（橙花叔醇），3,7,11-三甲基-1-十二碳烯-3-醇或3,7,11-三甲基-1,6-十二碳二烯-3-醇（二氢吗啉醇）。

3. 发明授权

US06054628A Reacting Grignard compounds with carbonyl compounds and ensuing hydrolysis 失效
标题翻译：用羰基化合物反应格利雅化合物，随后进行水解
公开(公告)号：US06054628A
公开(公告)日：2000-04-25
申请号：US955076
申请日：1997-10-21
申请人： Manfred Stroezel , Udo Rheude , Ralf-Thomas Rahn , Gerd Kaibel
发明人： Manfred Stroezel , Udo Rheude , Ralf-Thomas Rahn , Gerd Kaibel
IPC分类号： C07B49/00 , C07C29/124 , C07C29/40 , C07C31/00 , C07C33/02 , C07C35/18
CPC分类号： C07C29/40
摘要： In a process for carrying out an exothermal reaction, selected from the addition reaction of organomagnesium halide compounds to carbonyl compounds and the ensuing hydrolysis of the addition product, a considerable fraction of the heat liberated during the reaction is removed by evaporation of the solvent.
摘要翻译：在进行放热反应的方法中，选自有机卤化镁化合物与羰基化合物的加成反应以及随后的加成产物的水解，通过蒸发溶剂除去反应期间释放出的相当大部分的热量。

4. 发明授权

US5914012A Dividing wall column for continuous fractionation of multicomponent mixtures by distillation 失效
$Dividing wall column for continuous fractionation of multicomponent mixtures by distillation$
标题翻译：分隔壁柱，用于通过蒸馏连续分馏多组分混合物
公开(公告)号：US5914012A
公开(公告)日：1999-06-22
申请号：US845226
申请日：1997-04-21
申请人： Gerd Kaibel , Manfred Stroezel , Udo Rheude
发明人： Gerd Kaibel , Manfred Stroezel , Udo Rheude
IPC分类号： B01D3/14 , B01D3/16 , B01D3/32 , B01J19/32
CPC分类号： B01D3/141 , B01D3/14 , B01D3/16 , B01J19/325 , Y10S159/41 , Y10S159/42 , Y10S261/72
摘要： A dividing wall column for separating a mixture into 3 or more fractions by distillation is described, where at least one dividing wall is detachably attached within the dividing wall column.
摘要翻译：描述了用于通过蒸馏将混合物分离成3个或更多个馏分的分隔壁塔，其中至少一个分隔壁可拆卸地附接在分隔壁塔内。

5. 发明授权

US07319161B2 Method for producing cyclohexane dicarboxylic acids and the derivatives thereof 有权
标题翻译：环己烷二羧酸的制备方法及其衍生物
公开(公告)号：US07319161B2
公开(公告)日：2008-01-15
申请号：US10467234
申请日：2002-02-15
申请人： Ralf Noe , Hartmut Hibst , Klaus Halbritter , Melanie Maas-Brunner , Boris Breitscheidel , Gerd Kaibel , Klemens Massonne , Axel Salden , Klaus Ebel , Eike Johannes Bergner , Frank Haese
发明人： Ralf Noe , Hartmut Hibst , Klaus Halbritter , Melanie Maas-Brunner , Boris Breitscheidel , Gerd Kaibel , Klemens Massonne , Axel Salden , Klaus Ebel , Eike Johannes Bergner , Frank Haese
IPC分类号： C07C69/74 , C07C61/00 , C07C59/00
CPC分类号： C08K5/12 , C07C67/08 , C07C2601/14 , C07C69/75
摘要： The invention relates to a process for preparing cyclohexanedicarboxylic acids or derivatives thereof, such as esters and/or anhydrides, encompassing the reaction of diene/maleic acid anhydride mixtures, in particular of butadiene/maleic acid anhydride mixtures or of mixtures of maleic acid anhydrides and C5-dienes to give alkyl-substituted or unsubstituted cyclohexenedicarboxylic acid anhydrides in the condensed phase, ester formation, and then hydrogenation to give the corresponding cyclohexanedicarboxylic acid derivative, and also to the use of the cyclohexanedicarboxylic acids or derivatives thereof prepared according to the invention as plasticizers for plastics.
摘要翻译：本发明涉及一种制备环己烷二羧酸或其衍生物的方法，例如酯和/或酸酐，其包括二烯/马来酸酐混合物，特别是丁二烯/马来酸酐混合物或马来酸酐混合物的反应和 C5-二烯，在缩合相中得到烷基取代或未取代的环己烯二羧酸酐，酯形成，然后氢化得到相应的环己烷二羧酸衍生物，还可以使用根据本发明制备的环己烷二羧酸或其衍生物作为塑料增塑剂

6. 发明授权

US06518441B2 Method for oxidizing an organic compound containing at least one C-C double bond 有权
标题翻译：氧化含有至少一个C-C双键的有机化合物的方法
公开(公告)号：US06518441B2
公开(公告)日：2003-02-11
申请号：US09424847
申请日：1999-12-06
申请人： Georg Heinrich Grosch , Ulrich Müller , Andreas Walch , Norbert Rieber , Martin Fischer , Stefan Quaiser , Wolfgang Harder , Karsten Eller , Peter Bassler , Anne Wenzel , Gerd Kaibel , Achim Stammer , Jochem Henkelmann , Arnd Böttcher , Joaquim Henrique Teles , Michael Schulz , Gert Treiber
发明人： Georg Heinrich Grosch , Ulrich Müller , Andreas Walch , Norbert Rieber , Martin Fischer , Stefan Quaiser , Wolfgang Harder , Karsten Eller , Peter Bassler , Anne Wenzel , Gerd Kaibel , Achim Stammer , Jochem Henkelmann , Arnd Böttcher , Joaquim Henrique Teles , Michael Schulz , Gert Treiber
IPC分类号： C07D30112
CPC分类号： C07D301/19 , B01J29/90 , B01J38/14 , C07B41/00 , C07D301/12 , Y02P20/584
摘要： A process for oxidizing an organic compound having at least one C—C double bond or a mixture of two or more thereof comprises the following steps: (I) preparing a hydroperoxide, (II) reacting an organic compound having at least one C—C double bond or a mixture of two or more thereof with the hydroperoxide prepared in step (I) in the presence of a zeolite catalyst, (III) regenerating the at least partially deactivated zeolite catalyst used in step (II), and (IV) conducting the reaction of step (II) using a zeolite catalyst containing the catalyst regenerated in step (III).
摘要翻译：氧化具有至少一个CC双键的有机化合物或其两种或多种的混合物的方法包括以下步骤：（I）制备氢过氧化物，（II）使具有至少一个CC双键的有机化合物或在沸石催化剂存在下，在步骤（I）中制备的氢过氧化物的两种或更多种的混合物与再生步骤（II）中使用的至少部分失活的沸石催化剂的（III）反应，和（Ⅳ）进行步骤（II）使用含有在步骤（III）中再生的催化剂的沸石催化剂。

7. 发明申请

US20100081804A1 PROCESS FOR CONTINUOUS HYDROGENATION OR HYDROGENATING AMINATION 有权
标题翻译：连续加氢或加氢胺化的方法
公开(公告)号：US20100081804A1
公开(公告)日：2010-04-01
申请号：US12090377
申请日：2006-10-16
申请人： Bram Willem Hoffer , Hartwig Voss , Ekkehard Schwab , Udo Rheude , Gerd Kaibel , Mathias Haake , Jan Eberhardt , Michael Karcher
发明人： Bram Willem Hoffer , Hartwig Voss , Ekkehard Schwab , Udo Rheude , Gerd Kaibel , Mathias Haake , Jan Eberhardt , Michael Karcher
IPC分类号： C07D265/30 , C07C45/00
CPC分类号： C07C45/62 , C07C47/228 , C07C49/04 , C07C47/02
摘要： A process is described for continuously hydrogenating unsaturated compounds, in which particles of a first hydrogenation catalyst are suspended in a liquid phase in which an unsaturated compound is dissolved, the liquid phase, in the presence of a hydrogenous gas at a first partial hydrogen pressure and at a first temperature, is conducted through a packed bubble column reactor in cocurrent counter to the direction of gravity, the effluent from the bubble column reactor is sent to a gas-liquid separation, the liquid phase is sent to a crossfiltration to obtain a retentate and a filtrate, the retentate is recycled into the bubble column reactor and the filtrate, in the presence of a hydrogenous gas at a second partial hydrogen pressure and at a second temperature, is passed over a bed of a second hydrogenation catalyst, wherein the second partial hydrogen pressure is at least 10 bar higher than the first partial hydrogen pressure.
摘要翻译：描述了在第一部分氢气压力下在氢气存在下将不饱和化合物连续氢化的方法，其中第一氢化催化剂的颗粒悬浮在其中溶解不饱和化合物的液相中，液相，以及在第一个温度下，通过气泡塔反应器与重力方向并流，将来自泡罩塔反应器的流出物送入气液分离，将液相送至交叉过滤，得到滞留物和滤液，将滞留物再循环到泡罩塔反应器中，并且在第二部分氢气压力和第二温度下在氢气存在下将滤液通过第二氢化催化剂床，其中第二部分氢气压力比第一部分氢气压力高至少10巴。

8. 发明授权

US08557985B2 Process for continuous hydrogenation or hydrogenating amination 失效
标题翻译：连续氢化或氢化胺化的方法
公开(公告)号：US08557985B2
公开(公告)日：2013-10-15
申请号：US13423956
申请日：2012-03-19
申请人： Bram Willem Hoffer , Hartwig Voβ , Ekkehard Schwab , Udo Rheude , Gerd Kaibel , Mathias Haake , Jan Eberhardt , Michael Karcher
发明人： Bram Willem Hoffer , Hartwig Voβ , Ekkehard Schwab , Udo Rheude , Gerd Kaibel , Mathias Haake , Jan Eberhardt , Michael Karcher
IPC分类号： C07D265/30 , C07C211/01 , C07C5/02
CPC分类号： C07C45/62 , C07C47/228 , C07C49/04 , C07C47/02
摘要： A process continuously hydrogenating unsaturated compounds, in which particles of a first hydrogenation catalyst are suspended in a liquid phase in which an unsaturated compound is dissolved, the liquid phase, in the presence of a hydrogenous gas at a first partial hydrogen pressure and at a first temperature, is conducted through a packed bubble column reactor in cocurrent counter to the direction of gravity, the effluent from the bubble column reactor is sent to a gas-liquid separation, the liquid phase is sent to a crossfiltration to obtain a retentate and a filtrate, the retentate is recycled into the bubble column reactor and the filtrate, in the presence of a hydrogenous gas at a second partial hydrogen pressure and at a second temperature, is passed over a bed of a second hydrogenation catalyst, the second partial hydrogen pressure is at least 10 bar higher than the first partial hydrogen pressure.
摘要翻译：将第一氢化催化剂的颗粒悬浮在其中溶解有不饱和化合物的液相中的不饱和化合物的液相，在第一部分氢气压力下的氢气存在下的液相，温度，通过与泡沫塔反应器并流反向并流并通过气泡塔反应器进行气液分离，将液相送至交叉过滤以获得滞留物和滤液，将渗余物再循环到泡罩塔反应器中，并且在第二部分氢气压力和第二温度下在氢气存在下将滤液通过第二氢化催化剂床，第二部分氢气压力为比第一部分氢气压力高至少10巴。

9. 发明授权

US07388119B2 Method for the hydrogenation of aromatic compounds with hydrogen containing residual gas 失效
标题翻译：用含氢残留气体氢化芳香族化合物的方法
公开(公告)号：US07388119B2
公开(公告)日：2008-06-17
申请号：US10484247
申请日：2002-07-18
申请人： Arnd Böttcher , Ekkehard Schwab , Ralf Kästner , Jochem Henkelmann , Gerd Kaibel , Heinrich Laib
发明人： Arnd Böttcher , Ekkehard Schwab , Ralf Kästner , Jochem Henkelmann , Gerd Kaibel , Heinrich Laib
IPC分类号： C07C5/10
CPC分类号： C07C5/10 , C07C2521/04 , C07C2523/46 , C07C13/18
摘要： The present invention relates to a process for the hydrogenation of substituted or unsubstituted, monocyclic or polycyclicaromatics to form the corresponding cycloaliphatics, in particular of benzene to cyclohexane, by bringing the aromatic into contact with a hydrogen-containing gas in the presence of a catalyst, where hydrogen in which residual gases are present is used.
摘要翻译：本发明涉及通过在催化剂存在下使芳族烃与含氢气体接触来氢化取代或未取代的单环或多环芳烃以形成相应的环烯烃，特别是苯至环己烷的方法，其中使用存在残留气体的氢。

10. 发明授权

US06521767B1 Method for suspension hydrogenation of an anthraquinone compound in a special reactor in order to produce hydrogen peroxide 失效
标题翻译：用于制备过氧化氢的专用反应器中的蒽醌化合物的悬浮氢化
公开(公告)号：US06521767B1
公开(公告)日：2003-02-18
申请号：US09622852
申请日：2000-08-28
申请人： Arnd Böttcher , Jochem Henkelmann , Franz Josef Bröcker , Gerd Kaibel , Heinz Rütter
发明人： Arnd Böttcher , Jochem Henkelmann , Franz Josef Bröcker , Gerd Kaibel , Heinz Rütter
IPC分类号： C07J5300
CPC分类号： B01J8/0015 , B01J8/007 , B01J8/06 , B01J8/067 , B01J8/1863 , B01J8/20 , B01J8/22 , B01J8/228 , B01J8/34 , B01J19/2425 , B01J19/2465 , B01J2208/00212 , B01J2219/00103 , B01J2219/185 , B01J2219/1943 , B01J2219/32286 , B01J2219/32416 , C01B15/023 , C07C37/07 , C07C2602/24 , C07C39/12
摘要： In a process for the suspension hydrogenation of an anthraquinone compound or a mixture of two or more thereof in a reactor in which there are present the working solution in which at least one catalyst is suspended and, in addition, a hydrogen-containing gas phase, the working solution and the gas phase are, in the reactor, passed at least partly through a fitting having openings or channels whose hydraulic diameter is from 0.5 to 20 mm, preferably from 1 to 10 mm, particularly preferably from 1 to 3 mm.
摘要翻译：在其中存在悬浮至少一种催化剂的工作溶液的反应器中的蒽醌化合物或其两种或更多种的混合物的悬浮氢化方法中，另外，含氢气相，反应器中的工作溶液和气相至少部分地通过具有水力直径为0.5至20mm，优选为1至10mm，特别优选为1至3mm的开口或通道的配件。

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