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1. 发明授权

US4293657A Stable melamine polyol dispersions, a process for their manufacture and for the preparation of foamed polyurethane plastics 失效
标题翻译：稳定的三聚氰胺多元醇分散体，其制造方法和泡沫聚氨酯塑料的制备
公开(公告)号：US4293657A
公开(公告)日：1981-10-06
申请号：US166636
申请日：1980-07-07
申请人： Dietmar Nissen , Matthias Marx , Wolfgang Jarre , Ernst Schoen , Walter Decker
发明人： Dietmar Nissen , Matthias Marx , Wolfgang Jarre , Ernst Schoen , Walter Decker
IPC分类号： C08J9/00 , C08K5/3492 , C08G18/14
CPC分类号： C08J9/0028 , C08K3/34 , C08K5/34 , C08K5/34922 , C08J2375/04
摘要： Stable melamine-polyoxyalkylene polyether polyol dispersions are prepared by the in situ reduction of melamine particles wherein 90 percent of the melamine particles have a particle size of less than 10 microns. Stabilizers for the melamine-polyol dispersion are selected from the group consisting of(a) silicic acids and silicates,(b) salts of perfluorinated alkyl carboxylic acids having 4 to 20 carbon atoms, salts of alkyl sulfonic acids and perfluorinated alkylsulfonic acids having 4 to 20 carbon atoms and polyperfluoroether polyols having molecular weights of 300 to 6000, and(c) salts of fatty alcohol sulfates having 6 to 30 carbon atoms.These dispersions are useful for the preparation of polyurethane foams.
摘要翻译：通过原位还原三聚氰胺颗粒制备稳定的三聚氰胺 - 聚氧化烯聚醚多元醇分散体，其中90％的三聚氰胺颗粒具有小于10微米的粒度。三聚氰胺 - 多元醇分散体的稳定剂选自（a）硅酸和硅酸盐，（b）具有4至20个碳原子的全氟化烷基羧酸盐，烷基磺酸盐和全氟烷基磺酸的盐，其具有4至 20个碳原子和分子量为300〜6000的聚全氟醚多元醇，（c）碳原子数为6〜30的脂肪醇硫酸盐。这些分散体可用于制备聚氨酯泡沫体。

2. 发明授权

US4243755A Process for the manufacture of reinforced polyurethane foams 失效
标题翻译：制造增强聚氨酯泡沫的方法
公开(公告)号：US4243755A
公开(公告)日：1981-01-06
申请号：US93375
申请日：1979-11-13
申请人： Matthias Marx , Dietmar Nissen , Wolfgang Jarre
发明人： Matthias Marx , Dietmar Nissen , Wolfgang Jarre
IPC分类号： C08J9/00 , C08G18/14
CPC分类号： C08J9/0066 , C08J9/0061 , C08J2375/04
摘要： The invention relates to a process for the manufacture of reinforced polyurethane foams based on the reaction of organic polyisocyanates and polyols in the presence of filler dispersions. These dispersions are prepared by in situ crushing of the filler in the polyisocyanate or polyol to a particle size of less than 7 microns.
摘要翻译：本发明涉及一种基于有机多异氰酸酯和多元醇在填料分散体存在下的反应来制造增强聚氨酯泡沫体的方法。这些分散体通过将多异氰酸酯或多元醇中的填料原位粉碎至小于7微米的粒度来制备。

3. 发明授权

US4668708A Process for the preparation of elastic polyurethane flexible foams usable in cold-mold techniques to produce molded articles 失效
标题翻译：用于制备可用于冷模技术的弹性聚氨酯软质泡沫塑料的制备方法来生产模塑制品
公开(公告)号：US4668708A
公开(公告)日：1987-05-26
申请号：US869199
申请日：1986-05-30
申请人： Gerhard Mueller , Matthias Marx , Wolfgang Jarre , Edwin Baumann , Ingolf Buethe
发明人： Gerhard Mueller , Matthias Marx , Wolfgang Jarre , Edwin Baumann , Ingolf Buethe
IPC分类号： C08G18/10 , C08G18/14
CPC分类号： C08G18/10 , Y10S521/914
摘要： The invention is a process for the preparation of elastic polyurethane flexible foams having densities from approximately 25 to 60 kg/m.sup.3, and producing molded articles in closed molds at temperatures from 25.degree. to 80.degree. C., comprising reacting(A) an organic polyisocyanate prepolymer having an isocyanate content from 6 to 20 percent by weight prepared by reacting a toluene diisocyanate and/or a diphenylmethane diisocyanate with a di- to tetrafunctional polyether polyol having a hydroxyl number from 20 to 50 and oxyethylene terminal group content of at least 10 to 30 percent by weight(B) a mixture of compounds containing reactive hydrogen atoms, comprising a mixture of(a) from 55 to 89.5 parts by weight of at least one di- to tetrafunctional polyether polyol having a hydroxyl number of from 20 to 80 and less than 10 percent by weight terminal oxyethylene groups,(b) from 0.5 to 20 parts by weight of at least one alkanolamine, and(c) from 10 to 25 parts by weight water, in the presence of(C) a blowing agent,(D) a catalyst, and optionally(E) auxiliaries and/or additives.
摘要翻译：本发明是制备密度为约25至60kg / m 3的弹性聚氨酯柔性泡沫体的方法，并且在封闭模具中在25℃至80℃的温度下生产模制品，其包括使（A）有机多异氰酸酯预聚物的异氰酸酯含量为6〜20重量％，其通过使甲苯二异氰酸酯和/或二苯基甲烷二异氰酸酯与羟基数为20至50的二至四官能团聚醚多元醇反应制备，氧乙烯基端基含量为至少10至 30重量％（B）含有反应性氢原子的化合物的混合物，其包含（a）55至89.5重量份的至少一种羟基数为20至80的二官能或四官能团聚醚多元醇的混合物，以及末端氧乙烯基少于10重量％，（b）0.5至20重量份的至少一种链烷醇胺，和（c）10至25重量份的水，（C）发泡剂，（D）催化剂和任选的（E）助剂和/或添加剂。

4. 发明授权

US4279757A Process for separating hydrophobic organic liquids from water 失效
标题翻译：疏水性有机液体与水分离的方法
公开(公告)号：US4279757A
公开(公告)日：1981-07-21
申请号：US108424
申请日：1979-12-31
申请人： Gerard DeBeuckelaer , Wolfgang Jarre , Rolf Wurmb , Matthias Marx
发明人： Gerard DeBeuckelaer , Wolfgang Jarre , Rolf Wurmb , Matthias Marx
IPC分类号： B01D17/02 , B01D17/022 , C02F1/68 , C08G18/36 , C08G18/38 , C08G18/69 , C02F1/28
CPC分类号： C08G18/69 , B01D17/0202 , C08G18/36 , C08G18/3825 , C02F1/681 , C08G2101/0008 , C08G2101/0041 , C08G2101/0083
摘要： A process for separating hydrophobic organic liquids from water comprising passing a mixture of water and hydrophobic organic liquids through a column-like vessel which is filled with a hydrophobic, preferably open-celled, polyurethane foam, said foam having a high absorption capacity, permits high flow-through velocities even as the foam becomes covered and saturated with the hydrophobic organic liquids, is reversibly deformable, and can be reused.
摘要翻译：一种从水中分离疏水性有机液体的方法，包括使水和疏水性有机液体的混合物通过填充有疏水性，优选开孔聚氨酯泡沫的柱状容器，所述泡沫具有高吸收能力，允许高甚至当泡沫被疏水性有机液体覆盖并饱和时，流通速度是可逆变形的，并且可以重复使用。

5. 发明授权

US4590219A Process for the preparation of elastomeric molded parts having urethane or urethane and urea groups with improved light fastness and weather resistance 失效
标题翻译：具有氨基甲酸乙酯或氨基甲酸乙酯和脲基的弹性体模塑部件的制备方法具有改善的耐光性和耐候性
公开(公告)号：US4590219A
公开(公告)日：1986-05-20
申请号：US488038
申请日：1983-04-22
申请人： Dietmar Nissen , Matthias Marx , Hans U. Schmidt
发明人： Dietmar Nissen , Matthias Marx , Hans U. Schmidt
IPC分类号： C08G18/42 , C08G18/66 , B29C67/22 , B29C39/22 , B29C45/02 , C08J9/34
CPC分类号： C08G18/42 , C08G18/4236 , C08G18/4244 , C08G18/4247 , C08G18/4269 , C08G18/6637 , C08G2101/0033 , C08G2101/0066 , C08G2120/00 , Y10S264/83
摘要： The invention relates to a process for the preparation of elastomeric molded parts having urethane or urethane and urea linkages which comprises reacting(a) an organic polyisocyanate,(b) a polyhydroxyl compound selected from the group consisting of(i) polyester polyols with molecular weights of 1000 to 3000 and hydroxyl numbers of 170 to 35 produced by polycondensation of organic dicarboxylic acids and a polyol mixture of at least 3 polyols;(ii) polyether polyols having terminal ester groups, molecular weights of 1000 to 8000 and hydroxyl numbers of 170 to 15; and(iii) mixtures thereof;(c) a chain extenderwherein components (a) through (c) are processed according to reaction injection molding techniques in open or closed molds.The reaction is preferably carried out as a one-shot process and may also be carried out in the presence of blowing agents (d), auxiliaries (e), and additives (e).The non-cellular and/or microcellular elastomeric molded parts produced according to the method of this invention are particularly well suited for use in the automobile industry, for example, as bumper covers and body parts such as fenders, spoilers, wheel well expansions as well as engineering housing parts and runners. The cellular foams are used, for example, as shoe soles, armrests, headrests, safety coverings in the passenger compartment in automobiles as well as motorcycle and bicycle seats, seat cushions and cover layers in composite foams.
摘要翻译：本发明涉及一种制备具有氨基甲酸酯或氨基甲酸酯和脲键的弹性体模塑部件的方法，其包括使（a）有机多异氰酸酯，（b）选自（i）聚酯多元醇与分子量的多羟基化合物通过有机二羧酸和至少3种多元醇的多元醇混合物的缩聚产生的1000至3000的羟基数和170至35; （ii）具有末端酯基的聚醚多元醇，分子量为1000至8000，羟值为170至15; 和（iii）其混合物; （c）扩链剂，其中组分（a）至（c）根据在开模或封闭模具中的反应注塑技术进行加工。反应优选作为一步法进行，也可以在发泡剂（d），助剂（e）和添加剂（e）的存在下进行。根据本发明的方法生产的非细胞和/或微细胞弹性模制零件特别适用于汽车工业，例如保险杠盖和身体部件如挡泥板，扰流板，车轮井膨胀以及作为工程住房部件和跑步者。蜂窝状泡沫体例如用作鞋底，扶手，头枕，汽车乘客室中的安全覆盖物，以及摩托车和自行车座椅，座垫和复合泡沫中的覆盖层。

6. 发明授权

US4304708A Process for the manufacture of stable polyol-filler dispersions 失效
标题翻译：用于制备稳定的多元醇 - 填料分散体的方法
公开(公告)号：US4304708A
公开(公告)日：1981-12-08
申请号：US228928
申请日：1981-01-27
申请人： Matthias Marx , Dietmar Nissen
发明人： Matthias Marx , Dietmar Nissen
IPC分类号： C08K3/00 , C08K3/013 , C08K9/04 , C09D17/00 , C08L71/00
CPC分类号： C09D17/004 , C08K3/0033 , C08K9/04
摘要： This invention relates to a process for the manufacture of stable polyol-filler dispersions. The polyol-filler dispersions are prepared by the crushing of fillers in situ in polyols employing high localized energies.
摘要翻译：本发明涉及制备稳定的多元醇 - 填料分散体的方法。多元醇 - 填料分散体通过使用高定向能量在多元醇中原位粉碎填料来制备。

7. 发明授权

US4590242A Production of low-shrinkage nylon moldings 失效
标题翻译：生产低收缩尼龙成型品
公开(公告)号：US4590242A
公开(公告)日：1986-05-20
申请号：US513839
申请日：1983-07-14
申请人： Peter Horn , Hellmut Bunsch , Anton Hesse , Matthias Marx , Dietmar Nissen , Walter Heckmann
发明人： Peter Horn , Hellmut Bunsch , Anton Hesse , Matthias Marx , Dietmar Nissen , Walter Heckmann
IPC分类号： C08G69/18 , C08F8/30 , C08F283/04 , C08L77/00
CPC分类号： C08G69/18
摘要： Low-shrinkage nylon moldings are produced by activated alkaline lactam polymerization, preferably using the reactive injection molding technique, by a process wherein the polymerization is carried out in the presence of from 5 to 80% by weight of a polymer P which1. is completely soluble in the lactam,2. separates out in the course of polymerization at a conversion of from 1 to 50%,3. is composed of one or more blocks which are compatible with polylactam and one or more blocks which are incompatible therewith, and preferably4. possesses functional groups which are incorporated into the growing polylactam chain.
摘要翻译：低收缩尼龙模制品通过活性碱性内酰胺聚合制备，优选使用反应性注射成型技术，其中聚合反应在5-80重量％聚合物P的存在下进行，聚合物P是完全可溶于内酰胺，2.在聚合过程中以1至50％的转化率分离出来，3.由与多内酰胺相容的一个或多个嵌段和与其不相容的一个或多个嵌段组成，优选 4.具有并入生长的聚内酰胺链中的官能团。

8. 发明授权

US4440705A Process for the preparation of cellular and non-cellular polyurethane elastomers 失效
标题翻译：制备细胞和非细胞聚氨酯弹性体的方法
公开(公告)号：US4440705A
公开(公告)日：1984-04-03
申请号：US394460
申请日：1982-07-01
申请人： Dietmar Nissen , Wolfgang Straehle , Matthias Marx
发明人： Dietmar Nissen , Wolfgang Straehle , Matthias Marx
IPC分类号： C08G18/48 , C08G18/66 , C08G18/14
CPC分类号： C08G18/4841 , C08G18/4837 , C08G18/487 , C08G18/667 , C08G2120/00 , Y10S521/914
摘要： A process for the preparation of optionally cellular and non-cellular polyurethane elastomers, preferably by reaction injection molding, organic polyisocyanates, polyether polyols based on polyoxyalkylene polyether polyols with terminal hydroxyethylene groups and an ethoxylation degree of 1 to 13, having a content of primary hydroxyl groups at the corresponding degree of ethoxylation as the value of curve A to 100 percent with curve A describing the dependency of the primary hydroxyl group content upon the degree of ethoxylation are reacted with chain extenders and/or cross-linking agents in the presence of catalysts as well as optionally blowing agents, auxiliaries and additives.
摘要翻译：一种制备任选的细胞和非细胞聚氨酯弹性体的方法，优选通过反应注射成型，有机多异氰酸酯，基于具有末端羟基亚乙基的聚氧化烯聚醚多元醇的聚醚多元醇和1至13的乙氧基化度，具有伯羟基含量在相应的乙氧基化程度下的基团与扩链剂和/或交联剂在催化剂存在下与扩链剂和/或交联剂反应，曲线A的值为100％，曲线A描述了伯羟基含量对乙氧基化程度的依赖性以及任选的发泡剂，助剂和添加剂。

9. 发明授权

US4383050A Process for the preparation of low temperature flexible polyurethane elastomers 失效
标题翻译：制备低温柔性聚氨酯弹性体的方法
公开(公告)号：US4383050A
公开(公告)日：1983-05-10
申请号：US318754
申请日：1981-11-06
申请人： Dietmar Nissen , Hans U. Schmidt , Wolfgang Straehle , Uwe Schuett , Matthias Marx
发明人： Dietmar Nissen , Hans U. Schmidt , Wolfgang Straehle , Uwe Schuett , Matthias Marx
IPC分类号： C08G18/36 , C08G18/40 , C08G18/48 , C08G18/66 , C08G18/14
CPC分类号： C08G18/487 , C08G18/36 , C08G18/4018 , C08G18/4891 , C08G18/6629 , C08G2101/0008 , C08G2101/0058 , C08G2101/0066 , C08G2101/0083 , Y10S521/904
摘要： Low temperature flexible polyurethane elastomers are prepared by reacting organic polyisocyanates with polyester polyols which have glass transition temperatures of -10.degree. to -80.degree. C. and incorporating therein alkoxylated esters of fatty acids and/or alkoxylated terpene alcohols.
摘要翻译：通过使有机多异氰酸酯与玻璃化转变温度为-10℃至-80℃的聚酯多元醇反应并加入脂肪酸和/或烷氧基化萜烯醇的烷氧基化酯来制备低温柔性聚氨酯弹性体。

10. 发明授权

US4305861A Process for the manufacture of stable polymer polyol dispersions 失效
标题翻译：用于制造稳定的聚合物多元醇分散体的方法
公开(公告)号：US4305861A
公开(公告)日：1981-12-15
申请号：US198519
申请日：1980-10-20
申请人： Matthias Marx , Dietmar Nissen , Robert Gehm
发明人： Matthias Marx , Dietmar Nissen , Robert Gehm
IPC分类号： C08G59/18 , C08G59/50 , C08J3/11 , C08L63/00 , C08L71/02 , C08K5/05
CPC分类号： C08J3/11 , C08G59/18 , C08G59/50 , C08L63/00 , C08L71/02 , C08J2363/00
摘要： Polymer polyol dispersions are prepared by reacting polyepoxides with epoxide resin hardeners in the presence of polyester and polyoxyalkylene polyether polyols.
摘要翻译：聚合物多元醇分散体是通过聚环氧化物与环氧树脂硬化剂在聚酯和聚氧化烯聚醚多元醇存在下反应来制备的。

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