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1. 发明授权

US4590219A Process for the preparation of elastomeric molded parts having urethane or urethane and urea groups with improved light fastness and weather resistance 失效
标题翻译：具有氨基甲酸乙酯或氨基甲酸乙酯和脲基的弹性体模塑部件的制备方法具有改善的耐光性和耐候性
公开(公告)号：US4590219A
公开(公告)日：1986-05-20
申请号：US488038
申请日：1983-04-22
申请人： Dietmar Nissen , Matthias Marx , Hans U. Schmidt
发明人： Dietmar Nissen , Matthias Marx , Hans U. Schmidt
IPC分类号： C08G18/42 , C08G18/66 , B29C67/22 , B29C39/22 , B29C45/02 , C08J9/34
CPC分类号： C08G18/42 , C08G18/4236 , C08G18/4244 , C08G18/4247 , C08G18/4269 , C08G18/6637 , C08G2101/0033 , C08G2101/0066 , C08G2120/00 , Y10S264/83
摘要： The invention relates to a process for the preparation of elastomeric molded parts having urethane or urethane and urea linkages which comprises reacting(a) an organic polyisocyanate,(b) a polyhydroxyl compound selected from the group consisting of(i) polyester polyols with molecular weights of 1000 to 3000 and hydroxyl numbers of 170 to 35 produced by polycondensation of organic dicarboxylic acids and a polyol mixture of at least 3 polyols;(ii) polyether polyols having terminal ester groups, molecular weights of 1000 to 8000 and hydroxyl numbers of 170 to 15; and(iii) mixtures thereof;(c) a chain extenderwherein components (a) through (c) are processed according to reaction injection molding techniques in open or closed molds.The reaction is preferably carried out as a one-shot process and may also be carried out in the presence of blowing agents (d), auxiliaries (e), and additives (e).The non-cellular and/or microcellular elastomeric molded parts produced according to the method of this invention are particularly well suited for use in the automobile industry, for example, as bumper covers and body parts such as fenders, spoilers, wheel well expansions as well as engineering housing parts and runners. The cellular foams are used, for example, as shoe soles, armrests, headrests, safety coverings in the passenger compartment in automobiles as well as motorcycle and bicycle seats, seat cushions and cover layers in composite foams.
摘要翻译：本发明涉及一种制备具有氨基甲酸酯或氨基甲酸酯和脲键的弹性体模塑部件的方法，其包括使（a）有机多异氰酸酯，（b）选自（i）聚酯多元醇与分子量的多羟基化合物通过有机二羧酸和至少3种多元醇的多元醇混合物的缩聚产生的1000至3000的羟基数和170至35; （ii）具有末端酯基的聚醚多元醇，分子量为1000至8000，羟值为170至15; 和（iii）其混合物; （c）扩链剂，其中组分（a）至（c）根据在开模或封闭模具中的反应注塑技术进行加工。反应优选作为一步法进行，也可以在发泡剂（d），助剂（e）和添加剂（e）的存在下进行。根据本发明的方法生产的非细胞和/或微细胞弹性模制零件特别适用于汽车工业，例如保险杠盖和身体部件如挡泥板，扰流板，车轮井膨胀以及作为工程住房部件和跑步者。蜂窝状泡沫体例如用作鞋底，扶手，头枕，汽车乘客室中的安全覆盖物，以及摩托车和自行车座椅，座垫和复合泡沫中的覆盖层。

2. 发明授权

US4383050A Process for the preparation of low temperature flexible polyurethane elastomers 失效
标题翻译：制备低温柔性聚氨酯弹性体的方法
公开(公告)号：US4383050A
公开(公告)日：1983-05-10
申请号：US318754
申请日：1981-11-06
申请人： Dietmar Nissen , Hans U. Schmidt , Wolfgang Straehle , Uwe Schuett , Matthias Marx
发明人： Dietmar Nissen , Hans U. Schmidt , Wolfgang Straehle , Uwe Schuett , Matthias Marx
IPC分类号： C08G18/36 , C08G18/40 , C08G18/48 , C08G18/66 , C08G18/14
CPC分类号： C08G18/487 , C08G18/36 , C08G18/4018 , C08G18/4891 , C08G18/6629 , C08G2101/0008 , C08G2101/0058 , C08G2101/0066 , C08G2101/0083 , Y10S521/904
摘要： Low temperature flexible polyurethane elastomers are prepared by reacting organic polyisocyanates with polyester polyols which have glass transition temperatures of -10.degree. to -80.degree. C. and incorporating therein alkoxylated esters of fatty acids and/or alkoxylated terpene alcohols.
摘要翻译：通过使有机多异氰酸酯与玻璃化转变温度为-10℃至-80℃的聚酯多元醇反应并加入脂肪酸和/或烷氧基化萜烯醇的烷氧基化酯来制备低温柔性聚氨酯弹性体。

3. 发明授权

US4304708A Process for the manufacture of stable polyol-filler dispersions 失效
标题翻译：用于制备稳定的多元醇 - 填料分散体的方法
公开(公告)号：US4304708A
公开(公告)日：1981-12-08
申请号：US228928
申请日：1981-01-27
申请人： Matthias Marx , Dietmar Nissen
发明人： Matthias Marx , Dietmar Nissen
IPC分类号： C08K3/00 , C08K3/013 , C08K9/04 , C09D17/00 , C08L71/00
CPC分类号： C09D17/004 , C08K3/0033 , C08K9/04
摘要： This invention relates to a process for the manufacture of stable polyol-filler dispersions. The polyol-filler dispersions are prepared by the crushing of fillers in situ in polyols employing high localized energies.
摘要翻译：本发明涉及制备稳定的多元醇 - 填料分散体的方法。多元醇 - 填料分散体通过使用高定向能量在多元醇中原位粉碎填料来制备。

4. 发明授权

US4293657A Stable melamine polyol dispersions, a process for their manufacture and for the preparation of foamed polyurethane plastics 失效
标题翻译：稳定的三聚氰胺多元醇分散体，其制造方法和泡沫聚氨酯塑料的制备
公开(公告)号：US4293657A
公开(公告)日：1981-10-06
申请号：US166636
申请日：1980-07-07
申请人： Dietmar Nissen , Matthias Marx , Wolfgang Jarre , Ernst Schoen , Walter Decker
发明人： Dietmar Nissen , Matthias Marx , Wolfgang Jarre , Ernst Schoen , Walter Decker
IPC分类号： C08J9/00 , C08K5/3492 , C08G18/14
CPC分类号： C08J9/0028 , C08K3/34 , C08K5/34 , C08K5/34922 , C08J2375/04
摘要： Stable melamine-polyoxyalkylene polyether polyol dispersions are prepared by the in situ reduction of melamine particles wherein 90 percent of the melamine particles have a particle size of less than 10 microns. Stabilizers for the melamine-polyol dispersion are selected from the group consisting of(a) silicic acids and silicates,(b) salts of perfluorinated alkyl carboxylic acids having 4 to 20 carbon atoms, salts of alkyl sulfonic acids and perfluorinated alkylsulfonic acids having 4 to 20 carbon atoms and polyperfluoroether polyols having molecular weights of 300 to 6000, and(c) salts of fatty alcohol sulfates having 6 to 30 carbon atoms.These dispersions are useful for the preparation of polyurethane foams.
摘要翻译：通过原位还原三聚氰胺颗粒制备稳定的三聚氰胺 - 聚氧化烯聚醚多元醇分散体，其中90％的三聚氰胺颗粒具有小于10微米的粒度。三聚氰胺 - 多元醇分散体的稳定剂选自（a）硅酸和硅酸盐，（b）具有4至20个碳原子的全氟化烷基羧酸盐，烷基磺酸盐和全氟烷基磺酸的盐，其具有4至 20个碳原子和分子量为300〜6000的聚全氟醚多元醇，（c）碳原子数为6〜30的脂肪醇硫酸盐。这些分散体可用于制备聚氨酯泡沫体。

5. 发明授权

US4243755A Process for the manufacture of reinforced polyurethane foams 失效
标题翻译：制造增强聚氨酯泡沫的方法
公开(公告)号：US4243755A
公开(公告)日：1981-01-06
申请号：US93375
申请日：1979-11-13
申请人： Matthias Marx , Dietmar Nissen , Wolfgang Jarre
发明人： Matthias Marx , Dietmar Nissen , Wolfgang Jarre
IPC分类号： C08J9/00 , C08G18/14
CPC分类号： C08J9/0066 , C08J9/0061 , C08J2375/04
摘要： The invention relates to a process for the manufacture of reinforced polyurethane foams based on the reaction of organic polyisocyanates and polyols in the presence of filler dispersions. These dispersions are prepared by in situ crushing of the filler in the polyisocyanate or polyol to a particle size of less than 7 microns.
摘要翻译：本发明涉及一种基于有机多异氰酸酯和多元醇在填料分散体存在下的反应来制造增强聚氨酯泡沫体的方法。这些分散体通过将多异氰酸酯或多元醇中的填料原位粉碎至小于7微米的粒度来制备。

6. 发明授权

US4590242A Production of low-shrinkage nylon moldings 失效
标题翻译：生产低收缩尼龙成型品
公开(公告)号：US4590242A
公开(公告)日：1986-05-20
申请号：US513839
申请日：1983-07-14
申请人： Peter Horn , Hellmut Bunsch , Anton Hesse , Matthias Marx , Dietmar Nissen , Walter Heckmann
发明人： Peter Horn , Hellmut Bunsch , Anton Hesse , Matthias Marx , Dietmar Nissen , Walter Heckmann
IPC分类号： C08G69/18 , C08F8/30 , C08F283/04 , C08L77/00
CPC分类号： C08G69/18
摘要： Low-shrinkage nylon moldings are produced by activated alkaline lactam polymerization, preferably using the reactive injection molding technique, by a process wherein the polymerization is carried out in the presence of from 5 to 80% by weight of a polymer P which1. is completely soluble in the lactam,2. separates out in the course of polymerization at a conversion of from 1 to 50%,3. is composed of one or more blocks which are compatible with polylactam and one or more blocks which are incompatible therewith, and preferably4. possesses functional groups which are incorporated into the growing polylactam chain.
摘要翻译：低收缩尼龙模制品通过活性碱性内酰胺聚合制备，优选使用反应性注射成型技术，其中聚合反应在5-80重量％聚合物P的存在下进行，聚合物P是完全可溶于内酰胺，2.在聚合过程中以1至50％的转化率分离出来，3.由与多内酰胺相容的一个或多个嵌段和与其不相容的一个或多个嵌段组成，优选 4.具有并入生长的聚内酰胺链中的官能团。

7. 发明授权

US4440705A Process for the preparation of cellular and non-cellular polyurethane elastomers 失效
标题翻译：制备细胞和非细胞聚氨酯弹性体的方法
公开(公告)号：US4440705A
公开(公告)日：1984-04-03
申请号：US394460
申请日：1982-07-01
申请人： Dietmar Nissen , Wolfgang Straehle , Matthias Marx
发明人： Dietmar Nissen , Wolfgang Straehle , Matthias Marx
IPC分类号： C08G18/48 , C08G18/66 , C08G18/14
CPC分类号： C08G18/4841 , C08G18/4837 , C08G18/487 , C08G18/667 , C08G2120/00 , Y10S521/914
摘要： A process for the preparation of optionally cellular and non-cellular polyurethane elastomers, preferably by reaction injection molding, organic polyisocyanates, polyether polyols based on polyoxyalkylene polyether polyols with terminal hydroxyethylene groups and an ethoxylation degree of 1 to 13, having a content of primary hydroxyl groups at the corresponding degree of ethoxylation as the value of curve A to 100 percent with curve A describing the dependency of the primary hydroxyl group content upon the degree of ethoxylation are reacted with chain extenders and/or cross-linking agents in the presence of catalysts as well as optionally blowing agents, auxiliaries and additives.
摘要翻译：一种制备任选的细胞和非细胞聚氨酯弹性体的方法，优选通过反应注射成型，有机多异氰酸酯，基于具有末端羟基亚乙基的聚氧化烯聚醚多元醇的聚醚多元醇和1至13的乙氧基化度，具有伯羟基含量在相应的乙氧基化程度下的基团与扩链剂和/或交联剂在催化剂存在下与扩链剂和/或交联剂反应，曲线A的值为100％，曲线A描述了伯羟基含量对乙氧基化程度的依赖性以及任选的发泡剂，助剂和添加剂。

8. 发明授权

US4305861A Process for the manufacture of stable polymer polyol dispersions 失效
标题翻译：用于制造稳定的聚合物多元醇分散体的方法
公开(公告)号：US4305861A
公开(公告)日：1981-12-15
申请号：US198519
申请日：1980-10-20
申请人： Matthias Marx , Dietmar Nissen , Robert Gehm
发明人： Matthias Marx , Dietmar Nissen , Robert Gehm
IPC分类号： C08G59/18 , C08G59/50 , C08J3/11 , C08L63/00 , C08L71/02 , C08K5/05
CPC分类号： C08J3/11 , C08G59/18 , C08G59/50 , C08L63/00 , C08L71/02 , C08J2363/00
摘要： Polymer polyol dispersions are prepared by reacting polyepoxides with epoxide resin hardeners in the presence of polyester and polyoxyalkylene polyether polyols.
摘要翻译：聚合物多元醇分散体是通过聚环氧化物与环氧树脂硬化剂在聚酯和聚氧化烯聚醚多元醇存在下反应来制备的。

9. 发明授权

US4616070A Thermoplastic molding materials 失效
标题翻译：热塑性成型材料
公开(公告)号：US4616070A
公开(公告)日：1986-10-07
申请号：US733048
申请日：1985-05-08
申请人： Hartmut Zeiner , Gerhard Heinz , Peter Neumann , Juergen Fischer , Dietmar Nissen
发明人： Hartmut Zeiner , Gerhard Heinz , Peter Neumann , Juergen Fischer , Dietmar Nissen
IPC分类号： C08L67/00 , C08L69/00 , C08L71/00 , C08L77/00 , C08L81/06 , C08L101/02 , C08G65/48
CPC分类号： C08L71/00 , C08L101/02 , C08L67/00 , C08L69/00 , C08L77/00 , C08L81/06
摘要： Thermoplastic molding materials containing a mixture ofA. a heat-stable polymer, e.g. a polyether sulfone or polysulfone, which does not contain any reactive groups, andB. a heat-stable polymer which contains reactive groups, preferably nitrile or thioaryl groups and/or sulfur bridges,can be processed to moldings, which can be crosslinked, for example by being heated at above 200.degree. C., so that the plastic matrix becomes virtually insoluble.
摘要翻译：含有A.热稳定聚合物的混合物的热塑性成型材料，例如不含任何反应性基团的聚醚砜或聚砜，和B.含有反应性基团，优选腈或硫代芳基和/或硫桥的热稳定聚合物可以加工成可交联的模制品，用于例如通过在200℃以上加热，使得塑料基质几乎不溶解。

10. 发明授权

US4764397A Fiber-reinforced materials 失效
标题翻译：纤维增强材料
公开(公告)号：US4764397A
公开(公告)日：1988-08-16
申请号：US814917
申请日：1985-12-30
申请人： Juergen Fischer , Hartmut Zeiner , Dietmar Nissen , Gerhard Heinz
发明人： Juergen Fischer , Hartmut Zeiner , Dietmar Nissen , Gerhard Heinz
IPC分类号： B29B15/12 , B29K71/00 , C08G65/40 , C08G75/23 , C08J5/24 , C08L71/00 , B05D7/02 , C08J3/24 , C08L81/00
CPC分类号： C08J5/24 , C08G65/4056 , C08G75/23 , C08L71/00 , B29B15/12 , Y10T442/2566 , Y10T442/2721 , Y10T442/2992
摘要： Fiber-reinforced materials are produced by a process in which a heat-stable thermoplastic aromatic polyether A containing reactive groups, preferably nitrile groups and/or sulfur bridges and/or arylthio or alkylthio groups, if required together with a heat-stable thermoplastic polymer B which does not contain any reactive groups, is applied onto reinforcing fibers, the resulting semi-finished product is shaped, and the plastic matrix in the molding obtained is crosslinked so that there is virturally no increase in its glass transition temperature although the amount of soluble material is decreased to less than 60%, determined by extraction in boiling dichloromethane for one hour.
摘要翻译：纤维增强材料是通过一种方法制备的，其中如果需要的话，含有反应性基团，优选腈基和/或硫桥和/或芳硫基或烷硫基的热稳定的热塑性芳族聚醚A与热稳定的热塑性聚合物B 将不含任何反应性基团的化合物施加到增强纤维上，所得到的半成品成型，并且所获得的模制品中的塑料基质被交联，使得其玻璃化转变温度的实质上不会增加，尽管可溶的量材料通过在沸腾的二氯甲烷中萃取1小时而降低到小于60％。

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