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1. 发明授权

US5391691A Process for producing aromatic polycarbonate 失效
标题翻译：制备芳香族聚碳酸酯的方法
公开(公告)号：US5391691A
公开(公告)日：1995-02-21
申请号：US139848
申请日：1993-10-22
申请人： Masuzo Yokoyama , Kazuhide Takakura , Junji Takano
发明人： Masuzo Yokoyama , Kazuhide Takakura , Junji Takano
IPC分类号： C08G64/08 , C08G64/30 , C08G64/00
CPC分类号： C08G64/307 , C08G64/085
摘要： A process for producing an aromatic polycarbonate with improved heat resistance comprising melt polycondensing an aromatic diol compound and a carbonic acid diester compound in the presence of an interesterification catalyst and in the co-presence of an organosilicon compound.
摘要翻译：一种生产具有改进的耐热性的芳族聚碳酸酯的方法，其包括在酯交换催化剂的存在下和在有机硅化合物的共存下熔融缩聚芳族二醇化合物和碳酸二酯化合物。

2. 发明授权

US5250655A Melt preparation of polycarbonate with metal compound and p compound catalysts 失效
标题翻译：用金属化合物和p化合物催化剂熔融制备聚碳酸酯
公开(公告)号：US5250655A
公开(公告)日：1993-10-05
申请号：US934716
申请日：1992-08-24
申请人： Masuzo Yokoyama , Junji Takano , Kazuhide Takakura
发明人： Masuzo Yokoyama , Junji Takano , Kazuhide Takakura
IPC分类号： C08G64/28 , C08G64/20 , C08G64/30
CPC分类号： C08G64/307
摘要： An aromatic polycarbonate of improved color value and high molecular weight is obtained by the addition of phosphorous acid and/or a phosphorous ester to the melt polycondensation reaction medium containing aromatic diol, carbonate diester and a metal-containing compound as ester interchange catalyst during the polycondensation reaction

3. 发明授权

US5578694A Process for producing aromatic polycarbonate 失效
标题翻译：制备芳香族聚碳酸酯的方法
公开(公告)号：US5578694A
公开(公告)日：1996-11-26
申请号：US526548
申请日：1995-09-12
申请人： Masuzo Yokoyama , Junji Takano , Masami Hasegawa , Yukiko Tatsukawa
发明人： Masuzo Yokoyama , Junji Takano , Masami Hasegawa , Yukiko Tatsukawa
IPC分类号： C08G64/30 , C08G64/04 , C07C68/06
CPC分类号： C08G64/307 , C08G64/30
摘要： A process for producing an aromatic polycarbonate is described, which comprises melt-polycondensing an aromatic diol compound with a diaryl carbonate compound in the presence of an interesterification catalyst, said interesterification catalyst comprising a quaternary phosphonium salt compound represented by formula (II): ##STR1## wherein R.sup.3, R.sup.4, R.sup.5, and R.sup.6 each independently represent an alkyl group having 1 to 12 carbon atoms, an aryl group, an aralkyl group, or a cycloalkyl group, and X.sup.l- is an anion selected from the group consisting of a carbonate ion, a phosphate ion, and a tetrahydroxyboron ion, with the letter l indicating the valency of X.
摘要翻译：描述了一种制备芳族聚碳酸酯的方法，其包括在酯交换催化剂存在下使芳族二醇化合物与二芳基碳酸酯化合物熔融缩聚，所述酯交换催化剂包含由式（II）表示的季鏻盐化合物：

4. 发明授权

US5527875A Process for producing aromatic polycarbonate 失效
标题翻译：制备芳香族聚碳酸酯的方法
公开(公告)号：US5527875A
公开(公告)日：1996-06-18
申请号：US386268
申请日：1995-02-09
申请人： Masuzo Yokoyama , Fumio Keitoku , Junji Takano , Masami Hasegawa , Yukiko Tatsukawa
发明人： Masuzo Yokoyama , Fumio Keitoku , Junji Takano , Masami Hasegawa , Yukiko Tatsukawa
IPC分类号： C08G64/20 , C08G64/30 , C08G64/00
CPC分类号： C08G64/307
摘要： A process for producing an aromatic polycarbonate having a weight average molecular weight of from 7,000 to 60,000 is disclosed, comprising melt polycondensing an aromatic diol compound (e.g., bisphenol A) and a diaryl carbonate compound (e.g., diphenyl carbonate) in the presence of a combination of (a) an alkali metal compound and (b) a phosphonium hydroxide compound (e.g., tetraethylphosphonium hydroxide) as an interesterification catalyst. The aromatic polycarbonate has improved heat resistance and hue.
摘要翻译：公开了一种重均分子量为7,000至60,000的芳族聚碳酸酯的制备方法，其包括将芳族二醇化合物（例如双酚A）和碳酸二芳基酯化合物（例如碳酸二苯酯）熔融缩聚在（a）碱金属化合物和（b）氢氧化鏻化合物（例如氢氧化四乙基鏻）作为酯交换催化剂的组合。芳族聚碳酸酯具有改善的耐热性和色调。

5. 发明授权

US4985495A Resin composition 失效
标题翻译：树脂组成
公开(公告)号：US4985495A
公开(公告)日：1991-01-15
申请号：US289035
申请日：1988-12-23
申请人： Takeyoshi Nishio , Shinichi Yamauchi , Yusuke Arashiro , Kenyu Ohno , Masuzo Yokoyama , Hiroshi Nakano , Hiroshi Ohmori , Junji Mayumi , Michiharu Kihira
发明人： Takeyoshi Nishio , Shinichi Yamauchi , Yusuke Arashiro , Kenyu Ohno , Masuzo Yokoyama , Hiroshi Nakano , Hiroshi Ohmori , Junji Mayumi , Michiharu Kihira
IPC分类号： C08L25/04 , C08L23/00 , C08L23/10 , C08L23/14 , C08L23/16 , C08L25/00 , C08L51/00 , C08L51/06 , C08L53/00 , C08L53/02 , C08L71/00 , C08L71/12
CPC分类号： C08L53/025 , C08L23/10 , C08L23/142 , C08L51/003 , C08L51/06 , C08L53/00 , C08L71/12 , C08L71/123 , C08L2205/03 , C08L23/16 , C08L25/04 , C08L53/02 , Y10S525/905
摘要： Disclosed is a polymer alloy consisting essentially of a composition of a polyphenylene ether, a crystalline propylene resin, and an alkenyl aromatic monomer modified propylene-dialkenylbenzene compound copolymer. The composition excels in heat resistance and resistance to oils.
摘要翻译：公开了一种基本上由聚苯醚，结晶丙烯树脂和烯基芳族单体改性的丙烯 - 二烯基苯化合物共聚物的组合物组成的聚合物合金。该组合物的耐热性和耐油性优异。

6. 发明授权

US5332788A Process for producing graft-modified alpha-olefin copolymer 失效
标题翻译：接枝改性的α-烯烃共聚物的制备方法
公开(公告)号：US5332788A
公开(公告)日：1994-07-26
申请号：US864204
申请日：1992-04-03
申请人： Masuzo Yokoyama , Shinichi Yamauchi , Hiroshi Nakano , Michiharu Kihira , Hiroshi Omori
发明人： Masuzo Yokoyama , Shinichi Yamauchi , Hiroshi Nakano , Michiharu Kihira , Hiroshi Omori
IPC分类号： C08F255/00 , C08F257/02 , C08F255/02 , C08F4/46 , C08F255/08
CPC分类号： C08F255/00 , C08F257/02
摘要： A copolymer of an .alpha.-olefin with an aromatic diolefin such as divinylbenzene produced by means of Ziegler-Natta polymerization and having a vinylphenyl moiety is subjected to polymerization with an ethylenically unsaturated monomer by means of anion polymerization or free radical polymerization, whereby a graft-modified .alpha.-olefin copolymer is obtained.
摘要翻译：通过齐格勒 - 纳塔聚合制备并具有乙烯基苯基部分的α-烯烃与芳族二烯烃如二乙烯基苯的共聚物用烯属不饱和单体通过阴离子聚合或自由基聚合进行聚合，得到改性的α-烯烃共聚物。

7. 发明授权

US5037890A Process for producing graft-modified .alpha.-olefin copolymer 失效
标题翻译：生产接枝改性的α-烯烃共聚物的方法
公开(公告)号：US5037890A
公开(公告)日：1991-08-06
申请号：US264433
申请日：1988-10-28
申请人： Masuzo Yokoyama , Shinichi Yamauchi , Hiroshi Nakano , Michiharu Kihira , Hiroshi Omori
发明人： Masuzo Yokoyama , Shinichi Yamauchi , Hiroshi Nakano , Michiharu Kihira , Hiroshi Omori
IPC分类号： C08F255/00 , C08F257/02
CPC分类号： C08F255/00 , C08F257/02
摘要： A copolymer of an .alpha.-olefin with an aromatic diolefin such as divinylbenzene produced by means of Ziegler-Natta polymerization and having a vinylphenyl moiety is subjected to polymerization with an ethylenically unsaturated monomer by means of anion polymerization or free radical polymerization, whereby a graft-modified .alpha.-olefin copolymer is obtained.

8. 发明授权

US4151111A Process for preparing titanium trichloride compositions 失效
标题翻译：制备三氯化钛组合物的方法
公开(公告)号：US4151111A
公开(公告)日：1979-04-24
申请号：US787969
申请日：1977-04-15
申请人： Masuzo Yokoyama , Akira Yamada , Siyouzo Okosi , Tokuo Katou , Shinichi Yoshida
发明人： Masuzo Yokoyama , Akira Yamada , Siyouzo Okosi , Tokuo Katou , Shinichi Yoshida
IPC分类号： C08F4/00 , C01G23/02 , C08F4/60 , C08F4/64 , C08F10/00
CPC分类号： C08F10/00
摘要： A process for preparing a titanium trichloride composition comprises the steps of:(1) reducing titanium tetrachloride with oaganoaluminum compounds to produce a titanium trichloride composition having a .beta.-crystal structure;(2) heat treating the resulting titanium trichloride having a .beta.-crystal structure and subsequently pulverizing the heat-treated titanium trichloride in the presence or absence of titanium tetrachloride to produce a titanium trichloride composition containing substantially no titanium trichloride having a .beta.-crystal structure;(3) treating the pulverized titanium trichloride composition with a complexing agent; and(4) treating the resulting titanium trichloride composition with a compound selected from the group consisting of metal halide compounds having Lewis acidity and interhalogen compounds.
摘要翻译：制备三氯化钛组合物的方法包括以下步骤：

9. 发明授权

US4146502A Process for producing catalyst components for olefin polymerization 失效
标题翻译：制备烯烃聚合催化剂组分的方法
公开(公告)号：US4146502A
公开(公告)日：1979-03-27
申请号：US839843
申请日：1977-10-06
申请人： Masuzo Yokoyama , Shoichi Masukawa , Tsunenori Takahashi , Hideo Sakurai , Makoto Kouno , Shozo Ohkosi , Satosi Ohtaka
发明人： Masuzo Yokoyama , Shoichi Masukawa , Tsunenori Takahashi , Hideo Sakurai , Makoto Kouno , Shozo Ohkosi , Satosi Ohtaka
IPC分类号： C08F4/02 , C08F4/64 , C08F10/00 , C08F4/10
CPC分类号： C08F4/022 , C08F10/00
摘要： A catalyst component, which is to be combined with an organoaluminum component to form a Ziegler catalyst for olefin polymerization, is produced by treating (1) a solid composition resulting from a process of combining a magnesium halide such as magnesium chloride, an electron donor compound such as ethyl benzoate and a titanium halogen compound such as titanium tetrachloride with (2) an interhalogen compound or a halogen such as iodine trichloride.
摘要翻译：将与有机铝组分组合以形成用于烯烃聚合的齐格勒催化剂的催化剂组分通过处理（1）由卤化镁如氯化镁，电子给体化合物例如苯甲酸乙酯和钛卤素化合物如四氯化钛与（2）卤代化合物或卤素如三氯化碘。

10. 发明授权

US5137995A Process for preparation of olefin polymers 失效
标题翻译：制备烯烃聚合物的方法
公开(公告)号：US5137995A
公开(公告)日：1992-08-11
申请号：US711706
申请日：1991-06-07
申请人： Masuzo Yokoyama , Kouichi Katou , Toshihiko Sugano
发明人： Masuzo Yokoyama , Kouichi Katou , Toshihiko Sugano
IPC分类号： C08F4/64 , C08F4/00 , C08F4/60 , C08F4/658 , C08F10/00
CPC分类号： C08F10/00
摘要： A process for the preparation of olefin polymers, which comprises polymerizing an olefin in the presence of a catalyst which comprises: (A) a solid catalyst component obtained by contacting a magnesium dihalide such as MgCl.sub.2 with a titanium tetra-alkoxide such as Ti(O-nBu).sub.4 and then with a polymeric silicon compound having a structure represented by the formula ##STR1## wherein R stands for a hydrocarbon residue such as CH.sub.3, and contacting the obtained solid component with a halogen compound of silicon such as SiCl.sub.4 or with a halogen compound of silicon such as SiCl.sub.4 and a halogen compound of titanium such as TiCl.sub.4, (B) an organoaluminum compound such as Al(Et).sub.3 ; and (C) an organic silicon compound having an Si--O--C linkage such as PhSi(OEt).sub.3. According to this process, a polymer having a high stereoregularity, a narrow particle size distribution and a high bulk density can be obtained in a high yield with a high efficiency.
摘要翻译：一种制备烯烃聚合物的方法，其包括在催化剂存在下使烯烃聚合，所述催化剂包括：（A）通过使二氯化镁如MgCl 2与四烷氧基钛如Ti（O）接触而获得的固体催化剂组分 -nBu）4，然后与具有由式“IMAGE”表示的结构的聚合物硅化合物反应，其中R代表烃残基例如CH 3，并使得到的固体组分与硅的卤素化合物如SiCl 4或与诸如SiCl 4的硅卤素化合物和钛的卤素化合物如TiCl 4，（B）有机铝化合物如Al（Et）3; 和（C）具有Si-O-C键的有机硅化合物如PhSi（OEt）3。根据该方法，可以高效率地获得具有高立构规整性，窄粒度分布和高堆积密度的聚合物。

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