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1. 发明授权

US11285710B2 Multilayer body 有权
公开(公告)号：US11285710B2
公开(公告)日：2022-03-29
申请号：US16956015
申请日：2018-12-12
申请人： TEIJIN LIMITED
发明人： Tomohiro Nakazaki , Kenta Imazato , Katsuhiro Yamanaka
IPC分类号： B32B27/08 , B32B27/36 , C08G64/02 , C08G64/08 , C08G64/10
摘要： A multilayer body includes at least one layer (A) made of a polycarbonate resin (A) whose main repeating units include a unit (a-1) composed of an ether diol residue represented by the following formula (1) and a unit (a-2) composed of a diol residue represented by the following formula (2), and at least one layer (B) containing an aromatic polycarbonate resin (B), wherein the molar ratio of the unit (a-1) is 50 to 96 mol % and the molar ratio of the unit (a-2) is 4 to 50 mol %, with respect to 100 mol % of the total repeating units of the polycarbonate resin (A) and the proportion of the aromatic polycarbonate resin (B) in the layer (B) containing an aromatic polycarbonate resin (B) is 30% by weight or more, and the multilayer body is excellent in heat resistance, impact resistance, surface hardness, adhesion, and chemical resistance. In the formula (2), R1 and R2 each independently represent at least one group selected from the group consisting of a hydrogen atom, a halogen atom, an alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, a cycloalkyl having 6 to 20 carbon atoms, a cycloalkoxy group having 6 to 20 carbon atoms, an alkenyl group having 2 to 10 carbon atoms, an aryl group having 6 to 10 carbon atoms, an aryloxy group having 6 to 10 carbon atoms, an aralkyl group having 7 to 20 carbon atoms, an aralkyloxy group having 7 to 20 carbon atoms, a nitro group, an aldehyde group, a cyano group, and a carboxyl group, and when a plurality of R1 and R2 are present, they may be the same or different; a and b each represent an integer of 1 to 4; and W represents at least one bonding group selected from the group consisting of a single bond and a bonding group represented by the following formula (3). In the formula (3), R3, R4, R5, R6, R7, R1, R9, and R10 each independently represent at least one group selected from the group consisting of a hydrogen atom, an alkyl group having 1 to 10 carbon atoms, an aryl group having 6 to 10 carbon atoms, and an aralkyl group having 7 to 20 carbon atoms, and when a plurality of R3, R4, R5, R6, R7, R8, R9, and R10 are present, they may be the same or different; R11, R12, R13, and R14 each independently represent at least one group selected from the group consisting of an alkyl group having 1 to 10 carbon atoms, a cycloalkenyl group having 6 to 20 carbon atoms, an alkenyl group having 2 to 10 carbon atoms, an aryl group having 6 to 10 atoms, and an aralkyl group having 7 to 20 carbon atoms, and when a plurality of R11, R12, R13, and R14 are present, they may be the same or different; A represents a single bond, an oxygen atom or a sulfur atom; c represents an integer of 1 to 10; d represents an integer of 4 to 7; e represents an integer of 1 to 10; and f represents an integer of 1 to 100.

2. 发明授权

US11203664B2 Polycarbonate resin composition and molded article thereof 有权
公开(公告)号：US11203664B2
公开(公告)日：2021-12-21
申请号：US16638449
申请日：2018-09-06
申请人： IDEMITSU KOSAN CO., LTD.
发明人： Yasuhiro Ishikawa
IPC分类号： C08G64/10 , C08G64/04 , C08G63/183 , C08G64/08 , C08G64/18 , C08K5/20 , C08L83/06 , C08L83/08
摘要： Provided is a polycarbonate-based resin composition, including: 50 mass % or more to 99 mass % or less of a polycarbonate-based resin (S) containing 0.1 mass % or more to 100 mass % or less of a polycarbonate-polyorganosiloxane copolymer (A), which contains a polycarbonate block (A-1) formed of a specific repeating unit and a polyorganosiloxane block (A-2) containing a specific repeating unit, and 0 mass % or more to 99.9 mass % or less of an aromatic polycarbonate-based resin (B) except the polycarbonate-polyorganosiloxane copolymer (A); 1 mass % or more to 50 mass % or less of a polyester-based resin (C); and 0.001 part by mass or more to 1 part by mass or less of an amide compound (D) with respect to 100 parts by mass of a total amount of the polycarbonate-based resin (S) and the polyester-based resin (C).

3. 发明申请

US20210269590A1 COPOLYCARBONATE AND POLYCARBONATE COMPOSITION COMPRISING THE SAME 有权
公开(公告)号：US20210269590A1
公开(公告)日：2021-09-02
申请号：US17276678
申请日：2020-07-29
申请人： LG CHEM, LTD.
发明人： Young Young HWANG , Youngwook SON , Daehyeon HWANG , Mooho HONG
IPC分类号： C08G64/18 , C08L69/00 , C08G64/08
摘要： Provided are a copolycarbonate- and a polycarbonate composition comprising the same. The copolycarbonate comprises repeat units of the following Chemical Formula 1 and repeat units of the following Chemical Formula 2:

4. 发明申请

US20200316928A1 MULTILAYER BODY 审中-公开
公开(公告)号：US20200316928A1
公开(公告)日：2020-10-08
申请号：US16956015
申请日：2018-12-12
申请人： TEIJIN LIMITED
发明人： Tomohiro NAKAZAKI , Kenta IMAZATO , Katsuhiro YAMANAKA
IPC分类号： B32B27/36 , B32B27/08 , C08G64/02 , C08G64/08 , C08G64/10
摘要： A multilayer body includes at least one layer (A) made of a polycarbonate resin (A) whose main repeating units include a unit (a-1) composed of an ether diol residue represented by the following formula (1) and a unit (a-2) composed of a diol residue represented by the following formula (2), and at least one layer (B) containing an aromatic polycarbonate resin (B), wherein the molar ratio of the unit (a-1) is 50 to 96 mol % and the molar ratio of the unit (a-2) is 4 to 50 mol %, with respect to 100 mol % of the total repeating units of the polycarbonate resin (A) and the proportion of the aromatic polycarbonate resin (B) in the layer (B) containing an aromatic polycarbonate resin (B) is 30% by weight or more, and the multilayer body is excellent in heat resistance, impact resistance, surface hardness, adhesion, and chemical resistance. In the formula (2), R1 and R2 each independently represent at least one group selected from the group consisting of a hydrogen atom, a halogen atom, an alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, a cycloalkyl having 6 to 20 carbon atoms, a cycloalkoxy group having 6 to 20 carbon atoms, an alkenyl group having 2 to 10 carbon atoms, an aryl group having 6 to 10 carbon atoms, an aryloxy group having 6 to 10 carbon atoms, an aralkyl group having 7 to 20 carbon atoms, an aralkyloxy group having 7 to 20 carbon atoms, a nitro group, an aldehyde group, a cyano group, and a carboxyl group, and when a plurality of R1 and R2 are present, they may be the same or different; a and b each represent an integer of 1 to 4; and W represents at least one bonding group selected from the group consisting of a single bond and a bonding group represented by the following formula (3). In the formula (3), R3, R4, R5, R6, R7, R1, R9, and R10 each independently represent at least one group selected from the group consisting of a hydrogen atom, an alkyl group having 1 to 10 carbon atoms, an aryl group having 6 to 10 carbon atoms, and an aralkyl group having 7 to 20 carbon atoms, and when a plurality of R3, R4, R5, R6, R7, R8, R9, and R10 are present, they may be the same or different; R11, R12, R13, and R14 each independently represent at least one group selected from the group consisting of an alkyl group having 1 to 10 carbon atoms, a cycloalkenyl group having 6 to 20 carbon atoms, an alkenyl group having 2 to 10 carbon atoms, an aryl group having 6 to 10 atoms, and an aralkyl group having 7 to 20 carbon atoms, and when a plurality of R11, R12, R13, and R14 are present, they may be the same or different; A represents a single bond, an oxygen atom or a sulfur atom; c represents an integer of 1 to 10; d represents an integer of 4 to 7; e represents an integer of 1 to 10; and f represents an integer of 1 to 100.

5. 发明授权

US10738153B2 Ring-opening polymerizations using a flow reactor 有权
公开(公告)号：US10738153B2
公开(公告)日：2020-08-11
申请号：US16029025
申请日：2018-07-06
申请人： International Business Machines Corporation , The Board of Trustees of the Leland Stanford Junior University
发明人： Nathaniel H. Park , James L. Hedrick , Victoria A. Piunova , Dmitry Zubarev , Gavin O. Jones , Robert M. Waymouth , Binhong Lin
IPC分类号： C08G64/00 , C08G64/08
摘要： Techniques regarding the synthesis of one or more polymers through one or more ring-opening polymerizations conducted within a flow reactor and facilitated by one or more anionic catalysts are provided. For example, one or more embodiments can comprise a method, which can comprise functionalizing, via a post-polymerization reaction within a flow reactor, a chemical compound by covalently bonding a trimethylsilyl protected thiol to a pendent functional group of the chemical compound in a presence of a catalyst. The pendent functional group can comprise a perfluoroaryl group and a methylene group.

6. 发明申请

US20200010615A1 POLYCARBONATE-POLYORGANOSILOXANE COPOLYMER, POLYCARBONATE RESIN COMPOSITION INCLUDING SAME, AND MOLDED PRODUCT THEREOF 审中-公开
公开(公告)号：US20200010615A1
公开(公告)日：2020-01-09
申请号：US16490059
申请日：2018-03-01
申请人： IDEMITSU KOSAN CO., LTD.
发明人： Yasuhiro ISHIKAWA , Tomoko ABE , Takafumi AKIMOTO
IPC分类号： C08G64/18 , C08G64/08 , C08G64/10 , C08G64/14 , C08L69/00 , C08K3/34 , C08K7/14
摘要： Provided is a polycarbonate-polyorganosiloxane copolymer including polycarbonate blocks (A-1) each formed of a specific repeating unit and polyorganosiloxane blocks (A-2) each containing a specific repeating unit, wherein the polycarbonate-polyorganosiloxane copolymer satisfies the following expression (F1a): 15≤wM1 (F1a) wherein wM1 represents the average content of the polyorganosiloxane blocks (A-2) in polycarbonate-polyorganosiloxane copolymers each having a molecular weight determined by using a polycarbonate as a conversion reference of from 56,000 or more to 200,000 or less among polycarbonate-polyorganosiloxane copolymers obtained through the separation of the polycarbonate-polyorganosiloxane copolymer by gel permeation chromatography.

7. 发明授权

US10508239B2 Flame retarder, flame retardant resin composition and method of producing the flame retarder 有权
公开(公告)号：US10508239B2
公开(公告)日：2019-12-17
申请号：US13867601
申请日：2013-04-22
申请人： Sony Corporation
发明人： Yasuhito Inagaki
IPC分类号： C09K21/14 , C08G63/688 , C08G63/91 , C08G64/08 , C08G64/42 , C08L69/00 , C08F8/44 , C08L25/12 , C08L25/18 , C08L27/18 , C08L101/02
摘要： A flame retardant resin composition in which an acrylonitrile-styrene based polymer, into which sulfonic acid groups and/or sulfonate groups have been introduced by sulfonating processing with a sulfonating agent containing less than 3 wt % of moisture, is contained in a resin to be made flame retardant, so that flame retardant properties will be conferred on the resin flame resistant.

8. 发明授权

US10414860B2 Polycarbonate resin and preparation method therefor 有权
公开(公告)号：US10414860B2
公开(公告)日：2019-09-17
申请号：US15575547
申请日：2016-05-25
申请人： LOTTE ADVANCED MATERIALS CO., LTD.
发明人： Jong Chan Hur , Jun Ho Chi , Woo Suk Chei , O Sung Kwon , Jung Jae Lee
IPC分类号： C08G64/08 , C08L69/00 , C08G64/30 , C08K5/524
摘要： A polycarbonate resin of the present invention comprises: a repeat unit represented by chemical formula 1 in the specification; a repeat unit represented by chemical formula 2; and a repeat unit represented by chemical formula 3. The polycarbonate resin has excellent flame retardancy, thermal resistance, transparency, impact resistance, etc.

9. 发明授权

US10294365B2 Polycarbonate-based resin composition and molded article thereof 有权
公开(公告)号：US10294365B2
公开(公告)日：2019-05-21
申请号：US15523039
申请日：2015-12-03
申请人： LG CHEM, LTD.
发明人： Su Kyoung Lee , Min Ji Kim , Jong Hyun Lee , Ryul Lee , Sung Tae Ahn
IPC分类号： C08K7/14 , C08L69/00 , C08G64/18 , C08G64/38 , C08G77/448 , C08J5/00 , C08G64/16 , C08G64/06 , C08G64/30 , C08G64/08 , C08K5/3475 , C08L83/04 , C08G64/24 , C08L83/10 , C08K5/00 , C08G64/22 , C08G77/14 , C08L83/06 , C08J5/08 , C08K5/521 , C08L51/04 , C08K5/42 , C09K21/14 , C08G77/20 , C08K3/40
摘要： The present invention relates to a polycarbonate-based resin composition and a molded article thereof, and more specifically, to a polycarbonate-based resin composition exhibiting improved impact strength (impact resistance) and chemical resistance while including a glass fiber in a relatively small content, and a molded article formed therefrom.

10. 发明申请

US20190143582A1 COPOLYCARBONATE AS A SUPPORTING MATERIAL IN 3-D PRINTING 审中-公开
公开(公告)号：US20190143582A1
公开(公告)日：2019-05-16
申请号：US16098014
申请日：2017-05-03
申请人： Covestro Deutschland AG
发明人： Tim HUNGERLAND , Matthias ROTHE , Rolf WEHRMANN , Klaus HORN , Christopher SCHIRWITZ , Tanja CASSEL
IPC分类号： B29C64/106 , B29C64/40 , C08G64/12 , C08G64/08 , C08G77/04
摘要： The invention relates to the use of copolycarbonates stable at high temperature as a supporting material in the FDM (fused deposition modeling) method, said copolycarbonates having a Vicat temperature determined in accordance with ISO 306:2013 of at least 150° C. Polyester, polyamide, PC/polyester blend, and/or polyaryl ether ketone is used as a printing material. Used as copolycarbonates are copolycarbonates containing one or more monomer units selected from the group consisting of the structural units of general formulas (1a), (1b), (1c), (1d), in which R1 represents hydrogen or C1 to C4 alkyl, R2 represents C1 to C4 alkyl, n represents 0, 1, 2, or 3, and R3 represents C1 to C4 alkyl, aralkyl, or aryl, and/or containing one or more monomer units of formula (1e), in which R19 represents hydrogen, Cl, Br, or a C1 to C4 alkyl residue, R17 and R18 are the same or different and represent, independently of each other, an aryl residue, a C1 to C10 alkyl residue, or a C1 to C10 alkylaryl residue, and wherein X is a single bond, —CO—, —O—, a C1 to C6 alkylene residue, a C2 to C5 alkylidene residue, a C5 to C12 cycloalkylidene residue, or a C6 to C12 arylene residue, which optionally can be condensed with further aromatic rings that contain heteroatoms, n is a number from 1 to 500, m is a number from 1 to 10, and p is 0 or 1.

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