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1. 发明授权

US06797750B2 Flame-retardant epoxy resin composition, molded article thereof, and electronic part 失效
标题翻译：阻燃性环氧树脂组合物，其成型体和电子部件
公开(公告)号：US06797750B2
公开(公告)日：2004-09-28
申请号：US10221813
申请日：2002-11-07
申请人： Masatoshi Taniguchi , Yuji Tada , Yoichi Nishioka
发明人： Masatoshi Taniguchi , Yuji Tada , Yoichi Nishioka
IPC分类号： C08K549
CPC分类号： H01L23/49894 , C08G59/4071 , C08G79/025 , C08K5/5399 , C08L63/00 , C08L85/02 , H01L23/145 , H01L23/293 , H01L2924/0002 , H05K1/0373 , C08L85/00 , C08L71/00 , H01L2924/00
摘要： The present invention has an object to provide a flame-retardant epoxy resin composition excellent in heat resistance and moisture resistance. A flame-retardant epoxy resin composition relating to the present invention contains an epoxy resin (A), a phosphazene compound (B), an epoxy hardener (C) and an inorganic filler (D), wherein the phosphazene compound (B) and the epoxy hardener (C) are included in the range of 0.01 to 70% by weight and in the range of 0 to 70% by weight, respectively, relative to a total quantity of the epoxy resin (A), the phosphazene compound (B) and the epoxy hardener (C), and the inorganic filler (D) is included in the range of 0 to 95% by weight relative to a total quantity of the epoxy resin (A), the phosphazene compound (B), the epoxy hardener (C) and the inorganic filler (D), wherein the phosphazene compound (B) is at least one selected from the group consisting of (1) a cyclic and/or a chain phosphazene compound with a specific structure, (2) a polymer of the cyclic and/or the chain phosphazene compound; and (3) a reaction product of the cyclic and/or the chain phosphazene compound with one type of a compound selected from the group consisting of an epoxy compound, a phenol compound, an amine compound and an acid anhydride.
摘要翻译：本发明的目的是提供耐热性和耐湿性优异的阻燃性环氧树脂组合物。本发明的阻燃性环氧树脂组合物含有环氧树脂（A），磷腈化合物（B），环氧硬化剂（C）和无机填料（D），其中磷腈化合物（B）和相对于环氧树脂（A），磷腈化合物（B）的总量，环氧固化剂（C）的含量分别为0.01〜70重量％，0〜70重量％环氧固化剂（C）和无机填料（D）的含量相对于环氧树脂（A），磷腈化合物（B），环氧固化剂（B）的总量为0〜95重量％（C）和无机填料（D），其中磷腈化合物（B）为选自（1）具有特定结构的环状和/或链状磷腈化合物中的至少一种，（2）聚合物的环状和/或链状磷腈化合物; 和（3）环状和/或链状磷腈化合物与一种选自环氧化合物，酚化合物，胺化合物和酸酐的化合物的反应产物。

2. 发明授权

US06946578B2 Process for producing phenoxyphosphazene compound, flame-retardant resin composition, and flame-retardant resin molding 失效
标题翻译：苯氧基磷腈化合物的制备方法，阻燃树脂组合物和阻燃树脂成型
公开(公告)号：US06946578B2
公开(公告)日：2005-09-20
申请号：US10745255
申请日：2003-12-23
申请人： Shinji Nakano , Yuji Tada , Tadao Yabuhara , Takashi Kameshima , Yoichi Nishioka , Hiroyuki Takase
发明人： Shinji Nakano , Yuji Tada , Tadao Yabuhara , Takashi Kameshima , Yoichi Nishioka , Hiroyuki Takase
IPC分类号： C08J5/00 , C07F9/6581 , C07F9/659 , C08G79/04 , C08K5/5399 , C08K9/00 , C08L101/00 , C09K21/12 , C07F9/02
CPC分类号： C08K5/5399 , C07F9/65812 , C09K21/12
摘要： An improved phenoxyphosphazene compound is produced by treating a phenoxyphosphazene compound with (a) at least one adsorbent selected from activated carbon, silica gel, activated alumina, activated clay, synthetic zeolite and macromolecular adsorbents, (b) at least one reagent selected from metal hydrides, hydrazine, hypochlorites, thiosulfates, dialkyl sulfuric acids, ortho esters, diazoalkanes, lactones, alkanesultones, epoxy compounds and hydrogen peroxide, or (c) both the adsorbent and reagent, thereby reducing the acid value of said phosphazene compound to lower than 0.025 mgKOH/g.
摘要翻译：通过用（a）至少一种选自活性炭，硅胶，活性氧化铝，活性粘土，合成沸石和大分子吸附剂的吸附剂处理苯氧基磷腈化合物，制备改进的苯氧基磷腈化合物，（b）至少一种选自金属氢化物，肼，次氯酸盐，硫代硫酸盐，二烷基硫酸，原酸酯，重氮烷烃，内酯，烷基磺酸盐，环氧化合物和过氧化氢，或（c）吸附剂和试剂两者，从而将所述磷腈化合物的酸值降低至低于0.025mgKOH /G。

3. 发明授权

US06528559B1 Crosslinked phenoxyphosphazene compounds, process for the preparation thereof, flame retardants, flame-retardant resin compositions, and moldings of flame-retardant resins 有权
标题翻译：交联苯氧基磷腈化合物，其制备方法，阻燃剂，阻燃树脂组合物和阻燃树脂的模塑
公开(公告)号：US06528559B1
公开(公告)日：2003-03-04
申请号：US09762637
申请日：2001-02-12
申请人： Yoshifumi Nakacho , Tadao Yabuhara , Yuji Tada , Yoichi Nishioka
发明人： Yoshifumi Nakacho , Tadao Yabuhara , Yuji Tada , Yoichi Nishioka
IPC分类号： C08K515
CPC分类号： C07F9/65815 , C07F9/65812 , C08G79/025 , C08K5/5399 , C09K21/14
摘要： This invention provides a halogen-free flame retardant which advantageously has a high melting point and a low volatility and does not impair the inherent properties of resins. The flame retardant of the invention is a phosphazene compound crosslinked with a crosslinking group such as a phenylene group, wherein each of the crosslinking groups is interposed between the two oxygen groups left after the elimination of phenyl groups from the phosphazene compound; the crosslinked phenoxyphosphazene compound does not have any free hydroxyl groups (derived from crosslinking groups); and the amount of the phenyl groups in the crosslinked compound is 50 to 99.9%, based on the total number of the phenyl groups in the phosphazene compound.
摘要翻译：本发明提供一种无卤阻燃剂，其有利地具有高熔点和低挥发性，并且不损害树脂的固有性质。本发明的阻燃剂是与交联基团如亚苯基交联的磷腈化合物，其中每个交联基团插入在从磷腈化合物中除去苯基之后留下的两个氧基之间; 交联的苯氧基磷腈化合物不具有任何游离羟基（衍生自交联基团）; 并且交联化合物中苯基的量基于磷腈化合物中的苯基总数为50-99.9％。

4. 发明授权

US06632891B1 Flame-retardant resin, composition thereof, and process for producing the same 有权
标题翻译：阻燃树脂及其组合物及其制造方法
公开(公告)号：US06632891B1
公开(公告)日：2003-10-14
申请号：US09623472
申请日：2000-09-13
申请人： Yuji Tada , Yoichi Nishioka , Tadao Yabuhara , Takashi Kameshima , Shinji Nakano
发明人： Yuji Tada , Yoichi Nishioka , Tadao Yabuhara , Takashi Kameshima , Shinji Nakano
IPC分类号： C08G6391
CPC分类号： C08G64/083 , C08G63/692
摘要： A flame-retardant resin composition comprising a phosphazene flame retardant and a polyester resin, wherein the flame retardant is bonded to the molecules of the polyester resin via the ester group thereof, can retain a high flame retardance for a prolonged term with little or no vaporization with time and is excellent in flame retardance, impact resistance, properties and processability.
摘要翻译：包含磷腈阻燃剂和聚酯树脂的阻燃树脂组合物，其中阻燃剂经由其酯基与聚酯树脂的分子结合，可以在很少或不蒸发的情况下保持长时间的高阻燃性具有时间和优异的阻燃性，耐冲击性，性能和加工性

5. 发明授权

US06627122B1 Powdery flame retardant 失效
标题翻译：粉状阻燃剂
公开(公告)号：US06627122B1
公开(公告)日：2003-09-30
申请号：US09762988
申请日：2001-02-14
申请人： Yuji Tada , Tadao Yabuhara , Shinji Nakano , Takashi Kameshima , Yoichi Nishioka , Hiroyuki Takase
发明人： Yuji Tada , Tadao Yabuhara , Shinji Nakano , Takashi Kameshima , Yoichi Nishioka , Hiroyuki Takase
IPC分类号： C08K500
CPC分类号： C08K7/04 , C08K9/12
摘要： A powdery flame retardant which is obtained by mixing a flame retardant which is liquid or a viscous solid at ordinary temperature with an inorganic fibrous substance to adhere or adsorb the retardant to the fibrous substance, and which comprises 5 to 70 wt. % the flame retardant and 95 to 30 wt. % the fibrous substance. The powdery flame retardant can be easily handled because it is a powder, and is obtained by a simple and industrially advantageous method. It produces a remarkable effect that the performance of the liquid or viscous flame retardant is not impaired.
摘要翻译：一种粉末状阻燃剂，其通过将常温下为液体或粘性固体的阻燃剂与无机纤维物质混合以将阻燃剂粘附或吸附到纤维状物质上，并且其包含5至70重量％％阻燃剂和95〜30wt。％的纤维物质。粉状阻燃剂由于粉末而易于处理，并且通过简单且工业上有利的方法获得。它产生显着的效果，即液体或粘性阻燃剂的性能不受损害。

6. 发明授权

US06518336B1 Flame-retardent resin compositions compring thermoplastic resin, thermotropic liquid crystal polymer, and hoalogen-free phosphazen compound 失效
标题翻译：包含热塑性树脂的阻燃树脂组合物，热致液晶聚合物和无磷酸盐的磷腈化合物
公开(公告)号：US06518336B1
公开(公告)日：2003-02-11
申请号：US09720233
申请日：2000-12-19
申请人： Tadao Yabuhara , Yuji Tada , Takashi Kameshima , Shinji Nakano , Yoichi Nishioka , Hiroyuki Takase
发明人： Tadao Yabuhara , Yuji Tada , Takashi Kameshima , Shinji Nakano , Yoichi Nishioka , Hiroyuki Takase
IPC分类号： C08K55357
CPC分类号： C08K5/5399 , C08L55/02 , C08L67/02 , C08L69/00 , C08L71/12 , C08L77/00 , C08L101/00 , C08L2666/18
摘要： This invention provides a flame-retardant resin composition comprising: (A) 100 parts by weight of a thermoplastic resin other than a thermotropic liquid crystal polymer, (B) 0.01 to 50 parts by weight of a thermotropic liquid crystal polymer, and (C) 1 to 30 parts by weight of a halogen-free phosphazene compound, the invention providing a novel flame-retardant resin composition which is free of the problems arising due to the presence of halogen element, the composition being excellent in flame retardancy, mechanical properties, molding processability and the like, and being unlikely to cause dripping.
摘要翻译：本发明提供一种阻燃性树脂组合物，其包含：（A）100重量份热致变液晶聚合物以外的热塑性树脂，（B）0.01〜50重量份的热致液晶聚合物，（C） 1至30重量份的无卤素磷腈化合物，本发明提供了一种新的阻燃树脂组合物，其不存在由于卤素元素的存在而产生的问题，该组合物的阻燃性，机械性能，成型加工性等，不易引起滴落。

7. 发明授权

US06596893B2 Crosslinked phenoxyphosphazene compounds, flame retardants, flame-retardant resin compositions, and moldings of flame-retardant resins 有权
标题翻译：交联的苯氧基磷腈化合物，阻燃剂，阻燃树脂组合物和阻燃树脂的模塑制品
公开(公告)号：US06596893B2
公开(公告)日：2003-07-22
申请号：US09331013
申请日：1999-08-12
申请人： Yoshifumi Nakacho , Tadao Yabuhara , Yuji Tada , Yoichi Nishioka
发明人： Yoshifumi Nakacho , Tadao Yabuhara , Yuji Tada , Yoichi Nishioka
IPC分类号： C07F902
CPC分类号： C08K5/5399 , C08G75/0204 , C09K21/14
摘要： This invention has an object of providing a flame retardant which advantageously has a high melting point and a low volatility and is unlikely to depress the inherent properties of resins. The flame retardant of the invention is a phosphazene compound crosslinked with a crosslinking group such as phenylene group, each of the crosslinking groups being interposed between the two oxygen groups left after the elimination of phenyl groups from the phosphazene compound, the amount of the phenyl groups in the crosslinked compound being 50 to 99.9% based on the total number of the phenyl groups in the phosphazene compound. The invention also provides a resin composition containing the flame retardant, and a molded article of the resin.
摘要翻译：本发明的目的是提供阻燃剂，其有利地具有高熔点和低挥发性，并且不太可能降低树脂的固有性质。本发明的阻燃剂是与交联基团如亚苯基交联的磷腈化合物，每个交联基团插入在从磷腈化合物中除去苯基后留下的两个氧基之间，苯基的量在交联化合物中，相对于磷腈化合物中的苯基总数为50〜99.9％。本发明还提供含有阻燃剂的树脂组合物和树脂的模制品。

8. 发明授权

US06521689B1 Flame-retardant aromatic polyamide resin composition and molded object 有权
标题翻译：阻燃芳香族聚酰胺树脂组合物和成型体
公开(公告)号：US06521689B1
公开(公告)日：2003-02-18
申请号：US09889011
申请日：2001-07-06
申请人： Tadao Yabuhara , Yuji Tada , Shinji Nakano , Takashi Kameshima , Yoichi Nishioka , Hiroyuki Takase
发明人： Tadao Yabuhara , Yuji Tada , Shinji Nakano , Takashi Kameshima , Yoichi Nishioka , Hiroyuki Takase
IPC分类号： C08K535
CPC分类号： C08K7/04 , C08K3/22 , C08K5/5399 , C08K7/02 , C08K2003/2217 , C08L77/10 , C08L85/02 , C08L77/00 , C08L85/00 , C08L2666/84
摘要： An object of this invention is to impart excellent flame retardancy to an aromatic polyamide resin without use of a halogen compound which is responsible for generation of gases harmful to the human body and without decreasing preferred properties (e.g. mechanical properties, and molding processability) inherently possessed by aromatic polyamide resins, the flame-retardant aromatic polyamide resin composition of this invention comprising (a) 100 parts by weight of an aromatic polyamide resin, (b) 0.1 to 100 parts by weight of a crosslinked phosphazene compound which is a compound crosslinked with a crosslinking group, such as phenylene groups, the crosslinking group being interposed between the two oxygen atoms left after the elimination of phenyl groups from the phosphazene compound, no free hydroxyl group being present in the molecule, the amount of all phenyl groups in the crosslinked compound being 50 to 99.9% based on the total amount of the phenyl groups in the phosphazene compounds, (c) 1 to 60 parts by weight of an inorganic fibrous substance and (d) 1 to 60 parts by weight of magnesium hydroxide.
摘要翻译：本发明的目的是赋予芳族聚酰胺树脂优异的阻燃性，而不使用负责产生对人体有害的气体的卤素化合物，而不降低固有地具有的优选性能（例如机械性能和成型加工性）通过芳族聚酰胺树脂，本发明的阻燃芳族聚酰胺树脂组合物包含（a）100重量份的芳族聚酰胺树脂，（b）0.1至100重量份的交联的磷腈化合物，其是与交联基团，例如亚苯基，交联基团置于从磷腈化合物除去苯基后留下的两个氧原子之间，分子中不存在游离羟基，交联的所有苯基的量化合物的含量为磷腈中苯基的总量的50-99.9％（c）1〜60重量份的无机纤维状物质和（d）1〜60重量份的氢氧化镁。

9. 发明授权

US5376478A Lithium secondary battery of vanadium pentoxide and polyphosphazene 失效
标题翻译：锂二次电池五氧化二钒和聚磷腈
公开(公告)号：US5376478A
公开(公告)日：1994-12-27
申请号：US952138
申请日：1992-09-28
申请人： Yoshifumi Nakacho , Akiyoshi Inubushi , Yuji Tada , Shuji Masuda , Masatoshi Taniguchi
发明人： Yoshifumi Nakacho , Akiyoshi Inubushi , Yuji Tada , Shuji Masuda , Masatoshi Taniguchi
IPC分类号： C08G79/02 , C08G79/04 , H01B1/12 , H01M4/48 , H01M10/05 , H01M10/052 , H01M10/0565 , H01M6/18
CPC分类号： H01M10/052 , C08G79/025 , H01M10/0565
摘要： The present invention provides a lithium secondary battery which comprises a layer of vanadium pentoxide serving as the positive electrode active substance, a substance capable of occluding and releasing lithium ions and serving as the negative electrode active substance, and a polymer represented by the following formula (I) and having a lithium salt dissolved therein to serve as the electrolyte, wherein said formula is ##STR1## and wherein m is the average number of repeating ethyleneoxy units and is a real number of about 5 to about 25, and n is the average number of repetitions and is a real number in the range of 3.ltoreq.n.ltoreq.200000.The lithium secondary battery of the invention comprises two electrode active substances which have a high energy density and an electrolyte which is flame-retardant, nonflowable and safe, and is capable of retaining its characteristics even at low ambient temperatures of up to the ice point.
摘要翻译： PCT No.PCT / JP90 / 00209 Sec。 371 1990年10月19日第 102（e）日期1990年10月19日PCT 1990年2月21日提交PCT公布。第WO90 / 10316号公报日本1990年7月9日。本发明提供一种锂二次电池，其包含作为正极活性物质的五氧化二钒一层，能够吸留和释放锂离子并用作负极活性物质的物质，以及由下式（I）表示并具有溶解于其中的锂盐作为电解质的聚合物，其中所述式为（I），其中m是重复的乙烯氧基单元的平均数，并且是实际的约数 5至约25，并且n是平均重复次数，并且是3≤n≤200000的范围内的实数。本发明的锂二次电池包括具有高能量密度的两种电极活性物质和阻燃，不可流动和安全的电解质，并且即使在高达冰点的低环境温度下也能够保持其特性。

10. 发明授权

US07777513B2 Power supply voltage detection circuit and semiconductor integrated circuit device 失效
标题翻译：电源电压检测电路和半导体集成电路器件
公开(公告)号：US07777513B2
公开(公告)日：2010-08-17
申请号：US12213512
申请日：2008-06-20
申请人： Manabu Kitabatake , Yuji Tada , Kouji Naganawa , Tsuyoshi Hirakawa , Ichiro Mizuguchi
发明人： Manabu Kitabatake , Yuji Tada , Kouji Naganawa , Tsuyoshi Hirakawa , Ichiro Mizuguchi
IPC分类号： G01R31/26
CPC分类号： G01R31/31726 , G11C29/1201 , G11C29/12015 , G11C29/14 , G11C29/48 , G11C29/50012 , G11C29/56012 , G11C2029/0401 , G11C2029/5602 , H01L2924/0002 , H01L2924/00
摘要： A semiconductor integrated circuit device includes a first chip, a second chip to transmit and receive data to and from the first chip, and a through circuit provided in the first chip to transfer a clock signal and a test signal to the second chip. The clock signal and the test signal is inputted from an external device. The through circuit adjusts timing relation between the clock signal and the test signal based on a timing adjust signal. The timing adjust signal is inputted from the external device.
摘要翻译：半导体集成电路器件包括第一芯片，向第一芯片发送数据和从第一芯片接收数据的第二芯片，以及设置在第一芯片中的通过电路，将时钟信号和测试信号传送到第二芯片。时钟信号和测试信号从外部设备输入。通过电路基于定时调整信号调整时钟信号和测试信号之间的时序关系。定时调整信号从外部设备输入。

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